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Keywords = particle interlayer thickness

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24 pages, 7616 KiB  
Article
Stability Analysis and Support Optimization of Tunnel Surrounding Rock with Weak Interlayer Based on Catastrophe Theory
by Tuo Zhang, Jinhai Zhao, Renfei Kuang and Chengyang Li
Buildings 2025, 15(3), 507; https://doi.org/10.3390/buildings15030507 - 6 Feb 2025
Viewed by 922
Abstract
A tunnel excavation model with weak interlayers is established to analyze the effect of different angles and thicknesses on the displacement of the surrounding rock. Based on catastrophe theory, a stability criterion for surrounding rock displacement is derived, providing a theoretical framework for [...] Read more.
A tunnel excavation model with weak interlayers is established to analyze the effect of different angles and thicknesses on the displacement of the surrounding rock. Based on catastrophe theory, a stability criterion for surrounding rock displacement is derived, providing a theoretical framework for evaluating tunnel stability through numerical simulations. Finally, to minimize support construction costs, an optimization model is established by integrating the Particle Swarm Optimization (PSO) algorithm and the Radial Basis Function (RBF) neural network. The model is then validated through engineering projects. The results show that the deformation and stability of the surrounding rock are affected by the interlayer angle and thickness. As the angle increases, the maximum deformation of the surrounding rock gradually transitions from horizontal displacement to vertical displacement, while increased thickness amplifies deformation and concentrates it at the interlayer. The stability of the surrounding rock exhibits catastrophic characteristics, with instability often occurring in the middle and rear sections of the tunnel. Calculation costs are reduced by 88% using the PSO-RBF optimization model, and construction costs decreased by 34.96% after optimizing the support parameters. This study provides theoretical support for the stability analysis and construction optimization of tunnels with weak interlayers. Full article
(This article belongs to the Section Building Structures)
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25 pages, 43021 KiB  
Article
Interlayer Parallel Connection of Multiple Helmholtz Resonators for Optional Broadband Low Frequency Sound Absorption
by Xiaocui Yang, Qiang Li, Xinmin Shen, Binbin Zhou, Ning Wang, Enshuai Wang, Xiaonan Zhang, Cheng Shen, Hantian Wang and Shunjie Jiang
Materials 2025, 18(3), 682; https://doi.org/10.3390/ma18030682 - 4 Feb 2025
Cited by 3 | Viewed by 967
Abstract
The Helmholtz resonance acoustic metamaterial is an effective sound absorber in the field of noise reduction, especially in the low-frequency domain. To overcome the conflict between the number of Helmholtz resonators and the volume of the rear cavity for each chamber with a [...] Read more.
The Helmholtz resonance acoustic metamaterial is an effective sound absorber in the field of noise reduction, especially in the low-frequency domain. To overcome the conflict between the number of Helmholtz resonators and the volume of the rear cavity for each chamber with a given front area of single-layer metamaterial, a novel acoustic metamaterial of interlayer parallel connection of multiple Helmholtz resonators (IPC–MHR) is proposed in this study. The developed IPC–MHR consists of several layers, and the Helmholtz resonators among different layers are connected in parallel. The sound absorption property of IPC–MHR is studied by finite element simulation and further optimized by particle swarm optimization algorithm, and it is validated by standing wave tube measurement with the sample fabricated by additive manufacturing. The average sound absorption coefficient in the discrete frequency band [200 Hz, 300 Hz] U [400 Hz, 600 Hz] U [800 Hz, 1250 Hz] is 0.7769 for the IPC–MHR with four layers. Through the optimization of the thickness of each layer, the average sound absorption coefficient in 250–750 Hz is up to 0.8068. Similarly, the optimized IPC–MHR with six layers obtains an average sound absorption coefficient of 0.8454 in 300–950 Hz, which exhibits an excellent sound absorption performance in the low-frequency range with a wide band. The IPC–MHR can be used to suppress obnoxious noise in practical applications. Full article
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14 pages, 6455 KiB  
Article
Application of NIPOS-SVM Model for Evaluation of Water Richness of Coal Seam Roof Aquifer—A Case Study of the Xinhu Coal Mine in Huaibei, China
by Maolin Xing, Qiqing Wang, Jie Xu and Wenping Li
Water 2024, 16(24), 3670; https://doi.org/10.3390/w16243670 - 20 Dec 2024
Cited by 1 | Viewed by 813
Abstract
The sandstone roof of coal seams, with its high porosity and developed fissures, serves as a favorable reservoir for groundwater. Predicting and assessing the water-bearing capacity of the sandstone roof in coal seams is crucial for the rational development of coal tunnels, ensuring [...] Read more.
