Search Results (3,318)

Photosynthetic biogas upgrading (PBU) using microalgae is a promising biological approach for converting raw biogas into biomethane while recovering nutrients and fixing part of the biogenic CO₂ into algal biomass. Unlike conventional physicochemical technologies, which mainly separate CO₂ from CH₄, PBU can combine gas upgrading with wastewater or digestate treatment, nutrient recycling, and biomass production. This review assesses the current state of PBU technology, with particular emphasis on high-rate algal ponds, absorption columns, and closed photobioreactors. It examines the main operating parameters that control gas–liquid mass transfer, carbonate buffering, and photosynthetic activity, including the liquid-to-gas ratio, pH, alkalinity, temperature, light regime, light intensity, and gas retention time. Special attention is given to the combined effects of the L/G ratio, pH, and alkalinity, as these parameters strongly influence CO₂ absorption, CH₄ enrichment, and O₂ contamination of the upgraded gas. The use of wastewater or anaerobic digestate instead of synthetic growth media is identified as an important sustainability advantage, particularly at wastewater treatment plants with existing anaerobic digestion and nutrient-rich side streams. However, digestate use may also create operational challenges related to turbidity, ammonium inhibition, solids, and variable composition. Available studies indicate that PBU may reduce operating costs and greenhouse gas emissions under favorable conditions while creating additional value from algal biomass. Nevertheless, wider deployment is still limited by high land requirements, seasonal variability, O₂ contamination, biomass harvesting, and limited evidence from large-scale systems. Future development should therefore focus on improved oxygen management, more efficient reactor designs, nanoparticle-assisted enhancement of photosynthetic activity, better integration with wastewater treatment, and AI-supported monitoring and control to improve process stability and support scale-up. Full article

Waste lubricating oils (WLOs) represent a major stream of hazardous petroleum-based residues, with global generation exceeding 24 million tons annually. Improper disposal of WLOs poses risks to soil, water, and air quality, while their chemical composition makes them a potential secondary resource within circular economy frameworks. This review summarizes conventional, advanced, and emerging technologies reported for the recycling and valorization of WLOs into high-value petrochemicals and carbon-based materials. Established processes such as acid–clay treatment, solvent extraction, and vacuum distillation are discussed together with more recent approaches, including catalytic upgrading, hydrotreatment, membrane separation, and thermochemical conversion methods such as pyrolysis and catalytic cracking. Reported data on process performance, environmental considerations, techno-economic indicators, and life cycle assessment outcomes are comparatively analyzed to outline current trends, technical challenges, and future development directions in WLO recycling. Particular attention is given to thermochemical pathways capable of generating carbonaceous materials, including carbon black, porous carbons, and functional carbon nanostructures with potential applications in adsorption, catalysis, electrochemical systems, and tribological formulations. Hybrid and integrated process configurations described in the literature are highlighted for their potential to improve recovery efficiency, enhance product quality, and reduce environmental burdens. In addition, recent life cycle assessment (LCA) and techno-economic analysis (TEA) studies are reviewed to provide insight into the environmental and economic implications of advanced re-refining systems. Overall, the reviewed literature indicates that WLO recycling represents not only an important element of sustainable lubricant management but also a promising waste-to-carbon strategy for the production of value-added carbon-based materials and petrochemical products. Full article

Lithium has become one of the key raw materials for the energy transition due to the central role of lithium-ion batteries in electromobility, energy storage, and the integration of renewable energy sources. However, the rapid increase in demand reveals growing environmental, social, geopolitical, and market tensions. The aim of the paper is a critical synthesis of global lithium utilization from the perspective of challenges, technological innovations, and integrative strategies supporting a more sustainable material–energy system. A broad, systematic literature review covering the entire value chain was applied: resources, extraction, processing, end-use applications, second life of batteries, recycling, and governance. The analysis shows that the strategic importance of lithium arises from the increasing demand pressure from electric vehicles and stationary storage, while the sustainability of the current model is constrained by supply concentration, uneven control over downstream stages, the water–carbon footprint of extraction and processing, social conflicts, and incomplete integration of secondary loops. At the same time, innovations such as direct lithium extraction (DLE), recovery from geothermal brines, design for recycling, second life, and battery passports can partially alleviate these tensions, but they do not eliminate the need for primary supply in the short term. The conclusion of the work is that sustainable global lithium utilization requires simultaneous diversification of sources, development of circular value chains, and multi-level governance integrating resource security, environmental efficiency, and social legitimacy. Full article

