Search Results (17)

The dynamic relationship between microplastics (MPs) in the air and on the Earth’s surface involves both natural and anthropogenic forces. MPs are transported from the ocean to the air by bubble scavenging and sea spray formation and are released from land sources by air movements and human activities. Up to 8.6 megatons of MPs per year have been estimated to be in air above the oceans. They are distributed by wind, water and fomites and returned to the Earth’s surface via rainfall and passive deposition, but can escape to the stratosphere, where they may exist for months. Anthropogenic sprays, such as paints, agrochemicals, personal care and cosmetic products, and domestic and industrial procedures (e.g., air conditioning, vacuuming and washing, waste disposal, manufacture of plastic-containing objects) add directly to the airborne MP load, which is higher in internal than external air. Atmospheric MPs are less researched than those on land and in water, but, in spite of the major problem of a lack of standard methods for determining MP levels, the clothing industry is commonly considered the main contributor to the external air pool, while furnishing fabrics, artificial ventilation devices and the presence and movement of human beings are the main source of indoor MPs. The majority of airborne plastic particles are fibers and fragments; air currents enable them to reach remote environments, potentially traveling thousands of kilometers through the air, before being deposited in various forms of precipitation (rain, snow or “dust”). The increasing preoccupation of the populace and greater attention being paid to industrial ecology may help to reduce the concentration and spread of MPs and nanoparticles (plastic particles of less than 100 nm) from domestic and industrial activities in the future. Full article

The chemistry of atmospheric precipitation serves as an important proxy for discriminating the source(s) of air contaminants in urban environments as well as to discuss the dynamic of atmospheric chemistry exchanges. This approach can be undertaken at time scales varying from single events to seasonal and yearly time frames. Here, we characterized the chemical composition of two single rain episodes (18 July 2018 and 21 February 2019) collected in Wrocław (SW Poland). Our results demonstrated inner variations and seasonality (within the rain event as well as between summer and winter), both in ion concentrations as well as in their potential relations with local air contaminants and scavenging processes. Coupling statistical analysis of chemical parameters with meteorological/synoptic conditions and HYSPLIT back trajectories allowed us to identify three main factors (i.e., principal components; PC) controlling the chemical composition of precipitation, and that these fluctuated during each event: (i) PC1 (40%) was interpreted as reflecting the long-range transport and/or anthropogenic influences of emission sources that included biomass burning, fossil fuel combustion, industrial processes, and inputs of crustal origin; (ii) PC2 (20%) represents the dissolution of atmospheric CO₂ and HF into ionic forms; and (iii) PC3 (20%) originates from agricultural activities and/or biomass burning. Time variations during the rain events showed that each factor was more important at the start of the event. The study of both SO₄²⁻ and Ca²⁺ concentrations showed that while sea spray inputs fluctuated during both rain events, their overall impact was relatively low. Finally, below-cloud particle scavenging processes were only observed for PM₁₀ at the start of the winter rain episode, which was probably explained by the corresponding low rain intensity and an overlap from local aerosol emissions. Our study demonstrates the importance of multi-time scale approaches to explain the chemical variability in rainwater and both its relation to emission sources and the atmosphere operating processes. Full article

Semi-volatile organic contaminants (SVOCs) are known for their tendency to evaporate from source regions and undergo atmospheric transport to distant areas. Cold condensation intensifies dry deposition, particle deposition, and scavenging by snow and rain, allowing SVOCs to move from the atmosphere into terrestrial and aquatic ecosystems in alpine and polar regions. However, no standardized methods exist for the sampling, laboratory processing, and instrumental analysis of persistent organic pollutants (POPs) in snow. The lack of reference methods makes these steps highly variable and prone to errors. This study critically reviews the existing literature to highlight the key challenges in the sampling phase, aiming to develop a reliable, consistent, and easily reproducible technique. The goal is to simplify this crucial step of the analysis, allowing data to be shared more effectively through standardized methods, minimizing errors. Additionally, an innovative method for laboratory processing is introduced, which uses activated carbon fibers (ACFs) as adsorbents, streamlining the analysis process. The extraction method is applied to analyze polychlorobiphenyls (PCBs) and chlorinated pesticides (α-HCH, γ-HCH, p,p′-DDE, o,p′-DDT, HCB, and PeCB). The entire procedure, from sampling to instrumental analysis, is subsequently tested on snow samples collected on the Svalbard Islands. To validate the efficiency of the new extraction system, quality control measures based on the EPA methods 1668B and 1699 for aqueous methods are employed. This study presents a new, reliable method that covers both sampling and lab analysis, tailored for detecting POPs in snow. Full article

