Search Results (16)

The paper investigates the process of degumming substandard soybean oil using an enzyme complex of phospholipases to prepare it as a feedstock for biodiesel production. Dehumidification is an important refining step aimed at reducing the phosphorus content, which exceeds the permissible limits according to ASTM, EN, and ISO standards, by re-moving phospholipids. The enzyme complex of phospholipases includes phospholipase C, which specifically targets phosphatidylinositol, and phospholipase A2, which catalyzes the hydrolysis of phospholipids into water-soluble phosphates and lysophospholipids. This process contributes to the efficient removal of phospholipids, increased neutral oil yield, and reduced residual oil in the humic phase. The use of an enzyme complex of phospholipases provides an innovative, cost-effective, and environmentally friendly method of oil purification. The results of the study demonstrate the high efficiency of using the phospholipase enzyme complex in the processing of substandard soybean oil, which allows reducing the content of total phosphorus to 0.001% by weight, turning it into a high-quality raw material for biodiesel production. The proposed approach contributes to increasing the profitability of agricultural raw materials and the introduction of environmentally friendly technologies in the field of renewable energy. Full article

Polymer flooding has been gradually applied in Chinese offshore oilfields to enhance oil recovery (EOR). Injectivity loss during polymer flooding is a common issue that could cause lower displacement speed and efficiency, and eventually compromise the polymer flooding result. This paper presents a case study of a Chinese offshore field where injectivity loss issues were encountered in the polymer flooding project. A series of measures are applied to enhance the injectivity. The injectivity enhancement strategies are proposed and conducted from three main aspects, namely, (1) surface polymer fluid preparation; (2) downhole wellbore stimulation; and (3) reservoir–polymer compatibility, respectively. For the surface polymer fluid preparation, a series of sieve flow tests are conducted to obtain the optimal mesh size to improve the polymer fluid preparation quality and reduce the amount of “fish eyes”. The downhole wellbore stimulations involve oxidization-associated acidizing treatment and re-perforation. Polymer–reservoir compatibility tests are conducted to optimize the molecular weight (MW). Regarding the surface measures, the optimal filtration sieve mesh number is 200, which could reduce fish eyes to a desirable level without causing mesh plugging. After mesh refinement, the average injection pressure of the twelve injection wells decreases by 0.5 MPa. For the downhole stimulations, acidizing treatment are applied to six injection wells, which decreases the injection pressures by 6 to 7 MPa. For Well A, where acidizing does not work, the re-perforation measure is used and enhances the injectivity by 300%. Moreover, the laboratory and field polymer–reservoir compatibility tests show that the optimal polymer molecular weight (MW) is sixteen million. Proposed strategies applied from the surface, downhole, and reservoir aspects could be used to resolve different levels of injectivity loss, which could provide guidance for future offshore polymer projects. Full article

Motivated by South Africa’s need for the transition to a net-zero economy, this study investigates the integration of renewable energy sources (RESs) into oil refineries, considering the unique challenges and opportunities therein. The research focuses on optimising RES allocation using particle swarm optimisation (PSO), a data-driven approach that adapts to real-time operational conditions. Traditional energy management systems often struggle with the inherent variability of RESs, leading to suboptimal energy distribution and increased emissions. Therefore, this study proposes a PSO-based renewable energy allocation strategy specifically designed for oil refineries. It considers factors like the levelised cost of energy, geographical location, and available technology. The methodology involves formulating the optimisation problem, developing a PSO model, and implementing it in a simulated oil refinery environment. The results demonstrate significant convergence of the PSO algorithm, leading to an optimal configuration for integrating RESs and achieving cost reductions and sustainability goals. The optimisation result of ZAR 4,457,527.00 achieved through iterations is much better than the result of ZAR 4,829,638.88 acquired using linear programming as the baseline model. The mean cost, indicating consistent performance, has remained at its original value of ZAR 4,457,527.00, highlighting the convergence. The key findings include the average distance measurement decreasing from 4.2 to 3.4, indicating particle convergence; the swarm diameter decreasing from 4.7 to 3.8, showing swarm concentration on promising solutions; the average velocity decreasing from 7.8 to 4.25, demonstrating refined particle movement; and the optimum cost function achieved at ZAR 4,457,527 with zero standard deviation, highlighting stability and optimal solution identification. This research offers a valuable solution for oil refineries seeking to integrate RESs effectively, contributing to South Africa’s transition to a sustainable energy future. Full article

