Search Results (2,415)

To promote the sustainable development of power battery recycling, this study investigates the strategic interplay between altruistic preferences and channel structure. Addressing divergent interests and the dynamic evolution of recycling scale and brand reputation, a differential game model with two state variables is constructed to analyze four decision modes: resale/agency under selfish/altruistic scenarios. The results reveal that altruistic preferences induce Pareto improvements, reconciling the recycler’s utility with the partner’s profit growth. Notably, altruism acts as a moderating mechanism that reshapes channel advantages, enabling the Resale–Altruistic (RA) mode to surpass the agency mode as the system-wide optimal state. Furthermore, a substitutive compensation effect between altruistic preference and revenue-sharing contracts is identified. This research provides a quantitative framework for optimizing behavioral contract design and governance in battery recycling ecosystems. Full article

The recycling of technical textile waste represents a major challenge due to the complex and multilayered structure of these materials. Firefighter protective clothing, mainly composed of high-performance aramid fibers combined with polymeric membranes and auxiliary textile components, is commonly landfilled or incinerated at the end of its service life, resulting in a significant environmental impact. This work utilized recycled aramid-rich textile waste obtained from end-of-life firefighter protective clothing as reinforcement for polyamide 6 to develop high-performance thermoplastic composites within a circular economy framework. Composites containing 15, 30, 45, and 60 wt.% of recycled textile waste were manufactured by melt compounding followed by injection molding. In addition, a selected formulation containing 30 wt.% reinforcement was compatibilized using an amino-functional silane to improve interfacial adhesion. The materials were systematically characterized in terms of tensile properties, thermal behavior, thermomechanical performance, water uptake, flammability, colorimetric properties, and fracture morphology by field emission scanning electron microscopy. The results revealed a pronounced increase in stiffness and thermomechanical stability, with tensile strength increasing from approximately 65 MPa for neat PA6 up to 78 MPa at 30 wt.% reinforcement, and elastic modulus exceeding 5000 MPa at high reinforcement contents. An optimal balance between mechanical performance and ductility was achieved at 30 wt.% reinforcement, while higher contents enabled a substantial extension of the service temperature range, with HDT values increasing from 55 °C for neat PA6 up to 173 °C for highly reinforced systems. FESEM analysis confirmed improved interfacial adhesion in silane-compatibilized systems, explaining the enhanced mechanical and thermomechanical behavior. Furthermore, the incorporation of recycled aramid-rich textile waste led to a significant improvement in flame retardancy, enabling UL-94 V-0 classification at 30 wt.% reinforcement and above, without the use of additional flame-retardant additives, enabling UL-94 V-0 classification without additional flame-retardant additives. Overall, this study demonstrates the technical feasibility and high added-value potential of valorizing firefighter protective clothing waste into advanced PA6-based composites with enhanced mechanical, thermal, and fire-resistant properties, providing a sustainable route for the valorization of high-performance textile waste. Full article

The resource utilization of construction and demolition waste (CDW) is crucial for advancing the green transformation of the construction industry, but it faces challenges such as insufficient upstream R&D motivation and low downstream market acceptance. To investigate the impact of corporate social responsibility (CSR) and sales effort on the recycled cement supply chain, in this study, a Stackelberg game model of a two-tier supply chain comprising a single recycled cement manufacturer and retailers is constructed. Under government subsidy conditions, four CSR sharing modes are systematically compared: no CSR (NS), manufacturer-borne (MS), retailer-borne (RS), and shared by both (TS). The results indicate the following: (1) CSR implementation reduces wholesale and retail prices while increasing sales effort, the incorporation rate of recycled aggregates, and market demand, with retailers bearing CSR yielding the most significant pull effect; (2) heightened sensitivity to sales effort incentivizes retailers to increase sales investment and encourages manufacturers to increase the incorporation rate of recycled aggregates, thereby increasing overall supply chain profits and utility; and (3) when the CSR coefficient does not exceed the critical value of 0.97, both manufacturer profits and retailer profits increase as the CSR level increases under the TS model; under the RS model, total supply chain profits and total utility reach their maximum. Corporate social responsibility (CSR) undertaken or jointly undertaken by retailers can better align economic and social objectives. This study provides theoretical foundations and practical insights for policy formulation and corporate decision-making in construction waste resource management. Full article