Most research on air chemistry and human health has focused on negative consequences of air pollution from cities, rural dust, mining, or industrial sites. Research on nature tourism and nature therapy, in contrast, focuses on positive benefits of air quality for physical and mental health, e.g., via “clean air clean water” holidays. Aeroanions and terpenoids in forests have received particular attention, especially in China, Japan, and Korea. We review and analyse several hundred articles published in English and Chinese. With a few recent exceptions, English-language research has tested indoor negative ion generators, and concluded that they have no measurable health benefit. It has tested terpenoids in indoor aroma marketing. Chinese-language research, in contrast, has analysed fine-scale components of outdoor environments that affect concentrations of aeroanions and terpenoids: ecosystem, latitude, altitude, temperature, proximity to water, and individual plant species. Historically, health outcomes have been taken for granted, with little rigorous testing. Air quality research has shown that aeroanions can become attached to fine water droplets, e.g., after rain in forests, or in mists produced locally by waterfalls. We hypothesise that the health benefits of aeroanions in natural environments may arise through the scavenging of airborne particulates by negatively charged mists, creating especially clean, dust-free air. We propose that this particularly clean-tasting air, contrasting strongly with polluted urban air, creates positive effects on human mental health and perhaps, also on pulmonary physical health. Mechanisms and outcomes remain to be tested. We also propose testing psychological health effects of airborne terpenoid scents from forest trees. Full article

To investigate the variation in aerosol particles removed by rainfall, we determined the relationship between aerosols and raindrops observed on Jeju Island, Korea, during a heavy rainfall period (Changma) from 1–15 July 2012. Various instruments, including an aerodynamic particle sizer, rain gauge, and disdrometer, were installed at the Gosan meteorological observation site on Jeju Island. During the Changma period, precipitation between 0.7 and 25.4 mm per day was recorded, and large variations in aerosol and raindrop size distributions were observed. Aerosol removal by precipitation was indicated, and its scavenging effect was confirmed from the results. Three major parameters (Brownian diffusion, interception, and impaction) described the collision efficiency based on aerosol and raindrop size distributions. The variations in the scavenging coefficient and below-cloud scavenging rate produced similar results for the accumulated rain amount. Therefore, these field observations explained the relationship between aerosol and raindrop size distributions. Full article

Legumes play an important role in ensuring food security, improving nutrition and enhancing ecosystem resilience. Chickpea is a globally important grain legume adapted to semi-arid regions under rain-fed conditions. A growing body of research shows that aldehyde dehydrogenases (ALDHs) represent a gene class with promising potential for plant adaptation improvement. Aldehyde dehydrogenases constitute a superfamily of proteins with important functions as ‘aldehyde scavengers’ by detoxifying aldehydes molecules, and thus play important roles in stress responses. We performed a comprehensive study of the ALDH superfamily in the chickpea genome and identified 27 unique ALDH loci. Most chickpea ALDHs originated from duplication events and the ALDH3 gene family was noticeably expanded. Based on the physical locations of genes and sequence similarities, our results suggest that segmental duplication is a major driving force in the expansion of the ALDH family. Supported by expression data, the findings of this study offer new potential target genes for improving stress tolerance in chickpea that will be useful for breeding programs. Full article

