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Keywords = qiongzhusi formation

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22 pages, 16632 KiB  
Article
Multiscale Characterization of Pore Structure and Heterogeneity in Deep Marine Qiongzhusi Shales from Southern Basin, China
by Majia Zheng, Yana Chen, Tingke Tang, Ya Wu, Ying Chen, Junyu Chen, Shixuan Peng and Jizhen Zhang
Minerals 2025, 15(5), 515; https://doi.org/10.3390/min15050515 - 14 May 2025
Viewed by 410
Abstract
The pore structure of shale is a critical factor influencing the occurrence and flow of shale gas. Characterizing the pore structure and studying its heterogeneity are of paramount importance for a deeper understanding of the laws governing hydrocarbon occurrence, as well as for [...] Read more.
The pore structure of shale is a critical factor influencing the occurrence and flow of shale gas. Characterizing the pore structure and studying its heterogeneity are of paramount importance for a deeper understanding of the laws governing hydrocarbon occurrence, as well as for enhancing the efficiency of exploration and development. This work addresses the complex characteristics of multiscale coupling in the pore systems of shale reservoirs, focusing on the ultra-deep Qiongzhusi Formation shale in the southern region. Through the integrated application of cross-scale observation techniques and physicochemical analysis methods, a refined analysis of the pore structure is achieved. Utilizing field emission scanning electron microscopy imaging technology, the types and morphological characteristics of pores are identified. Additionally, a fluid–solid coupling analysis method employing high-pressure mercury intrusion and low-temperature gas adsorption (CO2/N2) is utilized to elucidate the characteristics of pore structure and heterogeneity while also analyzing the influence of matrix components on these features. The results indicate that the shale of the Qiongzhusi Formation is rich in feldspar minerals, facilitating the development of numerous dissolution pores, with the pore system predominantly consisting of inorganic mineral pores. The full pore size curve of the shale generally exhibits a bimodal characteristic, with a high proportion of mesopores. A strong positive linear relationship is observed between pore volume and specific surface area, whereby larger pore spaces reduce pore heterogeneity, with mesopore volume playing a decisive role. This study provides scientific support for the evaluation and strategic deployment of exploration and development in ultra-deep shale reservoirs of the Qiongzhusi Formation. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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15 pages, 8076 KiB  
Article
Applicability of Machine Learning and Mathematical Equations to the Prediction of Total Organic Carbon in Cambrian Shale, Sichuan Basin, China
by Majia Zheng, Meng Zhao, Ya Wu, Kangjun Chen, Jiwei Zheng, Xianglu Tang and Dadong Liu
Appl. Sci. 2025, 15(9), 4957; https://doi.org/10.3390/app15094957 - 30 Apr 2025
Viewed by 527
Abstract
Accurate Total Organic Carbon (TOC) prediction in the deeply buried Lower Cambrian Qiongzhusi Formation shale is constrained by extreme heterogeneity (TOC variability: 0.5–12 wt.%, mineral composition Coefficient of Variation > 40%) and ambiguous geophysical responses. This study introduces three key innovations to address [...] Read more.
Accurate Total Organic Carbon (TOC) prediction in the deeply buried Lower Cambrian Qiongzhusi Formation shale is constrained by extreme heterogeneity (TOC variability: 0.5–12 wt.%, mineral composition Coefficient of Variation > 40%) and ambiguous geophysical responses. This study introduces three key innovations to address these challenges: (1) A Dynamic Weighting–Calibrated Random Forest Regression (DW-RFR) model integrating high-resolution Gamma-Ray-guided dynamic time warping (±0.06 m depth alignment precision derived from 237 core-log calibration points using cross-validation), Principal Component Analysis-Deyang–Anyue Rift Trough Shapley Additive Explanations (PCA-SHAP) hybrid feature engineering (89.3% cumulative variance, VIF < 4), and Bayesian-optimized ensemble learning; (2) systematic benchmarking against conventional ΔlogR (R2 = 0.700, RMSE = 0.264) and multi-attribute joint inversion (R2 = 0.734, RMSE = 0.213) methods, demonstrating superior accuracy (R2 = 0.917, RMSE = 0.171); (3) identification of Gamma Ray (r = 0.82) and bulk density (r = −0.76) as principal TOC predictors, contrasted with resistivity’s thermal maturity-dependent signal attenuation (r = 0.32 at Ro > 3.0%). The methodology establishes a transferable framework for organic-rich shale evaluation, directly applicable to the Longmaxi Formation and global Precambrian–Cambrian transition sequences. Future directions emphasize real-time drilling data integration and quantum computing-enhanced modeling for ultra-deep shale systems, advancing predictive capabilities in tectonically complex basins. Full article
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17 pages, 3824 KiB  
Article
Machine Learning-Based Mineral Quantification from Lower Cambrian Shale in the Sichuan Basin: Implications for Reservoir Quality
by Xin Ye, Yan Liu, Tianyu Huang, Ting Chen, Chenglin Liu, Sibing Liu and Siding Jin
Minerals 2025, 15(3), 286; https://doi.org/10.3390/min15030286 - 12 Mar 2025
Viewed by 694
Abstract
In this study, cores from Well S1 in the Sichuan Basin were investigated to quantify mineral composition. A neural network analysis was employed to apply machine learning to X-ray fluorescence (XRF) datasets for predicting the mineralogical characteristics of Well S1. A total of [...] Read more.
