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Search Results (441)

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Keywords = optimum proportioning

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17 pages, 4364 KiB  
Article
An Investigation of the Effectiveness of Super White Cement in Improving the Engineering Properties of Organic Soils by Laboratory Tests
by Eyubhan Avci, Mehmet C. Balci, Muhammed A. Toprak, Melih Uysal, Emre Deveci, Gözde Algun Karataş and Yunus E. Dönertaş
Buildings 2025, 15(15), 2730; https://doi.org/10.3390/buildings15152730 (registering DOI) - 2 Aug 2025
Abstract
In this study, the efficacy of super white cement (SWC) to improve organic soils was researched. For stabilization, 10%, 15%, and 20% proportions of SWC were added to organic soil. After improvement with SWC, Atterberg limit testing, standard Proctor tests, triaxial compression tests, [...] Read more.
In this study, the efficacy of super white cement (SWC) to improve organic soils was researched. For stabilization, 10%, 15%, and 20% proportions of SWC were added to organic soil. After improvement with SWC, Atterberg limit testing, standard Proctor tests, triaxial compression tests, and swelling and compressibility tests were performed on the organic soil. Proctor tests showed that stabilization of organic soil with SWC increased maximum dry density (MDD) and optimum moisture content (OMC) values. After stabilization, the unconfined compressional strength values of the soil increased. This increase continued until the 28th day and had a reducing trend after improvement with SWC, linked to time. In addition to the reaction between SWC and OS, the time-dependent behavior of OS also contributed to this behavior. With the increase in SWC proportions, the cohesion intercept and internal friction angle values rapidly increased until the 56th day. This increase began to reduce after the 56th day. After stabilization, the swelling percentage and compressibility values for the soil reduced. The addition of SWC within organic soil appeared to improve the engineering properties of the soil. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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34 pages, 530 KiB  
Article
Optimal Governance for Post-Concession Logistics Infrastructure: A Comparative Study of Self-Operation vs. Delegation Under Information Asymmetry
by Minghua Xiong
Sustainability 2025, 17(15), 6982; https://doi.org/10.3390/su17156982 (registering DOI) - 31 Jul 2025
Viewed by 111
Abstract
Public–private partnership (PPP) logistics infrastructure projects have become increasingly prevalent globally. Consequently, the effective management of these projects as their concession periods expire presents a crucial challenge for governments, vital for the sustainable management of PPP logistics infrastructure. This study addresses this challenge [...] Read more.
Public–private partnership (PPP) logistics infrastructure projects have become increasingly prevalent globally. Consequently, the effective management of these projects as their concession periods expire presents a crucial challenge for governments, vital for the sustainable management of PPP logistics infrastructure. This study addresses this challenge by focusing on the pivotal post-concession decision: whether the government should self-operate the mature logistics infrastructure or re-delegate its management to a private entity. Our theoretical model, built on a principal–agent framework, first establishes a social welfare baseline under government self-operation and then analyzes delegated operation under symmetric information, identifying efficiency frontiers. Under symmetric information, we find that government self-operation is more advantageous when its own operational efficiency is sufficiently high, irrespective of the private enterprise’s efficiency; conversely, delegating to an efficient private enterprise is optimal only when government operational efficiency is low. We also demonstrate that if the government can directly specify the demand quantity and service level and delegates operation via a fixed fee, the enterprise can be incentivized to align with the social optimum. However, under asymmetric information, potential welfare gains from delegation are inevitably offset by informational rent and output distortion. We further uncover non-monotonic impacts of parameters like the proportion of low-cost firms on social welfare loss and demonstrate how information asymmetry can indirectly compromise the long-term resilience of the infrastructure. Ultimately, our work asserts that delegation is only superior if its potential efficiency gains sufficiently offset the inherent losses stemming from information asymmetry. Full article
(This article belongs to the Section Sustainable Transportation)
9 pages, 354 KiB  
Communication
Algorithm Providing Ordered Integer Sequences for Sampling with Replacement Confidence Intervals
by Lorentz Jäntschi
Algorithms 2025, 18(8), 459; https://doi.org/10.3390/a18080459 - 24 Jul 2025
Viewed by 216
Abstract
Sampling with replacement occurs when drawing without removing individuals from finite populations. It is a common distribution technique used in physics, biology, and medicine. It is used in state analysis of qubits, the physics of particle interactions, studies of genetic variation and variability, [...] Read more.
