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Keywords = oil cleanliness

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18 pages, 4036 KiB  
Article
Development of Oil-Free Lubricants for Cold Rolling of Low-Carbon Steel
by Leon Jacobs, Delphine Rèche, Andreas Bán, Valentina Colla, Orlando Toscanelli, Martin Raulf, Martin Schlupp, Bas Smeulders, Mike Cook and Wim Filemon
Processes 2025, 13(4), 1234; https://doi.org/10.3390/pr13041234 - 18 Apr 2025
Viewed by 601
Abstract
Oil-in-water emulsions (O/W emulsions) are generally used to lubricate the cold rolling process of low-carbon steel. In addition to the obvious advantages of efficient lubrication and cooling of the process, there are also some disadvantages, mainly related to emulsion bath maintenance, subsequent production [...] Read more.
Oil-in-water emulsions (O/W emulsions) are generally used to lubricate the cold rolling process of low-carbon steel. In addition to the obvious advantages of efficient lubrication and cooling of the process, there are also some disadvantages, mainly related to emulsion bath maintenance, subsequent production steps and waste disposal. In some application areas, Oil-Free Lubricants (OFL’s) have been shown to be at least equally effective in decreasing friction and wear as conventional oil-based lubricants, while resulting in benefits related to waste disposal. In 2023, a project named “Transfer of aqueous oil free lubricants into steel cold rolling practice” (acronym ‘RollOilFreeII’) began, with it receiving funding from the Research Fund for Coal and Steel (RFCS). This project aims at an industrial application of Oil-Free Lubricants in the steel cold rolling process. The project builds on the work of the ‘RollOilFree’ project (also carried out in the RFCS-framework). This article briefly recapitulates the findings in the RollOilFree project and describes the objectives, benefits, activities and first results of the RollOilFreeII project. Notably, a pilot mill trial at high speed has been carried out, showing a good performance of the investigated OFLs. Back-calculated friction values were equal to, or even slightly lower than, reference O/W emulsions. The strip cleanliness with OFLs is much better than it is with the reference O/W emulsions. Only for a very thin product, as is the case in tinplate rolling, does the direct application of a conventional O/W dispersion (a high-particle-sized O/W emulsion) give a better performance than the investigated OFLs. Further development of OFLs should focus on this aspect. Full article
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15 pages, 11357 KiB  
Article
Catastrophic Failure Analysis of a Wind Turbine Gearbox by the Finite Element Method and Fracture Analysis
by Jairo Aparecido Martins and Estaner Claro Romão
Designs 2025, 9(1), 4; https://doi.org/10.3390/designs9010004 - 5 Jan 2025
Viewed by 1736
Abstract
The wind turbine gearbox, used as a multiplier, is one of the main components directly related to a wind turbine’s efficiency and lifespan. Therefore, strict control of the gearbox and its manufacturing processes and even minor improvements in this component strongly and positively [...] Read more.
