Search Results (718)

Fine-grained sedimentary rocks exhibit significant textural heterogeneity, often obscured by conventional grain size analysis techniques that require sample disaggregation. We propose a non-destructive, image-based grain size characterization workflow, utilizing stitched polarized thin-section photomicrographs, k-means clustering, and watershed segmentation algorithms. Validation against laser granulometry data indicates strong methodological reliability (absolute errors ranging from −5% to 3%), especially for particle sizes greater than 0.039 mm. The methodology reveals substantial internal heterogeneity within Es3 laminated shale samples from the Shahejie Formation (Bohai Bay Basin), distinctly identifying coarser siliceous laminae (grain size >0.039 mm, Φ < 8 based on Udden-Wentworth classification) indicative of high-energy depositional environments, and finer-grained clay-rich laminae (grain size <0.039 mm, Φ > 8) representing low-energy conditions. Conversely, massive mudstones exhibit comparatively homogeneous grain size distributions. Additionally, a multifractal analysis (Multifractal method) based on the S_50bi/S_50si ratio further quantifies spatial heterogeneity and pore-structure complexity, significantly enhancing facies differentiation and reservoir characterization capabilities. This method significantly improves facies differentiation ability, provides reliable constraints for shale oil reservoir characterization, and has important reference value for the exploration and development of the Bohai Bay Basin and similar petroliferous basins. Full article

Rivers, vital for life and civilizations, face severe threats from human activities such as hydropower development, with heavy metal pollution emerging as a critical concern due to altered biogeochemical cycles. Understanding how river damming affects heavy metal transport processes and developing targeted remediation strategies are essential for safeguarding the health of river-reservoir ecosystems and enabling the sustainable utilization of hydropower resources. Therefore, this review first summarizes the global hydropower development, details how damming disrupts hydrology, environments, and ecosystems, and analyzes heavy metal distribution and transport in reservoir water, suspended sediments, and riverbed sediments. It reveals that river damming promotes heavy metal adsorption onto suspended particles, deposition in riverbed sediments, and re-release during reservoir regulation, and anthropogenic activities are a primary driver of significant pollution in key reservoirs worldwide. Additionally, we further evaluate in situ (e.g., stabilizing agents, sediment capping, and phytoremediation) and ex situ (e.g., dredging, chemical washing, electrochemical separation, and ultrasonic extraction) remediation techniques, highlighting the challenges of phytoremediation in deep, stratified reservoir environments. Moreover, solidification/stabilization emerges as a promising in situ strategy, emphasizing the need for specific approaches to balance pollution control with hydropower functionality in dammed river systems. Full article

Reliable information on the chemical and physical makeup of mine tailings is critical in meeting environmental and regulatory requirements, as well as identifying whether contained elements, including critical minerals, might be economically recovered in future to meet growing demands. Detailed mineralogical characterization, supported by chemical assays and automated mineralogy (MLA) data on different size fractions, underpins a case study of flotation tailings from the processing plant at the Carrapateena mine, South Australia. The study provides valuable insights into the deportment of minor and critical elements, including rare earth elements (REEs), along with uranium (U). REE-minerals are represented by major phosphates (monazite and florencite) and subordinate REE-fluorocarbonates (bastnäsite and synchysite). More than half the REE-minerals are concentrated in the finest size fraction (−10 μm). REEs in coarser fractions are largely locked in gangue, such that economic recovery is unlikely to be viable. MLA data shows that the main REE-minerals all display specific associations with gangue, which change with particle size. Quartz and hematite are the most common associations, followed by sericite. Synchysite shows a strong affiliation to carbonates. The contents of other critical elements (e.g., tungsten, molybdenum, cobalt) are low and for the most part occur within other common minerals as submicron-sized inclusions or in the lattice, rather than discrete minerals. Nevertheless, analysis of mine tailings from a large mining–processing operation provides an opportunity to observe intergrowth and replacement relationships in a composite sample representing different ore types from across the deposit. U-bearing species are brannerite (associated with rutile and chlorite), coffinite (in quartz), and uraninite (in hematite). Understanding the ore mineralogy of the Carrapateena deposit and how the ore has evolved in response to overprinting events is advanced by observation of ore textures, including between hematite and rutile, rutile and brannerite, zircon and xenotime, and the U-carbonate minerals rutherfordine and wyartite, the latter two replacing pre-existing U-minerals (uraninite, coffinite, and brannerite). The results of this study are fundamental inputs into future studies evaluating the technical and economic viability of potentially recovering value metals at Carrapateena. They can also guide efforts in understanding the distributions of valuable metals in analogous tailings from elsewhere. Lastly, the study demonstrates the utility of geometallurgical data on process materials to assist in geological interpretation. Full article