Sampling with replacement occurs when drawing without removing individuals from finite populations. It is a common distribution technique used in physics, biology, and medicine. It is used in state analysis of qubits, the physics of particle interactions, studies of genetic variation and variability, and analyzing the treatment effects from clinical trial analyses. When applied, sample statistics should be accompanied by confidence intervals. The major difficulty in expressing the confidence intervals in sampling with replacement consists of discreetness regarding the probability distribution. As a result, no mathematical formula can handle an optimum solution. Using a simple algorithm is proposed in order to obtain confidence intervals for sampling with replacement variables (x from m trials with replacement) and their proportion (x/m). A question-based discussion is presented. Traditional confidence intervals often require large sample sizes. Confidence intervals, constructed in a deterministic way provided by the proposed algorithm for sampling with replacement, allow constructing intervals without constraints. Full article
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13 pages, 3360 KiB  
Article
Effect of Edge-Oxidized Graphene Oxide (EOGO) on Fly Ash Geopolymer
by Hoyoung Lee, Junwoo Shin, Byoung Hooi Cho and Boo Hyun Nam
Materials 2025, 18(15), 3457; https://doi.org/10.3390/ma18153457 - 23 Jul 2025
Viewed by 222
Abstract
In this study, edge-oxidized graphene oxide (EOGO) was used as an additive in fly ash (FA) geopolymer paste. The effect of EOGO on the properties of the fly ash geopolymer was investigated. EOGO was added to the FA geopolymer at four different percentages [...] Read more.
In this study, edge-oxidized graphene oxide (EOGO) was used as an additive in fly ash (FA) geopolymer paste. The effect of EOGO on the properties of the fly ash geopolymer was investigated. EOGO was added to the FA geopolymer at four different percentages (0%, 0.1%, 0.5% and 1%), and the mixture was cured under two different conditions: room curing (~20 °C) and heat curing (~60 °C). To characterize the FA-EOGO geopolymer, multiple laboratory tests were employed, including compressive strength, Free-Free Resonance Column (FFRC), density, water absorption, and setting tests. The FFRC test was used to evaluate the stiffness at small strain (Young’s modulus) via the resonance of the specimen. The mechanical test results showed that the strength and elastic modulus were high during heat curing, and the highest compressive strength and elastic modulus were achieved at 0.1% EOGO. In the physical test, 0.1% EOGO had the highest density and the lowest porosity and water absorption. As a result of the setting time test, as the EOGO content increased, the setting time was shortened. It is concluded that the optimum proportion of EOGO is 0.1% in FA geopolymer paste. Full article
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22 pages, 3224 KiB  
Article
Performance Optimization of SBR-Modified Pervious Composite Incorporating Recycled Concrete Aggregates
by Abdulkader El-Mir, Perla Tannouri, Joseph J. Assaad, Dana Nasr, Maria Ghannoum, Firas Barraj and Hilal El-Hassan
J. Compos. Sci. 2025, 9(7), 372; https://doi.org/10.3390/jcs9070372 - 16 Jul 2025
Viewed by 280
Abstract
This study aimed to optimize the performance of pervious concrete (PC) while promoting sustainability using recycled concrete aggregates (RCAs), styrene butadiene rubber (SBR) waste, and silica fume (SF). The mixtures were developed using the Taguchi approach with four mix design factors, each at [...] Read more.