The sandstone roof of coal seams, with its high porosity and developed fissures, serves as a favorable reservoir for groundwater. Predicting and assessing the water-bearing capacity of the sandstone roof in coal seams is crucial for the rational development of coal tunnels, ensuring safe and efficient production in mining areas. This study targets the Cenozoic bottom aquifer of the No. 81 mining area of the Xinhu Coal Mine. By analyzing the geological and hydrogeological conditions of the mining area, it was found that the primary water-bearing strata of the coal seam roof are the Permian sandstone fracture waters. Key factors for evaluating the water richness of the sandstone aquifer were identified as aquifer thickness, aquifer depth, core recovery rate, coal seam dip angle, brittleness–plasticity ratio, and the sand–mud interlayer index. A novel particle swarm optimization algorithm incorporating improved sine chaos mapping (NIPSO) to enhance the support vector machine (SVM), thereby constructing the NIPSO-SVM model, was applied for quantitative evaluation of water richness in the study area. Experimental results indicated that the NIPSO-SVM model has high accuracy and practical engineering application value in predicting water richness, which is significant for ensuring the safe production of coal mines. Full article
(This article belongs to the Section Hydrogeology)
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15 pages, 3449 KiB  
Article
Propagation Behavior of P1-Wave Passing through Fluid-Saturated Porous Continuous Barrier in Layered Saturated Soil
by Xunqian Xu, Yu Li, Fengyi Kang, Shue Li, Guozhi Wan, Qi Li, Tao Wu and Siwen Wang
Buildings 2024, 14(2), 532; https://doi.org/10.3390/buildings14020532 - 16 Feb 2024
Viewed by 1479
Abstract
The fluid-saturated porous continuous barrier has a better vibration isolation effect than the single-phase solid continuous barrier, and layer-forming saturated soils will have an impact on the vibration isolation effect of the barriers due to their irregular layer-forming distribution. Based on Biot’s theory [...] Read more.
The fluid-saturated porous continuous barrier has a better vibration isolation effect than the single-phase solid continuous barrier, and layer-forming saturated soils will have an impact on the vibration isolation effect of the barriers due to their irregular layer-forming distribution. Based on Biot’s theory of saturated porous media and Snell’s law, a dynamic model of a fluid-saturated porous continuous barrier in layered saturated soil is established in this study. By introducing the potential function and using the continuous boundary condition of the interface between the saturated soil and the barrier, the analytical solution of the inverse transmission amplitude ratio of a P1-wave passing through the fluid-saturated porous continuous barrier in stratified saturated soil is obtained. The rationality of the proposed method is verified by comparing the solution of the P-wave model at the interface between the elastic medium and the saturated coarse particle interlayer. The differences in the propagation characteristics of fluid-saturated porous continuous barriers in layered saturated soils, homogeneous saturated soils, and layered single-phase soils are analyzed via numerical examples, and the influence of changes in the physical and mechanical parameters of the fluid-saturated porous continuous barriers on the reflectance amplitude ratios under the conditions of a layered saturated soil foundation are also analyzed. The results show that the presence of fluid in the stratified saturated soil model changes the trend of the reflection amplitude ratio with the incidence angle. The reflection amplitude ratio of the P2-wave and the SV-wave increases first and then decreases with the increase in the incident angle, while the reflection amplitude ratio of P1-wave decreases first and then increases. Barrier thickness and porosity change the energy distribution relationship at the interface; a relatively thicker barrier thickness and a higher porosity would result in a higher amplitude of barrier reflections. Full article
(This article belongs to the Section Construction Management, and Computers & Digitization)
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14 pages, 7742 KiB  
Article
Effect of Cold Rolling on Microstructure and Mechanical Properties of a Cast TiNbZr-Based Composite Reinforced with Borides
by Maxim Ozerov, Vitaly Sokolovsky, Nikita Yurchenko, Ilya Astakhov, Elizaveta Povolyaeva, Oleg Plekhov, Damir Tagirov, Nikita Stepanov and Sergey Zherebtsov
Metals 2024, 14(1), 104; https://doi.org/10.3390/met14010104 - 15 Jan 2024
Cited by 4 | Viewed by 2536
Abstract
The TiNbZr/(Ti, Nb)B metal matrix composite with 2.5 vol.% of borides was produced by vacuum arc melting. The composite was then cold-rolled to thickness strains of 10, 20, 50, or 80%. In the initial condition, the composite had a network-like microstructure consisting of [...] Read more.
