Search Results (41)

Antimony (Sb) contamination in water poses significant environmental and health risks due to its high toxicity, persistence and complex redox behavior. Magnetic spinel ferrites (MFe₂O₄) have shown promise for Sb removal; however, the intrinsic influence of divalent metal species (M²⁺) in regulating Sb(III)/Sb(V) adsorption performance and interfacial mechanisms remains poorly understood. In this study, MnFe₂O₄, ZnFe₂O₄ and NiFe₂O₄ nanoparticles were synthesized and systematically evaluated to elucidate how M²⁺ governs Sb immobilization behavior. Batch adsorption experiments revealed pronounced M–dependent selectivity. MnFe₂O₄ exhibited the highest Sb(III) adsorption capacity (229.89 mg·g⁻¹), whereas NiFe₂O₄ showed superior affinity toward Sb(V) (up to 257.07 mg·g⁻¹). Adsorption kinetics for both Sb species followed pseudo-second-order models, indicating chemically controlled processes. Isotherm analyses indicated predominantly monolayer complexation for Sb(III), while Sb(V) adsorption displayed mixed adsorption characteristics, reflecting surface heterogeneity. Mechanistic investigations based on FTIR and XPS analyses suggest that Sb(III) immobilization is dominated by inner-sphere complexation with surface Fe–O/Fe–OH groups, whereas Sb(V) adsorption involves synergistic coordination with both Fe–O and M–O (Mn–O/Ni–O) functional groups. XPS analysis of Sb-loaded ZnFe₂O₄ revealed the coexistence of Sb(III) and Sb(V) species after Sb(III) adsorption, indicating surface-confined partial oxidation; the extent of solution-phase conversion was not independently quantified. Therefore, the redox process is interpreted as an interfacial phenomenon rather than bulk oxidation in solution. These results clarify that M²⁺ species influence Sb removal behavior by modulating the reactivity of surface functional groups and interfacial redox characteristics, rather than merely altering adsorption capacity. This work provides spectroscopic insight into M-dependent structure–activity relationships in spinel ferrites and offers a theoretical basis for the rational design of magnetic adsorbents for selective and efficient Sb remediation. Full article

Slender structures such as minarets are highly susceptible to earthquake-induced damage in seismically active regions. Although various methods, including analytical and observational techniques, have been employed to study the seismic response of reinforced concrete (RC) minarets, the use of scaled physical models and shaking table testing remains limited. This research examines the numerical feasibility of employing scaled physical models for shaking table investigations of RC minarets under realistic laboratory constraints. A representative RC minaret with a height of 33.2 m was selected and a geometric scale ratio of 1:10 length was adopted. Established physical modeling approaches were evaluated through numerical implementation, with particular attention to similitude requirements, material properties, and laboratory limitations. Within this framework, the Artificial Mass Model (AMM) and the Neglected Gravity Model (NGM) were examined as candidate strategies for scaled modeling. Both approaches necessitate the use of a material with a reduced modulus of elasticity or an increased mass density relative to the prototype material. To satisfy these requirements, two micro-concrete mixes, designated as Mix-1 and Mix-2, incorporating partial replacement of the binder with lower-stiffness constituents such as plaster gypsum and fly ash, were developed and characterized. Numerical results indicate that both the AMM and NGM approaches are viable for modeling slender RC minaret structures. Although the AMM provides slightly higher accuracy in reproducing the prototype dynamic response, the NGM offers greater practical applicability by eliminating the need for additional artificial mass. Overall, this study presents a preliminary numerical feasibility assessment that supports the selection of appropriate physical modeling strategies and provides a rational basis for the subsequent execution of shaking table experiments. Full article

Drug-resistant bacteria cause millions of global infections each year, and the development of alternative antimicrobial drugs has become a serious undertaking. Currently, peptides with antimicrobial activity represent potential candidates for new antibiotic discovery as they are less likely to cause drug resistance in bacteria. In this study, bifunctional peptides with potent trypsin-inhibitory activity and antimicrobial activity were obtained by rational computation-based structural modifications to a novel Bowman–Birk-type inhibitor (BBI) peptide. The analogues not only displayed potent bacterial killing ability against two drug-resistant bacteria strains of E. coli but also an excellent safety profile, as assessed by low haemolytic activity and low anti-proliferation activity on HaCaT cells. Throughout the molecular dynamics simulations, the peptides exhibited stable adsorption onto the mixed POPE/POPG membrane; most amino acid residues of the AMPs remained bound to the membrane surface, with a few amino acid residues partially penetrating the membrane interior. This showed that the electrostatic interactions were the dominant driving force mediating the peptide–membrane associations. In addition, the tested peptides displayed a degree of stability in the presence of salt ions, serum, and trypsin. These modified peptides thus possess potential as clinical antibacterial agents, and the strategies used in structural modification may also provide a different path to developing new antimicrobial peptides. Full article