This study aimed to optimize the performance of pervious concrete (PC) while promoting sustainability using recycled concrete aggregates (RCAs), styrene butadiene rubber (SBR) waste, and silica fume (SF). The mixtures were developed using the Taguchi approach with four mix design factors, each at three levels: the water-to-binder ratio (w/b), RCA replacement percentage by weight of natural aggregates, the cement substitution rate with SF, and the SBR addition rate by binder mass. Thus, a total of nine mixes were prepared and tested for density, porosity, permeability, compressive strength, splitting tensile strength, abrasion resistance, and resistance to freezing and thawing. The results revealed that incorporating RCA and SBR decreased density and compressive strength but increased porosity and permeability. The performance of PC enhanced with SF addition and reduced w/b. TOPSIS was then employed to find the optimum mixture design proportions by considering multiple performance criteria. The results indicated that a high-performing sustainable PC mixture, with enhanced strength and durability characteristics, was formulated with a w/b ratio of 0.30, 25% RCA, 5% SF replacement, and 4% SBR addition. Full article
(This article belongs to the Special Issue Novel Cement and Concrete Materials)
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26 pages, 4164 KiB  
Review
Methodologies to Design Optimum 3D Printable Mortar Mix: A Review
by Isabelle Gerges, Faten Abi Farraj, Nicolas Youssef, Emmanuel Antczak and Fadi Hage Chehade
Buildings 2025, 15(14), 2497; https://doi.org/10.3390/buildings15142497 - 16 Jul 2025
Viewed by 214
Abstract
Nowadays, 3D printing has revolutionized the construction and building industry, enabling researchers to push the boundaries of creating structural components with this innovative technique. A key factor for the success of this approach lies in selecting the optimal mix design, which must possess [...] Read more.
Nowadays, 3D printing has revolutionized the construction and building industry, enabling researchers to push the boundaries of creating structural components with this innovative technique. A key factor for the success of this approach lies in selecting the optimal mix design, which must possess suitable properties for printing while ensuring strong performance once hardened. However, achieving this optimal mix is complex due to limited knowledge regarding the necessary fresh-state properties, the characteristics and proportions of the constituents, the influence of printing parameters on these properties, and the various challenges encountered during and post printing. This paper aims to address these aspects by offering a comprehensive review of the steps researchers have taken to develop an optimized 3D printable mix. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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36 pages, 6279 KiB  
Article
Eel and Grouper Optimization-Based Fuzzy FOPI-TIDμ-PIDA Controller for Frequency Management of Smart Microgrids Under the Impact of Communication Delays and Cyberattacks
by Kareem M. AboRas, Mohammed Hamdan Alshehri and Ashraf Ibrahim Megahed
Mathematics 2025, 13(13), 2040; https://doi.org/10.3390/math13132040 - 20 Jun 2025
Cited by 1 | Viewed by 482
Abstract
In a smart microgrid (SMG) system that deals with unpredictable loads and incorporates fluctuating solar and wind energy, it is crucial to have an efficient method for controlling frequency in order to balance the power between generation and load. In the last decade, [...] Read more.
In a smart microgrid (SMG) system that deals with unpredictable loads and incorporates fluctuating solar and wind energy, it is crucial to have an efficient method for controlling frequency in order to balance the power between generation and load. In the last decade, cyberattacks have become a growing menace, and SMG systems are commonly targeted by such attacks. This study proposes a framework for the frequency management of an SMG system using an innovative combination of a smart controller (i.e., the Fuzzy Logic Controller (FLC)) with three conventional cascaded controllers, including Fractional-Order PI (FOPI), Tilt Integral Fractional Derivative (TIDμ), and Proportional Integral Derivative Acceleration (PIDA). The recently released Eel and Grouper Optimization (EGO) algorithm is used to fine-tune the parameters of the proposed controller. This algorithm was inspired by how eels and groupers work together and find food in marine ecosystems. The Integral Time Squared Error (ITSE) of the frequency fluctuation (ΔF) around the nominal value is used as an objective function for the optimization