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13 pages, 6838 KiB  
Article
Preparation and Bonding Properties of Fabric Veneer Plywood
by Ziyi Yuan, Limei Cheng, Chengsheng Gui and Lu Fang
Coatings 2025, 15(8), 864; https://doi.org/10.3390/coatings15080864 - 23 Jul 2025
Viewed by 309
Abstract
Fabric veneer panels were prepared using ethylene-vinyl acetate copolymer film (EVA) as the intermediate layer and poplar plywood as the substrate. Eight fabrics with different compositions were selected for evaluation to screen out fabric materials suitable for poplar plywood veneer. The fabrics were [...] Read more.
Fabric veneer panels were prepared using ethylene-vinyl acetate copolymer film (EVA) as the intermediate layer and poplar plywood as the substrate. Eight fabrics with different compositions were selected for evaluation to screen out fabric materials suitable for poplar plywood veneer. The fabrics were objectively analyzed by bending and draping, compression, and surface roughness, and subjectively evaluated by establishing seven levels of semantic differences. ESEM, surface adhesive properties, and peel resistance tests were used to characterize the microstructure and physical–mechanical properties of the composites. The results show that cotton and linen fabrics and corduroy fabrics are superior to other fabrics in performance, and they are suitable for decorative materials. Because the fibers of the doupioni silk fabric are too thin, and the fibers of felt fabric are randomly staggered, they are not suitable for the surface decoration materials of man-made panels. The acetate veneer surface gluing performance was 1.31 MPa, and the longitudinal peel resistance was 20.98 N, significantly exceeding that of other fabric veneers. Through the subjective and objective analysis of fabrics and gluing performance tests, it was concluded that, compared with fabrics made of natural fibers, man-made fiber fabrics are more suitable for use as surface finishing materials for wood-based panels. The results of this study provide a theoretical basis and process reference for the development of environmentally friendly decorative panels, which can be expanded and applied to furniture, interior decoration, and other fields. Full article
(This article belongs to the Special Issue Innovations in Functional Coatings for Wood Processing)
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17 pages, 1090 KiB  
Review
Overview and Evaluation of Chemicals and Methods for Flame Retardancy in Glued Laminated Wood Systems
by Ewelina Depczynska and Izabela Burawska
Polymers 2025, 17(11), 1459; https://doi.org/10.3390/polym17111459 - 24 May 2025
Viewed by 677
Abstract
Due to the development of wooden construction as an ecological alternative to brick construction with a high carbon footprint, there is increasing interest in materials such as plywood and LVL (Laminated Veneer Lumber). These engineered wood products have many advantages compared to wood, [...] Read more.
Due to the development of wooden construction as an ecological alternative to brick construction with a high carbon footprint, there is increasing interest in materials such as plywood and LVL (Laminated Veneer Lumber). These engineered wood products have many advantages compared to wood, such as a more uniform distribution of bending, shear, tensile, and compressive strength. However, they require improvements in fire and biological resistance. The flammability of wood and wood composites is a challenge that will allow these materials to stand out as structural or finishing materials. During combustion, toxic gases may be released, which can be harmful to people and the environment. Therefore, it is crucial to clarify whether fire-resistant wood materials are truly resistant to fire and non-toxic in fire conditions. On the other hand, flame retardants should not reduce the mechanical parameters of panels. This work analyses the current requirements (standards) regarding plywood intended for construction and the existing flame retardants for plywood and LVL based on the latest reports in the literature. We then propose an original method for evaluating future chemicals. Additionally, methods for assessing the flame retardancy of plywood and LVL based on the latest reports in the literature are described, and an original method for assessing flame retardancy methods is proposed. Full article
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18 pages, 2729 KiB  
Article
Machine Learning and Industrial Data for Veneer Quality Optimization in Plywood Manufacturing
by Mario Ramos-Maldonado, Felipe Gutiérrez, Rodrigo Gallardo-Venegas, Cecilia Bustos-Avila, Eduardo Contreras and Leandro Lagos
Processes 2025, 13(4), 1229; https://doi.org/10.3390/pr13041229 - 18 Apr 2025
Cited by 1 | Viewed by 862
Abstract
The plywood industry is one of the most significant sub-sectors of the forestry industry and serves as a cornerstone of sustainable construction within a bioeconomy framework. Plywood is a panel composed of multiple layers of wood sheets bonded together. While automation and process [...] Read more.