Polyethylene terephthalate is a prominent polymer known for its mechanical properties, chemical resistance, and recyclability, and it is widely utilized across various industries. Enhancing the properties of polyethylene terephthalate (PET) through nanocomposite technology, particularly with the inclusion of nanoscale fillers, has garnered significant attention. This study investigates synthetic layered double hydroxides (LDHs), specifically MgAl LDH modified with calcium dodecylbenzene sulphonate in n-butyl alcohol (CDS) organic surfactant, as an alternative to natural clays for PET nanocomposites. Additionally, modified LDH serves a dual role as both a catalyst and a dispersive agent, promoting effective exfoliation within the PET matrix. A polymerization process was employed to ensure proportional and effective dispersion of the nanofillers, addressing the critical challenge of achieving uniform distribution. The resulting nanocomposites demonstrated superior mechanical strength, thermal stability, and barrier properties compared to traditional intercalated counterparts. Moreover, synthetic LDHs present a more sustainable solution, reducing the environmental footprint associated with natural clay mining, which includes land degradation, water pollution, energy consumption, and biodiversity loss. This research provides a promising pathway for developing high-performance, environmentally friendly PET nanocomposites, with significant implications for various industrial applications, from packaging to automotive and electronics. The findings highlight the potential of synthetic LDHs to advance material science while aligning sustainable development goals. Full article

Nano- and microplastic contamination poses a growing challenge to aquatic environments, driving the need for efficient and sustainable removal technologies. In this study, carbon–silica hybrid nanoparticles (CSNPs) were synthesized from rice husk-derived black liquor via controlled lignin–silica self-assembly followed by thermal carbonization, providing a waste-recycling biorefinery route for value-added material production. Structural characterizations revealed that carbonization generates a hierarchically porous carbon–silica hybrid with enhanced surface area. The CSNPs exhibited rapid and size-dependent adsorption toward nano- and microplastics (200–1000 nm), with optimal performance observed for 500 nm particles. Microscopic observations further demonstrated a size-adaptive capture mechanism, involving pore filling and surface adsorption for nanoplastics and aggregate-assisted encapsulation for larger microplastics. This study highlights CSNPs as low-cost and effective adsorbents for broad-spectrum plastic removal while offering a sustainable pathway for the high-value utilization of black liquor and rice husk biomass in water purification applications. Full article

In order to reduce the environmental pollution caused by waste white mud from the papermaking process, this paper proposes a new method of preparing lightweight concrete using waste white mud and shale ceramsite, aiming to provide a new approach for the recycling of papermaking waste. The main objective of this study is to investigate the feasibility of utilizing paper-making white clay as a cement replacement in lightweight concrete and to systematically evaluate the influence of key parameters, such as white clay content, on its fundamental mechanical properties. Based on lightweight ceramsite concrete, paper-making white clay was used to replace cement in preparing white clay lightweight concrete. Through orthogonal tests, mix proportion design and optimization were carried out, and the effects of factors like water–binder ratio and white clay content on the compressive strength, splitting tensile strength, and early-age cracking resistance of the concrete were studied. The results show that with the increase in white clay content, the cube compressive strength of concrete first increases and then decreases. When the white clay content is 5%, the splitting tensile strength of the concrete is the highest at all ages, and when the white clay content is 15%, the internal structural compactness of the concrete is optimal. Full article

This study assesses carbon footprint (CF) and explores mitigation potentials through improved resource efficiency for fire-resistant wood doors (WFDs) and fire-resistant bamboo doors (BFDs). Both WFDs and BFDs are certified to the Chinese national fire resistance standard GB 12955-2024, ensuring the same core fire resistance performance and functional equivalence. Results show that WFDs have a slightly lower CF (806.04 kg CO₂ e/m³) than BFDs (830.54 kg CO₂ e/m³), where the raw material phase acts as the main contributor (58.57–64.32%). Crucially, significant mitigation potentials are identified by enhancing resource efficiency across the product life cycle through reducing processing loss, and extending service lifespan, and sustainable recycling. Approximately 35.2 billion kg CO₂ will remain after reducing carbon loss by 5% in the Chinese wood/bamboo industrial sector. Recycling approaches (wood/bamboo panels, bio-based pellet fuel, and biochar) can be utilized with fewer emissions to economize bio-resources. The use of biochar provides greater carbon storage benefits and will help to limit the effects of climate change. Full article