process. A diesel engine generator (DEG), renewable sources such as wind turbine generators (WTGs), solar photovoltaics (PVs), and storage components such as flywheel energy storage systems (FESSs) and battery energy storage systems (BESSs) are all included in the SMG system. Additionally, electric vehicles (EVs) are also installed. In the beginning, the supremacy of the adopted EGO over the Gradient-Based Optimizer (GBO) and the Smell Agent Optimizer (SAO) can be witnessed by taking into consideration the optimization process of the recommended regulator’s parameters, in addition to the optimum design of the membership functions of the fuzzy logic controller by each of these distinct algorithms. The subsequent phase showcases the superiority of the proposed EGO-based FFOPI-TIDμ-PIDA structure compared to EGO-based conventional structures like PID and EGO-based intelligent structures such as Fuzzy PID (FPID) and Fuzzy PD-(1 + PI) (FPD-(1 + PI)); this is across diverse symmetry operating conditions and in the presence of various cyberattacks that result in a denial of service (DoS) and signal transmission delays. Based on the simulation results from the MATLAB/Simulink R2024b environment, the presented control methodology improves the dynamics of the SMG system by about 99.6% when compared to the other three control methodologies. The fitness function dropped to 0.00069 for the FFOPI-TIDμ-PIDA controller, which is about 200 times lower than the other controllers that were compared. Full article
(This article belongs to the Special Issue Mathematical Methods Applied in Power Systems, 2nd Edition)
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16 pages, 1472 KiB  
Article
Effects of Pineapple Peel on the Nutritional and Microbial Profiles of Napier Grass–Sugarcane Top Silage
by Huade Xie, Zhenhua Tang, Fanquan Zeng, Xianqing Luo, Fang Xie, Li Liang, Jingzhen Li, Pinfeng Liao, Lijuan Peng, Zhipei Li, Haiyu Bai, Xiaoqiang Guo and Chengjian Yang
Microorganisms 2025, 13(6), 1314; https://doi.org/10.3390/microorganisms13061314 - 5 Jun 2025
Viewed by 682
Abstract
Agricultural byproducts, including pineapple peel (PP), are valuable feed additives which support the livestock industry. However, conflicting evidence exists regarding the optimal amount of PP required to achieve optimal fermentation in silage. This study examines the impact of ensiling mixtures of equal proportions [...] Read more.
Agricultural byproducts, including pineapple peel (PP), are valuable feed additives which support the livestock industry. However, conflicting evidence exists regarding the optimal amount of PP required to achieve optimal fermentation in silage. This study examines the impact of ensiling mixtures of equal proportions of fresh Napier grass (NG) and sugarcane top (ST) with varying levels of PP (0% [C], 10% [P1], 20% [P2], and 30% [P3]) on fermentation quality, microbiological profiles, and in vitro ruminal digestion. Compared to the C silage, the dry matter, crude protein, and neutral detergent fiber contents decreased in the silage treated with increasing PP (p < 0.05). P1 exhibited lower (p > 0.05) pH, higher (p > 0.05) lactic acid content, and lower (p < 0.05) NH3-N content than other silage. The Chao 1, ACE index, and relative abundance of Lacticaseibacillus and Lactobacillales were decreased following the order of C > P1 > P2 > P3 (p < 0.05). Although there were no significant differences observed in most vitro ruminal fermentation parameters among four silages (p > 0.05), P1 exhibited higher total gas production, total volatile fatty acid, acetate acid, acetate-to-propionate ratio, and lower pH than the other silages. These results demonstrated that a NG and ST mixture co-ensiling with appropriate PP enhances the NG and ST mixture silage quality, and the optimum addition ratio for PP was 10% on a fresh matter basis. Full article
(This article belongs to the Section Food Microbiology)
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31 pages, 4854 KiB  
Article
Frequency Regulation Provided by Doubly Fed Induction Generator Based Variable-Speed Wind Turbines Using Inertial Emulation and Droop Control in Hybrid Wind–Diesel Power Systems
by Muhammad Asad and José Ángel Sánchez-Fernández
Appl. Sci. 2025, 15(10), 5633; https://doi.org/10.3390/app15105633 - 18 May 2025
Cited by 1 | Viewed by 519
Abstract
To modernize electrical power systems on isolated islands, countries around the world have increased their interest in combining green energy with conventional power plants. Wind energy (WE) is the most adopted renewable energy source due to its technical readiness, competitive cost, and environmentally [...] Read more.