The plywood industry is one of the most significant sub-sectors of the forestry industry and serves as a cornerstone of sustainable construction within a bioeconomy framework. Plywood is a panel composed of multiple layers of wood sheets bonded together. While automation and process monitoring have played a crucial role in improving efficiency, data-driven decision-making remains underutilized in the industrial sector. Many industrial processes continue to rely heavily on the expertise of operators rather than on data analytics. However, advancements in data storage capabilities and the availability of high-speed computing have paved the way for data-driven algorithms that can support real-time decision-making. Due to the biological nature of wood and the numerous variables involved, managing manufacturing operations is inherently complex. The multitude of process variables, and the presence of non-linear physical phenomena make it challenging to develop accurate and robust analytical predictive models. As a result, data-driven approaches—particularly Artificial Intelligence (AI)—have emerged as highly promising modeling techniques. Leveraging industrial data and exploring the application of AI algorithms, particularly Machine Learning (ML), to predict key performance indicators (KPIs) in process plants represent a novel and expansive field of study. The processing of industrial data and the evaluation of AI algorithms best suited for plywood manufacturing remain key areas of research. This study explores the application of supervised Machine Learning (ML) algorithms in monitoring key process variables to enhance quality control in veneers and plywood production. The analysis included Random Forest, XGBoost, K-Nearest Neighbors (KNN), Support Vector Machine (SVM), Lasso, and Logistic Regression. An initial dataset comprising 49 variables related to the maceration, peeling, and drying processes was refined to 30 variables using correlation analysis and Lasso variable selection. The final dataset, encompassing 13,690 records, categorized into 9520 low-quality labels and 4170 high-quality labels. The evaluation of classification algorithms revealed significant performance differences; Random Forest reached the highest accuracy of 0.76, closely followed by XGBoost. K-Nearest Neighbors (KNN) demonstrated notable precision, while Support Vector Machine (SVM) exhibited high precision but low recall. Lasso and Logistic Regression showed comparatively lower performance metrics. These results highlight the importance of selecting algorithms tailored to the specific characteristics of the dataset to optimize model effectiveness. The study highlights the critical role of AI-driven insights in improving operational efficiency and product quality in veneer and plywood manufacturing, paving the way for enhanced industrial competitiveness. Full article
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19 pages, 2090 KiB  
Article
Plywood Manufacturing Using Various Combinations of Hardwood Species
by Marcus Cordier, Nils Johannsen, Bettina Kietz, Dirk Berthold and Carsten Mai
Forests 2025, 16(4), 622; https://doi.org/10.3390/f16040622 - 2 Apr 2025
Viewed by 586
Abstract
This study evaluates the potential of various hardwood combinations in plywood production in response to increasing wood demand and a changing roundwood supply in Central Europe. Six different combinations of nine-layer plywood were produced using 2 mm rotary-cut veneers from lime (Tilia [...] Read more.
This study evaluates the potential of various hardwood combinations in plywood production in response to increasing wood demand and a changing roundwood supply in Central Europe. Six different combinations of nine-layer plywood were produced using 2 mm rotary-cut veneers from lime (Tilia spp.), Norway maple (Acer platanoides), European hornbeam (Carpinus betulus), Sycamore maple (Acer pseudoplatanus), mountain ash (Sorbus aucuparia), and European beech (Fagus sylvatica) with phenol–formaldehyde adhesive, and they were compared to silver birch (Betula pendula) plywood as a reference. The raw densities of the test panels varied between 0.85 and 1.04 times the reference density (795 kg m−3). Flexural strengths (the modulus of rupture, MOR) ranged from 68 N mm−2 to 104 N mm−2 for a parallel fibre orientation and 44 N mm−2 to 61 N mm−2 for a perpendicular fibre orientation of the top layers. The modulus of elasticity (MOE) ranged from 7160 N mm−2 to 11,737 N mm−2 for the parallel fibre orientation and from 4366 N mm−2 to 5575 N mm−2 for the perpendicular orientation. The tensile shear strength varied between 0.91 and 1.69 times the reference (1.49 N mm−2). The thickness swelling after 24 h was higher in all variants than the reference (6.4%), with factors between 1.39 and 1.64. A significant effect was observed when layers with a lower density were arranged on the outside and those with a higher density in the core, resulting in a more uniform density distribution across the cross-section after hot pressing. This created a levelling effect on mechanical and physical properties, especially the modulus of rupture (MOR) and the modulus of elasticity (MOE). Overall, the evaluated hardwood combinations demonstrated comparable properties to the birch reference and industrially produced birch plywood. Full article
(This article belongs to the Special Issue Novelties in Wood Engineering and Forestry—2nd Edition)
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18 pages, 13594 KiB  
Article
Upcycling Calcium Carbonate as an Alternative Filler in Layered Wood Composite Technology
by Julia Dasiewicz and Grzegorz Kowaluk
Materials 2025, 18(2), 226; https://doi.org/10.3390/ma18020226 - 7 Jan 2025
Viewed by 1074
Abstract
Chicken eggshells are a useful waste that may be used somewhere rather than being placed in landfills. They are created in poultry hatcheries, the food sector (making pasta, cakes, and egg products), or our homes. In this project, this study aimed to investigate [...] Read more.