The energy deposition process for the main components of SIC Schottky diodes is simulated based on Geant4. Particle bombardment results were simulated under different angles, target materials and doping concentrations on the same target material for different light particles and heavy ions, and then the Linear Energy Transfer of SiC materials and external conditions that affect LET are obtained. The results show that the LET value of protons exhibits significant oscillations at low energy incidence, gradually decreasing exponentially after 10⁻¹ MeV. Alpha particles have a LET peak near 1 MeV, while beta particles show an exponential decrease. The LET values at low energy levels increase exponentially, while at high energy levels, the LET values show a similar linear relationship with energy. For different incident angles, the average LET value of protons in the low-level region gradually increases as the incident angle increases. The average LET value of protons in the remaining energy ranges is less affected by angle; the incident angle has no significant effect on the LET distribution of alpha particles within the full spectrum range. The results provide important references for understanding the energy deposition process and LET distribution of silicon carbide devices under single-particle interaction. Full article

The Yellow River, with its extremely high sediment loads, and the Yellow River Estuary (YRE) serve as a vital conduit for material exchange between land and marine environments, where sediment–phosphorus interactions profoundly influence nutrient cycling, ecological health and eutrophication potential. This paper reviews the distribution of phosphorus in overlying water and sediment, the characteristics of phosphorus migration and transformation across the sediment–water interface, and the effecting factors of phosphorus migrate, such as sediment properties and environmental factors in the YRE. Inorganic phosphorus was the dominant form in the overlying water and sediment. Suspended sediment acts as a dynamic reservoir for phosphorus transportation in the YRE. The dynamic estuarine environment promotes sediment deposition, which helps reduce phosphorus levels in the water. Upon entering the Bohai Sea, sediment is transformed into the source of phosphorus. The released phosphorus may increase the nutrient load in shallow Bohai Sea waters. Fine particles demonstrate strong adsorption capacity for reactive phosphorus, acting as the primary carriers for phosphorus migration at the sediment–water interface. The grain size of the suspended sediment in the Yellow River exhibited significant sorting characteristics with varying sediment content, consequently affecting the forms of phosphorus. Likewise, the influence of biogeochemical conditions on the transport and transformation of sediment and phosphorus was further analyzed and the partial least squares-path model of related variables on estuarine phosphorus is constructed to interpret the behavior of sediment and phosphorus in the YRE. Finally, the current situation and indeterminacy of water quality models in the estuary were appraised. The priority of analyzing and revealing the environmental behaviors of phosphorus in a sediment-laden river estuary in the future was further proposed against the present deficiencies. This review holds significant practical importance for enhancing the assessment of ecological environment quality and ecological restoration in the YRE. Full article

