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19 pages, 18384 KB  
Article
Hot Deformation Behavior and Microstructural Evolution of a High-Strength Mg-Gd-Y-Zr Alloy
by Haitao Xie, Zhiwei Liang, Di Mei, Aiyue Zhang, Chenchen Jiang, Qingshan Du, Yang Xiao, Shijie Zhu, Liguo Wang, Chujie Liu, Jinxue Liu and Shaokang Guan
Metals 2026, 16(8), 934; https://doi.org/10.3390/met16080934 - 21 Aug 2026
Viewed by 145
Abstract
Mg-Gd-Y-Zr alloys, with strong age-hardening and thermal stability, are ideal for lightweight load-bearing components, yet forming large complex parts is limited by high sensitivity to hot deformation parameters. This work investigates the hot deformation behavior and microstructure evolution of a Mg-9Gd-4Y-0.5Zr (wt.%) alloy [...] Read more.
Mg-Gd-Y-Zr alloys, with strong age-hardening and thermal stability, are ideal for lightweight load-bearing components, yet forming large complex parts is limited by high sensitivity to hot deformation parameters. This work investigates the hot deformation behavior and microstructure evolution of a Mg-9Gd-4Y-0.5Zr (wt.%) alloy via hot compression at 400 to 510 °C and strain rates of 0.001 to 10 s−1. An Arrhenius constitutive equation with an activation energy Q of 158.63 kJ/mol was established, and a hot processing map was constructed. EBSD characterization revealed the dynamic recrystallization, grain size evolution, and texture transition. The results show that flow stress depends strongly on temperature and strain rate. At strain rates of 0.001~1 s−1, a dynamic balance between work hardening and dynamic softening is achieved, and the post-peak flow stress gradually stabilizes. At a high strain rate of 10 s−1, the flow stress continues to decrease because the competition between softening from dynamic recrystallization and work hardening is disrupted by deformation-induced heating. Low strain rates (≤0.01 s−1) and high temperatures (≥470 °C) promote dynamic recrystallization and significant grain refinement. Two optimal processing windows were determined: 400 to 430 °C at 0.001 to 0.01 s−1, giving fully recrystallized fine equiaxed grains, and 440 to 460 °C at 0.01 to 0.1 s−1 with a power dissipation efficiency η of 0.43 to 0.51, balancing processing efficiency and microstructural uniformity. This work provides systematic theoretical and data support for optimizing hot forming parameters of large Mg-Gd-Y-Zr load-bearing components and offers guidance for applying high-strength magnesium alloys in high-end equipment. Full article
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27 pages, 3296 KB  
Review
High-Strength Steel in Civil Engineering Structures: A Review of Material Behaviour, Durability, Fatigue and Component Performance
by Ziheng Ding, Xuanyi Xue, Fei Wang, Neng Wang, Shuai Li and Jianmin Hua
Materials 2026, 19(16), 3509; https://doi.org/10.3390/ma19163509 - 19 Aug 2026
Viewed by 283
Abstract
High-strength steel has attracted increasing attention in civil engineering because of its high strength-to-weight ratio and potential for material-efficient design. This narrative review, supported by a structured literature search, summarizes recent advances in the material behaviour, durability and structural performance of high-strength steel. [...] Read more.
High-strength steel has attracted increasing attention in civil engineering because of its high strength-to-weight ratio and potential for material-efficient design. This narrative review, supported by a structured literature search, summarizes recent advances in the material behaviour, durability and structural performance of high-strength steel. The discussion covers constitutive behaviour, fatigue and fracture, corrosion degradation, high-temperature and post-fire properties, residual stresses, structural members and connections. Existing studies show that increasing steel strength is commonly accompanied by reduced ductility and strain-hardening capacity, while local buckling, residual stress, welding-induced heterogeneity, fatigue damage, corrosion and thermal degradation remain important design concerns. The accuracy of current design provisions varies with steel grade, product form, section geometry, failure mode and exposure condition, and direct extension from conventional steels is not always appropriate. Future research should emphasize coupled degradation mechanisms, consistent material characterization, broader experimental validation and design models with clearly defined applicability limits. Full article
(This article belongs to the Section Construction and Building Materials)
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26 pages, 4754 KB  
Review
Bacterial Vaginosis vs. Aerobic Vaginitis: An Unresolved Conundrum?
by Lorenzo Agoni, Canio Martinelli and Francesco De Seta
Biology 2026, 15(16), 1393; https://doi.org/10.3390/biology15161393 - 14 Aug 2026
Viewed by 330
Abstract
Bacterial vaginosis (BV) and aerobic vaginitis (AV) are usually described as distinct forms of vaginal dysbiosis. BV is characterized by depletion of lactobacilli, overgrowth of anaerobic microorganisms, and biofilm formation, whereas AV is associated with inflammatory changes, epithelial disruption, and predominance of aerobic [...] Read more.
