Search Results (19)

This study investigates the effect of the surface functionalization of tungsten disulfide (WS₂) nanoparticles with aminoacetic acid (glycine) on the structure, curing behavior, and mechanical performance of epoxy nanocomposites. Aminoacetic acid, as a non-toxic, bio-based modifier, enables a sustainable approach to producing more efficient nanofillers. Functionalization, as confirmed by FTIR, EDS, and XRD analyses, led to elevated surface polarity and greater chemical affinity between WS₂ and the epoxy matrix, thereby promoting uniform nanoparticle dispersion. The strengthened interfacial bonding resulted in a notable decrease in the curing onset temperature—from 51 °C (for pristine WS₂) to 43 °C—accompanied by an increase in polymerization enthalpy from 566 J/g to 639 J/g, which reflects more extensive crosslinking. The SEM examination of fracture surfaces revealed tortuous crack paths and localized plastic deformation zones, indicating superior fracture resistance. Mechanical testing showed marked improvements in flexural and tensile strength, modulus, and impact toughness at the optimal WS₂ loading of 0.5 phr and a 7.5 wt% aminoacetic acid concentration. The surface-modified WS₂ nanoparticles, which perform dual functions, not only reinforce interfacial adhesion and structural uniformity but also accelerate the curing process through chemical interaction with epoxy groups. These findings support the development of high-performance, environmentally sustainable epoxy nanocomposites utilizing amino acid-modified 2D nanofillers. Full article

A novel approach to estimating the absorbed energy (toughness) in a uniaxial tensile test with only knowledge of the microstructure is presented. The flow behavior of each Dual-Phase (DP) steel grade is predicted using idealized Representative Volume Elements (RVEs) up to uniform elongation. To estimate the flow behavior beyond uniform elongation, the stress-modified fracture strain in a non-local damage model was implemented in Abaqus. Damage parameters were calibrated using Finite Element (FE) simulations of purely ferritic tensile specimens. The damage parameters remained unchanged, except for the coefficient of triaxiality. This coefficient was adjusted based on the average triaxiality of ferrite elements at the instability point of the uniaxially loaded RVEs for each DP steel grade. The proposed approach comprises two steps: micron-sized RVEs to predict the flow behavior up to the point of uniform elongation and the average triaxiality and full-scale tensile-test simulations to predict the rest of the curves. The results show that the damage parameters calibrated for high-strain ferrite effectively estimate the absorbed energy during failure in tension tests. This approach is also geometry-independent; varying the geometry of the tensile specimen, including miniature or notched specimens, still yields predicted absorbed energies that are in good agreement with the experimental results. Full article

Titanium carbonitride (Ti(C,N))-based ceramics are widely utilized in mechanical machining, aerospace, and electronics, particularly in cutting tools and wear-resistant components. Two single-phase solid solution powders, non-high-entropy (Ti_0.83,W_0.07,Mo_0.04,Nb_0.03,Ta_0.04)(C_0.7,N_0.3) and high-entropy (Ti_0.6,W_0.1,Mo_0.1,Nb_0.1,Ta_0.1)(C_0.78,N_0.22), were synthesized via the carbothermal reduction–nitridation (CRN) method. Gradient-structured non-high-entropy (C-TiCN) and high-entropy (HE-TiCN) cermets were fabricated at 1450 °C by tailoring the nitrogen partial pressure in the range of 1–8 kPa. The effect of nitrogen partial pressure on the microstructure and mechanical properties of both materials was thoroughly analyzed. Both materials exhibited a three-layer gradient structure comprising a hard-phase-enriched surface layer, a binder-rich subsurface layer, and a chemically uniform core. Optimal performance was achieved at 4 kPa nitrogen partial pressure, at which both HE-TiCN and C-TiCN exhibited a desirable combination of surface hardness and fracture toughness. Compared with C-TiCN, HE-TiCN showed improvements in surface hardness and fracture toughness at subsurface and core regions (40 µm from the surface) by 4.9%, 11.2%, and 12.0%, respectively. The enhanced surface hardness of HE-TiCN is attributed to the significant lattice distortion and the synergistic effects associated with its high-entropy configuration. The improved toughness of the binder-rich layer is primarily ascribed to mechanisms such as crack deflection, crack branching, and the formation of tear ridges. These findings offer a promising strategy for developing gradient Ti(C,N)-based cermets with enhanced mechanical performance. Full article