Chicken eggshells are a useful waste that may be used somewhere rather than being placed in landfills. They are created in poultry hatcheries, the food sector (making pasta, cakes, and egg products), or our homes. In this project, this study aimed to investigate the possibility of producing plywood using a filler in the gluing process in the form of ground eggshells. This study includes the production of plywood with 0, 1, 5, 10, and 20 parts by weight (pbw) of eggshell filler (called E0, E1, E5, E10, and E20, respectively) and one reference variant with rye flour (10 pbw; hereafter called REF10). This research also includes investigating the produced panels’ selected physical and mechanical properties. The results show that chicken eggshells can be used to produce plywood if the right amount of filler is chosen to improve specific mechanical and physical properties. Promising properties were obtained in the determination of the modulus of elasticity under bending (MOE) for samples E5 (11,310 N mm−2) and E10 (11,394 N mm−2) and modulus of rupture (MOR) for sample E5 (130 N mm−2). The results for the internal bond (IB) show that the addition of 5 pbw of filler in the form of ground shells shows good properties with as much as 5.23 N mm−2, but still, the reference sample with the addition of filler in the form of rye flour has higher results of 6.22 N mm−2. In the test of water absorption of fillers, the absorption of calcium carbonate is 207% and is lower than that of rye flour (224%). For the swelling thickness results, the E10 sample showed the weakest results of 7.6% after 2 h and 8.9% swelling after 24 h. Full article
(This article belongs to the Section Biomaterials)
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28 pages, 14370 KiB  
Article
Experimental Study on Mechanical Performance of Single-Side Bonded Carbon Fibre-Reinforced Plywood for Wood-Based Structures
by Krzysztof Szwajka, Joanna Zielińska-Szwajka, Tomasz Trzepieciński and Marek Szewczyk
Materials 2025, 18(1), 207; https://doi.org/10.3390/ma18010207 - 6 Jan 2025
Viewed by 1080
Abstract
In addition to the traditional uses of plywood, such as furniture and construction, it is also widely used in areas that benefit from its special combination of strength and lightness, particularly as a construction material for the production of finishing elements of campervans [...] Read more.