The wind turbine gearbox, used as a multiplier, is one of the main components directly related to a wind turbine’s efficiency and lifespan. Therefore, strict control of the gearbox and its manufacturing processes and even minor improvements in this component strongly and positively impact energy production/generation over time. Since only some papers in the literature analyze the mechanical aspect of wind turbines, focusing on some parts in depth, this paper fills the gap by offering an analysis of the gearbox component under the highest amount of stress, namely relating to the sun shaft, as well as a more holistic analysis of the main gear drives, its components, and the lubrification system. Thus, this work diagnoses the fracture mechanics of a 1600 kW gearbox to identify the main reason for the fracture and how the chain of events took place, leading to catastrophic failure. The diagnoses involved numerical simulation (finite element analysis—FEA) and further analysis of the lubrication system, bearings, planetary stage gears, helical stage gears, and the high-speed shaft. In conclusion, although the numerical simulation showed high contact stresses on the sun shaft teeth, the region with the unexpectedly nucleated crack was the tip of the tooth. The most likely factors that led to premature failure were the missed lubrication for the planetary bearings, a lack of cleanliness in regard to the raw materials of the gears (voids found), and problems with the sun shaft heat treatment. With the sun gear’s shaft, planet bearings, and planet gears broken into pieces, those small and large pieces dropped into the oil, between the gears, and into the tooth ring, causing the premature and catastrophic gearbox failure. Full article
(This article belongs to the Special Issue Design and Analysis of Offshore Wind Turbines)
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17 pages, 5039 KiB  
Article
Optimization of Parameters and Comparison of Detection Signals for Planar Coil Particle Detection Sensors with Different Core Materials
by Changzhi Gu, Chao Liu, Bo Liu, Wenbo Zhang, Chenzhao Bai, Chenyong Wang, Yuqing Sun and Hongpeng Zhang
Micromachines 2024, 15(12), 1520; https://doi.org/10.3390/mi15121520 - 20 Dec 2024
Cited by 1 | Viewed by 1033
Abstract
The cleanliness of lubricating oil plays a key role in determining the operational health of mechanical systems, serving as a critical metric that delineates the extent of equipment wear. In this study, we present a magnetic-core-type planar coil particle detection sensor. The detection [...] Read more.
The cleanliness of lubricating oil plays a key role in determining the operational health of mechanical systems, serving as a critical metric that delineates the extent of equipment wear. In this study, we present a magnetic-core-type planar coil particle detection sensor. The detection accuracy and detection limit are improved by optimizing the magnetic field inside the sensor. The optimization of the magnetic field is achieved through the finite element simulation analysis of the coil and the magnetic core. First, the finite element simulation software COMSOL 6.0 is used to model the sensor in three dimensions (3D). Then, we study the distribution of the magnetic field under different coil radii, core conductivity levels, and other parameters. We obtain the sensor structure after optimizing the magnetic field. The sensor is made using experimental methods, and the iron particles and copper particles are detected. The results show that the lower limit of detection of iron particles can reach 46 μm, and the lower limit of detection of copper particles can reach 110 μm. Full article
(This article belongs to the Special Issue Micro/Nanostructures in Sensors and Actuators, 2nd Edition)
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18 pages, 10290 KiB  
Article
Assessment of Hydraulic Oil Properties during Operation of a Mini Loader
by Diego Andrés Duque-Sarmiento and Daysi Alexandra Baño-Morales
Lubricants 2024, 12(9), 320; https://doi.org/10.3390/lubricants12090320 - 17 Sep 2024
Cited by 2 | Viewed by 2406
Abstract
This study employs a rigorous methodology to assess the condition of the hydraulic oil in a recently introduced mini skid-steer loader. The assessment is conducted through laboratory analysis, which adheres to a range of international standards. The objective is to provide accurate insights [...] Read more.
This study employs a rigorous methodology to assess the condition of the hydraulic oil in a recently introduced mini skid-steer loader. The assessment is conducted through laboratory analysis, which adheres to a range of international standards. The objective is to provide accurate insights into the viscosity, particle count, and characterisation of the oil, along with thermographic data. The friction of oil is evaluated at specific time points: 0, 10, 100, 125, and 150 h of operation. This examination offers a comprehensive insight into the alterations in oil characteristics during a pivotal period when machine components are undergoing initial consolidation and abrasion to attain the factory-defined performance thresholds. The principal aim of this research is to provide valuable insights into the wear of oil and hydraulic system components through an in-depth analysis of a range of variables. Moreover, the investigation aims to ascertain the impact of this factor on the temperature elevation of system components and accessories to formulate enhanced technical guidelines for implementation. The main results indicate the presence of particles in the oil, resulting in a cleanliness code of 23/21/13, which exceeds the permissible threshold of 20/18/15 specified in ISO 11171. In addition, hydraulic oil shows a viscosity instability of more than 10% due to moisture absorption, leading to wear of mechanical components composed of iron, nickel, copper, zinc, and silicon. This deterioration is corroborated by thermographic evaluations, which reveal a considerable temperature increase in components such as cylinders and system accessories. Full article
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26 pages, 11540 KiB  
Article
Physical Model of Inclusions Removal at Static Steel–Slag Interface
by Xin Tao, Jianqi Cao, Jia Wang, Xiaonai He, Lingyu Meng, Yongbo Guo, Tao Wang, Dongliang Li, Jinping Fan and Chao Chen
Materials 2024, 17(10), 2244; https://doi.org/10.3390/ma17102244 - 10 May 2024
Cited by 1 | Viewed by 1319
Abstract
Inclusions are one of the important factors affecting the cleanliness of molten steel. The current optimization of inclusion removal methods mainly focuses on promoting inclusions to float to the slag–steel interface so that the inclusions can be absorbed and removed by the refining [...] Read more.
