Search Results (50)

Titanium dioxide (TiO₂) is a wide-bandgap semiconductor material with broad application potential, known for its excellent photocatalytic performance, high chemical stability, low cost, and non-toxicity. These properties make it highly attractive for applications in photovoltaic energy, environmental remediation, and optoelectronic devices. For instance, TiO₂ is widely used as a photocatalyst for hydrogen production via water splitting and for degrading organic pollutants, thanks to its efficient photo-generated electron–hole separation. Additionally, TiO₂ exhibits remarkable performance in dye-sensitized solar cells and photodetectors, providing critical support for advancements in green energy and photoelectric conversion technologies. Boron-doped diamond (BDD) is renowned for its exceptional electrical conductivity, high hardness, wide electrochemical window, and outstanding chemical inertness. These unique characteristics enable its extensive use in fields such as electrochemical analysis, electrocatalysis, sensors, and biomedicine. For example, BDD electrodes exhibit high sensitivity and stability in detecting trace chemicals and pollutants, while also demonstrating excellent performance in electrocatalytic water splitting and industrial wastewater treatment. Its chemical stability and biocompatibility make it an ideal material for biosensors and implantable devices. Research indicates that the combination of TiO₂ nanostructures and BDD into heterostructures can exhibit unexpected optical and electrical performance and transport behavior, opening up new possibilities for photoluminescence and rectifier diode devices. However, applications based on this heterostructure still face challenges, particularly in terms of photodetector, photoelectric emitter, optical modulator, and optical fiber devices under high-temperature conditions. This article explores the potential and prospects of their combined heterostructures in the field of optoelectronic devices such as photodetector, light emitting diode (LED), memory, field effect transistor (FET) and sensing. TiO₂/BDD heterojunction can enhance photoresponsivity and extend the spectral detection range which enables stability in high-temperature and harsh environments due to BDD’s thermal conductivity. This article proposes future research directions and prospects to facilitate the development of TiO₂ nanostructured materials and BDD-based heterostructures, providing a foundation for enhancing photoresponsivity and extending the spectral detection range enables stability in high-temperature and high-frequency optoelectronic devices field. Further research and exploration of optoelectronic devices based on TiO₂-BDD heterostructures hold significant importance, offering new breakthroughs and innovations for the future development of optoelectronic technology. Full article

The energy efficiency potential of a considerable number of Europe’s historical buildings is noteworthy. However, policymakers often express concerns about energy retrofits that may compromise the integrity of these structures and their surroundings. On the contrary, various strategies exist for enhancing energy efficiency in historic buildings without compromising their architectural constraints. The main aim of this study is to examine energy efficiency and retrofit strategies for historic commercial buildings in the UK. The case study that was selected is a historical building constructed in 1865 for the Water Works Company in the UK, whose function has changed through the years. The research methodology employed a combination of techniques that incorporated literature reviews, a case study, semi-structured interviews, and dynamic thermal simulations. For the purpose of obtaining reductions in emissions of greenhouse gases and consumption of energy, the energy performance of five different retrofit treatment methods that have the smallest damaging effect on historical significance was examined. This study demonstrates the effectiveness of integrating advanced building performance strategies, including wall enhancements, the optimisation of HVAC systems, and the implementation of minimally intrusive photovoltaic solutions. These interventions collectively contributed to achieving remarkable reductions in energy consumption, with electricity usage reduced by 100% and natural gas consumption decreased by 88.2%. Applying retrofit strategies reduced CO₂ emissions by approximately 95% from 20,493.51 kg to 1274.76 kg per year. The findings underscore that, despite the considerable potential for enhancing energy efficiency in historic structures, there exists an extensive absence of understanding among homeowners concerning accessible regulations, grants, and practical energy-saving measures. Full article