In addition to the traditional uses of plywood, such as furniture and construction, it is also widely used in areas that benefit from its special combination of strength and lightness, particularly as a construction material for the production of finishing elements of campervans and yachts. In light of the current need to reduce emissions of climate-damaging gases such as CO2, the use of lightweight construction materials is very important. In recent years, hybrid structures made of carbon fibre-reinforced plastics (CFRPs) and metals have attracted much attention in many industries. In contrast to hybrid metal/carbon fibre composites, research relating to laminates consisting of CFRPs and wood-based materials shows less interest. This article analyses the hybrid laminate resulting from bonding a CFRP panel to plywood in terms of strength and performance using a three-point bending test, a static tensile test and a dynamic analysis. Knowledge of the dynamic characteristics of carbon fibre-reinforced plywood allows for the adoption of such cutting parameters that will help prevent the occurrence of self-excited vibrations in the cutting process. Therefore, in this work, it was decided to determine the effect of using CFRP laminate on both the static and dynamic stiffness of the structure. Most studies in this field concern improving the strength of the structure without analysing the dynamic properties. This article proposes a simple and user-friendly methodology for determining the damping of a sandwich-type system. The results of strength tests were used to determine the modulus of elasticity, modulus of rupture, the position of the neutral axis and the frequency domain characteristics of the laminate obtained. The results show that the use of a CFRP-reinforced plywood panel not only improves the visual aspect but also improves the strength properties of such a hybrid material. In the case of a CFRP-reinforced plywood panel, the value of tensile stresses decreased by sixteen-fold (from 1.95 N/mm2 to 0.12 N/mm2), and the value of compressive stresses decreased by more than seven-fold (from 1.95 N/mm2 to 0.27 N/mm2) compared to unreinforced plywood. Based on the stress occurring at the tensile and compressive sides of the CFRP-reinforced plywood sample surface during a cantilever bending text, it was found that the value of modulus of rupture decreased by three-fold and the value of the modulus of elasticity decreased by more than five-fold compared to the unreinforced plywood sample. A dynamic analysis allowed us to determine that the frequency of natural vibrations of the CFRP-reinforced plywood panel increased by about 33% (from 30 Hz to 40 Hz) compared to the beam made only of plywood. Full article
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14 pages, 3768 KiB  
Article
Enhancing the Performance of Layered Wood Composites Through the Non-Food Application of Dietary Fiber in Their Bonding Matrix
by Marta Wronka, Anita Wronka and Grzegorz Kowaluk
Appl. Sci. 2024, 14(24), 11780; https://doi.org/10.3390/app142411780 - 17 Dec 2024
Viewed by 952
Abstract
Rye flour is a commonly used filler in plywood production, made from finely ground rye grains. It enhances glue viscosity, ensuring even distribution and better adhesion, which improves the plywood’s mechanical properties, dimensional stability, and resistance to warping. Additionally, rye flour increases the [...] Read more.
Rye flour is a commonly used filler in plywood production, made from finely ground rye grains. It enhances glue viscosity, ensuring even distribution and better adhesion, which improves the plywood’s mechanical properties, dimensional stability, and resistance to warping. Additionally, rye flour increases the plywood’s strength and durability, making it more resistant to mechanical damage and external factors. Its affordability and availability further support its widespread use in plywood production. However, the growing availability of new raw materials has sparked interest in alternative fillers, especially considering food waste challenges caused by low demand or poor household management. This study explores the potential of spirulina, bamboo flour, lupine flour, and coconut flour as alternative fillers to rye flour, being part of the food chain, in three-layer plywood production. Plywood panels were manufactured using birch and pine veneers, urea-formaldehyde resin, and varying filler contents (10, 15, and 20 parts by weight/pbw). Key mechanical properties were evaluated, including modulus of elasticity (MOE), modulus of rupture (MOR), shear strength, density profile, and filler water absorption. The highest MOE for hardwood plywood was observed with coconut flour (20 pbw, 17,228 N mm−2). Conversely, the lowest MOE values were recorded for coniferous plywood with spirulina (8440 N mm−2). For MOR, the best performance in softwood was achieved using lupine flour (10 pbw, 113 N mm−2), while coconut flour yielded the highest MOR in hardwood plywood (20 pbw, 177 N mm−2). Spirulina exhibited the lowest MOR (72 N mm−2, 15 pbw). Shear strength peaked with lupine and coconut flour. The filler composition determines adhesive properties and bond performance through water absorption, structural interactions, and filler content optimization. These findings emphasize the potential for fine-tuning alternative fillers to achieve desired mechanical performance, ensuring sustainable and efficient plywood production. These also demonstrate the potential of certain alternative fillers, particularly coconut and lupine flours, excluded from the food value chain, in improving specific properties of plywood. Full article
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10 pages, 3406 KiB  
Article
Development and Characterization of an Environmentally Friendly Soy Protein-Modified Phenol–Formaldehyde Resin for Plywood Manufacturing
by Taotao Li, Zhanjun Liu, Shiquan Liu and Cheng Li
Forests 2024, 15(12), 2130; https://doi.org/10.3390/f15122130 - 1 Dec 2024
Viewed by 1202
Abstract
Most wood-based panels were currently prepared using aldehyde-based adhesives, making the development of natural, renewable, and eco-friendly biomass-based adhesives a prominent area of research. Herein, the phenolic resin was modified using a soybean protein isolate (SPI) treated with a NaOH/urea solution through a [...] Read more.