In this study, cores from Well S1 in the Sichuan Basin were investigated to quantify mineral composition. A neural network analysis was employed to apply machine learning to X-ray fluorescence (XRF) datasets for predicting the mineralogical characteristics of Well S1. A total of 77 sample points were divided into training, validation, and test sets at a ratio of 6:2:2. After training and fine-tuning the model using the training and validation sets, the performance of the neural network model was evaluated with the test set. The best result was achieved for calcite prediction, reaching an R-squared (R2) value of 95%. Predictions for the seven minerals, except quartz, all exhibited R2 values of 80% or higher. Quantitative laboratory-measured X-ray diffraction (XRD) mineralogy was used for training to develop a high-resolution semi-quantitative model, and the resulting mineralogical model shows promising potential. The modeled mineralogy represents continuous relative abundance, which provides more meaningful insights compared to discrete single-point XRD measurements. The significance of this research lies in its ability to utilize relatively inexpensive and non-destructive XRF logging analysis, requiring minimal sample preparation, to construct high-resolution mineral abundance profiles. With modern technological advancements, operators can adopt the proposed method to build semi-quantitative mineralogical models for evaluating potential lateral drilling intervals and designing completion strategies accordingly. Full article
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16 pages, 5239 KiB  
Article
The Distribution Characteristics and Genesis Analysis of Overpressure in the Qiongzhusi Formation in the Zizhong Area, Sichuan Basin
by Xuewen Shi, Yuran Yang, Qiuzi Wu, Yanyou Li, Yifan He, He Tian, Zhenxue Jiang, Zhongyu Bi and Huan Miao
Appl. Sci. 2025, 15(6), 2888; https://doi.org/10.3390/app15062888 - 7 Mar 2025
Cited by 1 | Viewed by 615
Abstract
Accurately predicting the genesis and distribution of reservoir pressure is essential for comprehending the distribution of oil and gas reservoirs while mitigating drilling risks. In the Qiongzhusi Formation of the Sichuan Basin, overpressure has developed, leading to high production levels in several wells. [...] Read more.
Accurately predicting the genesis and distribution of reservoir pressure is essential for comprehending the distribution of oil and gas reservoirs while mitigating drilling risks. In the Qiongzhusi Formation of the Sichuan Basin, overpressure has developed, leading to high production levels in several wells. However, the distribution and causal mechanism of overpressure within the Qiongzhusi Formation remain unclear at present. This study utilizes logging data from representative drilling wells to identify the causes of overpressure in the Qiongzhusi Formation and predict the characteristics of pressure distribution. The results indicate that the pressure coefficient of the Qiongzhusi Formation ranges from 1.01 to 2.05 and increases with burial depth. The overpressure in the Qiongzhusi Formation is attributed to fluid expansion, disequilibrium compaction, and pressure transmission. The contribution of disequilibrium compaction to pressure is 9.44 MPa, while hydrocarbon generation from organic matter contributes 82.66 MPa, and pressure transmission contributes 37.98 MPa. Additionally, the uplift erosion unloading effect and geothermal decline result in pressure reductions of approximately 26.68 MPa and 56.56 MPa, respectively. This study systematically elucidates the causes and distribution of overpressure in the Qiongzhusi Formation, providing valuable insights for subsequent exploration and development of shale gas in this formation. Full article
(This article belongs to the Section Energy Science and Technology)
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22 pages, 19268 KiB  
Article
Key Characteristics and Controlling Factors of the Gas Reservoir in the Fourth Member of the Ediacaran Dengying Formation in the Penglai Gas Field, Sichuan Basin
by Hongwei Chen, Shilin Wang, Ahmed Mansour, Qirong Qin, Mohamed S. Ahmed, Yongjing Cen, Feng Liang, Yuan He, Yi Fan and Thomas Gentzis
Minerals 2025, 15(2), 98; https://doi.org/10.3390/min15020098 - 21 Jan 2025
Cited by 1 | Viewed by 893
Abstract
This study focuses on the PS8 well in the Penglai Gas Field (Sichuan Basin), a newly identified key exploration area, where high-yield gas testing has been achieved from the Ediacaran Fourth Member of the Dengying Formation. Comprehensive analyses of drilling cores, cuttings, thin [...] Read more.
