Search Results (22)

This study aims to evaluate the influence of glass fibre (GF) type and content on the thermal, mechanical, and morphological properties of polyethylene terephthalate (PET)-based composites containing post-consumer PET flakes, intended for mouldings exposed to cementitious environments (e.g., anchors). Two chemically resistant GFs were compared: alkali-resistant (AR) fibres with soft sizing (SGFs) and electrical-/chemical-resistant (ECR) fibres with hard sizing (HGFs). Composites with fibre contents of 10–60 wt.% were prepared, with detailed analysis focused on 30 to 50 wt.%—the range typical for practical applications. AR fibres experienced greater shortening during processing, and their actual fibre content was lower than the intended value. Differential scanning calorimetry (DSC) revealed enhanced crystallisation kinetics for SGF composites, with higher crystallinity of the injection-moulded samples and elevated crystallisation temperatures (206–208 °C for SGF vs. 196–197 °C for HGF). Thermogravimetric analysis (TGA) indicated that thermal stability was primarily governed by fibre content; both SGF and HGF composites showed improved resistance compared to neat PET. Mechanical tests demonstrated that both fibre types effectively reinforced the matrix: HGF composites exhibited a higher elastic modulus (20.6 GPa for HGF-50 vs. 18.3 GPa for SGF-50), whereas SGF composites exhibited roughly 10–20% higher tensile, flexural, and impact strength, despite slightly lower fibre content. SEM analysis confirmed more uniform fibre distribution and fewer voids in SGF composites. These results highlight the importance of GF selection for PET composites in alkaline environments, taking into account the properties of the sizing film former and balancing trade-offs between mechanical performance, thermal stability, processability, and economic factors. Full article

Expansive clay soils present major challenges for infrastructure due to their high swelling potential and low bearing capacity. While conventional stabilisers, such as lime and Ordinary Portland Cement (OPC), are effective, they are environmentally unsustainable due to their high carbon footprint. This study examines the potential of shredded recycled polyethene terephthalate (PET) fibres as a low-carbon alternative for stabilising high-plasticity clays. PET fibres were incorporated at dosages ranging from 0% to 1.2% by dry weight, and their influence on compaction characteristics, unconfined compressive strength (UCS), California Bearing Ratio (CBR), swelling behaviour, and microstructure was evaluated through laboratory testing and Scanning Electron Microscopy (SEM). Among the tested mixes, the 1.0% PET content exhibited the highest measured performance, resulting in a 37% increase in UCS, a 125% enhancement in unsoaked CBR, more than a two-fold increase in soaked CBR, and a 15% reduction in the Differential Free Swell Index (DFSI). SEM analysis indicated the formation of a three-dimensional fibre matrix, which improved particle interlock and reduced microcrack propagation. However, higher fibre dosages caused agglomeration and macrovoid formation, which adversely affected performance. Overall, the findings suggest that the inclusion of PET fibres can enhance both geotechnical and environmental performance, providing a sustainable stabilisation strategy that utilises plastic waste while reducing reliance on OPC. Full article

Marine plastic pollution represents a critical environmental challenge, with millions of tons of plastic waste entering the oceans annually and threatening ecosystems, biodiversity, and human health. This systematic review evaluates the current state of the art in recycling and reusing marine plastic waste within the architecture, engineering, and construction (AEC) sectors, following the PRISMA methodology. Sixty-six peer-reviewed articles published between 2015 and 2025 were analysed, focusing on the integration of plastic waste. The review identifies mechanical recycling as the predominant method, involving washing and shredding plastics into fibres or flakes for use in cementitious composites, asphalt modifiers, bricks, panels, and insulation. Results indicate that recycled plastics, such as PET, HDPE, and PP, can enhance thermal insulation, water resistance, and flexural strength in non-structural applications. However, challenges persist regarding compressive strength, fibre dispersion, and chemical compatibility with cementitious matrices. Although the reuse of marine plastics supports circular economy goals by diverting waste from oceans and landfills, significant gaps remain in long-term durability, microplastic release, end-of-life recyclability, and comprehensive environmental assessments. The findings underscore the need for further research on the broader adoption of life cycle analysis, as well as long-term durability and environmental contamination analyses. Full article