The TiNbZr/(Ti, Nb)B metal matrix composite with 2.5 vol.% of borides was produced by vacuum arc melting. The composite was then cold-rolled to thickness strains of 10, 20, 50, or 80%. In the initial condition, the composite had a network-like microstructure consisting of the soft TiNbZr matrix (dendrites) and the rigid (Ti, Nb)B shell (interdendritic space). In comparison with the as-cast condition, cold rolling increased strength by 17–35%, depending on the thickness strain. After the maximum thickness strain of 80%, yield strength and ultimate tensile strength of the composite achieved 865 and 1080 MPa, respectively, while total elongation was found to be 5%. Microstructural analysis revealed that cold rolling to 50% resulted in the formation of crossing shear bands caused by the considerable difference in deformation behavior of the matrix and reinforcements. Cold rolling to 80% led to the formation of a lamellar-like microstructure comprising the interlayers of the (Ti, Nb)B phase between the TiNbZr laths. The maximum strain (80% cold rolling) shortened the (Ti, Nb)B fibers into nearly equiaxed particles, with a length to diameter ratio of ~2. Full article
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19 pages, 19389 KiB  
Article
Study of Tribological Properties and Evolution of Morphological Characteristics of Transfer Films in PTFE Composites Synergistically Reinforced with Nano-ZrO2 and PEEK Particles
by Yuan Qi, Bugong Sun, Yang Zhang, Gui Gao, Peng Zhang and Xiaobao Zheng
Polymers 2023, 15(17), 3626; https://doi.org/10.3390/polym15173626 - 1 Sep 2023
Cited by 7 | Viewed by 2126
Abstract
The materials tribology community has identified that the transfer film attached to the surface of the counterpart metal during the friction process is not only closely related to the filler modification material but also a key factor affecting the tribological properties of polymer [...] Read more.
The materials tribology community has identified that the transfer film attached to the surface of the counterpart metal during the friction process is not only closely related to the filler modification material but also a key factor affecting the tribological properties of polymer composites; however, there is a lack of feasible methods to quantify the characteristics of the transfer film. In this study, Nano-ZrO2 and polyetheretherketone (PEEK) were filled into a PTFE matrix in order to enhance the wear resistance of polytetrafluoroethylene (PTFE). The tribological properties of the modified PTFE composites were tested using a linear reciprocating friction and wear tester, and the entire friction experiment was designed in seven separate stages. Morphological features were extracted and analyzed from photographs of the transfer film acquired by optical microscopy at each friction stage using an image processing program. The thickness and roughness of the transfer film sections were measured using a non-contact profilometer. Abrasive debris were collected, and their morphological features were observed with an electron microscope. The results showed that the synergistic addition of soft PEEK and hard Nano-ZrO2 particles effectively inhibited interlayer slippage between PTFE molecular chains, dramatically reducing the size and yield of abrasive debris, and facilitated the improvement of the thickness and firmness of the transfer film, which significantly enhanced the wear resistance of the PTFE composites (the lowest volumetric wear rate for Nano-ZrO2/PEEK/PTFE was only 1.76 × 10−4 mm3/Nm). Quantitative analyses of the morphological characteristics of the transfer films revealed that the coverage and roundness of the transfer films gradually increase with the friction stroke, while the aspect ratio and texture entropy subsequently decrease gradually. The coverage, area, mean, third-order moments, and consistency of the transfer film strongly correlated with the volumetric wear rate (correlation coefficient |r| > 0.9). Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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27 pages, 4902 KiB  
Review
GO-Based Membranes for Desalination
by Rui Ge, Teng Huo, Zhongyong Gao, Jiding Li and Xia Zhan
Membranes 2023, 13(2), 220; https://doi.org/10.3390/membranes13020220 - 10 Feb 2023
Cited by 20 | Viewed by 5947
Abstract
Graphene oxide (GO), owing to its atomic thickness and tunable physicochemical properties, exhibits fascinating properties in membrane separation fields, especially in water treatment applications (due to unimpeded permeation of water through graphene-based membranes). Particularly, GO-based membranes used for desalination via pervaporation or nanofiltration [...] Read more.