Bacterial vaginosis (BV) and aerobic vaginitis (AV) are usually described as distinct forms of vaginal dysbiosis. BV is characterized by depletion of lactobacilli, overgrowth of anaerobic microorganisms, and biofilm formation, whereas AV is associated with inflammatory changes, epithelial disruption, and predominance of aerobic bacteria. Over the past two decades, this distinction has profoundly influenced the understanding, diagnosis, and management of vaginal disorders. Despite their apparent differences, the relationship between BV and AV remains incompletely understood. Growing evidence indicates that many women exhibit microbiological and microscopic patterns that cannot be readily classified within existing diagnostic frameworks. Intermediate Nugent scores, mixed vaginitis, transitional ecological states, post-treatment microbiota reconstitution, physiological hypoestrogenic conditions, and uncommon inflammatory patterns all challenge the traditional view of BV and AV as strictly separate entities. This narrative review examines the historical evolution of BV and AV concepts, compares their microbiological, immunological, and epithelial characteristics, and evaluates the diagnostic paradigms currently used to identify vaginal dysbiosis. The strengths and limitations of clinical and diagnostic approaches are discussed together with the extent to which contemporary international guidelines reflect current biological knowledge. Particular emphasis is placed on intermediate, mixed, and overlapping states that blur the boundaries between established diagnostic categories. The available evidence supports the clinical usefulness of distinguishing BV and AV as separate clinicopathological entities. However, it also indicates that vaginal ecosystem disturbances frequently extend beyond rigid dichotomous classifications. Current diagnostic categories remain valuable tools for clinical practice, yet they may only partially capture the complexity and dynamic nature of vaginal dysbiosis. Understanding how microbial communities, host responses, epithelial integrity, and physiological factors interact remains a major challenge for future research and clinical interpretation. Full article
(This article belongs to the Section Infection Biology)
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51 pages, 10220 KB  
Review
Machine Learning for Individual Credit Risk Assessment: A Systematic Literature Review of State-of-the-Art Methods, Challenges and Perspectives
by Bolun Zhang, Jun Luo, Ruobing Wu, Jie Wei, Zuzhuang Luo and Hongbo Shen
J. Risk Financ. Manag. 2026, 19(8), 607; https://doi.org/10.3390/jrfm19080607 - 12 Aug 2026
Viewed by 473
Abstract
Credit risk assessment forms a cornerstone of banking risk management and the stability of the wider financial system. Over the past decade, the rapid development of machine learning (ML) techniques has substantially enhanced traditional credit risk assessment methodologies. ML has now emerged as [...] Read more.
Credit risk assessment forms a cornerstone of banking risk management and the stability of the wider financial system. Over the past decade, the rapid development of machine learning (ML) techniques has substantially enhanced traditional credit risk assessment methodologies. ML has now emerged as a core technological pillar for the banking sector, strengthening risk identification capabilities, optimising credit decision-making, and advancing financial inclusion. Conventional credit scoring models, dominated by logistic regression (LR) and scorecard approaches, offer inherent strengths in interpretability and regulatory compliance. However, constrained by their linear assumptions, these methods struggle to capture complex non-linear relationships within credit data and deliver insufficient predictive accuracy for the “credit-invisible” population lacking formal credit histories. This paper presents a systematic literature review (SLR) of ML applications in credit risk assessment (CRA), covering publications from January 2016 to May 2026. A total of 894 papers were retrieved from five digital libraries, and following a rigorous multi-stage screening process, 129 studies were selected for final inclusion. Our analysis reveals that tree-based ensemble models and deep learning (DL) architectures predominate in contemporary research in this field. Meanwhile, post hoc explanation methods and machine learning operations (MLOps) are gaining significant traction as solutions to address fairness, transparency, and system maintenance challenges in real-world production environments. We synthesise prevailing methodologies into a unified end-to-end credit risk modelling framework spanning data preprocessing, feature engineering, model training, evaluation, and operational deployment. Through a critical assessment of the advantages, limitations, and inherent trade-offs of existing approaches, this SLR not only identifies current research gaps and future directions for the academic community, but also provides practical guidance for the banking sector to build compliant, fair, and efficient intelligent risk assessment systems. Full article
(This article belongs to the Section Risk)
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15 pages, 675 KB  
Article
Immediate Changes in Physical Function, Psychological Health, and Health-Related Quality of Life Following a Five-Day Multicomponent Coastal Health Program in Postmenopausal Women: A Randomized Controlled Trial
by Sung-Hyeon Kim, Jin-Hwa Jung, Ji-Eun Baek, Ho-Jin Shin and Hwi-Young Cho
J. Clin. Med. 2026, 15(15), 5926; https://doi.org/10.3390/jcm15155926 - 29 Jul 2026
Viewed by 318
Abstract
Background/Objectives: After menopause, hormonal, age-related, and lifestyle factors may adversely affect physical functioning and psychological well-being. This study compared immediate changes in physical function, psychological health, and health-related quality of life following a five-day Combined Marine Treatment Program (CMTP) with those observed [...] Read more.