A “rain-only” method is proposed to find out the precipitation effect on particle aerosol removal from the atmosphere, and this method is not only unique and novel but also very simple and can be easily adapted to predict aerosol particle scavenging over any region across the world irrespective of the topographical, orographical, and climatic features. By using this simple method, the influences of the rain intensity and particle mass concentration on the aerosol scavenging efficiency are discussed. The results show that a higher concentration, a higher rain intensity, and a larger particle size lead to a higher scavenging efficiency and a higher scavenging rate. The greater the rain intensity, the higher the scavenging efficiency. The scavenging efficiency of PM₁₀ by precipitation is better than that of PM_2.5. When the rain intensity is 10 mm h⁻¹, the scavenging efficiency of PM_2.5 reaches 5.1 μg m⁻³ h⁻¹, and the scavenging efficiency of PM₁₀ reaches 15.8 μg m⁻³ h⁻¹. The scavenging rate increases faster when accumulative precipitation is below 15 mm. The scavenging rate has obvious monthly variation, and the scavenging rate of coastal areas is less than that of inland Jiangsu. The growth of the particle mass concentration after precipitation is divided into two stages: the rapid growth stage after precipitation ends, and the slow growth stage about 24 h after precipitation ends. Full article

Alginate oligosaccharides (AOS) are known for functions in regulating plant growth and stress resistance. This study investigated the damage on rice leaves caused by acid rain (AR) and high temperature (HT) simultaneously, as well as the alleviating effect of AOS on these stresses. The results show that plant biomass and antioxidant enzyme activities (AEAs) after AR treatment reduced more severely under HT conditions than normal-temperature conditions. Both AR and HT triggered the accumulation of reactive oxygen species (ROS) in rice leaves. The suppressing effects of AR and HT were individual in most cases, except for AEAs. Microscopic analysis showed that pH 2 AR and HT injured leaf epidermis, particularly the bulliform cells, the veins and interveinal regions. Spraying AOS resulted in a slight elevation of biomass, a significant increase in AEAs and a remarkable decline in ROS concentrations under HT conditions with AR. Besides, the chlorophyll a contents of a leaf after pH 2 AR plus AOS treatment under HT conditions remained 66.1% of that after pH 7 treatment under normal-temperature conditions. Moreover, AOS protected the integrity of leaf tissue even after pH 3 treatment. Taken together, the above results suggest that AR and HT inhibited AEAs, led to the accumulation of ROS and damaged rice leaf. However, foliar applying AOS enhanced AEAs, scavenged ROS, and thus alleviated the stress induced by HT and AR. Full article

The Mediterranean region is frequently affected in autumn by heavy precipitation that causes flash-floods or landslides leading to important material damage and casualties. Within the framework of the international HyMeX program (HYdrological cycle in Mediterranean EXperiment), this study aims to evaluate the capabilities of two models, WRF (Weather Research and Forecasting) and DESCAM (DEtailed SCAvenging Model), which use two different representations of the microphysics to reproduce the observed atmospheric properties (thermodynamics, wind fields, radar reflectivities and precipitation features) of the HyMeX-IOP7a intense precipitating event (26 September 2012). The DESCAM model, which uses a bin resolved representation of the microphysics, shows results comparable to the observations for the precipitation field at the surface. On the contrary, the simulations made with the WRF model using a bulk representation of the microphysics (either the Thompson scheme or the Morrison scheme), commonly employed in NWP models, reproduce neither the intensity nor the distribution of the observed precipitation—the rain amount is overestimated and the most intense cell is shifted to the East. The different simulation results show that the divergence in the surface precipitation features seems to be due to different mechanisms involved in the onset of the precipitating system: the convective system is triggered by the topography of the Cévennes mountains (i.e., south-eastern part of the Massif Central) in DESCAM and by a low-level flux convergence in WRF. A sensitivity study indicates that the microphysics properties have impacted the thermodynamics and dynamics fields inducing the low-level wind convergence simulated with WRF for this HyMeX event. Full article