Arsenic contamination poses a severe health risk in regions with high water vulnerability and limited treatment infrastructure. This study evaluates a photovoltaic-powered water treatment system for arsenic removal in La Yarada Los Palos District, Tacna, Peru, where arsenic concentrations reached up to 0.0417 mg/L, significantly surpassing the World Health Organization (WHO) limit of 10 µg/L (0.01 mg/L) for drinking water. The system integrates a natural sedimentation pretreatment stage in a geomembrane-lined reservoir, followed by oxidation with sodium hypochlorite, coagulation, and adsorption. Arsenic removal efficiencies ranged from 99.72% to 99.85%, reducing residual concentrations below WHO guidelines. Pretreatment significantly improved performance, reducing turbidity by up to 66.67% and TSS by up to 70.37%, optimizing subsequent treatment stages. Operationally, pretreatment decreased cleaning frequency from six to four cleanings per month, while backwashing energy consumption dropped by 33% (from 45.72 kWh to 30.48 kWh). The photovoltaic system leveraged the region’s high solar radiation, achieving an average daily generation of 20.31 kWh and an energy surplus of 33.08%. The system’s performance was evaluated within the context of existing arsenic removal technologies, demonstrating that the integration of natural sedimentation and renewable energy constitutes a viable operational alternative. Given the regulatory framework in Peru, where arsenic limits align with WHO standards, conventional water treatment systems are normatively and technically unfeasible under national legislation. Furthermore, La Yarada Los Palos District faces challenges due to its limited infrastructure for conventional electrification via power grid, as identified in national reports on rural electrification and gaps in access to basic services. Beyond its performance in the study area, the system’s modular design allows adaptation to diverse water sources with varying arsenic concentrations, turbidity levels, and other physicochemical characteristics. In remote regions with limited access to the power grid, such as the study site, photovoltaic energy provides a self-sustaining and replicable alternative, particularly in arid and semi-arid areas with high solar radiation. These conditions are not exclusive to Latin America but are also prevalent in remote regions of Africa, the Middle East, Asia, and Oceania, where groundwater arsenic contamination is a significant issue and renewable energy availability can enhance water treatment sustainability. These findings underscore the potential of using sustainable energy solutions to address water contamination challenges in remote areas. The modular and scalable design of this system enables its replication in regions with adverse hydrogeological conditions, integrating renewable energy and pretreatment strategies to enhance water treatment performance. The framework presented in this study offers a replicable and efficient approach for implementing eco-friendly water treatment systems in regions with similar environmental and resource constraints. Full article

The removal of surface residues from single-layer graphene (SLG), including poly(methyl methacrylate) (PMMA) polymers and Cl⁻ ions, during the transfer process remains a significant challenge with regard to preserving the intrinsic properties of SLG, with the process often leading to unintended doping and reduced electronic performance capabilities. This study presents a rapid and efficient surface treatment method that relies on an aqueous sodium nitrite (NaNO₂) solution to remove such contaminants effectively. The NaNO₂ solution rinse leverages reactive nitric oxide (NO) species to neutralize ionic contaminants (e.g., Cl⁻) and partially oxidize polymer residues in less than 10 min, thereby facilitating a more thorough final cleaning while preserving the intrinsic properties of graphene. Characterization techniques, including atomic force microscopy (AFM), Kelvin probe force microscopy (KPFM), and X-ray photoelectron spectroscopy (XPS), demonstrated substantial reductions in the levels of surface residues. The treatment restored the work function of the SLG to approximately 4.79 eV, close to that of pristine graphene (~4.5–4.8 eV), compared to the value of nearly 5.09 eV for conventional SLG samples treated with deionized (DI) water. Raman spectroscopy confirmed the reduced doping effects and improved structural integrity of the rinsed SLG. This effective rinsing process enhances the reproducibility and performance of SLG, enabling its integration into advanced electronic devices such as organic light-emitting diodes (OLEDs), photovoltaic (PV) cells, and transistors. Furthermore, the technique is broadly applicable to other two-dimensional (2D) materials, paving the way for next-generation (opto)electronic technologies. Full article

Harnessing solar energy offers a sustainable alternative for powering electrolysis for green hydrogen production as well as wastewater treatment. The high costs and logistical challenges of electrolysis have resulted in limited widespread investigation and implementation of electrochemical technologies on an industrial scale. To overcome these challenges, this study designs and tests a new approach to chemical experiments and wastewater treatment research using a portable standalone open-source solar photovoltaic (PV)-powered station that can be located onsite at a wastewater treatment plant with unreliable electrical power. The experimental system is equipped with an energy monitoring data acquisition system. In addition, sensors enable real-time monitoring of gases—CO, CO₂, CH₄, H₂, H₂S, and NH₃—along with temperature, humidity, and volatile organic compounds, enhancing safety during electrochemical experiments on wastewater, which may release hazardous gases. SAMA software was used to evaluate energy-sharing scenarios under different grid-connected conditions, and the system can operate off the power grid for 98% of the year in Ontario, Canada. The complete system was tested utilizing a laboratory-scale electrolyzer (electrodes of SS316L, Duplex 2205, titanium grade II and graphite) with electrolyte solutions of potassium hydroxide, sulfuric acid, and secondary wastewater effluent. The electrolytic cell specifically developed for testing electrode materials and wastewater showed a Faraday efficiency up to 95% and an energy efficiency of 55% at STP, demonstrating the potential for use of this technology in future work. Full article