This study focuses on the PS8 well in the Penglai Gas Field (Sichuan Basin), a newly identified key exploration area, where high-yield gas testing has been achieved from the Ediacaran Fourth Member of the Dengying Formation. Comprehensive analyses of drilling cores, cuttings, thin sections, analytical data, well logging, and production testing data were conducted to investigate the main characteristics of the gas reservoir and the factors controlling the formation model of the reservoir. The results reveal that the reservoir rocks in the Fourth Member of the Dengying Formation are primarily algal-clotted dolomite, algal-laminated dolomite, and arenaceous dolomite. The reservoir porosity is dominated by secondary pores, such as algal-bonded framework pores, intergranular dissolved pores, and intercrystalline dissolved pores, which contribute to the overall low porosity and extremely low permeability. The gas reservoir is classified as a unified structural–lithological reservoir, with the upper sub-member of the Fourth Member serving as a completely gas-bearing unit. This unit is characterized as an ultra-deep, dry gas reservoir with medium sulfur and medium CO2 contents. The development of this gas reservoir follows a “laterally generated and laterally stored, upper generation and lower storage” reservoir formation model. Regional unconformities and fracture systems developed during the Tongwan II Episode tectonic movement provide efficient pathways for hydrocarbon migration and accumulation. The high-quality source rocks in the lower Cambrian Qiongzhusi Formation serve as both the direct cap rock and lateral seal of the gas reservoir, creating an optimal source–reservoir spatial configuration. This study provides valuable insights into the giant gas reservoir of the Dengying Formation, which can aid in optimizing exploration activities in the Sichuan Basin. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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21 pages, 5790 KiB  
Article
Sealing Effects on Organic Pore Development in Marine Shale Gas: New Insights from Macro- to Micro-Scale Analyses
by Qiumei Zhou, Hao Xu, Wen Zhou, Xin Zhao, Ruiyin Liu and Ke Jiang
Energies 2025, 18(1), 193; https://doi.org/10.3390/en18010193 - 5 Jan 2025
Cited by 1 | Viewed by 791
Abstract
The physics of how organic pores change under high thermal evolution conditions in overmature marine shale gas formations remains unclear. In this study, systematic analyses at the macro- to micro-scales were performed to reveal the effects of the sealing capacity on organic pore [...] Read more.
The physics of how organic pores change under high thermal evolution conditions in overmature marine shale gas formations remains unclear. In this study, systematic analyses at the macro- to micro-scales were performed to reveal the effects of the sealing capacity on organic pore development. Pyrolysis experiments were conducted in semi-closed and open systems which provided solid evidence demonstrating the importance of the sealing capacity. Low-maturity marine shale samples from the Dalong Formation were used in the pyrolysis experiments, which were conducted at 350 °C, 400 °C, 450 °C, 500 °C, 550 °C, and 600 °C. The pore characteristics and geochemical parameters of the samples were examined after each thermal simulation stage. The results showed that the TOC of the semi-closed system decreased gradually, while the TOC of the open system decreased sharply at 350 °C and exhibited almost no change thereafter. The maximum porosity, specific surface area, and pore volume of the semi-closed system (10.35%, 2.99 m2/g, and 0.0153 cm3/g) were larger than those of the open system (3.87%, 1.97 m2/g, and 0.0059 cm3/g). In addition, when the temperature was 600 °C, the pore diameter distribution in the open system was 0.001–0.1 μm, while the pore diameter distribution in the semi-closed system was 0.001–10 μm. The pore volumes of the macropores and mesopores in the semi-closed system remained larger than those in the open system. The pore volumes of the micropores in the semi-closed and open systems were similar. The pyrolysis results indicated that (1) the pressure difference caused by the sealing capacity controls organic pore development; (2) organic pores developed in the semi-closed system, and the differences between the two systems mainly occurred in the overmature stage; and (3) the differences were caused by changes in the macropore and mesopore volumes, not the micropore volume. It was concluded that the sealing capacity is the key factor for gas pore generation in the overmature stage of marine shale gas reservoirs when the organic matter (OM) type, volume, and thermal evolution degree are all similar. The macropores and mesopores are easily affected by the sealing conditions, but the micropores are not. Finally, the pyrolysis simulation results were validated with the Longmaxi shale and Qiongzhusi shale properties. The Longmaxi shale is similar to semi-closed system, and the Qiongzhusi shale is similar to open system. Two thermal evolution patterns of organic pore development were proposed based on the pyrolysis results. This study provides new insights into the evolution patterns of organic pores in marine shale gas reservoirs. Full article
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22 pages, 12725 KiB  
Article
Application of the Hydrocarbon Generation Potential Method in Resource Potential Evaluation: A Case Study of the Qiongzhusi Formation in the Sichuan Basin, China
by Hanxuan Yang, Chao Geng, Majia Zheng, Zhiwei Zheng, Hui Long, Zijing Chang, Jieke Li, Hong Pang and Jian Yang
Processes 2024, 12(12), 2928; https://doi.org/10.3390/pr12122928 - 21 Dec 2024
Cited by 3 | Viewed by 1048
Abstract
Global recoverable shale gas reserves are estimated to be 214.5 × 1012 m3. Estimation methods for shale gas resources, such as volumetric, analog, and genetic approaches, have been widely used in previous studies. However, these approaches have notable limitations, including [...] Read more.