Background/Objectives: After menopause, hormonal, age-related, and lifestyle factors may adversely affect physical functioning and psychological well-being. This study compared immediate changes in physical function, psychological health, and health-related quality of life following a five-day Combined Marine Treatment Program (CMTP) with those observed under a usual-routine control condition. Methods: A parallel-group randomized controlled trial was conducted with 62 postmenopausal women allocated equally to the CMTP and control groups. The CMTP included coastal walking, resistance exercises, mindfulness meditation, and visits to local natural attractions. Participants in the control group continued their customary daily activities. The co-primary outcomes were the Timed Up and Go test and the Short Form-36. Secondary outcomes were grip strength, pinch strength, static balance, the 10-item Perceived Stress Scale, and the Beck Depression Inventory-II. Mixed repeated-measures analysis of variance was used to test whether temporal changes differed between groups. Trial registration was completed through the Clinical Research Information Service of the Republic of Korea (KCT0009741). Results: Changes over time differed significantly between groups for the Timed Up and Go test, grip strength, pinch strength, eyes-open sway area, eyes-closed sway area, eyes-closed sway velocity, and all self-reported outcomes. Post-intervention values differed significantly between groups for the Timed Up and Go test, pinch strength, both eyes-closed balance measures, and all self-reported outcomes. No adverse events were reported during the trial. Conclusions: Relative to the usual-routine condition, the five-day CMTP was associated with immediate changes in selected performance-based physical outcomes and broader changes across self-reported psychological and health-related quality-of-life outcomes. Brief multicomponent coastal health programs therefore warrant further study in postmenopausal women. Full article
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14 pages, 2345 KB  
Article
Association Between Physical Function, Pulmonary Function, and Social Determinants of Health in Individuals with Post-Tuberculosis Lung Disease
by Nielza Moreira de Souza, Pedro Henrique Perpetuo de Lima Silva, Estephane Ramos de Souza Penna, Amanda Oliveira dos Anjos, Alícia Sales Carneiro, Walter Costa, Bruna Cuoco Provenzano, Ana Paula Santos and Agnaldo José Lopes
Adv. Respir. Med. 2026, 94(4), 52; https://doi.org/10.3390/arm94040052 - 27 Jul 2026
Viewed by 581
Abstract
Although poverty and tuberculosis are insidiously linked, knowledge of the relationship between social determinants of health (SDoHs) and post-tuberculosis lung disease (PTLD) is limited. This study aimed to analyze the association between physical function, pulmonary function, and SDoHs in individuals with PTLD (iwPTLD), [...] Read more.
Although poverty and tuberculosis are insidiously linked, knowledge of the relationship between social determinants of health (SDoHs) and post-tuberculosis lung disease (PTLD) is limited. This study aimed to analyze the association between physical function, pulmonary function, and SDoHs in individuals with PTLD (iwPTLD), considering the impact of social inequalities on physical performance. This cross-sectional study collected social data from 69 iwPTLDs using a standardized assessment form. The patients underwent pulmonary function testing via spirometry and body plethysmography, as well as respiratory muscle strength and quadriceps muscle strength (QMS) testing. They also completed the six-minute step test (6MST). The median value of steps climbed by participants on the 6MST was 88 (57–117), corresponding to 50.1% (34.9–73.2) of the predicted value. The mean QMS was 28.7 ± 11.9 kgf, with 11 participants (17.4%) showing QMS below the cutoff point. Spirometry revealed normal, obstructive, restrictive, and mixed patterns in 19 (27.5%), 20 (29%), 18 (26.1%), and 12 (17.4%) of the participants, respectively. Performance on the 6MST showed no statistically significant association with SDoHs. QMS showed a statistically significant association with treated sewage (W = 84, p = 0.026). Forced expiratory volume in one second showed significant correlations with education level (ρ = 0.248, p = 0.040), social protection (W = 207, p = 0.050, r = 0.238), and treated water (W = 24.5, p = 0.029, r = 0.264). Maximum inspiratory pressure showed significant correlations with education level (ρ = 0.246, p = 0.042) and treated water (W = 20, p = 0.021, r = 0.280). The regression model for 6MST and QMS performance showed that 12% and 45% of the variability was explained by the studied variables, respectively. In iwPTLD, impairments in physical function and damage to lung function are weakly associated with the deterioration of SDoHs. While this relationship is weak, it should not be ignored because it may operate through indirect pathways. Full article
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37 pages, 1128 KB  
Review
Vitamin D in Photosynthetic Organisms and Fungi: Sterol Photochemistry, UV-B Availability, and Biofortification Potential
by Ariam Abraham, Dorota Bartusik-Aebisher, Barbara Smolak, Klaudia Dynarowicz, Edward Kowalczyk, Wiesław Guz, David Aebisher and Gabriela Henrykowska
Curr. Issues Mol. Biol. 2026, 48(8), 760; https://doi.org/10.3390/cimb48080760 - 26 Jul 2026
Viewed by 361
Abstract
Vitamin D comprises a group of fat-soluble secosteroids traditionally associated with animal physiology, calcium-phosphate homeostasis, and skeletal metabolism. However, vitamin D and related compounds have also been reported in taxonomically distinct non-animal systems, including fungi, microalgae, other algae, phytoplankton, and higher plants, although [...] Read more.