Graphene oxide (GO), owing to its atomic thickness and tunable physicochemical properties, exhibits fascinating properties in membrane separation fields, especially in water treatment applications (due to unimpeded permeation of water through graphene-based membranes). Particularly, GO-based membranes used for desalination via pervaporation or nanofiltration have been widely investigated with respect to membrane design and preparation. However, the precise construction of transport pathways, facile fabrication of large-area GO-based membranes (GOMs), and robust stability in desalination applications are the main challenges restricting the industrial application of GOMs. This review summarizes the challenges and recent research and development of GOMs with respect to preparation methods, the regulation of GOM mass transfer pathways, desalination performance, and mass transport mechanisms. The review aims to provide an overview of the precise regulation methods of the horizontal and longitudinal mass transfer channels of GOMs, including GO reduction, interlayer cross-linking, intercalation with cations, polymers, or inorganic particles, etc., to clarify the relationship between the microstructure and desalination performance, which may provide some new insight regarding the structural design of high-performance GOMs. Based on the above analysis, the future and development of GOMs are proposed. Full article
(This article belongs to the Special Issue Green Membrane Technology)
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7 pages, 1397 KiB  
Article
Study on the Gamma Irradiation Characteristics of a Carbon Nanotube Sponge/Polydimethylsiloxane/Tungsten Oxide Flexible Force-Sensitive Structure
by Xingcheng Han, Xin Li, Ruirong Wang, Jinping Liu and Lishuang Liu
Micromachines 2022, 13(7), 1024; https://doi.org/10.3390/mi13071024 - 28 Jun 2022
Cited by 4 | Viewed by 1876
Abstract
This paper proposes a new type of flexible force-sensitive structure that is resistant to gamma radiation and is made of tungsten oxide (WO3) powder, polydimethylsiloxane (PDMS), and carbon nanotube (CNT) sponge. The thickness of the sample was 2.2 mm, the middle [...] Read more.
This paper proposes a new type of flexible force-sensitive structure that is resistant to gamma radiation and is made of tungsten oxide (WO3) powder, polydimethylsiloxane (PDMS), and carbon nanotube (CNT) sponge. The thickness of the sample was 2.2 mm, the middle interlayer was composed of a carbon nanotube (CNT) sponge and PDMS to form a conductive layer, and the upper and lower layers were made of tungsten oxide and PDMS, which formed a gamma-ray shielding layer. When the particle size of the tungsten oxide powder was 50 nm, 100 nm, and 1 µm, the composite force-sensitive structure exhibited better force-sensitive performance. The composite force-sensitive structure was irradiated with doses of 5, 20, 50, and 100 KGy through 60Co- rays with an energy of 1.25 MeV. The results showed that the force-sensitive characteristics changed little in significance after irradiation by different doses of gamma rays, indicating that the force-sensitive structure has good resistance to gamma radiation. This flexible stress sensor can be used in soft robots and health inspection, even in harsh environments without significant performance loss. Full article
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16 pages, 9912 KiB  
Article
Wear Resistance, Patterns of Wear and Plastic Properties of Cr,Mo-(Cr,Mo,)N-(Cr,Mo,Al)N Composite Coating with a Nanolayer Structure
by Alexey Vereschaka, Anton Seleznev and Vladislav Gaponov
Coatings 2022, 12(6), 758; https://doi.org/10.3390/coatings12060758 - 31 May 2022
Cited by 5 | Viewed by 2612
Abstract
This paper discusses the results of studies focused on the wear resistance, patterns of wear and plastic properties of Cr,Mo-(Cr,Mo,)N-(Cr,Mo,Al)N coating, containing 20 at.% Mo. The coating had a nanolayer structure with a modulation period λ = 50 nm. The studies revealed the [...] Read more.