The study investigates the economic aspects of red tilapia (Oreochromis sp.) production using biofloc technology under different electrical energy sources. Conducted at the El Vergel Fish Farming Association in Arauca, Colombia, the study examines four energy treatments: conventional energy (CE), combined conventional and photovoltaic energy (CPVE), full photovoltaic energy (PVE), and simulation of photovoltaic energy generating surplus for nighttime use (PVES). The water quality and zootechnical performance met the species requirements, with dissolved oxygen decreasing as fish size increased. The PVE treatment had the highest initial investment due to solar panels and battery costs, but it also had the lowest operating energy costs. However, the overall costs of the PVE treatment increased due to depreciation and maintenance. Feed was the largest production cost, followed by labor in most treatments, while depreciation was a major cost for the PVE treatment. The total operating cost (TOC) of the photovoltaic energy systems (PVE and PVES) was lower compared to that of conventional energy (CE), with PVES showing the highest cost savings. The reduction in energy costs highlights the potential for solar energy systems to enhance the economic viability of aquaculture production, making these systems a favorable option for sustainable production in the long term. Full article

In recent years, nitrate has emerged as a significant groundwater pollutant due to its potential ecotoxicity. In particular, nitrate contamination of brackish groundwater poses a serious threat to both ecosystems and human health and remains difficult to treat. A promising, sustainable, and environmentally friendly solution when biological treatments are not applicable is the conversion of nitrate to harmless nitrogen (N₂) or ammonia (NH₃) as a nutrient by electrocatalytic nitrate reduction (eNO₃R) using solar photovoltaic energy. This review provides a comprehensive overview of the current advances in eNO₃R for the production of nitrogen and ammonia. The discussion begins with fundamental concepts, including a detailed examination of the mechanisms and pathways involved, supported by Density Functional Theory (DFT) to elucidate specific aspects of ammonium and nitrogen formation during the process. Furthermore, the integration of artificial intelligence (AI) and machine learning (ML) offers promising advancements in enhancing the predictive power of DFT, accelerating the discovery and optimization of novel catalysts. In this review, we also explore various electrode preparation methods and emphasize the importance of in situ characterization techniques to investigate surface phenomena during the reaction process. The review highlights numerous examples of copper-based catalysts and analyses their feasibility and effectiveness in ammonia production. It also explores strategies for the conversion of nitrate to N₂, focusing on nanoscale zerovalent iron as a selective material and the subsequent oxidation of the produced ammonia. Finally, this review addresses the implementation of the eNO₃R process for the treatment of brackish groundwater, discussing various challenges and providing reasonable opinions on how to overcome these obstacles. By synthesizing current research and practical examples, this review highlights the potential of eNO₃R as a viable solution to mitigate nitrate pollution and improve water quality. Full article

Nanobubbles (NBs) are gaseous domains at the nanoscale that can exist in bulk liquid or on solid surfaces. They are noteworthy for their high potential for real-world applications and their long (meta)stability. “Platform-wide” applications abound in medicine, wastewater treatment, hetero-coagulation, boundary-slip control in microfluidics, and nanoscopic cleaning. Here, we compare and contrast the industrial NB-generation performance of various types of commercial NB generators in both water-flow and submerged-in-water settings—in essence, comparing electric-field NB-generation approaches versus mechanical ones—finding that the former embodiments are superior from a variety of perspectives. It was found that the electric-field approach for NB generation surpasses traditional mechanical approaches for clean-water NB generation, especially when considering the energy running cost. In particular, more passive electric-field approaches are very operationally attractive for NB generation, where water and gas flow can be handled at little to no cost to the end operator, and/or submersible NB generators can be deployed, allowing for the use of photovoltaic approaches (with backup batteries for night-time and “low-sun” scenarios and air-/CO₂-pumping paraphernalia). Full article