Vitamin D comprises a group of fat-soluble secosteroids traditionally associated with animal physiology, calcium-phosphate homeostasis, and skeletal metabolism. However, vitamin D and related compounds have also been reported in taxonomically distinct non-animal systems, including fungi, microalgae, other algae, phytoplankton, and higher plants, although the strength of evidence differs substantially among these groups. This review synthesizes current knowledge on the occurrence, structural chemistry, UV-B-driven photochemical mechanisms, environmental determinants, analytical challenges, and biofortification potential of vitamin D formation in photosynthetic organisms and fungi. Vitamin D synthesis is initiated by UV-B radiation, primarily within the 290–315 nm range, which converts sterol precursors such as 7-dehydrocholesterol and ergosterol into previtamin D intermediates and is followed by thermal isomerization to the corresponding vitamin D forms. Continued irradiation may additionally generate lumisterol, tachysterol, and other photoproducts, thereby limiting net vitamin D accumulation. This non-enzymatic mechanism supports the interpretation that vitamin D formation can occur outside vertebrates when an appropriate 5,7-diene sterol precursor is accessible to a sufficient UV-B dose. In photosynthetic organisms and fungal matrices, net vitamin D accumulation is constrained by the spectral dose of UV-B, environmental exposure, tissue architecture, sterol localization, oxygen availability, antioxidant capacity, and ROS-mediated degradation. Studies of microalgae and phytoplankton, including reports concerning Emiliania huxleyi, suggest the occurrence or UV-B-dependent formation of both vitamin D2 and vitamin D3. However, these findings require evaluation according to the analytical method, use of authentic standards, experimental conditions, and confidence of compound identification. In fungi, the UV-B-induced conversion of abundant ergosterol to vitamin D2 is well established. Microalgae represent a developing source of vitamin D2 and vitamin D3, whereas evidence for nutritionally relevant vitamin D accumulation in higher plants remains limited and heterogeneous. Although higher plants contain diverse phytosterols, the formation of vitamin D4, vitamin D5, or related analogues requires appropriate photoreactive 5,7-diene precursors and should not be inferred directly from the presence of common phytosterols such as β-sitosterol. Analytical detection remains challenging because of low concentrations, complex lipophilic matrices, and structural similarity among secosteroids and photoproducts; therefore, reliable identification requires validated analytical procedures. LC-MS/MS provides high sensitivity and selectivity but should be supported by authentic standards, preferably isotope-labelled internal standards, retention-time agreement, quantitative and qualifying ions, matrix-recovery assessment, limits of detection and quantification, and evaluation of ion suppression. Structurally similar analogues and photoproducts may additionally require orthogonal confirmation. Nutritionally, post-harvest UV-B enrichment of edible mushrooms is currently the best-validated strategy for increasing non-animal vitamin D2 content. Microalgae constitute a developing platform for vitamin D2 and vitamin D3 production, whereas biofortification of higher plants remains experimental. Full article
(This article belongs to the Section Molecular Plant Sciences)
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18 pages, 27755 KB  
Article
Influence of Post Processing and Alloying with Zn on Formability of an Mg–2Al–0.5Ca–0.4Mn Alloy
by Christopher Hale, Zhigang Xu, Prithu Dhar and Jagannathan Sankar
Materials 2026, 19(15), 3168; https://doi.org/10.3390/ma19153168 - 24 Jul 2026
Viewed by 439
Abstract
Single-pass differential speed rolling (DSR) is an effective route for strengthening magnesium alloys through grain refinement induced by dynamic recrystallization (DRX); however, the accompanying strong basal texture often limits ductility and formability. In previous work, an Mg–2Al–0.5Ca–0.4Mn alloy (namely AXM20504) in the T4 [...] Read more.