Global recoverable shale gas reserves are estimated to be 214.5 × 1012 m3. Estimation methods for shale gas resources, such as volumetric, analog, and genetic approaches, have been widely used in previous studies. However, these approaches have notable limitations, including the substantial effect of rock heterogeneity, difficulties in determining the similarity of analog accumulations, and unsuitability for evaluating high-mature–overmature source rocks. In the Qiongzhusi Formation (Є1q) of the Sichuan Basin, China, extensive development of high-mature–overmature shales has led to significant advancements in conventional and unconventional shale gas exploration. This progress highlights the need for the development of an integrated evaluation system for conventional and unconventional resources. Hence, this study uses the whole petroleum system theory and an improved hydrocarbon generation potential method to analyze the distribution patterns of hydrocarbon generation, retention, and expulsion during various stages of oil and gas accumulation in the Є1q. In addition, it assesses the resource potential of conventional and shale oil and gas. Hydrocarbon generation and expulsion centers are favorable exploration targets for conventional oil and gas, primarily located in the central and northern regions of the Mianyang—Changning rift trough, with an estimated resource potential of 6560 × 1012 m3. Hydrocarbon retention centers represent promising targets for shale oil and gas exploration, concentrated in the central Mianyang—Changning rift trough, with a resource potential of 287 × 1012 m3. This study provides strategic guidance for future oil and gas exploration in the Є1q and offers a methodological reference for integrated resource assessments of conventional and unconventional oil and gas systems of high-mature–overmature source rocks in similar basins worldwide. Full article
(This article belongs to the Special Issue Model of Unconventional Oil and Gas Exploration)
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19 pages, 9341 KiB  
Article
Effects of the Sedimentary Environment on Organic-Rich Shale in the Intracratonic Sag of the Sichuan Basin, China
by Xuewen Shi, Jia Liu, Yiqing Zhu, Liang Xu, Yuran Yang, Chao Luo, Yanyou Li, Kesu Zhong, Xue Yang, Qiuzi Wu, Liang He, Demin Shi and Xingzhi Wang
Appl. Sci. 2024, 14(19), 8594; https://doi.org/10.3390/app14198594 - 24 Sep 2024
Cited by 2 | Viewed by 1036
Abstract
The enrichment of organic matter in high-quality marine shale is generally controlled by factors such as the redox conditions of sedimentary environments, productivity levels, terrigenous input, and ancient productivity. However, the controlling effect of the sedimentary environment on organic matter enrichment in intracratonic [...] Read more.
The enrichment of organic matter in high-quality marine shale is generally controlled by factors such as the redox conditions of sedimentary environments, productivity levels, terrigenous input, and ancient productivity. However, the controlling effect of the sedimentary environment on organic matter enrichment in intracratonic sag is still unclear. This study takes samples from the Qiongzhusi formation shale in southern Sichuan Basin as the research object, focusing on trace elements as well as rare earth elements in different stratigraphic intervals. The provenance of the Qiongzhusi formation shale is mainly terrigenous, with sediment sources mainly consisting of sedimentary rocks and granites. The primary sedimentary environment transitions from a continental margin setting, influenced by rift-related tectonic activity and sediment influx from adjacent landmasses, to an open oceanic environment characterized by mid-ocean ridge processes and oceanic plate subduction zones. During sedimentation, saline water was present, with predominant sedimentary environments ranging from shallow water to deep water continental shelves. The shale in the study area is characterized by a higher content of silicates and a lower content of carbonate minerals. Its siliceous sources are mainly influenced by biogenic and terrigenous debris, indicating higher ancient primary productivity and representing a favorable target for shale gas exploration. Full article
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26 pages, 61394 KiB  
Article
Characteristics and Controlling Factors of Pores in Different Shale Lithofacies Reservoirs of Lower Cambrian Qiongzhusi Formation, Southwestern Sichuan Basin, China
by Yuqi Wang, Dongxia Chen, Yuchao Wang, Wenzhi Lei and Fuwei Wang
Minerals 2023, 13(11), 1442; https://doi.org/10.3390/min13111442 - 15 Nov 2023
Cited by 2 | Viewed by 1555
Abstract
The shale reservoirs of the Lower Cambrian Qiongzhusi Formation are widely distributed in the Sichuan Basin and have abundant gas resources. However, the shale lithofacies of the Qiongzhusi Formation are complex due to frequent sea level changes. The reservoir pore structure characteristics and [...] Read more.