The use of recycled materials is necessary to realize the green transition towards carbon neutrality. Several waste products are highly valued materials that cannot be landfilled without exploiting their full potential. Promoting the circular economy concept, this study aims to produce more sustainable paving materials using selected recycled products in binders and asphalt mixes. Rubber (R) from End-of-Life Tyres (ELTs) and Re-refined Engine Oil Bottom (REOB), i.e., the by-product of waste lubricants refining, were employed to produce extended bitumens (25%wt. bitumen replacement) trying to solve the ELTs and REOBs large production, thus disposal, worldwide. In addition, recycled aggregates from various urban and industrial sources were used to halve the quantity of virgin mineral aggregates in the developed asphalt mixtures. Considering two different types of REOBs, two mass proportions of R and REOB and two production temperatures of extended bitumens, eight asphalt mixes containing about 50%wt. of recycled materials were manufactured and underwent to preliminary mechanical tests. The stiffness, tensile and moisture resistances of the greener asphalt concretes were evaluated and compared to two reference mixes: one mainly consisted of virgin materials, and another contained 50%wt. of recycled aggregates and neat bitumen. The eight greener mixes exhibited promising responses in terms of stiffness and tensile strength, showing better intermediate values than the reference ones, but more water susceptibility. Full article

Stream and river monitoring have an influential role in agriculture, the fishing industry, land surveillance, the oil and gas industry, etc. Recognizing sudden changes in the behavior of streamflow could also provide tremendous insight for decision-making and administration purposes. The primary purpose of this study is to offer a new robust Regime Shift Change Detection (RSCD) algorithm which can identify periods and regime changes without any assumptions regarding the length of these periods. A regime shift algorithm using two different refined method approaches is proposed in this article. The RSCD with Relative Difference (RSCD-RD) and RSCD with Growth Rate (RSCD-GR) are the two main specializations of this regime shift algorithm. We compared these two specializations on train and test datasets and commented on the advantages and each specialization. RSCD-GR and RSCD-RD were equally effective in detecting regime changes when thresholds were pinpointed for each station and season. However, RSCD-RD outperformed RSCD-GR when general thresholds were used for cold and warm months. A strength of RSCD-GR is the ability to investigate newly observed data separately, while RSCD-RD may require re-investigation of historical data in some cases. A regime change was detected in the monthly streamflow data of the Athabasca River at Athabasca (07BE001) in May 2007, while no such change was observed in the monthly streamflow data of the Athabasca River below Fort McMurray (07DA001). The discrepancy could be attributed to factors such as the clarity of the river water from Saskatchewan or the utilization of industrial water. Additional investigation might be required to determine the underlying causes. Full article

The lubricating oil industry is widespread in the world, but getting rid of the used oils has become an environmental concern. Lubricating oils are used in industries and cars but potentially contaminate groundwater after use. This research uses montmorillonite clay to refine old oil treated with acetic acid. Compared to more conventional procedures, the suggested strategy for treating waste oil is more cost-effective due to the relatively inexpensive cost of the acid and the modest process conditions. Water content, sediment content, density, flash and fire points, viscosity, viscosity index, total acid and base number, pour points, and refractive index were among the physicochemical parameters of the treated oil that were examined as a result of this treatment. We analyzed the oils using Fourier transform infrared spectroscopy (FTIR) and atomic absorption spectrometry (AAS). New oil (10w 40), old oil, oil treated with acetic acid, and montmorillonite clay were all put through their paces in a battery of tests. The therapy’s physical and chemical alterations were examined across all fields. The findings demonstrated the efficiency of montmorillonite clay due to the strength of the acid to separate the sludge and the lack of compounds hazardous to the environment. The process described here enables recycled oil to be reclaimed as base oil. Full article