Copper is a critical material for energy transition and green technologies, making its sustainable use increasingly important. Its superior thermal and electrical conductivity make it highly well-suited for additive manufacturing (AM). In this study, copper sourced from offshore electrical cables was upcycled to produce high-quality metal powder for AM. The scrap was processed to separate the metal from plastic and rubber, then refined through ultrasonic atomization, achieving a purity of ~99.5% wt.% with minimal impurities. Characterization demonstrated good flowability, apparent and tap densities, and a well-distributed particle size. To assess its performance in AM, the powder was printed using Directed Energy Deposition (DED) with a laser beam, confirming its high printability and compatibility with the base material. Finally, a comparative Life Cycle Assessment (LCA) revealed a significant environmental advantage of the recycling-based process over conventional mining, reducing global warming potential by more than 70%. These findings highlight the importance of feedstock origin in AM sustainability and support the adoption of circular economy strategies to lower the environmental footprint of advanced manufacturing. Full article

In view of the problems existing in the application of greenhouse pesticides in China, this paper developed a swing-arm sprayer for greenhouse high-stem crops through field research and a literature review. Static and dynamic simulations of the swing-arm mechanism were carried out to verify the rationality of the structure. The average contact angle between the water and tomato leaves was 49.39°, while the contact angle of the auxiliary solution on the tomato leaves decreased to 40.98°. An indoor atomization test platform was designed to accurately test the particle size and spray performance. The relative span (RS) of droplet distribution showed that the RS values of nozzles 015, 02, and 03 were relatively small, while the RS value of nozzle 04 was about 1.734. With the addition of additives, the RS value of nozzle 02 decreased from 1.305 to 1.021. The field tests showed that the deposition of fog droplets on the front of tomato leaves was in the order of middle > lower > ground > upper (3.622 μL/cm², 3.005 μL/cm², 2.977 μL/cm², and 2.931 μL/cm², respectively). The results indicate that adding additives or increasing the swing-arm angle is beneficial for improving the uniformity of canopy droplet deposition. The front fog droplet coverage of the lower canopy of tomatoes was the lowest, with an average of 26.00%, while the middle and upper canopies had the highest, with an average of 50.58% and 50.72%, respectively. The research found that the spray coverage rate on the front and back sides of tomato leaves was relatively uniform, indicating that the swing-arm greenhouse sprayer designed in this paper could meet the spray quality requirements for tomato pest control. Full article

A novel process for the synthesis of binder-free, porous nickel/polythiophene-functionalized sulfur (Ni/S-PTh) composite cathodes for lithium–sulfur (Li–S) batteries is introduced in this paper. Initially, a polyvinyl butyl polymer scaffold is 3D printed, then coated with a graphite-based conducting layer, and, finally, it is pulse-plated for nickel deposition to produce a high-surface-area, mechanically stable current collector. S-PTh particles are afterwards co-deposited into the Ni matrix through composite electrodeposition. After the dissolution of the polymer template, the resulting self-standing electrodes still maintain porous structure with uniform sulfur distribution and a distinct transition between the dense Ni layer and the Ni/S-PTh composite layer. Electrochemical characterization of the Ni/S-PTh composite cathodes by galvanostatic cycling at C/10 rate results in an initial specific discharge capacity of ~1120 mAh·g⁻¹ and a specific capacity of ~910 mAh·g⁻¹ after 200 cycles, resulting in a high capacity retention of ~81 %. For our novel approach, no steps at high temperatures or toxic solvents are involved and the need for polymer binders and conductive additives is avoided. These results demonstrate the potential of composite electrodeposition in combination with 3D printing for producing sustainable, high-performance sulfur cathodes with tunable architecture. Full article

This work presents a systematic literature review of powder-gas jet stream (PGJS) characterisation techniques for coaxial nozzles in the laser directed energy deposition process (L-DEDp). The analysis includes thirty-four camera-based and four weight-based techniques. In weight-based techniques, the mapping of powder concentration is made by measuring the powder flow rate in certain areas within the PGJS. Despite being cost-effective, these methods are time-consuming, invasive, and less suitable for real-time monitoring. Camera-based techniques use laser light and a camera to capture particle intensities, allowing for the non-intrusive measurement of powder distribution. Despite its advantage, limitations are reported in the literature regarding the techniques. Detecting dense or fine powder flows accurately is challenging. Two-dimensional images cannot fully represent the jet’s three-dimensional structure, relying on image processing algorithms for the results. However, the non-existence of a common standard metric for evaluating and comparing results across various setups is a significant gap, as each characterisation often needs to be performed on a case-by-case basis. To address these challenges, a basic reporting structure is suggested to enable a standardised assessment of PGJS measurements, thereby supporting process control and quality assurance in L-DEDp applications. Full article