Most wood-based panels were currently prepared using aldehyde-based adhesives, making the development of natural, renewable, and eco-friendly biomass-based adhesives a prominent area of research. Herein, the phenolic resin was modified using a soybean protein isolate (SPI) treated with a NaOH/urea solution through a copolymerization method. The physicochemical properties, chemical structure, bonding properties, and thermal properties of the soybean protein-modified phenolic resin (SPF-U) were analyzed using Fourier transform infrared spectroscopy, thermogravimetric analysis, and formaldehyde emission tests. The results indicated that the molecular structure of the soy protein isolate degraded after NaOH/urea solution treatment, while the gel time was gradually shortened with increasing NaOH/urea solution-treated soy protein isolate (SPI-U) dosages. Although the thermal stability of the soy protein isolate was lower than that of the phenolic resin, the 20% SPF-U resin demonstrated better thermal stability than other modified resins. The PF modified with 30% SPI-U (SPF-U-3) exhibited the lowest curing peak temperature of 139.69 °C than that of the control PF resin. In addition, all modified PF resins exhibited formaldehyde emissions ranging from 0.18 to 0.38 mg/L when the SPI-U dosage varied between 20% and 50%, thereby meeting the E0 plywood grade standard (≤0.5 mg/L). Full article
(This article belongs to the Section Wood Science and Forest Products)
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13 pages, 3186 KiB  
Article
Modulus of Elasticity in Plywood Boards: Comparison between a Destructive and a Nondestructive Method
by Ricardo de la Cruz-Carrera, Artemio Carrillo-Parra, José Ángel Prieto-Ruíz, Francisco Javier Fuentes-Talavera, Faustino Ruiz-Aquino and José Rodolfo Goche-Télles
Forests 2024, 15(9), 1596; https://doi.org/10.3390/f15091596 - 11 Sep 2024
Cited by 1 | Viewed by 2281
Abstract
Nondestructive methods are a fast and accurate way to obtain information about the mechanical properties of plywood panels. The objective was to determine the modulus of rupture and compare the modulus of elasticity (MOE) in plywood boards made with Pinus spp. and Eucalyptus [...] Read more.
Nondestructive methods are a fast and accurate way to obtain information about the mechanical properties of plywood panels. The objective was to determine the modulus of rupture and compare the modulus of elasticity (MOE) in plywood boards made with Pinus spp. and Eucalyptus urograndis using the destructive method of three-point static bending and the nondestructive method of ultrasound in parallel and perpendicular directions, as well as in complete board and test specimens, both with the ultrasound method and the correlation between the variables studied. The plywood boards evaluated were 18, 25 and 30 mm nominal thickness. Five structures were evaluated using pine and pine–eucalyptus veneers. Three boards were collected per structure, and 28 specimens were made from each board (14 in a parallel direction and 14 in a perpendicular direction). The elastic modulus was determined by the ultrasound method in complete plywood boards and in specimens obtained from them using the IML Micro Hammer® equipment and through the conventional bending test, carried out in an Instron® universal mechanical testing machine. The Tukey test of means (p < 0.05) shows that in the nominal thickness of 18 mm, the modulus of elasticity by ultrasound was lower compared to the result obtained by static bending in four of the five structures in the perpendicular direction and lower in all the structures evaluated in the parallel direction; while in the nominal thickness of 25 and 30 mm, it was greater in all structures and in both directions. The results of static bending by ultrasound, in complete boards and specimens, show that the only significant difference (p < 0.05) occurs in the nominal thickness of 30 mm in the treatment made with pine–eucalyptus with urea formaldehyde resin being lower in the parallel direction and in complete boards The correlation between the modulus of elasticity determined on specimens using the nondestructive method and the destructive method was r = 0.75 and Pr < 0.05; while comparing the nondestructive method on test specimens and complete plywood panels, r = 0.73 and Pr < 0.05 were obtained. It is concluded that the mechanical bending property of plywood boards can be characterized by the ultrasound method. Full article
(This article belongs to the Special Issue Recent Advances in Wood Identification, Evaluation and Modification)
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18 pages, 4887 KiB  
Article
Finite Element Modeling of the Dynamic Response of Plywood
by Arkadiusz Charuk, Katarzyna Gawdzińska and Paweł Dunaj
Materials 2024, 17(17), 4358; https://doi.org/10.3390/ma17174358 - 3 Sep 2024
Cited by 2 | Viewed by 1409
Abstract
Modeling the dynamic properties of wood and wood-based composites is a challenging task due to naturally growing structure and moisture-dependent material properties. This paper presents the finite element modeling of plywood panels’ dynamic properties. Two panels differing in thickness were analyzed: (i) 18 [...] Read more.