Single-pass differential speed rolling (DSR) is an effective route for strengthening magnesium alloys through grain refinement induced by dynamic recrystallization (DRX); however, the accompanying strong basal texture often limits ductility and formability. In previous work, an Mg–2Al–0.5Ca–0.4Mn alloy (namely AXM20504) in the T4 condition was subjected to single-pass DSR with thickness reductions of 20% and 40% with a preheat temperature of 400 °C and a roll temperature of 300 °C, followed by post-annealing at 350–450 °C for durations of 20–60 min to systematically investigate static recrystallization (SRX), texture evolution, and mechanical response. Electron backscatter diffraction (EBSD) revealed that post-annealing promoted progressive SRX, with nearly complete recrystallization achieved at 450 °C for 40 min. This transition was accompanied by substantial basal texture weakening, reduced kernel average misorientation (KAM), and significantly lower grain orientation spread (GOS), indicating effective stress relief and formation of strain-free grains. As a result, tensile ductility increased from ~5% in the 40% as-rolled condition to ~12% after optimized post-annealing, while ultimate tensile strengths were retained above 200 MPa, much higher than the initial T4 strength. While these findings demonstrate that post-annealing is a critical step in restoring ductility and enhancing the formability of DSR-processed Mg alloys, certain types of alloying can also assist in a favorable balance between strength and formability for sheet forming applications. Alloying with Zn has been shown to improve ductility to a higher than 20% elongation at break as compared to 5% for the T4 AXM base material, showing that processing techniques and alloying have a high impact on the formability of Mg-based alloys. The zinc-based alloys in this study include Mg-2Al-0.5Ca-0.4Mn-0.5Zn (namely AXMZ2050405) and Mg-2Al-0.5Ca-0.4Mn-1Zn (namely AXMZ205041), both of which demonstrated improvements in mechanical properties as compared to the base alloy, AXM20504. Full article
(This article belongs to the Special Issue Metallic Rolling and Plastic Forming)
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15 pages, 4035 KB  
Article
Polymer Composition Modulates Dental Stem Cell Response and Mineralization in Electrospun Scaffolds for Hard Tissue Regeneration
by Caroline Anselmi, Sepideh Aminmansour, Igor Paulino Mendes Soares, Alexandre Henrique dos Reis-Prado, Sahar Aminmansour, Owen Liepman, Renan Dal-Fabbro, Josimeri Hebling and Marco C. Bottino
Biomimetics 2026, 11(8), 518; https://doi.org/10.3390/biomimetics11080518 - 23 Jul 2026
Viewed by 438
Abstract
Material selection is crucial to hard tissue regeneration, and matching scaffold properties to those of the target tissue can improve clinical outcomes. This study compared the physicochemical, mechanical, and biological performance of fibrous scaffolds fabricated from polycaprolactone (PCL), polydioxanone (PDO), and gelatin methacryloyl [...] Read more.
Material selection is crucial to hard tissue regeneration, and matching scaffold properties to those of the target tissue can improve clinical outcomes. This study compared the physicochemical, mechanical, and biological performance of fibrous scaffolds fabricated from polycaprolactone (PCL), polydioxanone (PDO), and gelatin methacryloyl (GelMA) for hard tissue regeneration. Polymeric fibers were produced by electrospinning, and their morphological, physical, and mechanical properties were characterized by scanning electron microscopy (SEM, n = 2), swelling and degradation analyses (n = 8), water contact angle measurements (n = 16), and tensile testing (n = 8). In addition, periodontal ligament stem cells (PDLSCs), alveolar bone marrow stem cells (aBMSCs), and dental pulp stem cells (DPSCs) were seeded onto the scaffolds to evaluate cell spreading (n = 4), viability (n = 8), and mineralized matrix formation (n = 6). Data were analyzed using one- or two-way ANOVA followed by appropriate post hoc tests (α = 5%). All polymers formed homogeneous fibrous scaffolds, with diameters within the nanoscale range. PDO and GelMA showed higher swelling than PCL, while PCL retained approximately 95% of its initial mass after three months. PCL and PDO showed higher elongation at break, tensile strength, and Young’s modulus than GelMA. Both PDO and GelMA displayed contact angles below 90°, with GelMA showing the lowest values. In vitro, all polymers were cytocompatible: PDO and GelMA enhanced DPSC viability at 7 days, whereas GelMA produced the highest viability for PDLSCs and aBMSCs at that time point. GelMA also promoted the highest mineralized matrix formation for DPSCs and PDLSCs, with no significant differences among polymers for aBMSCs. Overall, GelMA scaffolds promoted greater cell viability and mineralized matrix formation, while PCL and PDO provided superior mechanical properties, highlighting the importance of balancing biological and mechanical requirements when designing scaffolds for hard tissue regeneration. Full article
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15 pages, 6280 KB  
Article
Study on UV Aging of Thermoplastic Polyurethane and Its Crosslinked Product
by Hanyang Zhao, Qingjun Jin, Hongwei Zhao, Yunkai Yang, Xiang Cheng, Xiujuan Ren and Hongxing Shi
Polymers 2026, 18(14), 1778; https://doi.org/10.3390/polym18141778 - 21 Jul 2026
Viewed by 499
Abstract
To elucidate the formation of crosslinked products and their influence on material degradation, thermoplastic polyurethane (TPU) films were subjected to accelerated UV aging for various durations. Post-aging, the samples underwent Soxhlet extraction with tetrahydrofuran (THF), yielding an insoluble fraction—operationally defined as the crosslinked [...] Read more.