Pneumatic conveying of stiff shotcrete material plays a crucial role in mine support; however, the flow regime evolution mechanism of its complex multi-scale particle system during conveying remains insufficiently studied. This study establishes a customized pneumatic conveying experimental platform, integrating a high-speed camera and pressure sensors to systematically investigate the flow regime evolution and characteristics of stiff shotcrete material under different operating parameters. Experimental results indicate that air velocity and water–cement ratio significantly influence flow regime evolution: at low air velocities, the material primarily exhibits dune flow and stratified flow. As the air velocity increases to 475 m³/h, the flow regime gradually transitions to suspended flow. An increase in the water–cement ratio significantly enhances liquid bridge forces between particles, intensifying particle agglomeration and making the bottom-layer flow characteristics more pronounced. Additionally, pipe diameter plays a crucial role in flow regime distribution, with suspended flow dominating in smaller pipes and bottom-layer flow becoming more prominent in larger pipes. In the downstream section of the elbow, the abrupt decrease in airflow velocity causes the flow regime to degrade from suspended flow to bottom-layer flow, leading to significant particle deposition. This study reveals the flow regime evolution patterns of stiff shotcrete material in pneumatic conveying, providing essential experimental evidence and theoretical support for optimizing long-distance pneumatic conveying systems in mine support applications. Full article

Orchard air-assisted sprayers have become key equipment for the prevention and control of fruit tree diseases and pests. However, centrifugal fans are rarely used in orchard air-assisted sprayers. To address the issue that the airflow generated by single-duct centrifugal air-assisted sprayers is insufficient to cover the lower canopy, a flow-guiding device for the lower canopy of fruit trees was designed. The Flow Simulation software of SOLIDWORKS 2021 was used to simulate the airflow field, and various structural parameters of the air outlet were analyzed to determine the optimal configuration of the upper edge inclination angle, the position of the upper air outlet, and the length of the upper air outlet. The results showed that the position of the upper air outlet had the most significant impact on the uniformity of the external flow field, followed by the upper edge inclination angle and the length of the upper air outlet. The optimal parameter settings for the air supply guiding device were determined as follows: upper edge inclination angle of 79°, upper air outlet position of 307 mm, and upper air outlet length of 190 mm. The verification test showed that the relative error between the simulated and actual airflow velocity measurements did not exceed 10%, confirming the accuracy of the simulation. The orchard field test showed that the average deposition density in the inner canopy of fruit trees was 78 particles/cm², indicating strong penetration ability; the distribution of spray droplets in the vertical direction of the canopy was uniform, meeting the requirements of fruit tree pesticide application operations. This technology provides a new approach for the application of centrifugal fans in fruit tree pesticide spraying. Full article

Alumina (Al₂O₃) is a key material in inorganic and hybrid electronics due to its excellent dielectric, chemical, and thermal stability properties. In this work, we present the first results of alumina films deposited by ultrasonic spray pyrolysis (USP) at low temperatures (40–100 °C) using water as the sole solvent, followed by an annealing step at 100 °C. The films were characterized by SEM, XRD, EDS, and UV-Vis spectroscopy to evaluate their morphology, structure, composition, and optical properties. Preliminary results show an average thickness of approximately 8 µm, with surface features consisting of agglomerates (average particle size ≈ 7.252 µm) distributed over the film. XRD patterns revealed the presence of tetragonal and orthorhombic phases, while EDS confirmed the presence of aluminum and oxygen with slight compositional variations depending on deposition and annealing conditions. UV-Vis absorption spectra exhibited characteristic bands between 259 nm and 263 nm. These results provide a comprehensive understanding of the optical, structural, and morphological behavior of Al₂O₃ films processed at low temperatures. The motivation for studying these films is to enable more eco-friendly gate oxides for organic MIS structures, as well as functional layers in photonic devices. This approach represents a sustainable and straightforward route for obtaining Al₂O₃ coatings compatible with temperature-sensitive substrates, paving the way for future applications in hybrid and organic electronics. Full article