To enhance the utilization rate and mechanical performance of recycled sand (RS) in extrusion-based 3D printing, this study investigates the influence of varying incorporation ratios of RS across two particle size fractions: 0.075–1.18 mm (RS01) and 1.18–2.36 mm (RS12). The RS utilization rate was determined via the material balance method, while microstructural mechanisms were analyzed using scanning electron microscopy and Vickers microhardness testing. The results indicate that: a combination of 75% RS01 and 25% RS12 achieves the maximum RS utilization rate of 84.3%. At an RS12/RS01 ratio of 1:3, the printed specimens exhibit the smallest tilt angles in bidirectional buildability tests, measuring 7.6° and 7.2°, with corresponding tan θ values of 0.066 and 0.063. Compared to mortar with 100% RS01, this optimized mixture yields average increases of 36.5% in compressive strength, 40.7% in flexural strength, and 6.8% in interlayer splitting strength. Analysis of variance indicates that different particle size combinations have a significant effect on the mechanical properties. Microhardness analysis reveals that the combination of 75% RS01 and 25% RS12 achieves a minimum interfacial transition zone width of 46 µm. Utilizing larger-particle-size RS in 3D printing effectively enhances its utilization rate while maintaining satisfactory printability and mechanical properties. Full article

To investigate the effects of incorporating nanomaterials—carbon nanotubes (CNTs) and graphene oxide (GO)—on the axial compressive mechanical properties of alkali-activated recycled aggregate concrete (AARAC) after high-temperature exposure, this study designed 51 sets of specimens with recycled coarse aggregate replacement rate, nanomaterial content, and temperature as the main parameters. Compression tests were conducted to analyze the failure mode and strength variation in AARAC specimens after heating. In addition, microscopic tests, including X-ray diffraction, scanning electron microscopy, and computed tomography (CT scanning), were performed to analyze the microstructural characteristics of the post-heated AARAC specimens. The results indicate that as the replacement rate of recycled coarse aggregate increased from 0% to 100%, the residual compressive strength after exposure to 600 °C decreased from 33.6 MPa to 19 MPa. When 0.1 wt% of CNTs is added, the compressive strength of AARAC after exposure to a high temperature of 600 °C increases by approximately 30.4% compared to that of AARAC without nanomaterial addition. When 0.1 wt% of CNTs and 0.05 wt% of GO are added, the compressive strength after exposure to a high temperature of 600 °C increases by approximately 44.3%, while the size of scattered fragments upon failure increased, and the failure mode appeared more complete. Microscopic test results indicate that the high-temperature treatment did not cause significant changes in the main phase composition of AARAC. The synergistic effect of the nanomaterials CNTs and GO can fully utilize their functions as nucleation sites, pore fillers, and crack bridging agents. By strengthening the Interfacial Transition Zone between the recycled coarse aggregate and the cement paste, refining the Matrix Pore Structure, dispersing local thermal stress, and suppressing the propagation of high-temperature cracks, the mechanical properties of AARAC after high-temperature exposure can be effectively maintained. Full article