Developing highly permeable and selective membranes for energy-efficient CO₂/CH₄ separation remains challenging. Mixed-matrix membranes (MMMs) integrating polymer matrices with metal–organic frameworks (MOFs) offer significant potential. However, rational filler–matrix matching presents substantial difficulties, constraining separation performance. In this work, defects were engineered within fluorinated MOF ZU-61 through the partial replacement of 4,4′-bipyridine linkers with pyridine modulators, producing high-porosity HP-ZU-61 nanoparticles exhibiting a 267% BET surface area enhancement (992.9 m² g⁻¹) over low-porosity ZU-61 (LP-ZU-61) (372.2 m² g⁻¹). The HP-ZU-61/6FDA-DAM MMMs (30 wt.%) demonstrated homogeneous filler dispersion and pre-served crystallinity, achieving a CO₂ permeability of 1626 barrer and CO₂/CH₄ selectivity (33), surpassing the 2008 Robeson upper bound. Solution-diffusion modeling indicated ligand deficiencies generated accelerated diffusion pathways, while defect-induced unsaturated metal sites functioned as strong CO₂ adsorption centers that maintained solubility selectivity. This study establishes defect engineering in fluorinated MOF-based MMMs as a practical strategy to concurrently overcome the permeability–selectivity trade-off for efficient CO₂ capture. Full article

Using additives in sugarcane silage can reduce dry matter losses and enhance animal performance by preserving nutritional value. This study evaluated the performance, nutrient digestibility, and blood parameters of sheep fed sugarcane silage with or without cottonseed cake. Twenty-six uncastrated, mixed-breed male lambs (approximately 6 months of age; 26 ± 1.3 kg) were allocated to two dietary treatments based on sugarcane silage (SS) and cottonseed cake (CSC), which differed in the form of feed presentation: (1) the control, consisting of SS and fresh CSC provided simultaneously but offered separately, without physical mixing; and (2) the Partial Mixed Ration silage (S + CSC), in which SS and CSC were pre-mixed and ensiled together at a proportion of 80:20 (natural matter basis). Dry matter intake (1620 g/kg) was similar between diets, but dry matter digestibility (64.75%) and average daily gain (202.88 g/day) were higher in the cottonseed cake group, leading to greater total weight gain (8.11 kg). These animals also had a lower acetate/propionate ratio (4.2 vs. 2.0 mmol/L) and higher blood glucose (44 vs. 35 mg/dL). Higher N intake, urinary N, and retained N were observed in the cottonseed cake diet, which also improved the diet’s mineral balance. In conclusion, adding cottonseed cake to sugarcane silage enhances fermentation, preserves nutritional value, and improves sheep performance. Full article

Forest aboveground biomass (AGB) serves as a crucial indicator of productivity and carbon storage capacity. While the impact of stand structure on AGB is well-documented for pure moso bamboo stands, the specific structural factors influencing AGB and the mechanisms driving these effects in mixed moso bamboo forests, characterized by species diversity and structural complexity, require further elucidation. This study analyzed 9453 bamboos and arbor trees within the TianBao MetaPlot, which were tessellated into 108 standard plots in Tianbaoyan National Nature Reserve, Fujian, China. Using a multi-method voting approach, we identified the key structural factors influencing stand AGB and employed Partial Least Squares Path Modeling (PLS-PM) to assess their direct and indirect effects. We found that the stand density, moso bamboo mixing ratio, Shannon’s index, Simpson’s index, mean tree height, openness, and tree size variation coefficient were the key structural factors influencing the stand AGB. The PLS-PM analysis showed that stand density had a negative effect on stand AGB, which can be explicitly decomposed through a direct negative effect and an indirect negative effect. Tree diversity showed a strong positive effect, supporting the niche complementarity theory. The stand mean tree height and stand tree size variation had positive effects on stand AGB, while stand openness had a negative effect. The direct effects of tree diversity, stand mean tree height, and stand openness were stronger than the indirect effects on stand AGB, while the indirect effect of stand density was greater than the aforementioned effects. These results highlight the complex interactions between stand structure and stand AGB in mixed moso bamboo forests. The negative effect of stand density on stand AGB is in contrast with previous findings on arbor forests, wherein a higher stand density often promotes AGB, highlighting the unique structural characteristics of mixed moso bamboo forests. To promote biomass accumulation and enhance carbon sequestration in mixed moso bamboo stands, it is recommended to increase the tree size variability, enhance the tree species diversity, and apply rational thinning of moso bamboo, based on site-specific conditions. Full article