Regional-scale field observations of fine particles (PM_2.5) were carried out at urban, suburban and regional background sites across the Yangtze River Delta (YRD) from 15–30 January 2015. The coefficients of divergence (CD) values reveal the similarity of dataset at the three sites. The PM_2.5 concentrations and meteorological data exhibit temporal synchronization. From January 15 to 26, the YRD experienced severe PM_2.5 pollution resulting from a cold front moving through and high-pressure control. Then, a 4-day intermittent rain event from 27–30 January significantly scavenged PM_2.5. For the chemical components in PM_2.5, secondary inorganic ions were dominant, and they accounted for larger proportions at the urban and suburban sites than at the regional background site. The OC/EC ratios were higher in daytime than at night, and were lower on polluted days than on clean (rainy) days. The principal sources of PM_2.5 were secondary nitrate (38%) and sulfate (23%) formation, biomass burning (14%), and marine source (8%). Marine (16%) and sulfate (30%) sources were enhanced on clean (rainy) days, indicating the notable effect of marine air masses on PM_2.5 chemical components. The open burning source contribution at the regional site was the largest during the polluted period because more air masses arrived from combustion zones. Full article

Today, good food criteria also include healthy capacity. So, the wine on our table should not only have good organoleptic qualities, but should be characterized by a high healthy potential. For the first time, extensive research was conducted on commercial red wine grape varieties cultivated in different Bulgarian regions in two consecutive years. Antioxidants, including trans-resveratrol, quercetin, and total phenolic content and antioxidant potential in wine grapes and wines were determined by HPLC, UV, and NIR methods. The results obtained showed similar concentration levels compared to the same varieties, produced in other countries. Trans-resveratrol showed the greatest contribution to the radical scavenging capacity. The factor with largest impact on the content of the tested substances was definitely the variety. Among agro-meteorological condition, temperature amplitude, rain fall, and UV irradiation before ripening had strong influences. Maintaining the balance between the level of synthesized and degraded and captured antioxidants during the wine making process was crucial to preserving the antioxidant properties of the final wine product. NIR spectroscopy showed very good accuracy of determination of trans-resveratrol, quercetin, total phenolic content, and the antioxidant activity of tested grape varieties and red wines. It could be a promising technique in the quantification of their antioxidant parameters. Full article

The processes removing aerosols from the atmosphere during rainfall are generically referred to as scavenging. Scavenging influences aerosol distributions in the atmosphere, with consequent effects on cloud properties, radiative forcing, and human health. In this study, we investigated the below-cloud scavenging process, specifically focusing on the scavenging of 0.2 to 2 µm-sized microbial aerosols by populations of water drops with average diameters of 3.0 and 3.6 mm. Rainfall was simulated in convective boundary layer air masses by dispensing the water drops from a 55 m bridge and collecting them at ground level. Particles and microbial cells scavenged by the water drops were visualized, enumerated, and sized using scanning electron and epifluorescence microscopy. Aerosolized particles and DNA-containing microbial cells of 2 µm diameter were scavenged at efficiencies similar to those reported previously in empirical studies; however, the efficiencies derived for smaller aerosols were significantly higher (one to three orders of magnitude) than those predicted by microphysical modeling. Application of the derived scavenging efficiencies to cell data from rainfall implies that, on average, approximately 50 to 70% of the 1 µm microbial cells in the precipitation originated from within the cloud. Further study of submicron to micron-sized aerosol scavenging over a broader raindrop size distribution would improve fundamental understanding of the scavenging process and the capacity to estimate (bio)aerosol abundances in the source cloud through analysis of rainfall. Full article