In this study, the properties of electrophoretically deposited (EPD) coatings on orthodontic implants made from Ti-6Al-4V alloy were evaluated during simulated implantation trials on animal bones. Three types of chitosan-based coatings were prepared using EPD: titanium nitride microparticles (TiNPs), titanium nitride nanoparticles (TiNNPs), and boron nitride particles (BNPs). Each of these coatings was also modified by adding a polylactic acid (PLA) layer using a dip-coating technique to compare their properties with and without this additional layer. The coatings were analysed using optical microscopy, confocal microscopy, and scanning electron microscopy (SEM) with elemental analysis. Surface roughness measurements of the coated implants were also conducted to highlight differences that could significantly influence the type and strength of the bone-implant interface, directly affecting the stability of the implant as an anchorage unit. Eventually, to evaluate the antibacterial properties of the EPD coatings, their antibacterial activity against both Gram-positive and Gram-negative bacteria strains was tested. Scanning electron observations confirmed the homogenous distribution of micro- and nanoparticles in all coatings. The highest surface roughness values were observed in layers containing titanium nitride nanoparticles (TiNNPs) and chitosan. The presence of an additional dip-coating PLA layer improved the adhesion, and its effect on the surface roughness depended on the particle size. While the antibacterial properties of the coatings show promising results, achieving optimal adhesion of the coatings to implants remains a challenge that requires further development. Full article

Random packed beds (RPBs) of various particles are widely used in chemical reactors to enhance the contact between the reactants or the catalyst. This numerical study investigates the prospects of using a helical flow deflector spanning the whole cross-section of the reactor and the height of the random packing to control residence time distribution (RTD) in RPBs of spherical particles. The packed bed geometry is generated via sequential particle deposition, while flow equations are solved for the real geometry of the packing without additional modelling terms. The results demonstrate that in laminar conditions the flow deflector significantly increases flow tortuosity and residence time (even a few times for small helix pitches) when the effective velocity in the RPB is kept fixed. The relationship between the helix pitch and tortuosity, pressure drop, and RTD is quantified, revealing that residence time scale similarly to tortuosity while the increase in pressure drop is more pronounced. The study provides a validated framework for optimising helical deflector designs in RPBs (at least in the laminar regime), with implications for reactor efficiency. Full article

Oxide dispersion-strengthened (ODS) alloys are regarded as one of the most promising materials for Generation IV nuclear fission systems, owing to their exceptional attributes such as high strength, corrosion resistance, and irradiation tolerance. The traditional methods for fabricating oxide dispersion-strengthened (ODS) alloys are both time-consuming and costly. In contrast, additive manufacturing (AM) technologies enable precise control over material composition and geometric structure at the nanoscale, thereby enhancing the mechanical properties of components while reducing their weight. This novel approach offers significant advantages over conventional techniques, including reduced production costs, improved manufacturing efficiency, and more uniform distribution of oxide nanoparticles. This review begins by summarizing the state of the art in Fe-based and Ni-based ODS alloys fabricated via traditional routes. Subsequently, it examines recent progress in the AM of ODS alloys, including Fe-based, Ni-based, high-entropy alloys, and medium-entropy alloys, using powder bed fusion (PBF), directed energy deposition (DED), and wire arc additive manufacturing (WAAM). The microstructural characteristics, including oxide particle distribution, grain morphology, and alloy properties, are discussed in the context of different AM processes. Finally, critical challenges and future research directions for laser-based AM of ODS alloys are highlighted. Full article