Inclusions are one of the important factors affecting the cleanliness of molten steel. The current optimization of inclusion removal methods mainly focuses on promoting inclusions to float to the slag–steel interface so that the inclusions can be absorbed and removed by the refining slag. However, the research on the floating removal of inclusions cannot be carried out directly in the ladle, so methods such as mathematical models and physical models were developed. This article uses silicone oil to simulate the slag layer; polypropylene particles; and aluminum oxide particles to simulate inclusions to establish a water model experiment. By changing the viscosity of silicone oil and the diameter of particles, the factors affecting the movement of inclusions at the slag–steel interface were explored. Based on the water model, a mathematical model of the floating behavior of inclusions at the slag–steel interface was constructed, and parameters such as particle diameter and interfacial tension in the water model experiment were studied by the mathematical model for calculation. Both the mathematical model and the water model experimental results show that after the viscosity of silicone oil increases from 0.048 Pa·s to 0.096 Pa·s, the dimensionless displacement and terminal velocity of the particles decreases. When the diameter of the same particle increases, the dimensionless displacement and terminal velocity increases. The dimensionless displacement of polypropylene particles of the same diameter is larger than that of aluminum oxide particles, and the terminal velocity is smaller than that of aluminum oxide particles. This is attributed to the better overall three-phase wettability of polypropylene particle. When the liquid level increases, the dimensionless displacement and terminal velocity of particles under the same conditions show only slight differences (less than 10%). Full article
(This article belongs to the Special Issue Advanced Metallurgy Technologies: Physical and Numerical Modelling)
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15 pages, 1300 KiB  
Article
Eco-Friendly Sanitization of Indoor Environments: Effectiveness of Thyme Essential Oil in Controlling Bioaerosol Levels and Disinfecting Surfaces
by Daniela Sateriale, Giuseppina Forgione, Giuseppa Anna De Cristofaro, Leonardo Continisio, Chiara Pagliuca, Roberta Colicchio, Paola Salvatore, Marina Paolucci and Caterina Pagliarulo
BioTech 2024, 13(2), 12; https://doi.org/10.3390/biotech13020012 - 26 Apr 2024
Cited by 2 | Viewed by 3752
Abstract
Bioaerosols and pathogens in indoor workplaces and residential environments are the primary culprits of several infections. Techniques for sanitizing air and surfaces typically involve the use of UV rays or chemical sanitizers, which may release chemical residues harmful to human health. Essential oils, [...] Read more.