A smart city (SC) includes different systems that are highly interconnected. Transportation and energy systems are two of the most important ones that must be operated and planned in a coordinated framework. In this paper, with the complete implementation of the SC, the performance of each of the network elements has been fully analyzed; hence, a nonlinear model has been presented to solve the operation and planning of the SC model. In the literature, water treatment issues, as well as energy hubs, subway systems (SWSs), and transportation systems have been investigated independently and separately. A new method of subway and electric vehicle (EV) interaction has resulted from stored energy obtained from subway braking and EV parking. Hence, considering an SC that simultaneously includes renewable energy, transportation systems such as the subway and EVs, as well as the energy required for water purification and energy hubs, is a new and unsolved challenge. In order to solve the problem, in this paper, by presenting a new system of the SC, the necessary planning to minimize the cost of the system is presented. This model includes an SWS along with plug-in EVs (PEVs) and different distributed energy resources (DERs) such as Photovoltaics (PVs), Heat Pumps (HPs), and stationary batteries. An improved grey wolf optimizer has been utilized to solve the nonlinear optimization problem. Moreover, four scenarios have been evaluated to assess the impact of the interconnection between SWSs and PEVs and the presence of DER technologies in the system. Finally, results were obtained and analyzed to determine the benefits of the proposed model and the solution algorithm. Full article

Solar-boosted photo-technology stands out as a powerful strategy for photosynthesis and photocatalytic processes due to its minimal energy requirements, cost-effectiveness and operation under milder, environmentally friendly conditions compared to conventional thermocatalytic options. The design and development of photocatalysts have received a great deal of attention, whereas photoreactor development must be studied deeper to enable the design of efficient devices for practical exploitation. Furthermore, scale-up issues are important for this application, since light distribution through the photoreactor is a concurrent factor. This review represents a comprehensive study on the development of photoreactors to be used mainly for the photoreduction of CO₂ to fuels, but with concepts easily transferable to other photosynthetic applications such as ammonia synthesis and water splitting, or wastewater treatment, photovoltaics combined to photoreactors, etc. The primary categories of photoreactors are thoroughly examined. It is also explained which parameters influence the design of a photoreactor and next-generation high-pressure photoreactors are also discussed. Last but not least, current technologies for solar concentrators are recalled, considering their possible integration within the photoreactor. While many reviews deal with photocatalytic materials, in the authors’ view, photoreactors with significant scale and their merged devices with solar concentrators are still unexploited solutions. These are the key to boost the efficiency of these processes towards commercial viability; thus, the aim of this review is to summarise the main findings on solar photoreactors for the photoreduction of CO₂ and for related applications. Full article

Polyaniline has been utilized in various applications, yet its widespread adoption has often been impeded by challenges. Composite systems have been proposed as a means of mitigating some of these limitations, and anthranilic acid (2-aminobenzoic acid) has emerged as a possible moderator for use in co-polymer systems. It offers improved solubility and retention of electroactivity in neutral and alkaline media, and, significantly, it can also bestow chemical functionality through its carboxylic acid substituent, which can greatly ease post-polymer modification. The benefits of using anthranilic acid (as a homopolymer or copolymer) have been demonstrated in applications including corrosion protection, memory devices, photovoltaics, and biosensors. Moreover, this polymer has been used as a versatile framework for the sequestration of metal ions for water treatment, and, critically, these same mechanisms serve as a facile route for the production of catalytic metallic nanoparticles. However, the widespread adoption of polyanthranilic acid has been limited, and the aim of the present narrative review is to revisit the early promise of anthranilic acid and assess its potential future use within modern smart materials. A critical evaluation of its properties is presented, and its versatility as both a monomer and a polymer across a spectrum of applications is highlighted. Full article

The world’s population is expected to increase by nearly two billion in the next 30 years; the population will increase from 8 billion to 9.7 billion by 2050 and could peak at 10.4 billion by the mid-2080s. The extreme weather triggered by global climate change has severely hit crop yields in open-field cultivation and led to an increase in food prices. Furthermore, in the last few years, emergency events such as the COVID-19 pandemic, wars/conflicts, and economic downturns have conditioned agricultural production and food security around the world. Greenhouses could be efficient cultivation systems because they enable food production in a sustainable way, limiting contact between pollutants and plants and optimizing the use of water, energy, and soil. This paper proposes a novel dome-soilless greenhouse concept for tomato cultivation in the Mediterranean area. The proposed greenhouse is fixed on a sea platform to take advantage of the seawater cooling environment and to integrate water consumption into a hydroponic system. In order to evaluate the best covering solution material to adopt, a few thermal and photometric characteristics of greenhouse covering materials were evaluated using a simplified method. A dynamic simulation was carried out to compare the proposed seawater cooling system with a conventional cooling tower in terms of the electric energy spent to maintain the inside temperature range at 13–25 °C across all seasons in the year. The proposed heating, ventilation, and air conditioning (HVAC) system allowed a total annual energy saving of more than 10%. The energy saved was a result of the better cooling performance of the seawater heat exchange that allowed energy saving of about 14% on cooling. The comparison between the model characterised by a 6 mm polycarbonate coupled with UbiGro film and a seawater cooling system, and the model including a 6 mm polycarbonate coupled with a clarix blue film covering and a tower cooling system highlighted energy saving of about 20%. The obtained results indicate possible future directions for offshore greenhouses to carry out independent production together with the integration of photovoltaic modules, water treatment plants, and smart remote-control systems. Full article