The shale reservoirs of the Lower Cambrian Qiongzhusi Formation are widely distributed in the Sichuan Basin and have abundant gas resources. However, the shale lithofacies of the Qiongzhusi Formation are complex due to frequent sea level changes. The reservoir pore structure characteristics and gas content of different shale lithofacies vary significantly, which makes identifying the ‘sweet spot’ a challenging task. In this study, core observation and X-ray diffraction (XRD) were used to analyze the lithofacies types and characteristics of the study area. The pore types of different shale lithofacies were observed using field emission-scanning electron microscopy. Pore structures were studied using low-temperature gas (including N2 and CO2) physisorption, and the pore volume (PV), specific surface area (SSA) and pore structure were systematically characterized. The primary factors influencing pore formation in different types of shale lithofacies were analyzed by combining geochemical experiments and mineral contents. The results indicate that the lithofacies of the Qiongzhusi Formation shale in the study area can be classified into five categories according to mineral compositions: Siliceous argillaceous shale (CM-1), Argillaceous siliceous mixed shale (M-2), Argillaceous siliceous shale (S-3), Siliceous rock (S) and Calcareous siliceous shale (S-2). Pores are abundant in S-3 shale, M-2 shale and CM-1 shale. The S-3 shale is more enriched in organic pores and clay mineral pores compared to other lithofacies shales, and the pore morphology is mainly wedge-shaped and plate-like. M-2 shale and CM-1 shale are rich in clay minerals and mainly develop clay mineral pores and are mainly wedge-shaped and plate-like. The S shale and S-2 shale mainly develop interparticle pores and clay mineral pores, which are mainly slit-like. The results show that TOC, pyrite content, quartz and feldspar mineral content, clay mineral type and content affect the pore structure in the study area. Quartz and feldspar content have a negative effect on micropore and mesopore volumes. TOCs have a weak positive correlation with micropore volume and micropore SSA. Clay mineral content has significant positive effects on the PV and SSA of micropores and mesopores, indicating that clay mineral content is the main factor affecting the pore structure of shale. Full article
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19 pages, 4028 KiB  
Article
Multiple Controls on Organic Matter Accumulation in the Intraplatform Basin of the Early Cambrian Yangtze Platform, South China
by Qiyang Zhang, Entao Liu, Songqi Pan, Hua Wang, Zhenhua Jing, Zhengfu Zhao and Ruiyue Zhu
J. Mar. Sci. Eng. 2023, 11(10), 1907; https://doi.org/10.3390/jmse11101907 - 2 Oct 2023
Cited by 6 | Viewed by 1879
Abstract
Studying the accumulation rules of organic matter (OM) in paleo-ocean sediments can not only enhance our understanding of how OM becomes enriched in ancient oceans but also provide guidance for the exploration of shale gas in unconventional shale strata. A breakthrough has been [...] Read more.
Studying the accumulation rules of organic matter (OM) in paleo-ocean sediments can not only enhance our understanding of how OM becomes enriched in ancient oceans but also provide guidance for the exploration of shale gas in unconventional shale strata. A breakthrough has been made in shale gas exploration in the early Cambrian Qiongzhusi Formation in South China. However, less attention has been paid to the intraplatform basin of the Yangtze Platform, and the factors controlling organic matter enrichment in this special region remain unclear. This study focuses on a continuous drilling core across the full well section of the Qiongzhusi Formation in the intraplatform basin of the Yangtze Platform. Through the comprehensive analysis of total organic carbon (TOC), major and trace elements, and Mo isotopes, this study investigates the controlling factors for OM enrichment with δ98/95Mo ratios utilized to identify the existence of euxinic bottom water. The examined 240 m long core can be divided into four units, where the TOC values of the lower Units 1 and 2 (0.2–5.0 wt.%) average higher than the upper Units 3 and 4 (0.2–2.5 wt.%). Redox indicators (U/Th, Ni/Co, EF(Mo)—EF(U)) indicate an increasing oxidation of bottom waters from the bottom upwards. δ98/95Mo data further confirm the presence of weakly euxinic conditions in Units 1 and 2, addressing the ongoing controversy surrounding bottom water redox environments. Primary productivity indicators (Ni/Al, Cu/Al) suggest a relatively low average productivity level within the intraplatform basin. The upwelling indicators EF(Co) * EF(Mn) of different profiles in the Yangtze Platform suggest that low productivity within the intraplatform basin can be mainly attributed to the absence of upwelling. Consequently, this study proposes an organic matter enrichment mechanism for the Qiongzhusi Formation in the intraplatform basin, which emphasizes the significance of the redox environment in the formation of high-quality hydrocarbon source rocks in restricted environments that lack upwelling, setting it apart from the deep ocean. These findings have the potential to provide valuable insights for the exploration of high-quality hydrocarbon source rocks in other similar regions. Full article
(This article belongs to the Special Issue High-Efficient Exploration and Development of Oil & Gas from Ocean)
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14 pages, 10865 KiB  
Article
Paleoenvironment Comparison of the Longmaxi and Qiongzhusi Formations, Weiyuan Shale Gas Field, Sichuan Basin
by Qin Zhang, Feng Liang, Jingbo Zeng, Zhen Qiu, Shangwen Zhou, Wen Liu and Weiliang Kong
Processes 2023, 11(7), 2153; https://doi.org/10.3390/pr11072153 - 19 Jul 2023
Cited by 2 | Viewed by 1437
Abstract
The Lower Cambrian Qiongzhusi formation and the Lower Silurian Longmaxi Formation are the two most important shale strata. Although differences between these two shales have become the focus of current research, a comparative study of the depositional environments has not been performed. Using [...] Read more.