Bioaerosols and pathogens in indoor workplaces and residential environments are the primary culprits of several infections. Techniques for sanitizing air and surfaces typically involve the use of UV rays or chemical sanitizers, which may release chemical residues harmful to human health. Essential oils, natural substances derived from plants, which exhibit broad antimicrobial properties, could be a viable alternative for air and surface sanitation. The objective of this study has been to investigate the efficacy of thyme essential oil (TEO) in environmental sanitation processes. In Vitro assays through agar well diffusion, disk volatilization and tube dilution methods revealed significant antimicrobial activity of TEO 100% against foodborne and environmental isolates, with both bacteriostatic/fungistatic and bactericidal/fungicidal effects. Therefore, aqueous solutions of TEO 2.5% and 5% were formulated for air sanitation through nebulization and surface disinfection via direct contact. Bioaerosol samples and surface swabs were analyzed before and after sanitation, demonstrating the efficacy of aqueous solutions of TEO in reducing mesophilic and psychrophilic bacteria and environmental fungi levels in both air and on surfaces. The obtained results prove the antimicrobial potential of aqueous solutions of TEO in improving indoor air quality and surface cleanliness, suggesting thyme essential oil as an effective and safe natural sanitizer with minimal environmental impact compared to dangerous chemical disinfectants. Full article
(This article belongs to the Section Environmental Biotechnology)
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20 pages, 8807 KiB  
Article
Degradation of Hydraulic System due to Wear Particles or Medium Test Dust
by Nejc Novak, Ana Trajkovski, Mitjan Kalin and Franc Majdič
Appl. Sci. 2023, 13(13), 7777; https://doi.org/10.3390/app13137777 - 30 Jun 2023
Cited by 13 | Viewed by 4160
Abstract
Contamination in hydraulic systems is the cause of 70% of failures. This study highlights the performance degradation caused by solid particle contamination of hydraulic components: hydraulic gear pump, 4/3 valve, and orbital motor. Experimental durability tests of components with wear particles and test [...] Read more.
Contamination in hydraulic systems is the cause of 70% of failures. This study highlights the performance degradation caused by solid particle contamination of hydraulic components: hydraulic gear pump, 4/3 valve, and orbital motor. Experimental durability tests of components with wear particles and test dust are used to investigate the effects of accelerated wear caused by these two types of contaminants. Results show that oil contaminated with wear particles reduces the volumetric efficiency of the gear pump by 18% and the hydraulic valve by only 0.8%, while oil contaminated with test dust reduces the efficiency of the pump by 76% and the hydraulic valve by 0.9%. This research provides insights for accelerating hydraulic component testing to improve system reliability and longevity. Full article
(This article belongs to the Special Issue Research Progress on Hydraulic Fluid and Hydraulic Systems)
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12 pages, 1774 KiB  
Systematic Review
Castor Oil in Bowel Preparation Regimens for Colon Capsule Endoscopy: A Systematic Review with Meta-Analysis
by Ulrik Deding, Sofie Sajan Jensen, Benedicte Schelde-Olesen, Lasse Kaalby, Thomas Bjørsum-Meyer and Anastasios Koulaouzidis
Diagnostics 2022, 12(11), 2795; https://doi.org/10.3390/diagnostics12112795 - 15 Nov 2022
Cited by 5 | Viewed by 6190
Abstract
Completing colon capsule endoscopy (CCE) investigations rely on successful transit and acceptable bowel preparation quality. We investigated the effect of adding castor oil to the CCE bowel preparation regimen on the completion rate using a meta-analysis of existing literature. We conducted a systematic [...] Read more.
Completing colon capsule endoscopy (CCE) investigations rely on successful transit and acceptable bowel preparation quality. We investigated the effect of adding castor oil to the CCE bowel preparation regimen on the completion rate using a meta-analysis of existing literature. We conducted a systematic literature search in PubMed, Web of Science, and Embase. Included studies underwent quality assessment, and data for meta-analysis were extracted. Pooled estimates for excretion rate and acceptable bowel preparation rate were calculated. We identified 72 studies matching our search criteria, and six were included in the meta-analysis. Three of the studies had control groups, although two used historical cohorts. The pooled excretion rate (92%) was significantly higher in patients who received castor oil than in those who did not (73%). No significant difference in acceptable colonic cleanliness was observed. Castor oil has been used in a few studies as a booster for CCE. This meta-analysis shows the potential for this medication to improve excretion rates, and castor oil could be actively considered in conjunction with other emerging laxative regimens in CCE. Still, prospective randomized trials with appropriate control groups should be conducted before any conclusions can be drawn. Prospero ID: CRD42022338939. Full article
(This article belongs to the Section Biomedical Optics)
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12 pages, 2071 KiB  
Article
Data Preprocessing for Vibration Analysis: Application in Indirect Monitoring of ‘Ship Centrifuge Lube Oil Separation Systems’
by Marta Zamorano, Deivis Avila, Graciliano Nicolás Marichal and Cristina Castejon
J. Mar. Sci. Eng. 2022, 10(9), 1199; https://doi.org/10.3390/jmse10091199 - 26 Aug 2022
Cited by 9 | Viewed by 2753
Abstract
Air quality can be affected by merchant ships, so it is important to regulate emissions that are produced, as well as to use energy efficiently. In this sense, the cleanliness of the oil used in lubrication is essential to achieve a better use [...] Read more.