Ionic liquids remain attractive alternatives as multifunctional media for the sustainable biosynthesis of lactones. Their unique physicochemical properties, including negligible vapor pressure, high thermal stability, and tunable polarity, offer significant advantages in terms of biocatalyst stabilization and reaction selectivity. For lactone synthesis, ionic liquids facilitate improved control over enzymatic transformations, enable efficient catalyst recycling, and reduce solvent consumption. This review summarizes recent advances in the application of ionic liquids as solvents or support modifiers in enzymatic lactone synthesis, focusing also on ε-caprolactone biosynthesis. A green chemistry metrics evaluation was also performed for selected examples from the literature. The role of ionic liquids in enhancing process efficiency and supporting green, sustainable process design is critically discussed, highlighting their potential for the development of more sustainable and environmentally friendly lactone production technologies. Full article

Cellulose is the most promising abundant renewable polymer material with the highest potential for the future low-carbon biorefineries. However, its utilization in industry is limited by the structural recalcitrance as a result of organization of crystalline domains, fibrillar architecture hierarchy and intramolecular and intermolecular hydrogen bonding which is responsible for access restriction for the catalysts and consequent cleavage of the glycosidic bonds. Therefore, efficient depolymerization of cellulose is of paramount importance as a step in biomass conversion into the low molecular products. In this review, the recent advances in cellulose depolymerization are discussed. The chemical, enzymatic, thermal, thermochemical, mechanochemical, oxidative and hybrid catalytic method is thoroughly discussed. Attention is paid to the mechanism of the depolymerization reaction steps as glycosidic bond activation as hydrolytic, radical mediated, and energy assisted pathways. Selectivity and conversion efficiency based on substrate morphology, solvent system and catalyst design are also discussed. Further, there is a comparison of key performance metrics which are relevant for the industrial process as product yield, carbon efficiency, energy demand, stability of the catalyst, solvent recyclability and impact to the environmental lifecycle. The pros and cons of the various methods are also represented. Processes based on mineral acids enable rapid conversion. However, they suffer from corrosion, waste handling issues and degradation by-products. On the other hand, enzymatic depolymerization processes offer relatively high selectivity but they are limited in terms of feedstock sensitivity and slow reaction kinetics. The downstream valorization mechanisms are also described with the result being that no single available technology is capable of satisfying all industrial requirements. Thus, future progress expects integrated circular processes where advanced catalysis, process intensification and digital optimization strategies take place. Full article

In this work, we introduce the novel possibility of producing blue fluorescent ultraviolet pigments from phosphogypsum. The obtained materials are characterized by X-ray diffraction (XRD), transmission electron microscopy, and X-ray photoelectron spectroscopy (XPS). The formation of the CaS phase in the sample during the reduction of calcium sulfate was established. Thermal treatment of phosphogypsum in the presence of a reducing agent (potato starch) under environmental isolation conditions is found to yield high-quality products with high added value. The highest luminosity is established in samples containing 0.6 mol. %, which were heat-treated under a temperature of 1100 °C for 60 min. The synthesized CaS:Cu materials are shown to emit light in the blue region of the spectrum, with an emission maximum at a wavelength of 480–490 nm. The developed technological methods open the possibility to recycle chemical industry waste, which contributes to the achievement of sustainable development goals, in particular, the goal of ensuring rational consumption and production patterns. Full article

Municipal solid waste (MSW) management is a critical challenge to advancing recycling and circular economy approaches. This review provides a comprehensive overview of MSW management, encompassing sourcing, policy frameworks, characterization techniques, separation technologies, preprocessing strategies, and utilization pathways. First, generation patterns and sourcing mechanisms are discussed in both U.S. and global contexts, with emphasis on the influence of policy frameworks on waste reduction and diversion. Second, characterization techniques are evaluated, focusing on physical and chemical analysis for material recyclability. Third, sorting technologies are critically reviewed, covering conventional methods and emerging sensor-based approaches. Preprocessing techniques are then evaluated for their role in improving downstream conversion efficiency. Finally, valorization pathways such as waste-to-syngas, waste-to-biochar, and waste-to-sustainable aviation fuel (SAF) are assessed in terms of their role in climate mitigation and the circular economy. It is anticipated that this review will provide a foundational reference for researchers, policymakers, and industry stakeholders aiming to strengthen the recyclability infrastructure and maximize the efficiency of MSW management systems in the framework of the circular economy. Full article

Western saline soil areas contain a large amount of chloride and sulfate ions, leading to a reduction in the service life of Portland concrete in this environment. Magnesium oxychloride cement recycled concrete (MOCRC) is mainly prepared with light-burnt magnesia and magnesium chloride, which is more suitable for application in a western saline soil environment than Portland concrete. In this paper, ultrasonic non-destructive testing technology was used to investigate the effects of multiple factors on the deterioration process and service life of MOCRC in a western saline soil environment. The results showed a clear functional relationship between the relative dynamic elastic modulus and the compressive strength or size of MOCRC. On this basis, a multiparameter time-varying degradation model for MOCRC considering the compressive strength, size effect, and environmental error is established. Moreover, a service life prediction model for MOCRC based on the relative dynamic elastic modulus is proposed, using reliability theory and the first-order second-moment method. This study provides a foundational method for the durability examination and service life prediction of MOCRC. Full article