The recycling of old concrete from the demolition of concrete structures is necessary for the rational use of natural aggregate resources. Recycled concrete aggregates (RCAs) are the highest quality recycled aggregates as they are the closest to natural aggregates. However, the use of RCAs is always associated with greater fluctuations and usually with a deterioration in workability, mechanical properties and long-term properties. The use of RCA in self-compacting concrete (SCC), where the proportion of aggregate is lower than in conventional concrete, is one way of mitigating the effects of RCAs. In this paper, the effects of coarse and fine RCA are investigated, focusing on dimensional changes due to shrinkage and creep. SCC mixes were developed in which the dolomite aggregates were partially or completely replaced by RCAs and additionally mixes in which 50% of the cement was replaced by fly ash. The average shrinkage strain measured after 180 days increased from 0.34 mm/m for a mix with natural aggregates to 1.04 mm/m for a mix made entirely with RCAs, showing an almost proportional increase in strain with RCA content. At the same age, the creep compliance ranged from 0.07 GPa⁻¹ for the mix with natural aggregates to 0.34 GPa⁻¹ for the mix made entirely with RCAs, and is most strongly correlated with hardened concrete density. Full article

Near-infrared spectroscopy (NIRS) is an efficient, non-destructive method for evaluating the chemical composition of various compounds. This study aimed to assess both the proximate composition, fibres, and fatty acid (FA) content of Total Mixed Rations (TMRs) in dairy buffalo nutrition. A total of 240 TMR samples were collected from ten dairy buffalo farms across four seasons to develop predictive models using Partial Least Squares Regression (PLSR). Calibration models for dry matter (DM), crude protein (CP), ether extract (EE), and starch demonstrated good predictive accuracy, with coefficients of determination in cross-validation (R²cv) around 0.90 and Residual Predictive Deviation (RPDcv) values exceeding 3.0. Fatty acid models showed slightly lower R²cv values, ranging from 0.80 to 0.90. A good predictive performance was observed for linoleic acid (18:2 n-6) and α-linolenic acid (18:3 n-3), with RPDp values above 3.0, indicating reliable predictions. The inclusion of omega-3-rich compounds in the diet provides significant benefits for both animal health and product quality, highlighting the importance of ration monitoring. The findings confirm that while NIRS is effective for assessing chemical composition, further refinement is needed to improve FA prediction accuracy. These results support the use of NIRS as a practical tool for nutritional monitoring in lactating buffaloes. Full article

In both capitalist and socialist economies, agricultural planning has been understood as the allocation of areas for planting of certain products; the production potential and ability to act rationally of farmers, the main productive actors, have been neglected. In addition, in both economic structures, the desired results have only been partially achieved by determining prices. These experiences reveal two important results. Firstly, agriculture can not be fully planned, but it cannot be continued without planning either. Secondly, it is necessary for agricultural products to have an exchange value, but price is a multifunctional phenomenon and how it is determined is important. The current equivalent of the claim that prices are determined through the market mechanism is to advocate that prices are determined by capitalist companies that have monopoly power in the markets. The increasingly severe problems and increasing fragility of agricultural food markets, which are already largely under the control of these institutions, already show that this structure is not a solution. On the other hand, it is no longer possible to provide food security by planning for primary agricultural products alone; agro-food production and distribution have acquired different structural characteristics, and it has become necessary to address food security within the framework of agro-food systems. Therefore, effective agricultural planning requires the planning of the agricultural food system as a whole. The e-nam system being popularized in India has achieved a certain success and shows not only that it is possible to organize and manage agricultural food markets after primary production but also that technological opportunities offer effective planning opportunities. In this study, based on historical and current experiences, the inadequacies of the market mechanism, the fact that agricultural production is carried out by using living things to produce living things, and the dependency of uncontrollable factors are taken into consideration in the development of a democratic mix of centralized and decentralized planning aimed at determining both the production quantities and prices by utilizing the capacity and conditions of farmers and technological opportunities to meet today’s needs. In accordance with this result, a basic planning proposal is presented. Full article