This study investigates the impact of violet laser irradiation on the optical properties of thick films composed of polyvinyl alcohol (PVA), methyl orange (MO), and their composite (PVA/MO). Aimed at exploring potential medical applications, the films were synthesized through a casting process involving the dissolution of PVA and MO in distilled water. The optical properties, including absorbance spectra, energy gaps, and various optical constants, were meticulously measured before and after exposure to laser irradiation. The results revealed a notable decrease in the absorbance spectra and optical constants, along with an increase in the energy gaps, suggesting a structural modification induced by the laser treatment. These findings hold significance for the advancement of materials with customized optical features, potentially serving as a model for future developments in optoelectronic and photovoltaic devices. The research outcomes provide a foundation for the exploration of polymers and dyes in medical applications, particularly in the realms of non-invasive surgical procedures and simulations. Full article

The increase in electricity generation prices represents a reason why water utility companies are looking for ways to reduce costs. One of the first ideas of users was to build photovoltaic installations. Water treatment plants or sewage treatment plants usually have large unused areas. They look different in facilities that consume a lot of energy but occupy little land, and include water intakes (wells) and water pumping stations. Facilities equipped with pumps are characterized by high electricity consumption. This article assesses the possibility of using PV installations at the water intake. An analysis of energy production from the 3.0 kW PV installation in Polanica-Zdrój was carried out, and then, simulations of the possibility of providing energy via installations with capacities of 3.0 kW, 4.2 kW, and 6.0 kW were performed. Analyses of energy production and demand, as well as analyses of water production based on annual, monthly, daily, and hourly data, were performed. An analysis of the hourly coverage of the WPS’s demand for electricity was carried out with regard to the current production of energy from the PV installation, as was an analysis of the overproduction of energy from the PV installation regarding the energy demand of the WPS. The simulation results are presented for cloudy and sunny days. Full article

In recent years, reverse osmosis water desalination has developed rapidly and has become the most competitive and widely used technology in the world. The number of desalination plants is increasing rapidly as freshwater needs increase. Various membrane technologies have been developed and improved, including nanofiltration (NF) and reverse osmosis (RO), whose desalination costs have been relatively reduced. Therefore, this work proposes an experimental study for a small desalination unit based on RO generated by renewable energy, which is mainly suitable for arid regions or desert areas that do not have electricity and water and can be applied for emergency treatment to meet strong freshwater resource needs. In this study, to meet the drinking water demand, a reverse osmosis desalination system is designed and evaluated in order to improve and optimize its operation. This system has a daily capacity of 2 m³. We used brackish groundwater, which has been characterized as reference water, to produce synthetic water for different salinities until seawater. The analysis is based on data obtained from experiments carried out in the standalone RO pilot designed for the production of fresh water. For this purpose, we conducted relevant experiments to examine the influence of applied pressure, salt concentration and temperature on the RO membrane performance. The effects of different factors that affect the energy consumption in the RO desalination process were analyzed, and those with significant influence were explored. The effectiveness of RO desalination coupled with a photovoltaic (PV) energy system is shown. We found the recovery rate for system operation to be 32%. An optimization study is presented for the operation of an autonomous RO desalination system powered by photovoltaic panels. The energy produced by the PV system was used to feed two pumps forthe production of drinking waterwithanRO membrane, under the conditions of the town of Bou-Ismail. As results, a 3 kWp PV system was installed based on the energy demand. The design data have shown that a 3 kWp PV system can power a 1.8 W RO load given the Bou-Ismail climate. Energy consumption in the case study under Bou-Ismail weather conditions were analyzed. The desalination of brackish water at a TDS value of 5 g/L requires an energy of about 1.5 kWh/m³. Using seawater at a TDS value of 35 g/L, this value increases to 5.6 kWh/m³. The results showed that the optimal recovery rate for system operation was determined to be 32% for a feedwater salinity of 35 g/L, and 80% for a feedwater salinity of 1 g/L. Full article