The exponential increase in photovoltaic panel (PV) waste highlights the urgent need to develop efficient and sustainable recycling processes. It is estimated that by 2030, 8 million tons of PV modules will reach their end-of-life stage, posing a significant environmental challenge and requiring the development of green technologies for resource recovery. This study assessed the performance of imidazolium-based ionic liquids (ILs) as “designer solvents” for the selective leaching of copper and silver from disused PV panels. Specifically, four quaternary imidazolium salts were evaluated: [Bmim]HSO₄, [Emim]HSO₄, [Bmim]Cl, and [Emim]Cl. Leaching tests were conducted on silicon wafers containing 0.28% Ag and 0.19% Cu under varying temperatures (25, 50, and 80 °C), IL concentrations (20% and 60% v/v), and hydrogen peroxide (H₂O₂) dosages (0% and 3% v/v) as an oxidizing agent. The results identified [Bmim]HSO₄ as the most effective leaching agent. The system achieved a maximum copper extraction of 96.70% at 60% v/v concentration and 80 °C. For silver, the highest extraction of 45.13% was obtained using [Bmim]HSO₄ at 20% v/v and 80 °C. The addition of H₂O₂ was crucial, demonstrating a clear synergistic effect with the imidazolium-based ILs by promoting oxidative dissolution. These findings confirm that imidazolium-based ionic liquids represent a promising and environmentally friendly alternative for the recovery of high-value metals in the circular economy of photovoltaic recycling. Full article

The transition toward circular economy practices and CO₂ reduction goals is driving the development of new sound absorption technologies. Traditional absorbers made from mineral wool or foams provide broadband absorption; however, their production is associated with intensive energy consumption and non-renewable resources. This is why the focus has been shifting from the mere substitution of materials to integrated solutions that combine sustainability with structure. This paper reviews recent innovations in sustainable absorbers based on bio-based and recycled materials. The acoustic performance of porous materials depends on such factors such as pore structure, airflow resistivity and geometric parameters such as thickness, multi-layer structure and resonances. At the same time, additive manufacturing (AM) allows creating geometry-controlled absorbers providing advanced acoustic properties. Despite many sustainable absorbers demonstrating sufficient sound absorption properties at medium and high frequencies, their use at low frequencies remains challenging. Additionally, concerns regarding durability, flame retardance, and environmental consistency continue to limit their broader application. Yet, hybrid, multi-material strategies, particularly those combining geopolymer matrices with bio-based or recycled fillers, are identified as a promising route to address these limitations. This review outlines current trends and highlights key challenges and future directions in the design of sustainable sound-absorbing systems. Full article

Inadequate management of municipal solid waste represents a critical challenge for the sustainability of modern cities, characterized by low citizen participation rates due to the lack of direct incentives. Unlike existing approaches that isolate hardware classification or fleet monitoring, this article presents RENOVA as a socio-technical closed-loop system based on the Internet of Things (IoT) and artificial intelligence (AI). This system integrates an IoT-enabled smart bin, a gamified mobile application for citizens, and an administrative web panel for merchant redemption, all interconnected via a REST API. The system employs computer vision through the GPT-4o (OpenAI, San Francisco, CA, USA) multimodal model for the automatic classification of recyclable materials (PET plastic and Aluminum) and integrates a gamified rewards program to incentivize citizen participation. The methodology follows an applied technological development approach under the agile Scrum framework. Prototype validation demonstrated successful real-time communication between the IoT device and the cloud platform, achieving classification accuracy exceeding 95% under controlled conditions. A diagnostic survey applied to a convenience sample of 51 participants revealed that 94.1% accepted the proposed gamification model, while user experience evaluation (n = 74; consisting primarily of university-affiliated individuals aged 15–24) yielded a mean overall satisfaction score of 4.77/5.0 (SD = 0.48), with 79.7% of participants assigning the maximum rating. These findings reflect stated user acceptance and behavioral intention under prototype conditions rather than observed long-term behavioral change, and should not be generalized to broader urban populations without further validation. The proposed solution directly contributes to Sustainable Development Goals 11 (Sustainable Cities) and 12 (Responsible Consumption), suggesting a potentially scalable framework. Full article