Separation of free fatty acids and triglycerides is important in the edible oil industry. In this study, both experimental and simulation approaches were conducted using falling film molecular distillation. A binary mixture of oleic acid as free fatty acid with refined soybean oil as triglyceride was used. Evaporation temperature range tested was from 110 to 160 °C, while other parameters such as condensation temperature, feeding rate, and vacuum pressure were fixed. The free fatty acid content of retentate was gradually decreased as evaporation temperature increased, while the free fatty acid content of distillate was approximately 100 wt.%, regardless of temperature. Triglycerides had an extremely low vapor pressure compared to oleic acid; therefore, their fraction in distillate was negligible. The mass conservation and transport equations were selected to explain the evaporation mechanism, and analytical solutions were simply introduced under the conditions of low mass fraction of volatile compound in the feeding mixture. Some experimental data are re-quired to determine the coefficient of molecular distillation in the governing equation. Using this obtained parameter, the proposed model could simulate all mass amounts and fractions of each component in retentate and distillate with a good agreement between experimental and simulation data, indicating the reasonable accuracy of the model proposed. Full article

Used Lubricant Oil (ULO) is a hazardous waste resulting from lubricant oil used in motorized equipment to reduce friction between moving surfaces that, over time, wear outs and becomes contaminated. The purpose of this study is to compare the sustainability of two ULO management systems in Brazil: one designated in this study by the TTR scenario (which includes transportation, trans-shipment, and re-refining phases), the other designated by the TsTR scenario (without the trans-shipment phase) to evaluate which scenario is socially, economically, and environmentally more efficient. The study uses the life cycle sustainability assessment (LCSA) methodology. As a combination of life cycle assessment (LCA), life cycle cost (LCC), and social life cycle assessment (s-LCA), it integrates the three sustainability dimensions (environmental, social, and economic). The sustainability index was calculated by aggregating data from eight environmental indicators, five economic indicators, and five social indicators. The results showed that the TsTR scenario presented the best values for the sustainability assessment than the TTR scenario. The TsTR scenario had the best social and economic performance, and the TTR scenario had the best environmental performance. The differences observed in those scenarios’ performances were noted by the absence or presence of the trans-shipment center. The absence of this center improved the social and economic performance of the scenario. The social dimension was improved by the elimination of the stage that causes problems related to social and economic dimensions by reducing several costs that can be associated with it. The presence of the trans-shipment center improves the environmental performance scenario by reducing the number of hazards that could impact the re-refining phase. The LCSA methodology enables a comparative life cycle assessment of two alternative system evaluations of ULO management by the sustainability index of each scenario. This index helps to analyze the contributions of each of the 18 categories and subcategories in the perspective of the sustainability dimensions and, consequently, to carry out their integrated evaluation, aiming to define the best sustainability scenario. Full article

Recent studies have worked towards addressing environmental issues such as global warming and greenhouse gas emissions due to the increasing awareness of the depletion of natural resources. The asphalt industry is seeking to implement measures to reduce its carbon footprint and to promote sustainable operations. The reuse of several wastes and by-products is an example of a more eco-friendly activity that fulfils the circular economy principle. Among all possible solutions, the road pavement sector encourages, on one hand, the use of recycled materials as a partial replacement of the virgin lithic skeleton; on the other hand, it promotes the use of recycled materials to substituting for a portion of the petroleum bituminous binder. This study aims to use Re-refined Engine Oil Bottoms (REOBs) as a main substitute and additives from various industrial by-products as a full replacement for virgin bitumen, producing high-performing alternative binders. The REOBs have been improved by utilizing additives in an attempt to improve their specific properties and thus to bridge the gap between REOBs and traditional bituminous binders. An even larger amount of virgin and non-renewable resources can be saved using these new potential alternative binders together with the RAP aggregates. Thus, the reduction in the use of virgin materials is applied at the binder and the asphalt mixture levels. Rheological, spectroscopic, thermogravimetric, and mechanical analysis were used to characterize the properties, composition, and characteristics of the REOBs, REOB-modified binders, and asphalt mixes. Thanks to the rheological investigations of possible alternative binders, 18 blends were selected, since they behaved like an SBS-modified bitumen, and then they were used for producing the corresponding asphalt mixtures. The preliminary mechanical analysis of the asphalt mixtures shows that six mixes have promising responses in terms of stiffness, tensile resistance, and water susceptibility. Nevertheless, the high variability of recycled materials and by-products has to be taken into consideration during the definition of alternative binders and recycled asphalt mixtures. In fact, this study highlights the crucial effects of the chemical composition of the constituents and their compatibility on the behaviour of the final product. This preliminary study represents a first attempt to define alternative binders, which can be used in combination with recycled aggregates for producing more sustainable road materials. However, further analysis is necessary in order to assess the durability and the ageing tendency of the materials. Full article