To elucidate the formation of crosslinked products and their influence on material degradation, thermoplastic polyurethane (TPU) films were subjected to accelerated UV aging for various durations. Post-aging, the samples underwent Soxhlet extraction with tetrahydrofuran (THF), yielding an insoluble fraction—operationally defined as the crosslinked product—and a soluble uncrosslinked fraction. The mechanical properties, molecular weight distribution, swelling behavior, thermal properties, and chemical structure were analyzed. As UV aging progressed, both tensile strength and elongation at break deteriorated markedly. Concurrently, GPC analysis revealed a continuous decrease in molecular weight and a broadening of the molecular weight distribution, confirming that chain scission was the dominant degradation pathway. An insoluble network-like residue, defined as the crosslinked product, first appeared after 12 h of aging, with its content increasing to 22.9% after 300 h. Swelling tests showed that the crosslinked product had a high gel fraction, and its swelling ratio decreased from 196.8% to 157.4%, indicating the formation of a stable and increasingly dense network. DSC and TG results revealed restricted segmental motion, altered thermal transition behavior, and enhanced char-forming ability. The glass transition temperature of the crosslinked product exceeded that of the pristine TPU film. FTIR analysis showed variations in the -NH2, C=O, C-O, and C-O-C bands, confirming structural evolution within both hard and soft segments. In summary, UV aging of TPU involves a complex interplay among chain scission, degradation of soft segments, rearrangement of hard segments, evolution of hydrogen bonds, and radical-induced crosslinking. Crucially, the crosslinked network formed during aging plays a pivotal role in determining the macroscopic structural, thermal, and mechanical properties of the polymer. Full article
(This article belongs to the Special Issue State-of-the-Art Polyurethane Research and Technology)
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17 pages, 10661 KB  
Article
Coupled Zircon Trace Element Systematics and Whole-Rock Geochemistry in Neoproterozoic A-Type Granites
by Aliaa Diab, Basem Zoheir, Ali Farrag Osman, Mokhles Azer, Rongqing Zhang and Mark Feigenson
Minerals 2026, 16(7), 715; https://doi.org/10.3390/min16070715 - 8 Jul 2026
Viewed by 460
Abstract
A-type granites represent high-temperature, highly differentiated felsic magmas formed in post-collisional and intraplate tectonic settings. While whole-rock geochemistry constrains bulk melt evolution, zircon trace element systematics provide higher-resolution insights into crystallization conditions, including temperature, oxidation state, and differentiation intensity. This study integrates whole-rock [...] Read more.
A-type granites represent high-temperature, highly differentiated felsic magmas formed in post-collisional and intraplate tectonic settings. While whole-rock geochemistry constrains bulk melt evolution, zircon trace element systematics provide higher-resolution insights into crystallization conditions, including temperature, oxidation state, and differentiation intensity. This study integrates whole-rock geochemical data with zircon trace element analyses to evaluate the extent to which zircon records magmatic evolution in Neoproterozoic A-type granites from Sinai, Egypt. Whole-rock compositions define a high-silica, ferroan differentiation trend characterized by enrichment in high-field-strength elements (HFSE) and pronounced negative Ba–Sr–Ti anomalies, indicating advanced fractional crystallization. Zircon trace element patterns exhibit strong heavy rare earth element (HREE) enrichment (Yb up to 1757 ppm), systematically negative Eu anomalies (mean Eu/Eu* = 0.32), and elevated Hf concentrations (up to 14,453 ppm; mean = 4763 ppm), reflecting progressive melt differentiation. Ti-in-zircon thermometry yields crystallization temperatures ranging from 562 °C to 1384 °C. However, most values cluster between 757 °C and 872 °C (mean ≈ 837 °C), indicating sustained high-temperature magmatic conditions. The broader temperature range likely reflects analytical uncertainties, assumptions in Ti activity, and possible outliers. Positive Ce anomalies indicate moderately oxidized crystallization environments. Systematic relationships among zircon Hf, Eu/Eu*, Yb/Gd, Th/U, and Ti-in-zircon temperatures demonstrate a strong coupling between zircon chemistry and whole-rock differentiation trends. These relationships are supported by statistically significant correlations, indicating that zircon trace element systematics provide a robust, semi-quantitative framework for interpreting melt evolution, while preserving independent constraints on temperature and redox state. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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16 pages, 9637 KB  
Article
Large Improvement of the Mechanical Strength of Carbon Nanotube Films by Joule Heating Dominated Post Treatments
by Zujia Hu, Yifan Feng, Heng Zhang, Kangfei Liu, Xinran Cheng, Yunxiao Du and Jiannong Wang
Materials 2026, 19(13), 2917; https://doi.org/10.3390/ma19132917 - 7 Jul 2026
Viewed by 511
Abstract
Carbon nanotube (CNT) films prepared via floating catalyst chemical vapor deposition generally suffer from residual iron impurities, structural defects, and weak inter-tube interfaces, which severely limit their mechanical performance. Here, we propose a post-treatment approach, which is dominated by Joule heating, to substantially [...] Read more.