To modernize electrical power systems on isolated islands, countries around the world have increased their interest in combining green energy with conventional power plants. Wind energy (WE) is the most adopted renewable energy source due to its technical readiness, competitive cost, and environmentally friendly characteristics. Despite this, a high penetration of WE in conventional power systems could affect their stability. Moreover, these isolated island power systems face frequency deviation issues when operating in hybrid generation mode. Generally, under contingency or transient conditions for hybrid isolated wind–diesel power systems (WDPSs), it is only the diesel generator that provides inertial support in frequency regulation (FR) because wind turbines are unable to provide inertia themselves. Frequency deviations can exceed the pre-defined grid code limits during severe windy conditions because the diesel generator’s inertial support is not always sufficient. To overcome this issue, we propose a control strategy named emulation inertial and proportional (EI&P) control for Variable-Speed Wind Turbines (VSWTs). VSWTs can also contribute to FR by releasing synthetic inertia during uncertainties. In addition, to enhance the effectiveness and smoothness of the blade pitch angle control of WTs, a pitch compensation (PC) control loop is proposed in this paper. The aim of this study was to provide optimal primary frequency regulations to hybrid wind–diesel power systems (WDPSs). Therefore, the hybrid WDPS on San Cristobal Island was considered in this study. To achieve such goals, we used the above-mentioned proposed controls (EI&P and PC) and optimally tuned them using the Student-Psychology-Based Algorithm (SPBA). The effectiveness of this algorithm is in its ability to provide the best optimum controller gain combinations of the proposed control loops. As a result, the FD in the WDPS on San Cristobal Island was reduced by 1.05 Hz, and other quality indices, such as the integral absolute error (IAE), integral square error (ISE), and controller quality index (Z), were improved by 159.65, 16.75, and 83.80%, respectively. Moreover, the proposed PC control, which was further simplified using exhaustive searches, resulted in a reduction in blade pitch angle control complexity. To validate the results, the proposed approach was tested under different sets of perturbations (sudden loss of wind generator and gradual increase in wind speed and their random behavior). Furthermore, hybrid systems were tested simultaneously under different real-world scenarios, like various sets of load or power imbalances, wind variations, and their combinations. The Simulink results showed a significant improvement in FR support by minimizing frequency deviations during transients. Full article
(This article belongs to the Section Green Sustainable Science and Technology)
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15 pages, 10425 KiB  
Article
The Effects of CeO2 Content on the Microstructure and Property of Duplex Stainless Steel Layer Obtained by Plasma Arc Cladding Technology
by Juan Pu, Di Wu, Xiaohui Shi, Fei Long and Huawei Sun
Coatings 2025, 15(5), 590; https://doi.org/10.3390/coatings15050590 - 16 May 2025
Viewed by 443
Abstract
The mixture powders were designed by adding 0 wt.%~1.0 wt.% CeO2 into the 2205 duplex stainless steel (DSS) powders. The 2205 DSS cladding layer was prepared on the surface of Q345 steel by plasma arc cladding technology. The effects of different CeO [...] Read more.