Geopolymeric concrete beams are gaining increasing attention as sustainable structural members. The paper presents an experimental investigation on the deflection and cracking behavior of geopolymeric recycled aggregate concrete (GRAC) beams, with emphasis on effects of the longitudinal reinforcement ratio and the recycled aggregate (RA) replacement ratio. Using digital image correlation (DIC) technology, the failure modes, load–deflection curves, deflection characteristics, stiffness, and cracking behavior were systematically analyzed. The results indicated that increasing the reinforcement ratio leads to the same trend in GRAC beams as that observed in ordinary reinforced concrete beams. At 50% RA replacement, GRAC beams exhibit improved cracking resistance, 13.41% higher cracking stiffness, 6.93% lower deflection, and enhanced ductility compared to specimens without RA, attributed to the enhanced RA–matrix interface. However, a further increase in the RA replacement ratio leads to poorer flexural performance of the GRAC beams. In addition, predictive models for cracking moment, stiffness, deflection, and maximum crack width of GRAC beams were proposed based on the experimental results, incorporating the plastic influence coefficient, the comprehensive coefficient for the average strain at the extreme compression zone of concrete and the maximum crack width correction factor. The calculated values agreed well with the test data, offering a basis for structural design and engineering application. Full article

The rapid expansion of solar photovoltaic (PV) deployment has led to increasing concerns regarding end-of-life module management and the sustainability of material supply chains, where waste volumes are projected to reach 3.3–5.6 million tons by 2045. This study evaluates the environmental and economic impact of advanced photovoltaic recycling in Germany, focusing on high-value material recovery from crystalline silicon modules. A Full Recovery of End-of-Life Photovoltaics (FRELP) pathway is developed, integrating light-pulse delamination and molten salt etching, and a comparative life cycle assessment and economic assessment framework is applied. The results indicate that advanced recycling achieves high recovery rates for silicon, silver, aluminum, copper and low-iron glass, yielding around €1174.88 per ton of panels recycled. Economic analysis shows that manufacturing PV modules from recycled materials reduces costs by approximately 60–77% compared to virgin material production, mainly due to avoided energy-intensive upstream processes. From an environmental perspective, the recycling-based pathway yields net benefits across impact categories, as avoided impacts from primary material extraction outweigh additional burdens associated with recycling. Overall, PV recycling in Europe is shown to be environmentally and economically favorable; however, technological maturity and policy constraints remain key barriers to large-scale implementation and a holistic overall recycling process, indicating the need for targeted policy support. Full article

With the increased application of porous asphalt, the recycling and reutilization of aged materials have become a critical issue for sustainable pavement engineering. This study investigates the evolution of the performance characteristics of porous asphalt mixtures under high-temperature heating conditions, with the aim of providing a theoretical basis for hot in-place recycling (HIR) technology in the rehabilitation of porous asphalt pavements. The heating states of asphalt, mortar and mixtures in HIR were simulated using controlled oven heating. Their microscopic, mechanical and thermal properties were evaluated under different aging conditions and with the incorporation of different rejuvenators. The results show that asphalt aging intensifies with the increasing heating temperature and time. The incorporation of bio-based rejuvenators significantly alleviates aging effects and demonstrates superior performance compared to conventional rejuvenators. Furthermore, aggregates and rejuvenators enhance the thermal conductivity of materials, while aging reduces the thermal conductivity coefficient and increases the risk of temperature gradient diseases. The rheological properties of asphalt are closely related to the degree of aging. While aging mitigation improves low-temperature cracking resistance and acoustic damping performance, it may compromise high-temperature deformation resistance. In conclusion, to achieve an optimal balance between performance recovery and aging control, it is recommended that the HIR of porous asphalt pavements be conducted at a heating temperature of 180 °C for 5 min, with the addition of 3% bio-based rejuvenator. Full article

Modern photovoltaic technologies are increasingly evaluated not only in terms of power conversion efficiency and cost, but also with respect to resource origin, toxicity, recyclability, and overall life-cycle impacts. Within this broader sustainability framework, bio-based and bio-inspired materials derived from biomass or mimicking biological structures have emerged as promising candidates for a wide range of photovoltaic components, including active layers, interfacial modifiers, substrates, encapsulants, and natural dyes. This review provides a layer-by-layer overview of such materials implemented or proposed in dye-sensitized, organic, perovskite, biohybrid, and silicon solar cells, linking their molecular structures and optoelectronic properties to representative device performances and key degradation pathways. Cross-cutting challenges related to moisture and thermal stability, barrier performance, feedstock variability, and the risk of “greenwashing” are highlighted, emphasizing that sustainability claims must be supported by quantitative metrics such as life-cycle assessment, circularity indicators, and durability studies. Finally, we outline promising research directions in molecular engineering, hybrid biosynthetic architectures, and advanced encapsulation concepts that could enable bio-based materials to make a meaningful contribution to low-impact photovoltaic technologies. Full article