Recycling polyethylene terephthalate (rPET) from packaging materials consumes a vast amount of energy and incurs significant economic and environmental costs. This study proposes directly recycling rPET into woven fabrics to eliminate reprocessing while still preserving the mechanical performance of the material. The mechanical properties of rPET were tested along two orthogonal directions, and the resulting test data were used to calibrate an elasto-plastic model in order to capture the constitutive behaviour of the material. Additionally, the virtual weaving of rPET fibres into fabrics was modelled using finite element analysis (FEA) to replicate the actual manufacturing process. The results show that rPET that is directly recycled into woven fabrics exhibits superior performance to the same material derived from reprocessing. A strong anisotropy of rPET materials was observed, with distinct elastic and ductile behaviours. The FEA simulation also revealed the critical role of the ductility of rPET fibres when used as warp yarns. The process parameters to achieve a successful weaving operation for different yarn configurations, taking into account the motion and tension of the fibres during manufacture, were also identified. A further sensitivity study highlights the influence of friction between the fibres on the tension force of warp yarns. The virtual manufacture-by-weaving model suggests that utilising rPET with a simplified recycling approach can lead to the sustainable manufacture of fabrics with broad industrial applications. Full article

Design and production technology of natural fibre reinforced polymers not only aims to offer products with a lower environmental impact than conventional glass fibre composites but also caters for designers’ needs for the fabrication of lightweight free-formed architectural components. To combine both characteristics, the forming process itself, once scaled up, needs to be based on efficient material moulding strategies. Based on case studies of adaptive forming techniques derived from the composite industry and concrete casting, two approaches for the mass production of customised NFRP profiles are proposed. Both processes are based on foam from recycled PET, which is used as either a removable mould or a stay-in-place (SIP) core. Once the textile reinforcement is placed on a mould, either by helical winding of natural fibre prepregs or in the form of mass-produced textile preforms, its elastic properties allow for the free-forming of the composite profile before the resin is fully cured. This paper investigates the range of deformations that it is possible to achieve by each method and describes the realisation of a small structural demonstrator, in the form of a stool, through the helical winding of a flax prepreg on a SIP core. Full article

This article addresses the potential use of secondary polymer fibres in the field of structural concrete as a replacement for primary polymer fibres (mainly polypropylene/PP/), which are used in concrete to enhance its resistance when exposed to high temperatures (especially in the case of fire). Research has shown that, in addition to PP fibres, polyethylene terephthalate/PET/fibres, produced by recycling packaging materials (mainly PET bottles), can also be used as an alternative. These fibres are industrially produced in similar dimensions as PP fibres and exhibit similar behaviour when added to fresh and hardened concrete. In terms of their effect on increasing resistance to extreme heat loads, it has been found that despite a higher melting point (Tm), concrete with these fibres demonstrates comparable fire resistance. Therefore, it can be concluded that secondary PET fibres represent an interesting alternative to primary PP fibres from the perspective of a circular economy, and their use in construction represents a potentially valuable application for PET obtained through the collection and recycling of PET packaging materials. Full article

The textile industry, renowned for its comfort-providing role, is undergoing a significant transformation to address its environmental impact. The escalating environmental impact of the textile industry, characterised by substantial contributions to global carbon emissions, wastewater, and the burgeoning issue of textile waste, demands urgent attention. This study aims at identifying the feasibility of the future use of textile scraps in the construction and architecture industry by analysing the effect of different binders. In this study, synthetic knitted post-consumer-waste fabrics were taken from a waste market for use as a reinforcement, and different binders were used as the matrix. In the experiment phase, the waste fabrics were mixed with synthetic binders and hydraulic binders to form brick samples. The mechanical and thermal properties of these samples were tested and compared with those of clay bricks. In terms of mechanical properties, unsaturated polyester resin (UPR) samples showed the highest mechanical strength, while acrylic glue (GL) samples had the lowest mechanical strength. White cement (WC) samples showed moderate mechanical properties. Through several tests, it was observed that UPR samples showed the highest values of tensile, bending, and compressive strengths, i.e., 0.111 MPa, 0.134 MPa, and 3.114 MPa, respectively. For WC, the tensile, bending, and compressive strengths were 0.064 MPa, 0.106 MPa, and 2.670 MPa, respectively. For GL, the least favourable mechanical behaviour was observed, i.e., 0.0162 MPa, 0.0492 MPa, and 1.542 MPa, respectively. In terms of thermal conductivity, WC samples showed exceptional resistance to heat transfer. They showed a minimum temperature rise of 54.3 °C after 15 min, as compared to 57.3 °C for GL-based samples and 58.1 °C for UPR. When it comes to polymeric binders, UPR showed better thermal insulation properties, whereas GL allowed for faster heat transfer for up to 10 min of heating. This study explores a circular textile system by assessing the potential of using textile waste as a building material, contributing to greener interior design. This study demonstrated the usefulness of adding short, recycled PET fibres as a reinforcement in UPR composites. The use of the PET fibre avoids the need to use a surface treatment to improve interfacial adhesion to the UPR matrix because of the chemical affinity between the two polyesters, i.e., the PET fibre and the unsaturated polyester resin. This can find application in the construction field, such as in the reinforcement of wooden structural elements, infill walls, and partition walls, or in furniture or for decorative purposes. Full article