Air quality can be affected by merchant ships, so it is important to regulate emissions that are produced, as well as to use energy efficiently. In this sense, the cleanliness of the oil used in lubrication is essential to achieve a better use of energy and reduce losses in marine engines. For that, it is vital to carry out good maintenance strategies. Therefore, it is important to develop techniques that allow condition monitoring during engine operation. In order to detect potential problems as soon as possible, it is common to analyze vibratory signals, since sustainable changes in the rotating frequency and its harmonics can be detected, which was the objective of this work, by analyzing the time-frequency domain using wavelet packet transform. A methodology to select the optimal function (mother wavelet) and the best patterns to monitor, in order to determine the state of the purifiers of the marine lube oils, was carried out, including intelligent classification systems. Specifically, this document considers centrifugal oil lubricant separators systems, since the monitoring of these systems can determine the condition of different mechanical systems. Full article
(This article belongs to the Special Issue Energy Optimization of Ship and Maritime Structures)
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16 pages, 101815 KiB  
Article
Classification of Adulterated Particle Images in Coconut Oil Using Deep Learning Approaches
by Attapon Palananda and Warangkhana Kimpan
Appl. Sci. 2022, 12(2), 656; https://doi.org/10.3390/app12020656 - 10 Jan 2022
Cited by 8 | Viewed by 2758
Abstract
In the production of coconut oil for consumption, cleanliness and safety are the first priorities for meeting the standard in Thailand. The presence of color, sediment, or impurities is an important element that affects consumers’ or buyers’ decision to buy coconut oil. Coconut [...] Read more.
In the production of coconut oil for consumption, cleanliness and safety are the first priorities for meeting the standard in Thailand. The presence of color, sediment, or impurities is an important element that affects consumers’ or buyers’ decision to buy coconut oil. Coconut oil contains impurities that are revealed during the process of compressing the coconut pulp to extract the oil. Therefore, the oil must be filtered by centrifugation and passed through a fine filter. When the oil filtration process is finished, staff inspect the turbidity of coconut oil by examining the color with the naked eye and should detect only the color of the coconut oil. However, this method cannot detect small impurities, suspended particles that take time to settle and become sediment. Studies have shown that the turbidity of coconut oil can be measured by passing light through the oil and applying image processing techniques. This method makes it possible to detect impurities using a microscopic camera that photographs the coconut oil. This study proposes a method for detecting impurities that cause the turbidity in coconut oil using a deep learning approach called a convolutional neural network (CNN) to solve the problem of impurity identification and image analysis. In the experiments, this paper used two coconut oil impurity datasets, PiCO_V1 and PiCO_V2, containing 1000 and 6861 images, respectively. A total of 10 CNN architectures were tested on these two datasets to determine the accuracy of the best architecture. The experimental results indicated that the MobileNetV2 architecture had the best performance, with the highest training accuracy rate, 94.05%, and testing accuracy rate, 80.20%. Full article
(This article belongs to the Section Applied Industrial Technologies)
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13 pages, 5301 KiB  
Article
An Impedance Sensor for Distinguishing Multi-Contaminants in Hydraulic Oil of Offshore Machinery
by Haotian Shi, Dian Huo, Hongpeng Zhang, Wei Li, Yuqing Sun, Guobin Li and Haiquan Chen
Micromachines 2021, 12(11), 1407; https://doi.org/10.3390/mi12111407 - 17 Nov 2021
Cited by 5 | Viewed by 2722
Abstract
The cleanliness of hydraulic oil can reflect the service life of the oil and the wear state of hydraulic machinery. An impedance sensor is proposed to distinguish multi-contaminants in hydraulic oil. The impedance sensor has two detection modes: the inductance-resistance mode is used [...] Read more.