The mixture powders were designed by adding 0 wt.%~1.0 wt.% CeO2 into the 2205 duplex stainless steel (DSS) powders. The 2205 DSS cladding layer was prepared on the surface of Q345 steel by plasma arc cladding technology. The effects of different CeO2 contents on the macro-morphology, microstructure composition, and corrosion resistance of the cladding layer were studied. The action mechanism of CeO2 in the cladding layer was also discussed. The results showed that the addition of CeO2 modified the appearance and decreased the defect of the cladding layer. Also, the austenite grains were refined, and the austenite proportion was increased under the action of CeO2. When the CeO2 content was 0.5 wt.%, the appearance of the cladding layer was optimum; the austenite proportion in the upper cladding layer and the lower cladding layer reached up to 52.6% and 55.5%, respectively, and the crystal changed from columnar to equiaxed. CeO2 decomposes into Ce element and O element under the action of the plasma arc, after which Ce element is easily absorbed at the grain boundary to reduce the surface tension and improve the fluidity of the liquid metal so as to modify the appearance of the cladding layer. Meanwhile, Ce element primarily reacts with O, S, Al, and Si elements to form low-melting-point oxygen sulfides and are then removed, which eliminates the defect of the cladding layer. Moreover, the high melting point of CeO2 acts as heterogeneous nucleation sites during solidification, thus improving the value of nucleation rate/growth rate of the grain and promoting the transformation from ferrite to austenite. According to the electrochemical corrosion testing result, Ce element inhibited the enrichment of Cr element at grain boundaries and promoted the formation of Cr2O3, which improved the corrosion resistance of the 2205 DSS cladding layer. It was optimum with the CeO2 content of 0.5 wt.%. Full article
(This article belongs to the Special Issue Laser Surface Engineering and Additive Manufacturing)
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19 pages, 5048 KiB  
Article
Stabilization of Clay Subgrade Soil by Using Waste Foundry Sand with a Geogrid
by Qais Sahib Banyhussan, Jaafar Abdulrazzaq, Ahmed A. Hussein, Anmar Dulaimi, Jorge Miguel de Almeida Andrade and Luís Filipe Almeida Bernardo
CivilEng 2025, 6(2), 26; https://doi.org/10.3390/civileng6020026 - 10 May 2025
Viewed by 1111
Abstract
Various stabilizers, such as jute, gypsum, rice-husk ash, fly ash, cement, lime, and discarded rubber tires, are commonly used to improve the shear strength and overall characteristics of clay subgrade soil. In this study, waste foundry sand (WFS) is utilized as a stabilizing [...] Read more.
Various stabilizers, such as jute, gypsum, rice-husk ash, fly ash, cement, lime, and discarded rubber tires, are commonly used to improve the shear strength and overall characteristics of clay subgrade soil. In this study, waste foundry sand (WFS) is utilized as a stabilizing material to enhance the properties of clay subgrade soil and strengthen the bond between clay subgrade soil and subbase material. The materials employed in this study include Type B subbase granular materials, clay subgrade soil, and 1100 Biaxial Geogrid for reinforcement. The clay subgrade soil was collected from the airport area in the Al-Muthanna region of Baghdad. To evaluate the effectiveness of WFS as a stabilizer, soil specimens were prepared with varying replacement levels of 0%, 5%, 10%, and 15%. This study conducted a Modified Proctor Test, a California Bearing Ratio test, and a large-scale direct shear test to determine key parameters, including the CBR value, maximum dry density, optimum moisture content, and the compressive strength of the soil mixture. A specially designed large-scale direct shear apparatus was manufactured and utilized for testing, which comprised an upper square box measuring 20 cm × 20 cm × 10 cm and a lower rectangular box with dimensions of 200 mm × 250 mm × 100 mm. The findings indicate that the interface shear strength and overall properties of the clay subgrade soil improve as the proportion of WFS increases. Full article
(This article belongs to the Section Geotechnical, Geological and Environmental Engineering)
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19 pages, 9914 KiB  
Article
Lithium Orthosilicate Solid Porous Membranes for CO2 Capture Obtained from Silica Microfibers
by Joaquín Penide, Efstratios Stavrakakis, Félix Quintero, Danai Poulidi, Antonio Riveiro, Jesús del Val, Rafael Comesaña, Fernando Lusquiños and Juan Pou
Fibers 2025, 13(5), 59; https://doi.org/10.3390/fib13050059 - 7 May 2025
Viewed by 894
Abstract
Lithium orthosilicate (Li4SiO4) has demonstrated a high CO2 adsorption rate and capacity and its suitability to be implemented in industry as CO2 capture technology at high temperatures. The optimum solid adsorbent should present a porous structure to [...] Read more.