This paper investigates making an injection mouldable conductive plastic formulation that aims for conductivity into the electromagnetic interference (EMI) shielding range, with good mechanical properties (i.e., stiffness, strength, and impact resistance). While conductivity in the range (electrostatic charge dissipation) and EMI shielding have been attained by incorporating conductive fillers such as carbon black, metals powders, and new materials, such as carbon nanotubes (CNTs), this often occurs with a drop in tensile strength, elongation-to-break resistance, and impact resistance. It is most often the case that the incorporation of high modulus fillers leads to an increase in modulus but a drop in strength and impact resistance. In this work, we have used short carbon fibres as the conductive filler and selected a 50/50 PBT/rPET (recycled PET) for the plastic matrix. Carbon fibres are cheaper than CNTs and graphenes. The PBT/rPET has low melt viscosity and crystallises sufficiently fast during injection moulding. To improve impact resistance, a styrene-ethylene-butadiene-styrene (SEBS) rubber toughening agent was added to the plastic. The PBT/rPET had very low-impact resistance and the SEBS provided rubber toughening to it; however, the rubber caused a drop in the tensile modulus and strength. The short carbon fibre restored the modulus and strength, which reached higher value than the PBT/rPET while providing the conductivity. Scanning electron microscope pictures showed quite good bonding of the current filler (CF) to the PBT/rPET. An injection mouldable conductive plastic with high conductivity and raised modulus, strength, and impact resistance could be made. Full article

Population expansion and the development of technology have led to an increase in construction activities. In many cases, foundation grounds do not have a high enough bearing capacity and are not capable of ensuring the safe exploitation of the construction. A soil with poor mechanical characteristics must be improved using various methods, such as adding hydraulic binders (lime and cement), natural fibres, or more recently, plastic waste materials. This work aims to study the behaviour of plastic waste materials made from polyethylene terephthalate (PET) in soil improvement. Thus, the mechanical characteristics of a clay improved with shredded PET were studied. PET was added in relation to the dry mass of the clay, in percentages of 2%, 4% and 6%. The studied clay was collected from a construction site around Cluj-Napoca, Romania, from a depth of 1 ÷ 10 m. PET was provided by a local plastic waste repository. It comes from recycled water, beer and soda bottles and was cleaned using specific methods for cleaning and recycling plastic waste. PET was shredded into irregular shapes with sizes ranging from 3 mm to 12 mm and was randomly distributed in the test specimens. Compression and direct shear tests were carried out to study the compressibility and shear parameters of the improved soil (internal friction angle and cohesion). The experimental results showed an improvement in the mechanical characteristics of the clay even at a low PET addition of 2% and 4%. This method can contribute to solving two current problems of the modern world: reducing pollution by recycling plastic waste materials and using them to improve the mechanical characteristics of soil. Full article

Additive manufacturing (AM, aka 3D printing) is generally acknowledged as a “green” technology. However, its wider uptake in industry largely relies on the development of composite feedstock for imparting superior mechanical properties and bespoke functionality. Composite materials are especially needed in polymer AM, given the otherwise poor performance of most polymer parts in load-bearing applications. As a drawback, the shift from mono-material to composite feedstock may worsen the environmental footprint of polymer AM. This perspective aims to discuss this chasm between the advantage of embedding advanced functionality, and the disadvantage of causing harm to the environment. Fused filament fabrication (FFF, aka fused deposition modelling, FDM) is analysed here as a case study on account of its unparalleled popularity. FFF, which belongs to the material extrusion (MEX) family, is presently the most widespread polymer AM technique for industrial, educational, and recreational applications. On the one hand, the FFF of composite materials has already transitioned “from lab to fab” and finally to community, with far-reaching implications for its sustainability. On the other hand, feedstock materials for FFF are thermoplastic-based, and hence highly amenable to recycling. The literature shows that recycled thermoplastic materials such as poly(lactic acid) (PLA), acrylonitrile-butadiene-styrene (ABS), and polyethylene terephthalate (PET, or its glycol-modified form PETG) can be used for printing by FFF, and FFF printed objects can be recycled when they are at the end of life. Reinforcements/fillers can also be obtained from recycled materials, which may help valorise waste materials and by-products from a wide range of industries (for example, paper, food, furniture) and from agriculture. Increasing attention is being paid to the recovery of carbon fibres (for example, from aviation), and to the reuse of glass fibre-reinforced polymers (for example, from end-of-life wind turbines). Although technical challenges and economical constraints remain, the adoption of recycling strategies appears to be essential for limiting the environmental impact of composite feedstock in FFF by reducing the depletion of natural resources, cutting down the volume of waste materials, and mitigating the dependency on petrochemicals. Full article