The cleanliness of hydraulic oil can reflect the service life of the oil and the wear state of hydraulic machinery. An impedance sensor is proposed to distinguish multi-contaminants in hydraulic oil. The impedance sensor has two detection modes: the inductance-resistance mode is used to detect metal debris, and the capacitance mode is used to distinguish water droplets and air bubbles. By adding a built-in silicon steel strip and an external silicon steel strip with high magnetic permeability, the distribution area, strength, and uniformity of the magnetic field are enhanced to improve the detection sensitivity under inductance and resistance parameters. In addition, the silicon steel strips are used as electrode plates to introduce capacitance parameter detection. The experimental results show that the resistance detection method based on coil successfully improves the detection ability for non-ferromagnetic metal debris. The impedance sensor for distinguishing multi-contaminants in hydraulic oil can provide technical support for fault diagnosis of offshore hydraulic machinery. Full article
(This article belongs to the Special Issue Ocean MEMS and Related Technology)
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10 pages, 5122 KiB  
Article
Efficacy and Cytotoxicity of Binary Mixtures as Root Canal Filling Solvents
by Inês Ferreira, Liliana Grenho, Pedro Gomes, Ana Cristina Braga, Maria Helena Fernandes, Maria Ascensão Lopes and Irene Pina-Vaz
Materials 2020, 13(14), 3237; https://doi.org/10.3390/ma13143237 - 21 Jul 2020
Cited by 10 | Viewed by 2940
Abstract
Objectives: This study reports the efficacy of two solvent mixtures on the dissolution of gutta-percha and AH Plus sealer, together with the cytotoxicity. Methods: Methyl ethyl ketone (MEK), orange oil, tetrachloroethylene, MEK/tetrachloroethylene (1:1), MEK/orange oil (1:1), and chloroform (control) were tested. Twelve groups [...] Read more.
Objectives: This study reports the efficacy of two solvent mixtures on the dissolution of gutta-percha and AH Plus sealer, together with the cytotoxicity. Methods: Methyl ethyl ketone (MEK), orange oil, tetrachloroethylene, MEK/tetrachloroethylene (1:1), MEK/orange oil (1:1), and chloroform (control) were tested. Twelve groups (n = 15) of standardized stainless-steel molds filled with softened gutta-percha cones and twelve (n = 15) filled with AH Plus were immersed in the corresponding mixture or individual solvent, in an ultrasonic bath, for either 2 or 5 min. The effect of the solvents was assessed qualitatively by a topographical analysis (scanning electron microscopy) and chemical analysis (Fourier transform infrared spectroscopy), and quantitatively by a weight loss and viscoelastic property (dynamic mechanical analysis) evaluation. The cytotoxicity was assessed on MG63 human osteoblastic cells. Results: The mixtures did not show the formation of new compounds. Both presented significantly higher efficacies compared to their individual solvents, suggesting a synergistic effect. Their dissolution efficacy was similar to that of chloroform, showing high cytocompatibility. Conclusions: The proposed strategy, incorporating ultrasound agitation and profiting from the synergy of adequate solvents, might enhance root canal cleanliness allowing a single-step procedure to dissolve gutta-percha and the sealer remnants, while assuring cytocompatibility with the periapical tissues. Full article
(This article belongs to the Special Issue Contemporary Endodontic Materials)
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13 pages, 6049 KiB  
Article
Experimental Analysis on Skid Damage of Roller Bearing with the Time-Varying Slip and Temperature Distribution
by Junning Li, Jiafan Xue, Ka Han, Qian Wang and Wuge Chen
Appl. Sci. 2020, 10(1), 9; https://doi.org/10.3390/app10010009 - 18 Dec 2019
Cited by 10 | Viewed by 4130
Abstract
Skid damage affects the performance of aviation bearing, which covers different disciplines in tribology, thermology, materials science, dynamics, et al. In this manuscript, a novel horizontal skid damage test rig of a rolling bearing with higher rotation accuracy and better linear contact was [...] Read more.