Accelerated urbanization and continuous infrastructure renewal have led to a rapid increase in construction and demolition waste (CDW), which accounts for approximately 20–50% of municipal solid waste in many developed countries. Consequently, effective management and resource utilization of CDW have become critical challenges for sustainable urban development. To address these challenges, this study develops an integrated analytical framework for CDW recycling systems. Specifically, it constructs a “cloud-edge-terminal” collaborative recycling system and clarifies the interactions among material, information, and value flows. A three-dimensional coupling framework is further established to reconceptualize CDW management as a multivariate decision-making problem, alongside a multidimensional evaluation structure to support practical implementation and system optimization. Methodologically, the study adopts an integrative review approach supported by knowledge mapping analysis. A structured literature search and screening process was conducted using the Web of Science Core Collection (2015–2026) to ensure transparency and reproducibility in the literature identification and sample construction. The results propose a multidimensional coupling framework integrating resource coordination, information communication, and market trading into a unified decision system. The framework contributes an engineering-oriented analytical paradigm that promotes hierarchical decision coordination, dynamic multi-objective regulation, and integrated management of CDW recycling systems. Full article

Against the backdrop of dual-carbon goals and resource constraints, the high-value utilization of recycled fine aggregates (RFAs) remains limited, leading to inconsistent engineering performance and insufficient durability. Enzyme-induced carbonate precipitation (EICP) represents a promising low-carbon cementation method, yet its deposition uniformity and cementation efficiency are influenced by the pore structure of granular media and associated mass transfer pathways. This study employs a two-stage experimental design to investigate the synergistic effects of particle size distribution characteristics, represented primarily by d₅₀, and fiber addition on EICP-cemented RFA. Phase I (fiber-free; d₅₀ = 0.67–1.14 mm) results indicate that, across the tested gradation schemes, the CaCO₃ content generally decreased from 9.49% to 7.72% as the representative d₅₀ increased, while the dry density changed only slightly (1.637–1.617 g/cm³). However, the unconfined compressive strength (UCS) decreased from 1000 kPa to 541 kPa (45.9% reduction), indicating that strength is primarily governed by the connectivity of the cementation network rather than solely by the degree of densification. In Phase II, glass fiber (GF), polypropylene fiber (PPF), and jute fiber (JF) were incorporated into the ERFA4 gradation scheme selected for fiber modification. All three systems exhibited a unimodal optimum pattern: the peak CaCO₃ contents reached 10.71% (GF 0.5%), 10.11% (PPF 0.7%), and 11.46% (JF 0.7%), corresponding to peak UCS values of 1917, 1874, and 2450 kPa, respectively. Microscopic analysis suggested that fiber bridging coupled with CaCO₃ deposition may contribute to the formation of a “fiber-CaCO₃-particle” stress-transfer network, which is consistent with the observed enhancements in load-bearing capacity, ductility, and post-peak stability. Full article

Uranium is a critical raw material for the nuclear industry. Given the vast uranium reserves in seawater, the development of efficient adsorbents is central to extraction technologies. Polyamidoxime (PAO)-based adsorbents are widely utilized due to their high affinity for uranium; however, traditional PAO materials often suffer from low mechanical strength and poor recyclability. To address these limitations, this study utilized natural balsa wood as a substrate. A three-dimensional porous cellulose skeleton (DES-W) featuring high porosity, hydrophilicity, and retained mechanical strength was constructed by partially removing lignin using a deep eutectic solvent (DES). Subsequently, polyamidoxime was loaded onto the inner walls of the DES-W via vacuum impregnation, resulting in a polyamidoxime-functionalized wood-based adsorbent (PAO-WA). The results indicated that PAO-WA achieved an equilibrium adsorption capacity of 45.31 mg/g at pH 6.0 with an initial uranium concentration of 50 mg/L, representing a twofold increase compared to the unmodified DES-W. The adsorption kinetics and isotherms followed the pseudo-second-order and Langmuir models, respectively, suggesting a mechanism dominated by monolayer chemisorption. Mechanism analysis confirmed that uranyl ions were primarily captured via coordination with nitrogen and oxygen atoms in the amidoxime groups, with residual carboxyl groups in the wood contributing to the adsorption process. This work offers a novel strategy for developing efficient, environmentally friendly, and mechanically robust adsorbents for uranium extraction from seawater. Full article