This paper discusses the results of studies focused on the wear resistance, patterns of wear and plastic properties of Cr,Mo-(Cr,Mo,)N-(Cr,Mo,Al)N coating, containing 20 at.% Mo. The coating had a nanolayer structure with a modulation period λ = 50 nm. The studies revealed the hardness, fracture resistance in scratch testing, as well as elemental and phase composition of the coating. The studies of the tool life of carbide cutting tools with the Cr,Mo-(Cr,Mo,)N-(Cr,Mo,Al)N coating proved their longer tool life compared to that of uncoated tools and tools with the reference Cr-(Cr,Al)N coating of equal thickness and equal content of aluminum (Al). The studies included the comparison of the tools coated with Cr,Mo-(Cr,Mo,)N-(Cr,Mo,Al)N and Cr-(Cr,Al)N. The experiments focused on the specific features of the coating nanostructure and were conducted using a transmission electron microscope (TEM), revealing the different mechanisms of fracture. The penetration of particles of the material being machined between nanolayers of the coating results in interlayer delamination. When exposed to a moving flow of the material being machined, plastic deformation (bending) of the coating nanolayers occurs. The diffusion of iron into the coating (up to 200 nm) and diffusion of Cr and Mo into the cut material to a depth of up to 250 nm are observed. The presented information can help in the design of metal cutting tools and the choice of coatings for them. Full article
(This article belongs to the Special Issue Technologies of Coatings and Surface Hardening for Tool Industry II)
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15 pages, 5541 KiB  
Article
Study on the Design, Preparation, and Performance Evaluation of Heat-Resistant Interlayer-Polyimide-Resin-Based Neutron-Shielding Materials
by Hu Xu, Dan Liu, Wei-Qiang Sun, Rong-Jun Wu, Wu Liao, Xiao-Ling Li, Guang Hu and Hua-Si Hu
Materials 2022, 15(9), 2978; https://doi.org/10.3390/ma15092978 - 19 Apr 2022
Cited by 5 | Viewed by 2301
Abstract
Polymers have an excellent effect in terms of moderating fast neutrons with rich hydrogen and carbon, which plays an indispensable role in shielding devices. As the shielding of neutrons is typically accompanied by the generation of γ-rays, shielding materials are developed from monomers [...] Read more.
Polymers have an excellent effect in terms of moderating fast neutrons with rich hydrogen and carbon, which plays an indispensable role in shielding devices. As the shielding of neutrons is typically accompanied by the generation of γ-rays, shielding materials are developed from monomers to multi-component composites, multi-layer structures, and even complex structures. In this paper, based on the typical multilayer structure, the integrated design of the shield component structure and the preparation and performance evaluation of the materials is carried out based on the design sample of the heat-resistant lightweight polymer-based interlayer. Through calculation, the component structure of the polymer-based materials and the three-layer thickness of the shield are obtained. The mass fraction of boron carbide accounts for 11% of the polymer-based material. Since the polymer-based material is the weak link of heat resistance of the multilayer shield, in terms of material selection and modification, the B4C/TiO2/polyimide molded plate was prepared by the hot-pressing method, and characterization analysis was conducted for its structure and properties. The results show that the ball milling method can mix the materials well and realize the uniform dispersion of B4C and TiO2 in the polyimide matrices. Boron carbide particles are evenly distributed in the material. Except for Ti, the other elemental content of the selected areas for mapping is in good agreement with the theoretical values of the elemental content of the system. The prepared B4C/TiO2/polyimide molded plate presents excellent thermal properties, and its glass transition temperature and initial thermal decomposition temperature are as high as 363.6 °C and 572.8 °C, respectively. In addition, the molded plate has good toughness performs well in compression resistance, shock resistance, and thermal aging resistance, which allows it to be used for a long time under 300 °C. Finally, the prepared materials are tested experimentally on an americium beryllium neutron source. The experimental results match the simulation results well. Full article
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16 pages, 4359 KiB  
Article
Printed Nanocarbon Heaters for Stretchable Sport and Leisure Garments
by Andrew Claypole, James Claypole, Neil Bezodis, Liam Kilduff, David Gethin and Tim Claypole
Materials 2022, 15(2), 573; https://doi.org/10.3390/ma15020573 - 13 Jan 2022
Cited by 7 | Viewed by 2936
Abstract
The ability to maintain body temperature has been shown to bring about improvements in sporting performance. However, current solutions are limited with regards to flexibility, heating uniformity and robustness. An innovative screen-printed Nanocarbon heater is demonstrated which is robust to bending, folding, tensile [...] Read more.