Skid damage affects the performance of aviation bearing, which covers different disciplines in tribology, thermology, materials science, dynamics, et al. In this manuscript, a novel horizontal skid damage test rig of a rolling bearing with higher rotation accuracy and better linear contact was built, which can simulate the rolling/sliding contact between the roller and inner ring. Combining with temperature, load, speed, slip, and surface microscopy, the skid damage mechanism of roller bearings was analyzed from a multi-information perspective. Meanwhile, the dynamic lubrication failure process of the contact pair in rolling bearings with the time-varying slip and temperature distribution was revealed. The effect of different radial loads, inner ring speeds, lubricating oil quantities, and states of cleanliness on the time-varying characteristics of the temperature and the slip of the rolling bearing were obtained. Among them, the radial load has the greatest influence on the slip rate of rolling bearing. In addition, the test results show that the skid damage under extremely light load is the comprehensive effect of adhesive wear and thermal failure. Full article
(This article belongs to the Special Issue Advances in Rotordynamics)
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12 pages, 3736 KiB  
Article
Dispersion Stability and Lubrication Performance Correlation of Vegetable Oil-In-Water Emulsions with Nanoparticle-Shielded Oil Droplets
by Reza Taheri, Buyung Kosasih, Hongtao Zhu and Anh Kiet Tieu
Lubricants 2018, 6(2), 55; https://doi.org/10.3390/lubricants6020055 - 9 Jun 2018
Cited by 9 | Viewed by 4724
Abstract
Vegetable oil-in-water (VO/W) emulsions are bio-based metal working lubricants. The emulsions’ lubrication performance depends on the stability of oil droplets. In this paper, the oil droplets’ dispersion stability and lubrication of emulsions containing TiO2/SiO2 nanoparticles (NPs) as dispersant and lubrication [...] Read more.
Vegetable oil-in-water (VO/W) emulsions are bio-based metal working lubricants. The emulsions’ lubrication performance depends on the stability of oil droplets. In this paper, the oil droplets’ dispersion stability and lubrication of emulsions containing TiO2/SiO2 nanoparticles (NPs) as dispersant and lubrication agents have been investigated. Enhanced dispersion of NP-shielded oil droplets was found. Increasing the NPs’ mass fraction initially lowers the average size of NP-shielded droplets up to the saturation of the droplets’ surface with NPs at 0.5 wt % mass fraction. NPs also form NP agglomerates in emulsions, more so after the droplets’ surfaces have been saturated with NPs. There is an apparent minimum quantity of NPs (~0.5 wt %) required to ensure sustained dispersions of the droplets which is thought to be related to the oil concentration and the droplets’ total surface-area-to-volume ratio. Below the required quantity of NPs, partially shielded and fully shielded droplets coexist. The partially shielded droplets initially attract other droplets and undergo limited coalescence but retain their long-term stability. A small quantity of NPs improves the antiwear property of the lubricants. However, emulsions with NPs have slightly higher friction than the NP-free emulsion due to the reduced strength of the tribofilm. Despite the increased friction, the tribofilm formed in presence of NPs can easily be removed from the surface with water, indicating cleaner surfaces after the lubrication (i.e., less oil residue on the surfaces), which, for the sake of cleanliness, is favourable in many applications. Full article
(This article belongs to the Special Issue Biolubrication and Biomimetic Lubrication)
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