Modeling the dynamic properties of wood and wood-based composites is a challenging task due to naturally growing structure and moisture-dependent material properties. This paper presents the finite element modeling of plywood panels’ dynamic properties. Two panels differing in thickness were analyzed: (i) 18 mm and (ii) 27 mm. The developed models consisted of individual layers of wood, which were discretized using three-dimensional finite elements formulated using an orthotropic material model. The models were subjected to an updating procedure based on experimentally determined frequency response functions. As a result of a model updating relative errors for natural frequencies obtained numerically and experimentally were not exceeding 2.0%, on average 0.7% for 18 mm thick panel and not exceeding 2.6%, on average 1.5% for 27 mm thick panel. To prove the utility of the method and at the same time to validate it, a model of a cabinet was built, which was then subjected to experimental verification. In this case, average relative differences for natural frequencies of 6.6% were obtained. Full article
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14 pages, 3478 KiB  
Article
The Influence of Various Modifications of Hazelnut Shell Flour as Potential Filler in Plywood Technology
by Marta Wronka, Damian Wojnicz and Grzegorz Kowaluk
Materials 2024, 17(16), 4128; https://doi.org/10.3390/ma17164128 - 20 Aug 2024
Cited by 6 | Viewed by 1383
Abstract
This study investigates the potential of utilizing hazelnut shells (HS) as an innovative filler in three-layer plywood technology, addressing the growing need for sustainable, high-performance materials. Traditional plywood production relies on adhesives enhanced with various fillers to improve physical, mechanical, and operational characteristics. [...] Read more.
This study investigates the potential of utilizing hazelnut shells (HS) as an innovative filler in three-layer plywood technology, addressing the growing need for sustainable, high-performance materials. Traditional plywood production relies on adhesives enhanced with various fillers to improve physical, mechanical, and operational characteristics. This research explores using native, chemically modified, and activated carbon derived from hazelnut shells as fillers in urea–formaldehyde (UF) resin. The produced plywood’s mechanical properties, water absorption, and formaldehyde emissions were thoroughly analyzed. Key findings demonstrate that incorporating 10 part by weight (pbw) native hazelnut shell flour significantly enhances the modulus of rupture (MOR) to 138.6 N mm−2 and modulus of elasticity (MOE) to 13,311 N mm−2. Chemically modified hazelnut shell flour achieves optimal results at 5 pbw, while activated carbon from hazelnut shells, even at 1 pbw, markedly improves bonding strength (2.79 N mm−2 referred to 0.81 N mm−2 for reference sample without filler added). Notably, activated carbon effectively reduces formaldehyde emissions (2.72 mg 100 g−1 oven dry panel referred to 3.32 mg 100 g−1 oven dry panel for reference samples with 10 pbw filler) and improves water resistance, indicating better further dimensional stability and lower environmental impact. The study also shows that excessive filler content negatively affects strength parameters, confirming the importance of optimizing filler concentration. These results highlight the potential of hazelnut shells as an eco-friendly alternative filler in plywood production, contributing to waste valorization and environmental sustainability. This study supports the practical application of hazelnut shell fillers, promoting a circular economy and reducing reliance on traditional, less sustainable materials, thus providing a valuable solution for the wood composite industry. Full article
(This article belongs to the Special Issue Modern Wood-Based Materials for Sustainable Building)
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17 pages, 7366 KiB  
Article
A Potential Replacement to Phenol–Formaldehyde-Based Adhesives: A Study of Plywood Panels Manufactured with Bio-Based Wood Protein and Nanolignin Adhesives
by Mario Núñez-Decap, Catherine Friz-Sánchez, Camila Opazo-Carlsson, Boris Moya-Rojas and Marcela Vidal-Vega
Forests 2024, 15(8), 1345; https://doi.org/10.3390/f15081345 - 2 Aug 2024
Cited by 4 | Viewed by 1516
Abstract
Plywood production relies on phenol–formaldehyde (PF), which is why bio-based wood adhesives (BBWAs) were developed as potential replacements, showing promising results in several tests performed. A control sample (PLY-C) with PF and two samples (PLY-1 and PLY-2) with BBWA were manufactured, on which [...] Read more.