The ability to maintain body temperature has been shown to bring about improvements in sporting performance. However, current solutions are limited with regards to flexibility, heating uniformity and robustness. An innovative screen-printed Nanocarbon heater is demonstrated which is robust to bending, folding, tensile extensions of up to 20% and machine washing. This combination of ink and substrate enables the heated garments to safely flex without impeding the wearer. It is capable of producing uniform heating over a 15 × 4 cm area using a conductive ink based on a blend of Graphite Nanoplatelets and Carbon Black. This can be attributed to the low roughness of the conductive carbon coating, the uniform distribution and good interconnection of the carbon particles. The heaters have a low thermal inertia, producing a rapid temperature response at low voltages, reaching equilibrium temperatures within 120 s of being switched on. The heaters reached the 40 °C required for wearable heating applications within 20 s at 12 Volts. Screen printing was demonstrated to be an effective method of controlling the printed layer thickness with good interlayer adhesion and contact for multiple printed layers. This can be used to regulate their electrical properties and hence adjust the heater performance. Full article
(This article belongs to the Special Issue Advanced Flexible Materials for Printed Electronics)
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20 pages, 11706 KiB  
Article
Study on Geometry, Dimensional Accuracy and Structure of Parts Produced by Multi Jet Fusion
by Martyna Adach, Paweł Sokołowski, Tomasz Piwowarczyk and Krzysztof Nowak
Materials 2021, 14(16), 4510; https://doi.org/10.3390/ma14164510 - 11 Aug 2021
Cited by 17 | Viewed by 3661
Abstract
Multi Jet Fusion (MJF) is one of the newest additive manufacturing technologies for polymer powders, introduced in recent years. This fully industrial technology is gaining big interest as it allows fast, layer-by-layer, printing process, short production cycle, and very high printing resolution. In [...] Read more.
Multi Jet Fusion (MJF) is one of the newest additive manufacturing technologies for polymer powders, introduced in recent years. This fully industrial technology is gaining big interest as it allows fast, layer-by-layer, printing process, short production cycle, and very high printing resolution. In this paper, twelve thin-walled, spherical PA12 prints were studied in terms of geometry, dimensional accuracy, and fracture surface characteristics. The various characteristic features for MJF prints were observed here for parts produced according to four various print orientations and having different thicknesses, i.e., 1, 2 or 3 mm. The study showed that MJF technology can print such difficult shapes. However, the set of parameters allowing producing parts with highest geometrical and dimensional accuracy causes at the same time some microstructural issues, like great interlayer porosity or high number of non-processed powder particles embedded in the print structure. Full article
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14 pages, 5430 KiB  
Article
Improvement of the Adhesion and Diamond Content of Electrodeposited Cu/Microdiamond Composite Coatings by a Plated Cu Interlayer
by Xiaoli Wang, Chau-Chang Chou, Liberty Tse-Shu Wu, Rudder Wu, Jyh-Wei Lee and Horng-Yi Chang
Materials 2021, 14(10), 2571; https://doi.org/10.3390/ma14102571 - 15 May 2021
Cited by 7 | Viewed by 2858
Abstract
Diamond-incorporated copper metal matrix layers were fabricated on brass substrates by using electrodeposition technology in this study. To improve the adhesion of the composite coatings on the brass substrate, a plated copper was applied as the interlayer between the multilayers and the substrate. [...] Read more.