Precipitation modifies atmospheric column thermodynamics through the process of evaporation and serves as a proxy for latent heat modulation. For this reason, a correct precipitation parameterization (especially for low-intensity precipitation) within global scale models is crucial. In addition to improving our modeling of the hydrological cycle, this will reduce the associated uncertainty of global climate models in correctly forecasting future scenarios, and will enable the application of mitigation strategies. In this manuscript we present a proof of concept algorithm to automatically detect precipitation from lidar measurements obtained from the National Aeronautics and Space Administration Micropulse lidar network (MPLNET). The algorithm, once tested and validated against other remote sensing instruments, will be operationally implemented into the network to deliver a near real time (latency <1.5 h) rain masking variable that will be publicly available on MPLNET website as part of the new Version 3 data products. The methodology, based on an image processing technique, detects only light precipitation events (defined by intensity and duration) such as light rain, drizzle, and virga. During heavy rain events, the lidar signal is completely extinguished after a few meters in the precipitation or it is unusable because of water accumulated on the receiver optics. Results from the algorithm, in addition to filling a gap in light rain, drizzle, and virga detection by radars, are of particular interest for the scientific community as they help to fully characterize the aerosol cycle, from emission to deposition, as precipitation is a crucial meteorological phenomenon accelerating atmospheric aerosol removal through the scavenging effect. Algorithm results will also help the understanding of long term aerosol–cloud interactions, exploiting the multi-year database from several MPLNET permanent observational sites across the globe. The algorithm is also applicable to other lidar and/or ceilometer network infrastructures in the framework of the Global Aerosol Watch (GAW) aerosol lidar observation network (GALION). Full article

Melatonin is a multifunctional signaling molecule, ubiquitously distributed in different parts of plants and responsible for stimulating several physiological responses to adverse environmental conditions. In the current review, we showed that the biosynthesis of melatonin occurred in plants by themselves, and accumulation of melatonin fluctuated sharply by modulating its biosynthesis and metabolic pathways under stress conditions. Melatonin, with its precursors and derivatives, acted as a powerful growth regulator, bio-stimulator, and antioxidant, which delayed leaf senescence, lessened photosynthesis inhibition, and improved redox homeostasis and the antioxidant system through a direct scavenging of reactive oxygen species (ROS) and reactive nitrogen species (RNS) under abiotic and biotic stress conditions. In addition, exogenous melatonin boosted the growth, photosynthetic, and antioxidant activities in plants, confirming their tolerances against drought, unfavorable temperatures, salinity, heavy metals, acid rain, and pathogens. However, future research, together with recent advancements, would support emerging new approaches to adopt strategies in overcoming the effect of hazardous environments on crops and may have potential implications in expanding crop cultivation against harsh conditions. Thus, farming communities and consumers will benefit from elucidating food safety concerns. Full article

Acid rain is a serious worldwide environmental problem which reduces the growth and yield of crops. Melatonin, as a pleiotropic molecule has been known to improve stress tolerance by limiting the oxidative damage of plants exposed to adverse environments. However, the role of exogenous melatonin particularly on the yield and antioxidant compounds in tomato fruits under abiotic stress condition remains inexpressible. This observation aims to identify the influence of melatonin treatment under simulated acid rain (SAR) condition on fruit qualities, phenolics, flavonoids, and carotenoids concentration in fruits, and yield of tomatoes. Our study results showed that the fruits of SAR-stressed plants had higher quality traits and antioxidant bioactive compounds by increasing antioxidant activities against SAR-induced oxidative stress compared with fruits of control plants. Nonetheless, these improvements to antioxidant activities in fruits under SAR-condition remained unable to prevent the reduction of the yield. However, SAR-stressed plants treated by melatonin exhibited upgradation on the fruit quality traits, antioxidant compounds and yield attributes through accelerating oxidant-scavenging antioxidant actions in fruits compared with fruits of SAR-stressed plants. Meanwhile, our results suggest that exogenous melatonin plays an important role in improvement of bioactive compounds and yield traits in tomato fruits through regulating antioxidant system. Full article