Plywood production relies on phenol–formaldehyde (PF), which is why bio-based wood adhesives (BBWAs) were developed as potential replacements, showing promising results in several tests performed. A control sample (PLY-C) with PF and two samples (PLY-1 and PLY-2) with BBWA were manufactured, on which physical and mechanical properties, adhesive bonding morphology, formaldehyde emissions, and accelerated UV aging were evaluated. The adhesive penetration results, into the wood cells, were according to the viscosity of each adhesive. About the mechanical properties, the sample PLY-2 presented the same MOE and tensile strength as the sample PLY-C and reached 87% of the sample PLY-C MOR in the parallel direction. On the other hand, the sample PLY-1 presented the same behavior in the Janka hardness test as the sample PLY-C. All the samples subjected to shear strength tests met the requirement, and the samples PLY-1 and PLY-2 reached 68% and 80% of the PLY-C sample, respectively. The samples manufactured with BBWA presented a decrease in formaldehyde emissions by 88% and they were less susceptible to color change than the control sample under UV aging. According to the results obtained, it is concluded that plywood manufactured with BBWA might be a considerable replacement for plywood manufactured with PF adhesives at a laboratory scale. Full article
(This article belongs to the Special Issue Sustainable Valorization of Forestry Byproducts)
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19 pages, 9043 KiB  
Article
New Bio-Based Binding Systems for Plywood Panels
by Electra Papadopoulou, Dimitrios Moutousidis, Sotirios Kountouras, Aikaterini Argyropoulou, Panagiotis Stathopoulos, Alexios Leandros Skaltsounis, Rafail O. Ioannidis, Eleftheria Xanthopoulou, Lamprini Malletzidou and Konstantinos Chrissafis
Appl. Sci. 2024, 14(13), 5862; https://doi.org/10.3390/app14135862 - 4 Jul 2024
Viewed by 1477
Abstract
This study investigated the use of non-formaldehyde binders in the production of plywood panels, focusing on mixtures containing 70% poly 4,4’-methylene diphenyl isocyanate (pMDI) and 30% soy flour (SF), along with blends of soy flour and agricultural residues (olive by-products—with and without extraction [...] Read more.
This study investigated the use of non-formaldehyde binders in the production of plywood panels, focusing on mixtures containing 70% poly 4,4’-methylene diphenyl isocyanate (pMDI) and 30% soy flour (SF), along with blends of soy flour and agricultural residues (olive by-products—with and without extraction of their bioactive ingredients—and defatted hemp seeds). The basic properties of these biomaterials, such as moisture content, pH, and buffering capacity, were determined with laboratory analysis. Adhesive mixtures were characterized using attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and thermogravimetric analysis (TGA). The adhesive’s bonding ability was evaluated by manufacturing plywood panels on a laboratory scale, simulating industrial practices. The glue lines were visually inspected with a stereomicroscope. Micro-ATR-FTIR study of the cross-sections of plywood panels showed the full consumption of isocyanate groups indicating effective curing of the adhesive. Mixtures containing olive residues, particularly olive skin and stones, showed improved thermal stability in the TGA study. The mechanical properties of the plywood panels were assessed with three-point bending tests, while their shear strength and wood failure performance were tested according to the European standards used in the relevant industry (EN 314.1:2004 and EN 314.2:1993). In terms of flexural properties, the adhesive with non-extracted (NE) residual olive skin (ROS) showed the highest flexural strength of around 17 MPa and a flexural modulus of 650 MPa. The formulations containing extracted materials from hemp seeds (HSs) and residual olive skin (ROS) showed the best overall performance with wood failure values of 85% and 75% after the most severe cyclic test (EN314.1:2004-Pretreatment 5.1.3). Overall, the results showed that binders prepared with residual olive skin and defatted hemp seeds have promising performance and can be used in the manufacture of plywood panels. Full article
(This article belongs to the Special Issue Advances in Engineered Wood Products and Timber Structures)
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14 pages, 5622 KiB  
Article
Self-Neutralizing Melamine–Urea–Formaldehyde–Citric Acid Resins for Wood Panel Adhesives
by Xuedong Xi, Antonio Pizzi, Hong Lei, Xiaojian Zhou and Guanben Du
Polymers 2024, 16(13), 1819; https://doi.org/10.3390/polym16131819 - 27 Jun 2024
Cited by 6 | Viewed by 1775
Abstract
In this study, we used a self-neutralizing system to counteract too acidic a pH, unsuitable for wood adhesives, and tested it on MUF resins augmented by the addition of citric acid or other organic acids, based on the addition of small percentages of [...] Read more.