This study was conducted at a commercial dairy farm in Queensland, Australia to evaluate the effects of feeding a lactic acid bacteria-based direct-fed microbial (DFM) during gestation on the metabolic profile of periparturient dairy cows and its effects on milk production and body weight. A total of 150 multiparous Holstein cows were randomly selected based on parity (2.3) and days in milk (130 DIM) and divided into two groups of 75 cows each (control and DFM). The control cows were assigned to a basal diet consisting of a silage-based partial mixed ration (PMR), concentrate fed in the dairy twice a day, and ad libitum pasture. The DFM group received the same basal diet supplemented with three strains of Lactobacillus top-dressed in the feed. The DFM supplementation continued during both the dry period and the subsequent lactation. A subset of 82 cows (40 control and 42 DFM) were monitored during the calving season (March to July 2022) to assess the metabolic profile and postpartum performance. Blood samples were collected during the periparturient period (−4 to −2 w prepartum, around calving, and at weeks 1, 3, and 6 postpartum) to measure the levels of metabolites, enzymes, and minerals. Overall, the serum glucose, NEFA, and chloride levels were higher, while protein and urea were lower in cows supplemented with the DFM (p < 0.005). The pre-calving levels of glucose were higher and the total bilirubin, urea, and BHB were lower in cows supplemented with DFM than in the control (p < 0.05). The post-calving levels of glucose and Mg were also higher in the DFM cows than in the control cows (p < 0.05). Average milk production at 110 DIM was significantly higher in the DFM cows compared to control cows (p = 0.03). Although the total milk production over 305 days was numerically greater in the DFM cows, the difference was not statistically significant (p = 0.3), whereas the milk protein percentage was higher in the control cows (p = 0.03). The body weight of the DFM cows was greater during the periparturient period (p = 0.001) than that of the control cows. In the DFM cows, glucose levels had a positive correlation (r = 0.16) with milk yield, at 110 DIM, while serum total protein had a positive correlation with body weight (r = 0.32) (p < 0.05). In conclusion, feeding Lactobacillus-based DFM during gestation can positively influence the metabolic profile of periparturient cows, which, in turn, may affect the milk production and body weight of postpartum dairy cows. Full article

Six hundred fifty-nine farms in three regions of Germany (North: n = 240, East: n = 247, and South: n = 172) were included in the study, which aims at determining the association of management-related risk factors with farm-level lameness in German dairy herds. For each risk factor, a generalised linear regression model with negative binomial distribution and logit link was built. Results showed that cows housed in deep-bedded cubicles had a lower risk of being lame than cows housed in other cubicle types. A larger cubicle width was associated with a lower risk of being lame. Feeding a total mixed ration was associated with lower lameness prevalence (compared to feeding a partial mixed ration or single components). For first lactation cows, lameness assessment performed daily (compared to less than daily) and during other work tasks (compared to lameness assessment as a separate work task) were associated with lower risk for lameness. Finally, the present study provided evidence for crucial associations of management-related risk factors with lameness in German dairy cows, especially in the fields of cubicle design, feeding management, and lameness assessment. Full article

Raw potato fries are a type of potato by-product (PBP), and they have great potential as a partial replacement of grain in animal feeds to improve the environmental sustainability of food production. This study aimed to investigate the effects of replacing corn with different levels of PBP (0%, 12.84%, 25.65%, and 38.44%) in the total mixed ration (TMR) of Angus bull. Sixty 16-month-old Angus bulls (548.5 ± 15.0 kg, mean ± SD) were randomly assigned to four treatments. The results indicated that with the increase in the substitution amount of PBP, the body weight decreased significantly. The dry matter apparent digestibility and starch apparent digestibility linearly decreased as PBP replacement increased. The feed ingredient composition in the TMR varied, leading to a corresponding change in the rumen microbiota, especially in cellulolytic bacteria and amylolytic bacteria. The abundance of Succiniclasticum in the 12.84% PBP and 38.44% PBP diets was significantly higher than that in the 0% PBP and 25.65% PBP diets. The abundance of Ruminococcus linearly increased. In conclusion, using PBP to replace corn for beef cattle had no negative impact on rumen fermentation, and the decrease in apparent digestibility explained the change in growth performance. Its application in practical production is highly cost-effective and a strategy to reduce food waste. Full article