Lithium orthosilicate (Li4SiO4) has demonstrated a high CO2 adsorption rate and capacity and its suitability to be implemented in industry as CO2 capture technology at high temperatures. The optimum solid adsorbent should present a porous structure to maximize surface and enable a high sorption rate. In this work, we present an original approach based on the use of a novel architecture of precursors in the form of very thin free-standing solid silica fibers. An original technique called continuous fiberizing by laser melting (Cobiflas) was used to obtain membranes of pure silica fibers with diameters in the micrometer range, forming a porous membrane which offer a high surface and porous connectivity to be used as precursors without any supporting substrate. Then, we employed a method based on the impregnation of the silica fibers within a lithium-containing aqueous solution and subsequent calcination to obtain a porous solid adsorbent with the maximum proportion of lithium orthosilicate. This method is compared with the results obtained using a sol-gel powder method by analyzing their composition using X-Ray Diffraction (XRD), and their adsorption capacity and adsorption kinetics by Thermogravimetric analyses (TGA). As a result, an outstanding type of solid adsorbent is reported with a 31% adsorption capacity and a total regeneration capacity, which is over 0.8 efficiency with regard to the theoretical maximum adsorption of this material. Full article
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35 pages, 22378 KiB  
Article
Study of Properties of Novel Geopolymers Prepared with Slate Stone Cutting Sludge and Activated with Olive Stone Bottom Ash
by Elena Picazo Camilo, Juan José Valenzuela Expósito, Raúl Carrillo Beltrán, Griselda Elisabeth Perea Toledo and Francisco Antonio Corpas Iglesias
Materials 2025, 18(8), 1774; https://doi.org/10.3390/ma18081774 - 13 Apr 2025
Cited by 2 | Viewed by 593
Abstract
The sustainable development of building materials is based on reusing by-products to reduce environmental impact and promote alternatives to traditional materials. In this study, geopolymers were developed from by-products of the mining, ceramic, and thermal industries: slate stone cutting sludge (SSCS) and chamotte [...] Read more.
The sustainable development of building materials is based on reusing by-products to reduce environmental impact and promote alternatives to traditional materials. In this study, geopolymers were developed from by-products of the mining, ceramic, and thermal industries: slate stone cutting sludge (SSCS) and chamotte (CH) as aluminosilicate sources, and olive stone bottom ash (OSBA) as an alkaline activator, combined with sodium silicate (Na2SiO3). Eight geopolymer families were prepared with constant amounts of SSCS and CH and varying proportions of OSBA/Na2SiO3 (0.88–1.31). The evaluation phase included physical, chemical, mechanical, and microstructural tests. The results showed that the optimum geopolymer formulation (GP E) contained 25% SSCS, 15% CH, and 19% OSBA with a Na2SiO3/OSBA ratio of 1.0, achieving a compressive strength of 24.12 MPa after 28 days of curing. GP E also showed the lowest porosity (19.54%), minimal water absorption (6.86%), and favorable thermal conductivity (0.688 W/mK). Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) confirmed the formation of dense and homogeneous matrices. These results demonstrate the feasibility of manufacturing geopolymers using SSCS, CH, and OSBA as substitutes for traditional binders, promoting sustainable practices, reusing industrial by-products, and reducing carbon emissions in construction. Full article
(This article belongs to the Special Issue Advances in Function Geopolymer Materials)
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18 pages, 9628 KiB  
Article
Determining the Optimum Harvest Point in Oil Palm Interspecific Hybrids (O × G) to Maximize Oil Content
by Hernán Mauricio Romero, Rodrigo Ruiz-Romero, Arley Fernando Caicedo-Zambrano, Iván Ayala-Diaz and Jenny Liset Rodríguez
Agronomy 2025, 15(4), 887; https://doi.org/10.3390/agronomy15040887 - 1 Apr 2025
Viewed by 904
Abstract
Elaeis oleifera and Elaeis guineensis, two oil palm species capable of intercrossing to produce interspecific Elaeis oleifera × Elaeis guineensis (O × G) hybrids, exhibit genetic variability in key agronomic traits such as fruit development, oil accumulation, and bunch composition. This variability [...] Read more.