On average, approximately 22 thousand tons of new lubrication oil were marketed annually in Serbia in the period 2015–2019. Less than 20% of the waste lubrication oil (WLO) generated was treated, whereas the remainder was mostly uncollected or improperly disposed of. The purpose of this study is to examine different WLO management scenarios that could be implemented in Serbia in the future and to quantify their potential environmental benefits. Different WLO treatment processes (namely the re-refining of used oil for base oil recovery, the use of WLO as a substitute to fossil fuels in cement kilns, and the combustion of WLO in waste incinerators with energy recovery) were evaluated using the life cycle assessment (LCA) and ReCiPe 2016 impact assessment methods. The LCA results obtained indicate that no single WLO treatment process consistently exerts diminished environmental impacts according to all the impact categories considered. From a human health perspective, the incineration of WLO in waste incinerators was found more favourable than the other treatment processes considered, whereas the combustion in cement kilns was the most favourable approach with regard to ecosystem protection. In terms of fossil fuel savings, re-refining technologies performed slightly better than the other processes considered. This can be accounted for by significant amounts of marketable co-products generated in the re-refining process, which can be used as a substitute to fossil-based primary products. Furthermore, a total of four possible WLO management scenarios were developed on the basis of the annual quantities of untreated WLO and a mix of treatment options. The results obtained indicate that up to 22,100 t CO₂ equivalent and 34,300 t oil equivalent could be saved annually in Serbia provided the most favourable WLO management scenario is considered. Full article

Petroleum-derived products, such as lubricant oils, are non-renewable resources that, after use, must be collected and processed properly to avoid negative environmental impacts. A circular economy of used oils requires the re-refining and reuse of the same. Similar to most countries in Latin America, the management of used oils in Ecuador is still incipient and few cities collect and treat this material properly. In Cuenca, the ETAPA company collects ~1344 t/year of used oils, which are subjected to pretreatment operations prior to their use as fuel in a cement factory. However, combustion generates polluting gases and disallows the adding of value to the used oils. The lack of studies on the characterization and methods utilized for recovering used oils under the conditions found in medium-size Latin-American cities (e.g., Cuenca), alongside a lack of government policies, have hindered the adoption of re-refining operations. The objective of this work is to characterize the used lubricant oils in Cuenca, to compare them with the properties of used oils from other countries, and to suggest some re-refining technologies for oils with similar properties. Used oil samples were collected from mechanic shops and car-lubricating shops for characterization. Its physicochemical properties and metal contents are comparable to the used oils in other countries globally. Specifically, the flash point, kinematic viscosity, TBN, and concentrations of Zn, Cd, and Mg are similar to the properties of used oils in Iraq, Egypt, and the United Arab Emirates. Based on these results, the best re-refining option for used oils in Cuenca is extraction with solvents in which sedimentation and dehydration (already conducted in Cuenca) is followed by a solvent reaction process, a vacuum distillation process, a finishing process with bentonite, and a final filtration step. Full article

Thanks to greater attention to the environment and the depletion of non-renewable resources, the sustainability and the circular economy have become crucial topics. The current trend of pavement engineering is to reduce the use of standard bitumen by replacing it with more sustainable materials such as industrial residues and by-products. In this regard, the present study aims to characterize innovative extended bitumen using recycled materials. Due to promising preliminary results as bitumen modifiers, the powdered rubber from end-of-life tires and the re-refined engine oil bottom (REOB) have been investigated as feasible components of bitumen extenders. Nevertheless, several variables strongly affect the performance of the resulting binder, which cannot be neglected. Hence, this research focuses on the rubber–REOB interaction in order to evaluate their optimum ratio, which may maximize the use and advantages of both recycled materials as suitable partial replacements for bitumen. Various rubber–REOB ratios were considered and investigated by means of low and high frequency nuclear magnetic resonance (NMR) spectrometers and scanning electron microscope (SEM). Full article