Carbon nanotube (CNT) films prepared via floating catalyst chemical vapor deposition generally suffer from residual iron impurities, structural defects, and weak inter-tube interfaces, which severely limit their mechanical performance. Here, we propose a post-treatment approach, which is dominated by Joule heating, to substantially improve the mechanical properties of CNT films. Acid washing after Joule heating effectively removes iron catalyst and amorphous carbon, increasing the specific strength from 0.64 N/tex to 2.96 N/tex. Pre-stretching induces alignment of the CNTs along the stretching direction, further raising the specific strength to 5.57 N/tex. Subsequent Joule heating not only raises graphitization degree and repairs lattice defects but also transforms the weak van der Waals contacts between tubes into continuous carbon networks, leading to network densification and locking of the aligned structure. The final specific strength reaches 7.04 N/tex and true tensile strength 8.05 GPa, surpassing previous representative carbon materials. The purification mechanism of Joule heating depends on the initial iron content of the film: for high-iron films, iron melts, migrates and forms Fe/Fe3C@C core–shell particles, which can be converted into hollow carbon shells via acid etching; for low-iron films, iron is removed via atomic diffusion and evaporation. This work provides a fast, controllable and synergistic technical route for the preparation of high-performance CNT macrostructures. Full article
(This article belongs to the Section Advanced Nanomaterials and Nanotechnology)
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27 pages, 5089 KB  
Review
Toward Predictive Design of Lignocellulosic Mycelium-Bound Composites: A Process–Structure–Property Framework, Quantitative Synthesis, and Standardization Roadmap
by Musiliu A. Liadi, Tawakalt O. Ayodele, Ibrahim A. Bello, C. Igathinathane and Hammed M. Ademola
Polymers 2026, 18(13), 1652; https://doi.org/10.3390/polym18131652 - 2 Jul 2026
Viewed by 709
Abstract
Mycelium-bound composites (MBCs) have emerged as a promising class of biofabricated materials that integrate fungal hyphal networks with lignocellulosic substrates to form lightweight, biodegradable structures without synthetic adhesives. Despite rapid growth in the field, the current literature remains fragmented, with inconsistent methodologies and [...] Read more.
Mycelium-bound composites (MBCs) have emerged as a promising class of biofabricated materials that integrate fungal hyphal networks with lignocellulosic substrates to form lightweight, biodegradable structures without synthetic adhesives. Despite rapid growth in the field, the current literature remains fragmented, with inconsistent methodologies and widely varying reported material properties. This review advances the field by moving beyond descriptive synthesis toward a quantitative and conceptual integration of existing studies. We systematically analyze how key fabrication variables—including fungal species, substrate composition, growth conditions, and post-processing parameters—govern density, porosity, and mechanical performance. A process–structure–property (PSP) framework is proposed to combine these relationships and explain discrepancies across studies. We highlight the dominant role of densification and moisture conditioning in determining compressive strength, often outweighing species-level effects. A comparative synthesis of reported data reveals significant variability in compressive strength (0.05–1.2 MPa) and elastic modulus, attributable to inconsistencies in sample preparation, testing protocols, and environmental conditioning. To address this, we identify critical gaps in standardization and propose actionable testing protocols and reporting guidelines for reproducibility. Furthermore, we assess the technology readiness level (TRL) of MBC systems and distinguish between laboratory-scale innovations and commercially viable processes. While hybridization strategies and biofunctional applications offer promising avenues, their maturity varies widely. This work provides a decision-oriented framework for MBC design and a roadmap for transitioning these materials from experimental systems to scalable, standardized, and application-ready biomaterials. Full article
(This article belongs to the Special Issue Advanced Study on Lignin-Containing Composites)
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37 pages, 857 KB  
Article
A Modular Knowledge-Extraction Framework for Deep Learning Forecasts of Multi-Tier Commodity Prices
by Montchai Pinitjitsamut
Mach. Learn. Knowl. Extr. 2026, 8(7), 185; https://doi.org/10.3390/make8070185 - 1 Jul 2026
Viewed by 301
Abstract
Vertically linked commodity markets—global futures, regional spot, and farm-gate prices—transmit information through directed cross-market channels whose strength varies with latent volatility regimes. Standard deep learning forecasters absorb both the directed cross-market dependence and the regime dependence of intrinsic-mode-aligned latent components into shared model [...] Read more.