The Lower Cambrian Qiongzhusi formation and the Lower Silurian Longmaxi Formation are the two most important shale strata. Although differences between these two shales have become the focus of current research, a comparative study of the depositional environments has not been performed. Using cores of both Longmaxi and Qiongzhusi formations of well W201, the in situ comparison of the sedimentary environment was realized, and the interference of other factors was eliminated, which made the results more reliable. In this study, 72 samples from both formations were collected from well W201, Weiyuan shale gas field, Sichuan Basin. A systematic study, including total organic carbon (TOC) content, mineral composition, and major/trace elemental analyses, was conducted to elucidate the paleoenvironments of the Qiongzhusi and Longmaxi formations. The results show both formations were deposited in non-sulfidic environments. The depositional conditions of the Longmaxi formation varied from reducing to oxidizing from bottom to top. The detrital flow happened during the deposition of the Qiongzhusi formation, which resulted in three stages of the redox conditions, from anoxic to oxic and then to anoxic from bottom to top of the Qiongzhusi formation. The anoxic conditions of the Qiongzhusi formation were considerably stronger than those of the Longmaxi formation. Both formations were deposited in warm and humid climates. Ratios of Eu/Eu*, Y/Y*, LaN/YbN, light rare earth element (LREE) and heavy rare earth element (HREE) revealed that the Longmaxi formation was primarily controlled by seawater, whereas the Qiongzhusi formation was jointly influenced by seawater and hydrothermal fluid. The organic matter enrichment for the Longmaxi and Qiongzhusi formations was controlled by paleoproductivity and redox conditions. Due to the slightly lower paleoproductivity and influence of detrital input, the degree of organic matter enrichment in the Qiongzhusi formation was lower than that in the Longmaxi formation. Full article
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28 pages, 6312 KiB  
Article
Genetic Relationship between Mississippi Valley-Type Pb–Zn Mineralization and Hydrocarbon Accumulation in the Wusihe Deposits, Southwestern Margin of the Sichuan Basin, China
by Guozhi Wang, Qing Lei, Zhu Huang, Gang Liu, Yuzhen Fu, Na Li and Jinlong Liu
Minerals 2022, 12(11), 1447; https://doi.org/10.3390/min12111447 - 16 Nov 2022
Cited by 10 | Viewed by 2253
Abstract
The coexistence of numerous Mississippi Valley-type (MVT) Pb–Zn deposits and oil/gas reservoirs in the world suggests a close genetic relationship between mineralization and hydrocarbon accumulation. The Wusihe MVT Pb–Zn deposits are located along the southwestern margin of the Sichuan Basin. Based on the [...] Read more.