An attempt was made to study the corrosion behavior of austenitic stainless-steel SS 316L/Monel 400 alloy dissimilar metal welded joints using gas tungsten arc welding. This combination of welded joints is used in re-heaters and heat exchangers in gas processing and oil refining industries. The welded specimens were subjected to post-weld treatments, such as annealing and deep cryogenic treatment. The welded specimens were sectioned into five different parts: SS 316L base, SS 316L HAZ, weld, Monel HAZ, and Monel base. The polarization method and electrochemical impedance analysis were used to analyze the corrosion resistance in a NaCl solution. A polarization graph, Nyquist plot, and Bode plot were constructed for all regions, separately, for the heat-treated and cryo-treated specimens, to analyze the variation in corrosion resistance in different regions, and then the results were compared. To validate the results of electrochemical impedance analysis, scanning electron microscope (SEM) and energy dispersive spectroscope (EDS) analyses were also performed. The results indicated that the cryo-treated specimens have better corrosion resistance when compared to the annealed ones. Weld region on both specimens exhibited better corrosion resistance when compared to other zones. Full article

Activated clay minerals have been widely used in the edible oil refining industry for decolorization of crude oil by adsorption, and so far many methods have been used to improve their decolorization efficiency. Herein, we successfully prepared a series of carbon/attapulgite (C/APT) composite adsorbents by a one-step in-situ carbonization process with natural starch (St) as the carbon source. It has been revealed that the adsorbent had better decolorization efficiency for crude palm oil than acid-activated APT. However, more than a million tons of decolorized waste is produced every year in the oil-refining industry, which was often treated as solid waste and has not yet been reutilized effectively. In order to explore a viable method to recycle and reuse the decolorant, the waste decolorant was further prepared into new C/APT adsorbents for the removal of dyes from wastewater, and then the dyes adsorbed on the adsorbent were used as the carbon sources to produce new C/APT adsorbents by a cyclic carbonization process. The results showed that the adsorbents prepared from the decolorized waste could remove more than 99.5% of the methylene blue (MB), methyl violet (MV), and malachite green (MG) dyes from the simulated wastewater with the dye concentration of 200 mg/L, and the C/APT–Re adsorbent consecutively regenerated five times using the adsorbed dyes as a carbon source still exhibit good adsorption efficiency for dyes. As a whole, this process opens a new avenue to develop efficient decolorants of palm oil and achieves recyclable utilization of decolored waste. Full article

Pyrolysis is considered the most promising way to convert biomass to fuels. Upgrading biomass pyrolysis oil is essential to produce high quality hydrocarbon fuels. Upgrading technologies have been developed for decades, and this review focuses on the hydrodeoxygenation (HDO). In order to declare the need for upgrading, properties of pyrolysis oil are firstly analyzed, and potential analysis methods including some novel methods are proposed. The high oxygen content of bio-oil leads to its undesirable properties, such as chemical instability and a strong tendency to re-polymerize. Acidity, low heating value, high viscosity and water content are not conductive to making bio-oils useful as fuels. Therefore, fast pyrolysis oils should be refined before producing deoxygenated products. After the analysis of pyrolysis oil, the HDO process is reviewed in detail. The HDO of model compounds including phenolics monomers, dimers, furans, carboxylic acids and carbohydrates is summarized to obtain sufficient information in understanding HDO reaction networks and mechanisms. Meanwhile, investigations of model compounds also make sense for screening and designing HDO catalysts. Then, we review the HDO of actual pyrolysis oil with different methods including two-stage treatment, co-feeding solvents and in-situ hydrogenation. The relative merits of each method are also expounded. Finally, HDO catalysts are reviewed in order of time. After the summarization of petroleum derived sulfured catalysts and noble metal catalysts, transitional metal carbide, nitride and phosphide materials are summarized as the new trend for their low cost and high stability. After major progress is reviewed, main problems are summarized and possible solutions are raised. Full article