Vertically linked commodity markets—global futures, regional spot, and farm-gate prices—transmit information through directed cross-market channels whose strength varies with latent volatility regimes. Standard deep learning forecasters absorb both the directed cross-market dependence and the regime dependence of intrinsic-mode-aligned latent components into shared model weights, with no explicit architectural mechanism that exposes either as an inspectable structure. This paper proposes HVB-RA, a modular framework that combines two such mechanisms with a per-tier Variational Mode Decomposition and bidirectional LSTM backbone: (i) a directed cross-market attention layer in which the upstream-to-downstream topology is supplied from domain knowledge and the time-varying upstream-source attention intensities at the farm-gate tier (the regional-spot tier, with a single upstream key, reduces algebraically to a fixed residual upstream fusion) are extracted from data, and (ii) a regime-informed modal-weighting layer that mixes two trainable softmax weight profiles over IMF-aligned latent components through a filtered Markov-switching state probability fitted in a separate stage. An auxiliary post hoc projection enforces an exact linear constraint defined by long-run sample-mean ratios across tiers; the paper does not claim that these descriptive ratios are cointegrating relations or equilibrium coefficients. The framework is evaluated on three tiers of daily natural-rubber prices spanning 2038 trading days, against three external benchmarks (random walk, ARIMA(2,0,2), and an exogenous-only LSTM) and a contemporary neural hierarchical-interpolation forecaster (NHITS). Root mean squared error is reported per tier-horizon cell; a decision-aware income-smoothing metric quantifies the operational value of h=5 farm-gate forecasts under a 5-day selling rule; and a within-method comparison evaluates the marginal contribution of the auxiliary constraint projection. On the present single-regime test window, HVB-RA attains a lower point error than the contemporary NHITS baseline at every tier-horizon cell, while no method—including HVB-RA—improves on the random-walk floor at most cells; the regime-conditional components of the architecture are not identifiable because every calibration and test origin is classified as a high-volatility regime by the trained Markov-switching model. The paper contributes to machine learning and knowledge extraction by demonstrating how time-varying upstream-source attention intensities at the farm-gate tier and regime-dependent latent-component-weight profiles—two forms of latent structure typically absorbed into model weights—can be exposed as explicit, inspectable, and individually testable components of a multi-tier forecasting architecture, and by providing a reproducibility package documenting the conditions under which each component is expected to be identifiable. Full article
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31 pages, 3736 KB  
Article
Potentials of Different Water-Storage Mats Treating Greywater from a Canteen: From Laboratory to Pilot-Scale Testing
by Khaja Zillur Rahman, Emilia Engelhardt, Jens Mählmann, Michael Blumberg, Katy Bernhard, Roland A. Müller and Lucie Moeller
Urban Sci. 2026, 10(7), 361; https://doi.org/10.3390/urbansci10070361 - 30 Jun 2026
Viewed by 457
Abstract
Water scarcity is an increasingly urgent global challenge, prompting the development of new water purification technologies that surpass conventional solutions. Decentralized greywater treatment is emerging as a viable option for enhancing water reuse in multifunctional systems that contribute to microclimate regulation, cooling, and [...] Read more.
Water scarcity is an increasingly urgent global challenge, prompting the development of new water purification technologies that surpass conventional solutions. Decentralized greywater treatment is emerging as a viable option for enhancing water reuse in multifunctional systems that contribute to microclimate regulation, cooling, and urban climate adaptation. In this context, water-storage mats have been identified as a form of decentralized, roof-based biofilter for greywater treatment. The aim of this study was to assess the performance of newly developed, innovative, bio-based textile mats and assess their effectiveness in treating pre-treated greywater from a canteen (CGW) with a high organic content, in both laboratory- and pilot-scale experiments. The findings from the lab-scale testing revealed that the mats made from polyethylene terephthalate (PET) nonwoven fabric materials had the highest water storage capacity and dried out more slowly in outdoor conditions than mats made from polylactide (PLA) spunbonded fabric and polyhydroxyalkanoate (PHA) spunbonded nonwoven fabric. The PET hydroentangled nonwoven fabric mat (PET-WS) performed better than the other sample mats in the lab-scale experiment, and also outperformed the PHA mat consistently in the pilot-scale experiment when treating CGW. Apparent reductions in the concentration of the macro-pollutant parameters were observed at the outflow of the PET-WS mat compared to the inflow (p < 0.05) at the pilot-scale. Mean concentration reductions were comparatively higher for the five-day biochemical oxygen demand (BOD5), chemical oxygen demand (COD), total nitrogen (TN), and total suspended solids (TSS), with mean reductions of 64%, 54%, 39% and 60%, respectively. This indicated the superior treatment performance of the PET-WS mat compared to the PHA mat, with mean reductions of only 36%, 25%, 6%, and 32%, respectively. However, the lower E. coli counts of 1.1 and 0.5 log reduction for the PET-WS and PHA mats, respectively, indicated that an additional disinfection unit was necessary. The findings of this study may help to determine the performance, stability and reliability of using lightweight, nonwoven fabric mats to treat high-strength GW, which is currently considered as an intermediate treatment step. The study also provides recommendations for process optimization. Additional post-treatment steps are required to produce high-quality treated effluent for non-potable reuse, particularly in urban areas facing high water scarcity, provided that the relevant reuse regulations or discharge criteria are met. Full article
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