The coexistence of numerous Mississippi Valley-type (MVT) Pb–Zn deposits and oil/gas reservoirs in the world suggests a close genetic relationship between mineralization and hydrocarbon accumulation. The Wusihe MVT Pb–Zn deposits are located along the southwestern margin of the Sichuan Basin. Based on the spatiotemporal relation between Pb–Zn deposits and paleo-oil/gas reservoirs, ore material sources, and processes of mineralization and hydrocarbon accumulation, a new genetic relationship between mineralization and hydrocarbon accumulation is suggested for these deposits. The Wusihe Pb–Zn deposits are hosted in the Ediacaran Dengying Formation dolostone, accompanied by a large amount of thermally cracked bitumen in the ore bodies. The Pb–Zn deposits and paleo-oil/gas reservoirs are distributed along the paleokarst interface; they overlap spatially, and the ore body occupies the upper part of the paleo-oil/gas reservoirs. Both the Pb–Zn ore and sphalerite are rich in thermally cracked bitumen, in which µm sized galena and sphalerite may be observed, and the contents of lead and zinc in the bitumen are higher than those required for Pb–Zn mineralization. The paleo-oil/gas reservoirs experienced paleo-oil reservoir formation, paleo-gas reservoir generation, and paleo-gas reservoir destruction. The generation time of the paleo-gas reservoirs is similar to the metallogenic time. The source rocks from the Cambrian Qiongzhusi Formation not only provided oil sources for paleo-oil reservoirs but also provided ore-forming metal elements for mineralization. Liquid oil with abundant ore-forming metals accumulated to form paleo-oil reservoirs with mature organic matter in source rocks. As paleo-oil reservoirs were buried, the oil underwent in situ thermal cracking to form overpressure paleo-gas reservoirs and a large amount of bitumen. Along with the thermal cracking of the oil, the metal elements decoupled from organic matter and H2S formed by thermochemical sulfate reduction (TSR) and minor decomposition of the organic matter dissolved in oilfield brine to form the ore fluid. The large-scale Pb–Zn mineralization is mainly related to the destruction of the overpressured paleo-gas reservoir; the sudden pressure relief caused the ore fluid around the gas–water interface to migrate upward into the paleo-gas reservoirs and induced extensive metal sulfide precipitation in the ore fluid, resulting in special spatiotemporal associated or paragenetic relations of galena, sphalerite, and bitumen. Full article
(This article belongs to the Special Issue The Relationship between Metal Deposits and Hydrocarbon Accumulation)
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19 pages, 4056 KiB  
Article
Depositional Paleo-Environments of Lower Cambrian Qiongzhusi Formation in the Western Middle Yangtze Block and Its Controlling Effect on the Organic Matter Enrichment
by Zhengkai Lan and Junjun Shen
Energies 2022, 15(10), 3761; https://doi.org/10.3390/en15103761 - 20 May 2022
Cited by 6 | Viewed by 1804
Abstract
No systematic comparative study has been conducted on the factors controlling organic matter enrichment in the different depositional environments of the Lower Cambrian Qiongzhusi Formation in the western Middle Yangtze Block, leading to a large discrepancy in our understanding. Based on organic geochemical [...] Read more.
No systematic comparative study has been conducted on the factors controlling organic matter enrichment in the different depositional environments of the Lower Cambrian Qiongzhusi Formation in the western Middle Yangtze Block, leading to a large discrepancy in our understanding. Based on organic geochemical and elemental analyses of core, outcrop, rock, and mineral samples from the slope, deep-water shelf, and shallow-water shelf, in this study, comparative analysis of the organic matter content, sedimentological characteristics, and depositional paleoenvironments of the Lower Cambrian Qiongzhusi Formation in the western Middle Yangtze Block was conducted, and the main controlling factors and models of the organic matter enrichment were investigated. The results revealed that the organic matter enrichment in the Qiongzhusi Formation was jointly controlled by redox conditions, water restriction, upwelling currents, terrigenous inputs, and paleo-productivity, but the main factors controlling the enrichment during the different periods were significantly different. (1) During the deposition of the Qiong 1 Member, the extensional rifting was strong, and the sea level was always high. The low degree of terrigenous dilution and anoxic conditions favored organic matter preservation. In this period, the upwelling currents were the main factor controlling organic matter enrichment. The paleo-productivity decreased as the intensity of the upwelling currents gradually weakened from the slope to the shelf, leading to a decrease in the total organic carbon (TOC) content and thereby a gradual decrease in the biogenic silica content of the shale. (2) During the deposition of the Qiong 2 Member, the extensional rifting weakened, and the sea level continued to drop. The upwelling currents, terrigenous input, and redox conditions were all important factors controlling the organic matter enrichment in the region. From the slope to the shelves, the conditions favorable for organic matter enrichment gradually worsened, and the TOC content gradually decreased, with the lithofacies gradually transitioning from biogenic siliceous shale to clayey shale or clayey-calcareous shale. (3) During the deposition of the Qiong 3 Member, the Yangzi Platform underwent a filling and leveling-up process, and the redox conditions played a major role in controlling the organic matter enrichment. The entire region was dominated by an oxygen-rich environment, and the conditions were no longer favorable for organic matter preservation, leading to a low average TOC content. Overall, the spatial variability of the TOC content was closely associated with changes in the depositional paleoenvironment caused by sea-level changes. Full article
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26 pages, 8705 KiB  
Article
Effects of Regional Differences in Shale Floor Interval on the Petrophysical Properties and Shale Gas Prospects of the Overmature Niutitang Shale, Middle-Upper Yangtz Block
by Yijun Zheng, Yuhong Liao, Yunpeng Wang, Yongqiang Xiong and Ping’an Peng
Minerals 2022, 12(5), 539; https://doi.org/10.3390/min12050539 - 26 Apr 2022
Cited by 2 | Viewed by 2131
Abstract
The lower Cambrian Niutitang/Qiongzhusi shale gas in the Middle-Upper Yangtz Block had been regarded as a very promising unconventional natural gas resource due to its high total organic carbon, great thickness, and large areal distribution. However, no commercial shale gas fields have yet [...] Read more.