A pasture or concentrate-based dietary regime impacts a variety of factors including both ruminal health and function, and consequently milk production and quality. The objective of this study was to examine the effect of feeding differing pasture levels on the metabolite composition of bovine ruminal fluid. Ruminal fluid was obtained from rumen-cannulated spring-calving cows (N = 9, Holstein-Friesian breed, average lactation number = 5) fed one of three diets across a full lactation season. Group 1 (pasture) consumed perennial ryegrass supplemented with 5% concentrates; group 2 received a total mixed ration (TMR) diet; and group 3 received a partial mixed ration (PMR) diet which included pasture and a TMR. Samples were taken at two timepoints: morning and evening. Metabolomic analysis was performed using nuclear magnetic resonance (¹H-NMR) spectroscopy. Statistical analysis revealed significant changes across the dietary regimes in both morning and evening samples, with distinct alterations in the metabolite composition of ruminal fluid from pasture-fed cows (FDR-adjusted p-value < 0.05). Acetate and butyrate were significantly higher in samples derived from a pasture-based diet whereas sugar-related metabolites were higher in concentrate-based samples. Furthermore, a distinct diurnal impact on the metabolite profile was evident. This work lays the foundation for understanding the complex interaction between dietary regime and ruminal health. Full article

Eighty-four autumn (ACS, n = 45)- and spring (SCS, n = 39)-calved multiparous early lactation Holstein cows were assigned to groups of either: (a) grazing + mixed ration (MR) during partial confinement in outdoor soil-bedded pens with shade (OD-GRZ); (b) grazing + MR during partial confinement in a compost-bedded pack barn with cooling (CB-GRZ); or (c) total confinement fed a totally mixed ration (CB-TMR) in a compost-bedded pack barn. Data were analyzed using the SAS MIXED procedure with significance at p ≤ 0.05. In both seasons, despite behavioral differences (p < 0.05) between the OD-GRZ and CB-GRZ groups (i.e., standing, first grazing meal length, bite rate), the milk and component yields, DM intake, microbial CP output (MCP) and NE efficiency were unaffected by the housing conditions, possibly due to mild weather conditions. The milk yield was substantially higher in the CB-TMR group versus the OD-TMR and CB-TMR groups (p < 0.01) in both ACS (~35%) and SCS (~20%) despite there being no intake differences, without any impact on milk component levels. In ACS, this was associated with a higher MCP, likely due to the higher nutritional value of TMR compared to pasture, which was not the case in SCS. In conclusion, the OD-GRZ group achieved the same milk production as the CB-GRZ group through behavior adaptation, under mild weather conditions, in both calving seasons. The CB-TMR group outperformed the grazing systems in both calving seasons, regardless of the MCP. Full article

With the advancement of urbanization, land resources are becoming increasingly strained, particularly for urban greening purposes. In this context, a large number of newly cultivated lands dominated by construction waste and backfill soil are emerging in cities. Assessing the soil quality of these newly cultivated lands and achieving their rational utilization accurately and quantitatively has become an urgent issue. In this study, soil samples of five land use types, namely newly cultivated land (NCL, control), adjacent cropland (CL), arbor–shrub mixed forest (ASF), arbor forest (AF), and shrubland (SL) were selected around Beijing, China. ASF, AF, and SL are also newly cultivated lands composed of construction waste and backfill before greening. Based on principal component analysis (PCA), a total data set (TDS) and a minimum data set (MDS) were used to construct the soil quality index (SQI) model. Soil quality indicators covering the physical and chemical characteristics of the soil and their relationships with land use types were studied with the Partial Least Squares Path Model (PLS-PM). The results were summarized as follows: (1) The soil quality index under different land use types in the Beijing plain area were in the order of arbor–shrub mixed forest (ASF) > arbor forest (AF) > shrubland (SL) > cropland (CL) > newly cultivated land (NCL). (2) Soil organic carbon (SOC), soil water content (SWC), maximum water-holding capacity (MWHC), capillary water-holding capacity (CWHC), Pb, and Cd were identified as the MDS. The MDS of the soil quality assessment model showed a linear relationship with the TDS (y = 0.946x + 0.050, R² = 0.51). (3) Land use types have an indirect impact on soil quality by changing the content of Pb. The chemical indicators’ coefficient (0.602) contributed more to the SQI than did the physical indicators’ (0.259) and heavy metal elements’ (−0.234). In general, afforestation and agricultural production could improve the newly cultivated lands’ soil quality, but afforestation is much better than agricultural production. These results will help to evaluate the SQI in the Beijing plain area objectively and accurately, and they have significant implications for soil restoration and management. Full article