Diamond-incorporated copper metal matrix layers were fabricated on brass substrates by using electrodeposition technology in this study. To improve the adhesion of the composite coatings on the brass substrate, a plated copper was applied as the interlayer between the multilayers and the substrate. The surface morphologies of the interlayer and the diamond-incorporated copper composite layers were studied by scanning electron microscopy. The effect of the copper interlayer on the incorporation and the distribution of the diamond content in the coatings was analyzed by surface roughness, electrochemical impedance spectroscopy, and cyclic voltammetry. The diamond content of the composite coating was measured by energy-dispersive X-ray. The film thickness was evaluated by the cross-sectional technique of focused ion beam microscopy. The element, composition, and crystallization direction of diamond with Cu matrix was measured by X-ray diffraction and transmission electron microscope. The adhesion of the multilayers was studied by scratch tests. The experiment results indicated that the diamond content and distribution of the coating were higher and more uniform with the Cu interlayer than that without one. The plated copper interlayer reduced the electrical double-layer impedance and enhanced the adsorption of diamond particles by the surrounding Cu ions, which promoted the diamond content in the composite coatings. The roughened surface caused by the plated Cu interlayer also improved the substrate’s mechanical interlock with the composite coating, which contributed to the strong adhesion between them. Full article
(This article belongs to the Special Issue Tribology and Surface Engineering 2021)
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14 pages, 2965 KiB  
Article
Adsorption Characteristics of Stone-Bentonite Mixtures towards Zn: Equilibrium and Kinetic Tests
by Sifa Xu, Yajun Fu, Weiwei Wei, Cuifeng Li, Mengdan Bian and Zhe Wang
Processes 2021, 9(4), 619; https://doi.org/10.3390/pr9040619 - 1 Apr 2021
Viewed by 2010
Abstract
In the treatment of industrial polluted sites and the construction of landfill sites, anti-pollution barriers are usually used to prevent the diffusion of pollutants. In this paper, the adsorption characteristics of Zn ions by the rock-bentonite anti-pollution barrier were observed by means of [...] Read more.
In the treatment of industrial polluted sites and the construction of landfill sites, anti-pollution barriers are usually used to prevent the diffusion of pollutants. In this paper, the adsorption characteristics of Zn ions by the rock-bentonite anti-pollution barrier were observed by means of static equilibrium and dynamic adsorption tests. The experimental results showed that the adsorption of Zn by stone chips—bentonite was close to the nonlinear Freundlich and Langmuir models. When the concentration of Zn ion is constant, the adsorption capacity increases with the increase in temperature. At a certain temperature, the adsorption removal rate decreases with the increase in concentration. Further study found that the adsorption of Zn from mixed soil was mainly an ion exchange process, and the adsorption mode of Zn from mixed soil was controlled by both intra-particle diffusion and membrane diffusion. Zeta potential, X-ray diffraction (XRD) and The Fourier Transform Infrared spectroscopy (FTIR) showed that with the increase in concentration, the mixed soil adsorbed more metal ions, and the thickness of the double electric layer decreased. Moreover, the adsorption of Zn2+ by bentonite was mainly interlayer adsorption and ion exchange. As an anti-pollution barrier material, the mixed soil of stone chips -bentonite can prevent the diffusion of pollutants, which has certain reference significance for engineering construction. Full article
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19 pages, 7182 KiB  
Article
Optimization of Mechanical Properties and Damage Tolerance in Polymer-Mineral Multilayer Composites
by Johannes Wiener, Hannes Kaineder, Otmar Kolednik and Florian Arbeiter
Materials 2021, 14(4), 725; https://doi.org/10.3390/ma14040725 - 4 Feb 2021
Cited by 16 | Viewed by 3437
Abstract
Talcum reinforced polypropylene was enhanced with a soft type of polypropylene in order to increase the impact strength and damage tolerance of the material. The soft phase was incorporated in the form of continuous interlayers, where the numbers of layers ranged from 64 [...] Read more.
Talcum reinforced polypropylene was enhanced with a soft type of polypropylene in order to increase the impact strength and damage tolerance of the material. The soft phase was incorporated in the form of continuous interlayers, where the numbers of layers ranged from 64 to 2048. A blend with the same material composition (based on wt% of the used materials) and the pure matrix material were investigated for comparison. A plateau in impact strength was reached by layered architectures, where the matrix layer thickness was as small or smaller than the largest talcum particles. The most promising layered architecture, namely, 512 layers, was subsequently investigated more thoroughly using instrumented Charpy experiments and tensile testing. In these tests, normalised parameters for stiffness and strength were obtained in addition to the impact strength. The multilayered material showed remarkable impact strength, fracture energy and damage tolerance. However, stiffness and strength were reduced due to the addition of the soft phase. It could be shown that specimens under bending loads are very compliant due to a stress-decoupling effect between layers that specifically reduces bending stiffness. This drawback could be avoided under tensile loading, while the increase in toughness remained high. Full article
(This article belongs to the Special Issue Structure Property Relationship of Polymeric Materials)
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