Worldwide, the need for thermal insulation materials used to increase the energy performance of buildings and ensure indoor thermal comfort is constantly growing. There are several traditional, well-known and frequently used thermal insulation materials on the building materials market, but there is a growing trend towards innovative materials based on agro-industrial waste. This paper analyses the performance of 10 such innovative thermal insulation materials obtained by recycling cellulosic and/or animal waste, using standardised testing methods. More precisely, thermal insulation materials based on the following raw materials were analysed: cellulose acetate, cigarette filter manufacturing waste; cellulose acetate, cigarette filter manufacturing waste and cigarette paper waste; cellulose acetate, waste from cigarette filter manufacturing, waste cigarette paper and waste aluminised paper; cellulose from waste paper (two types made by two independent manufacturers); wood fibres; cellulose from cardboard waste; cellulose from waste cardboard, poor processing, inhomogeneous product; rice husk waste and composite based on sheep wool, recycled PET fibres and cellulosic fibres for the textile industry. The analysis followed the performance in terms of thermal insulating quality, evidenced by the thermal conductivity coefficient (used as a measurable indicator) determined for both dry and conditioned material at 50% RH, in several density variants, simulating the subsidence under its own weight or under various possible stresses arising in use. The results showed in most cases that an increase in material density has beneficial effects by reducing the coefficient of thermal conductivity, but exceptions were also reported. In conjunction with this parameter, the analysis of the 10 types of materials also looked at their moisture sorption/desorption capacity (using as a measurable indicator the amount of water stored by the material), concluding that, although they have a capacity to regulate the humidity of the indoor air, under low RH conditions the water loss is not complete, leaving a residual quantity of material that could favour the development of mould. Therefore, the impact on indoor air quality was also analysed by assessing the risk of mould growth (using as a measurable indicator the class and performance category of the material in terms of nutrient content conducive to the growth of microorganisms) under high humidity conditions but also the resistance to the action of two commonly encountered moulds, Aspergillus niger and Penicillium notatum. The results showed a relative resistance to the action of microbiological factors, indicating however the need for intensified biocidal treatment. Full article

The structure and properties of blends of a novel polyethylene terephthalate copolymer (COPET) obtained by chemical recycling of commercial PET with high-molar-mass poly-L-lactide (PLLA) are investigated and compared to corresponding composites with chopped flax fibres. The focus is on the morphology at nano- and micro-scales, on the thermal characteristics and on the mechanical behaviour. The blends are immiscible, as evidenced by virtually unchanged glass transition temperatures of the blend components compared to the neat polymers (49 °C for COPET and 63 °C for PLLA by DSC). At low PLLA content, the blends display a sea–island morphology with sub-micron to micron droplet sizes. As the composition approaches 50/50, the morphology transitions to a coarser co-continuous elongated structure. The blends and composites show strongly improved stiffness compared to COPET above its glass transition temperature, e.g., from melt behaviour at 60 °C for COPET alone to almost 600 MPa for the 50/50 blend and 500 MPa for the 20% flax composite of the 80/20 COPET/PLLA blend. The flax fibres increase the crystallisation rate of PLLA in blends with dispersed PLLA morphology. The evidence of cavitation on the fracture surfaces of blends shows that despite the immiscibility of the components, the interfacial adhesion between the phases is excellent. This is attributed to the presence of aliphatic ester spacers in COPET. The tensile strength of the 80/20 blend is around 50 MPa with a Young’s modulus of 2250 MPa. The corresponding 20% flax composite has similar tensile strength but a high Young’s modulus equal to 6400 MPa, which results from the individual dispersion and strong adhesion of the flax fibres and leads close to the maximum possible reinforcement of the composite, as demonstrated by tensile tests and nano-indentation. The Ashby approach to eco-selection relying on the embodied energy (EE) further clarifies the eco-friendliness of the blends and their composites, which are even better positioned than PLLA in a stiffness versus EE chart. Full article