The widespread utilization of plastic materials across various industrial sectors drives a continuous increase in global polymer demand. The exponential production growth generates severe environmental challenges regarding municipal solid waste management, as substantial fractions of post-consumer residuals enter landfills due to limited recycling infrastructure. Mitigating the global environmental burden requires the implementation of advanced recovery strategies to transition polymer waste into viable secondary feedstocks. Consequently, deploying efficient sorting techniques constitutes a fundamental requirement to integrate plastic materials into formal waste management protocols and optimize recycling yields. Technological innovations currently drive the transition from traditional manual segregation towards highly sophisticated automated sensor-based sorting architectures, maximizing separation efficiency. In this context, the present study comprehensively reviews pretreatment classification techniques engineered to fractionate heterogeneous waste streams into high-purity material flows. Rather than restricting the analysis to polyolefins, this review encompasses a broad spectrum of commodity polymers predominantly found in urban solid waste environments. Full article

This study explores the potential of biomimetic reasoning to inform early-stage design thinking, with a focus on enhancing the consideration of material utilization and textile waste. While sustainability efforts within the field of textiles are often focused on recycling and end-of-life management strategies, it is important to recognize that a substantial proportion of final waste-related outcomes are determined during the conceptual design stage and the initial prototyping iterations. This study investigates the potential of organizational principles derived from natural systems to inform the definition of problems, the generation of ideas, and early conceptual prototyping. This is achieved by the introduction of ecological constraints and material life-cycle awareness in conjunction with user-centered requirements. To address the conceptual gap between biological forms and manufacturing, biomimicry is approached as a mode of systemic reasoning, utilizing topological skeletonization as a tool for logic extraction rather than formal imitation, with emphasis placed on continuity, modularity, and adaptive organization. This computational proof-of-concept employs a Particle Swarm Optimization (PSO) framework, utilizing biological venation as a topological guide to demonstrate how distinct organizational logics influence pattern configuration while incorporating manufacturing-inspired constraints (such as path continuity and density) as optimization penalties. The findings are exploratory in nature and are confined to the computational domain; while the study utilizes proxy indicators to simulate potential textile behaviors, it acknowledges the lack of direct experimental validation of physical fabrication as a current limitation. By framing waste as an outcome of upstream design choices, this paper contributes a methodological perspective. This perspective places biomimetic design thinking as a reflective tool within sustainable and regenerative design practice. It also supports earlier engagement with ecological considerations in textile development. Full article

This research investigates novel polymeric composite materials made from recycled polyolefin and waste plant biomass (poplar seeds and vegetable peels), which have potential applications in the relatively unexplored field of electrical insulation. For composites made from poplar seeds with low density polyethylene matrix, the structure appears more uniform, even with increased biomass content, in contrast to those utilizing high density polyethylene matrix, which displays notable heterogeneous areas where the polymer appears separated from the fibrous network at higher biomass levels. Concerning the composites of vegetable peels with high density polyethylene matrix, the fragments of vegetable peels are clearly recognizable, and their bond to the polymer matrix appears weaker. When incorporating vegetable peels into the polypropylene matrix, it results in a better distribution of the vegetable peel fragments within the polymer matrix, as well as enhanced structural homogeneity. Overall, the incorporation of biomass reduces the Shore hardness measurement for every polymer matrix. Regarding tear resistance, the inclusion of biomass reduces the values only for low density polyethylene with poplar seeds. For both high density polyethylene and polypropylene, regardless of the biomass type, the property seems to enhance marginally with the addition of biomass. The primary advantage of utilizing these composites is that their water absorption rate is at least twice as low as that of transformer board, while still offering a similar capacity for absorbing transformer oil. All composite types exceeded the minimum required threshold of 70 °C for service exposure, and adhered to insulation class A, similar to cellulose-based insulations. The addition of cellulose to polyolefin composites appears to slightly improve their breakdown strength. The conductivity for this type of composite is at least three times lower than that of cellulose insulation materials, rendering them beneficial for applications in electrical engineering as potential substitutes for cellulose-based materials in multiple electrical insulation uses, e.g., for insulating low voltage electrical machines, as well as serving as a substitute for pressboard in transformers. Additionally, their thermoplastic properties offer enhanced processing versatility, opening up new opportunities for electrical engineering technology, especially with regard to electrical insulation recyclability in the context of a circular economy. Full article