The lower Cambrian Niutitang/Qiongzhusi shale gas in the Middle-Upper Yangtz Block had been regarded as a very promising unconventional natural gas resource due to its high total organic carbon, great thickness, and large areal distribution. However, no commercial shale gas fields have yet been reported. From the northwest to the southeast there are considerable differences in the sedimentary environments, lithology, and erosive nature of the underlying interval (the floor interval) of the Niutitang shale. However, systematic research on whether and how these regional differences influence shale petrophysical properties and shale gas preservation in the Niutitang shale is lacking. A comparison of Niutitang shale reservoirs as influenced by different sedimentary and tectonic backgrounds is necessary. Samples were selected from both the overmature Niutitang shales and the floor interval. These samples cover the late Ediacaran and early Cambrian, with sedimentary environments varying from carbonate platform and carbonate platform marginal zone facies to continental shelf/slope. Previously published data on the lower Cambrian samples from Kaiyang (carbonate platform), Youyang (carbonate platform marginal zone) and Cen’gong (continental shelf/slope) sections were integrated and compared. The results indicate that the petrophysical properties of the floor interval can affect not only the preservation conditions (sealing capacity) of the shale gas, but also the petrophysical properties (pore volume, porosity, specific surface area and permeability) and methane content of the Niutitang shale. From the carbonate platform face to the continental shelf/slope the sealing capacity of the floor interval gradually improves because the latter gradually passes from high permeability dolostone (the Dengying Formation) to low permeability dense chert (the Liuchapo Formation). In addition, in contrast with several unconformities that occur in the carbonate platform face in the northern Guizhou depression, no unconformity contact occurs between the Niutitang shale and the floor interval on the continental shelf/slope developed in eastern Chongqing Province and northwestern Hunan Province. Such regional differences in floor interval could lead to significant differences in hydrocarbon expulsion behaviour and the development of organic pores within the Niutitang shale. Therefore, shale gas prospects in the Niutitang shales deposited on the continental shelf/slope should be significantly better than those of shales deposited on the carbonate platform face. Full article
(This article belongs to the Special Issue Shale and Tight Reservoir Characterization and Resource Assessment)
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24 pages, 8262 KiB  
Article
Characteristics of Vein-Forming Fluids in the Sinian Dengying Formation Reservoir and Its Relationship with the Hydrocarbon Accumulation Process in the Southwest and Southeast of the Sichuan Basin
by Jing Luo, Furong Wang, Sheng He, Zhiliang He, Yahao Huang, Dianwei Zhang, Yanxian Zhu, Ziming Sun and Tao Luo
Minerals 2022, 12(4), 443; https://doi.org/10.3390/min12040443 - 3 Apr 2022
Cited by 5 | Viewed by 2238
Abstract
Multistage fluid activities and hydrocarbon accumulation processes have occurred in the Dengying Formation of the Sichuan Basin during its long geological history. Petrography and cathodoluminescence observations; in situ microanalysis of rare earth elements, carbon, oxygen, and strontium isotopes; fluid inclusion microthermometric experiments; laser [...] Read more.
Multistage fluid activities and hydrocarbon accumulation processes have occurred in the Dengying Formation of the Sichuan Basin during its long geological history. Petrography and cathodoluminescence observations; in situ microanalysis of rare earth elements, carbon, oxygen, and strontium isotopes; fluid inclusion microthermometric experiments; laser Raman experiments; burial history; thermal history; and hydrocarbon generation history simulation have been applied to study the characteristics of vein-forming fluid in the Dengying Formation reservoirs in the southeast and southwest of Sichuan Basin and to analyze in-depth the multistage fluid activity and hydrocarbon accumulation process. The results show that two stages of dolomite and one stage of quartz are developed in the 4th member of the Dengying Formation in the southeast of Sichuan Basin, and three stages of dolomite are developed in the 2nd member of the Dengying Formation in the southwest of Sichuan Basin. The source of the dolomite veins is mainly reservoir marine diagenetic fluid. Dolomites developed in the Hercynian period were affected by hydrothermal activity to a certain extent which may have been caused by the activity of the Emei mantle plume. The diagenetic mineral sequence of the 4th member of the Dengying Formation in the southeast of Sichuan Basin is quartz (432 Ma)/dolomite I (421 Ma)/dolomite II (288 Ma), and the 2nd member of the Dengying Formation in the southwest of the Sichuan Basin is dolomite I (425 Ma)/dolomite II (283 Ma)/dolomite III (262 Ma). The main hydrocarbon accumulation period was during the Hercynian–Indosinian stage which was related to the thermal influence of the Emei mantle plume activity on the source rock of the Qiongzhusi Formation. Combined with petrography, inclusion thermometry, burial history, and hydrocarbon generation history simulation, the fluid activity and hydrocarbon accumulation evolution sequence in the southeast and southwest of the Sichuan Basin are determined comprehensively. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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