In this study, we used a self-neutralizing system to counteract too acidic a pH, unsuitable for wood adhesives, and tested it on MUF resins augmented by the addition of citric acid or other organic acids, based on the addition of small percentages of hexamine or another suitable organic base to form an acid–base buffer. In this manner, the pH of the adhesive was maintained above the minimum allowed value of 4, and the strength results of wood particleboard and plywood bonded with this adhesive system increased due to the additional cross-linking imparted by the citric acid. Thus, the wood constituents at the wood/adhesive interface were not damaged/degraded by too low a pH, thus avoiding longer-term service failure of the bonded joints. The addition of the buffering system increased the strength of the bondline in both the plywood and particleboard, both when dry and after hot water and boiling water tests. The IB strength of the particleboard was then increased by 15–17% when dry but by 82% after boiling. For the plywood, the shear strengths when dry and after 3 h in hot water at 63 °C were, respectively, 37% and 90% higher than for the control. The improvement in the bonded panel strength is ascribed to multiple reasons: (i) the slower, more regular cross-linking rate due to the action of the buffer; (ii) the shift in the polycondensation–degradation equilibrium to the left induced by the higher pH and the long-term stability of the organic buffer; (iii) the additional cross-linking by citric acid of some of the MUF resin amine groups; (iv) the already known direct linking of citric acid with the carbohydrates and lignin constituents at the interface of the wood substrate; and (v) the likely covalent linking to the interfacial wood constituents of the prelinked MUF–citric acid resin by some of the unreacted citric acid carboxyl groups. Full article
(This article belongs to the Section Circular and Green Sustainable Polymer Science)
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15 pages, 4032 KiB  
Article
Toward Cost-Effective Timber Shell Structures through the Integration of Computational Design, Digital Fabrication, and Mechanical Integral ‘Half-Lap’ Joints
by Emerson Porras, Doris Esenarro, Lidia Chang, Walter Morales, Carlos Vargas and Joseph Sucasaca
Buildings 2024, 14(6), 1735; https://doi.org/10.3390/buildings14061735 - 9 Jun 2024
Cited by 1 | Viewed by 3329
Abstract
In a global context, where the construction industry is a major source of CO2 emissions and resource use, is dependent on concrete and its risks, and lags behind in digitalization, a clear need arises to direct architecture towards more practical, efficient, and [...] Read more.
In a global context, where the construction industry is a major source of CO2 emissions and resource use, is dependent on concrete and its risks, and lags behind in digitalization, a clear need arises to direct architecture towards more practical, efficient, and sustainable practices. This research introduces an alternative technique for building timber space structures, aiming to expand its applications in areas with limited access to advanced technologies such as CNCs with more than five axes and industrial robotic arms. This involves reconfiguring economic and ecological constraints to maximize the structural and architectural advantages of these systems. The method develops a parametric tool that integrates computational design and manufacturing based on two-axis laser cutting for shells with segmented hexagonal plywood plates. It uses a modified ‘half-lap joint’ mechanical joint, also made of plywood and without additional fasteners, ensuring a precise and robust connection. The results demonstrate the compatibility of the geometry with two-axis CNC machines, which simplifies manufacturing and reduces the cuts required, thus increasing economic efficiency. The prototype, with a span of 1.5 m and composed of 63 plywood panels and 163 connectors, each 6 mm thick, supported a point load of 0.8 kN with a maximum displacement of 5 mm, weighing 15.1 kg. Assembly and disassembly, carried out by two students, took 5 h and 1.45 h, respectively, highlighting the practicality and accessibility of the method. In conclusion, the technique for building timber shells based on two-axis CNC is feasible and effective, proven by practical experimentation and finite element analysis. Full article
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