Elaeis oleifera and Elaeis guineensis, two oil palm species capable of intercrossing to produce interspecific Elaeis oleifera × Elaeis guineensis (O × G) hybrids, exhibit genetic variability in key agronomic traits such as fruit development, oil accumulation, and bunch composition. This variability influences the productivity and oil quality of the resulting hybrids. Harvesting, a critical practice in oil palm production, significantly impacts oil yield and quality. Therefore, this study aimed to ascertain the optimum harvest point (OHP) in widely cultivated O × G hybrids and its correlation with genetic backgrounds. The O × G cultivars, “Coari × La Mé” (C × LM), “Manaos × Compacta” (M × C), and “Brazil × Djongo” (B × DJ), were examined to identify notable changes during various phenological stages of bunch ripening using the O × G BBCH scale, a standardized system for describing plant growth stages based on phenological development. The research was conducted in the Southwest Colombian oil palm zone during dry and rainy seasons. Observations revealed distinctive fruit coloration patterns and increased bunch weights throughout the maturation process. However, final fruit coloration did not consistently align with maximum oil rates, indicating it as an unsuitable descriptor for OHP. The C × LM cultivar exhibited the shortest ripening period (173 days after anthesis, DAA), while M × C showed the longest at 207 DAA, followed by B × DJ at 187 DAA. Pollination efficiency varied among cultivars, with C × LM and M × C displaying higher proportions of parthenocarpic fruits. Findings suggest harvesting can occur for all cultivars between phenological stages 807 and 809—corresponding to late maturity stages in fruit development—regardless of the time of year, when maximum oil per bunch is attained. Fruit opacity, fruit cracking, and fruit detachment at stages 807 and 809 were identified as pivotal descriptors for determining the right OHP, albeit unique to each cultivar. Implementing two of these three descriptors by field workers will likely result in the highest oil yields for O × G cultivars. In conclusion, this research provides valuable insights into optimizing oil palm harvest practices, emphasizing the importance of considering genetic variability and phenological indicators for determining the optimum harvest point in interspecific O × G hybrids. Full article
(This article belongs to the Section Farming Sustainability)
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16 pages, 7281 KiB  
Article
One-Part Geopolymer for Stabilising Crushed Rock Road Base Material
by Guilherme C. Camarini, Hayder H. Abdullah and Mohamed A. Shahin
Geosciences 2025, 15(4), 122; https://doi.org/10.3390/geosciences15040122 - 1 Apr 2025
Cited by 1 | Viewed by 603
Abstract
Geopolymers have attracted wide attention as effective soil stabilisers, presenting significant potential for several geotechnical engineering applications. These binders offer environmental benefits by utilising abandoned aluminosilicate industrial by-products, such as fly ash and slag, through mixing with an alkaline solution. In addition, they [...] Read more.
Geopolymers have attracted wide attention as effective soil stabilisers, presenting significant potential for several geotechnical engineering applications. These binders offer environmental benefits by utilising abandoned aluminosilicate industrial by-products, such as fly ash and slag, through mixing with an alkaline solution. In addition, they also decrease dependency on conventional Ordinary Portland Cement (OPC), which is identified with substantial artificial greenhouse gas emissions and high energy consumption during manufacture. However, the practical utilisation of geopolymers for the stabilisation of road materials is hindered by the intricate preparation process, which necessitates precise control over the proportions of the ingredients to achieve the required mechanical properties. This complexity becomes more pronounced when compared to the relatively simple method of using conventional cement, which requires fewer safety precautions while mixing with soil. This study investigates the development of a One-Part Geopolymer (OPG) powder, specifically formulated for the stabilisation of a Crushed Rock Base (CRB) material used for road construction. The optimal blend of OPG powder, comprising fly ash, slag and sodium metasilicate, is identified by assessing the monotonic and dynamic mechanical performances of the treated CRB compacted at the optimum moisture content using Unconfined Compressive Strength (UCS) and Repeated Load Triaxial (RLT) tests. The results of the study indicate that enhancing the strength performance of the OPG-treated CRB requires the calibration of the sodium oxide (Na2O) content in the alkaline activator with the total binder. It was also found that increasing the OPG content from 1% to 3% significantly enhances both the uniaxial strength and resilient modulus of the treated CRB, while simultaneously reducing the permanent deformation. Notably, the CRB specimens stabilised with 2% OPG exhibit mechanical properties comparable to those of bound Portland cemented materials. Full article
(This article belongs to the Section Geomechanics)
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