Surfboard manufacturing has begun to utilise Expanded Polystyrene as a core material; however, surf literature relatively ignores this material. This manuscript investigates the mechanical behaviour of Expanded Polystyrene (EPS) sandwich composites. An epoxy resin matrix was used to manufacture ten sandwich-structured composite panels with varying fabric reinforcements (carbon fibre, glass fibre, PET) and two foam densities. The flexural, shear, fracture, and tensile properties were subsequently compared. Under common flexural loading, all composites failed via compression of the core, which is known in surfing terms as creasing. However, crack propagation tests indicated a sudden brittle failure in the E-glass and carbon fibre facings and progressive plastic deformation for the recycled polyethylene terephthalate facings. Testing showed that higher foam density increased the flex and fracture mechanical properties of composites. Overall, the plain weave carbon fibre presented the highest strength composite facing, while the single layer of E-glass was the lowest strength composite. Interestingly, the double-bias weave carbon fibre with a lower-density foam core presented similar stiffness behaviour to standard E-glass surfboard materials. The double-biased carbon also improved the flexural strength (+17%), material toughness (+107%), and fracture toughness (+156%) of the composite compared to E-glass. These findings indicate surfboard manufacturers can utilise this carbon weave pattern to produce surfboards with equal flex behaviour, lower weight and improved resistance to damage in regular loading. Full article

The increase in waste has motivated the adoption of the circular economy concept, which assumes particular relevance in the case of plastic materials. This has led to research of new possibilities for recycling plastics after their end-of-life. To achieve this goal, it is fundamental to understand how the materials’ properties change after recycling. This study aims to evaluate the thermal and mechanical properties of recycled plastics, namely polycarbonate (PC), polystyrene (PS), glass fibre-reinforced polyamide 6 (PA6-GF30), and polyethylene terephthalate (PET). With this purpose, injected samples were mechanically recycled twice and compared through thermal and mechanical tests, such as differential scanning calorimetry, hardness, tensile strength, and the melt flow rate. The results show that the amorphous materials used do not suffer significant changes in their properties but exhibit changes in their optical characteristics. The semicrystalline ones present some modifications. PET is the material that suffers the biggest changes, both in its flowability and mechanical properties. This work demonstrates that the mechanical recycling process may be an interesting possibility for recycling depending on the desired quality of final products, allowing for some materials to maintain comparable thermal and mechanical properties after going through the recycling process. Full article

A major societal issue of disposal and environmental pollution is raised by the enormous and fast-growing production of single-use polyethylene terephthalate (PET) bottles, especially in developing countries. To contribute to the problem solution, an original route to recycle PET in the form of value-added environmentally friendly thermoplastic composites with banana fibres (Musa acuminata) has been developed at the laboratory scale. Banana fibres are a so far undervalued by-product of banana crops with great potential as polymer reinforcement. The melt-processing constraints of commercial PET, including used bottles, being incompatible with the thermal stability limits use of natural fibres; PET has been modified with bio-sourced reactants to produce co-polymers with moderate processing temperatures below 200 °C. First, commercial PET were partially glycolyzed with 1.3-propanediol to produce co-oligomers of about 20 repeating units, which were next chain extended with succinic anhydride and post-treated in a very unusual “soft solid state” process at temperatures in the vicinity of the melting point to generate co-polymers with excellent ductility. The molar mass build-up reaction is dominated by esterification of the chain ends and benefits from the addition of succinic anhydride to rebalance the acid-to-hydroxyl end-group ratio. Infra-red spectroscopy and intrinsic viscosity were extensively used to quantify the concentration of chain ends and the average molar mass of the co-polymers at all stages of the process. The best co-polymers are crystallisable, though at slow kinetics, with a T_g of 48 °C and a melting point strongly dependent upon thermal history. The composites show high stiffness (4.8 GPa at 20% fibres), consistent with the excellent dispersion of the fibres and a very high interfacial cohesion. The strong adhesion can be tentatively explained by covalent bonding involving unreacted succinic anhydride in excess during solid stating. A first approach to quantify the sustainable benefits of this PET recycling route, based on a rational eco-selection method, gives promising results since the composites come close to low-end wood materials in terms of the stiffness/embodied energy balance. Moreover, this approach can easily be extended to many other natural fibres. The present study is limited to a proof of concept at the laboratory scale but is encouraging enough to warrant a follow-up study toward scale-up and application development. Full article