Stress analysis is of great significance for components in thermal power plants, and an inaccurate model could cause inaccuracy in the life assessment of the plant. During the manufacturing process of elbows, issues such as cross-sectional elliptical deformation and uneven wall thickness frequently occur. However, existing studies have not thoroughly investigated these phenomena. In this study, a modified finite element model based on the dimension of an actual elbow was established for stress analysis and compared with that of the ideal uniform model. Subsequently, microstructure characterization and mechanical property tests were conducted on the elbow to validate both models. The stress concentration area in the corrected model has shifted from the inner arc region of the ideal model to the inner wall of the neutral plane region. Both optical microscopy and SEM results indicate that microstructural degradation in the neutral plane region is more pronounced, characterized by non-uniform grains, coarse carbides, and creep cavities. The hardness values of the inner wall in the neutral plane area are significantly lower than that in the inner arc area, and the tensile sample in the neutral plane area fractures rapidly after yielding, exhibiting poorer toughness compared to the samples in the inner arc area. Moreover, the creep resistance in the neutral plane area is much lower than that in the inner arc area. By integrating finite element simulation with experimental validation, the accuracy of the corrected finite element model presented in this paper has been confirmed, providing valuable theoretical and experimental guidance for the life assessment of elbows in thermal power plants. Full article

Fracture toughness is a critical indicator for the application of NiTi alloys in medical fields. We propose to enhance the fracture toughness of NiTi alloys by controlling the spatial grain size (GS) gradient. Utilizing rolling processes and heat treatment technology, three categories of NiTi alloys with distinct spatial GS distributions were fabricated and subsequently examined through multi-field synchronous fracture tests. It is found that the one with a locally ultra-high GS gradient (20 nm−3.4 μm) has significantly enhanced fracture toughness, which is as high as 412% of that of the normally distributed nano-grains with an average GS of 8 nm and 178% of that of the coarse-grains with an average GS of 100 nm. Theoretical analysis reveals that in such a gradient structure, phase transition in the coarse-grained matrix greatly absorbs the surface energy of subcritical and stable propagation. Meanwhile, the locally non-uniform GS distribution leads to deviation and tortuosity of the crack path, increasing the critical fracture stress. Furthermore, the nanocrystalline clusters distributed in the form of network nodes reduce the stress intensity factor due to their higher elastic modulus compared to the coarse-grained matrix. This work provides guidance for developing new gradient nanostructured NiTi alloys with high fracture toughness. Full article

The key structural components of a wind turbine blade, such as the skin, spar cap, and shear web, are fabricated from fiber-reinforced composite materials. The spar, predominantly manufactured via resin infusion—a process of resin injection and curing in carbon fibers—is prone to initial defects, such as pores, wrinkles, and delamination. This study suggests employing the pultrusion technique for spar production to consistently obtain a uniform cross-section and augment the reliability of both the manufacturing process and the design. In this context, this study introduces carbon fiber-reinforced polymer (CFRP/CFRP) and glass fiber-reinforced polymer (GFRP/CFRP) test specimens, which mimic the bonding structure of the spar cap, utilizing pultruded CFRP in accordance with ASTM standards to analyze the delamination traits of the spar. Delamination tests—covering Mode I (double cantilever beam), Mode II (end-notched flexure), and mixed mode (mixed-mode bending)—were performed to gauge displacement, load, and crack growth length. Through this crack growth mechanism, the interlaminar fracture toughness derived was examined, and the stiffness and strength changes compared to CFRP based on the existing prepreg manufacturing method were analyzed. In addition, the interlaminar fracture toughness for GFRP, which is a material in contact with the spar structure, was analyzed, and through this, it was confirmed that the crack behavior has less deviation compared to a single CFRP material depending on the stiffness difference between the materials when joining dissimilar materials. This means that the higher the elasticity of the high-stiffness material, the higher the initial crack resistance, but the crack growth behavior shows non-uniform characteristics thereafter. This comparison provides information for predicting interlaminar delamination damage within the interior and bonding area of the spar and skin and provides insight for securing the reliability of the design life. Full article

This study investigates the influence of various heat treatment processes on the microstructure and properties of laser cladding Fe314 coatings. The microstructure, phases, and impact fracture morphology of the cladding layer were observed using X-ray diffraction and scanning electron microscopy, among other methods. The hardness and impact performance of the cladding layer were also tested. The results indicated that there was compositional segregation and non-equilibrium microstructure in the untreated cladding layer, with an average microhardness of 368.67 HV and an impact toughness of 27 J, exhibiting quasi-cleavage fracture. The stress-relief annealing treatment resulted in a uniform distribution of M23C6 carbides inside the cladding layer. The pinning effect generated by M23C6 reduced the microhardness by 16.26% and increased the impact toughness to 54 J. The impact fracture surface exhibited ductile fracture. After secondary normalizing and annealing, the microstructure of the cladding layer transformed into a fine single-phase austenite structure, and fine M7C3 carbides precipitated at the grain boundaries. Under the effects of fine grain strengthening and dispersion strengthening, the microhardness of the cladding layer decreased by 38.14%, and the average impact absorbed energy of the specimen was 64 J, showing complete ductile fracture. Full article

The non-uniformity of microstructures and mechanical properties across a whole welded joint is a crucial factor leading to its weakening performance and premature failure. Post-weld heat treatment is a primary method for increasing the mechanical properties. However, the evolution mechanism of mechanical properties related to heterogeneous microstructure after heat treatment remains unclear, making it challenging to design the heat treatment process and evaluate its effect comprehensively. In this study, microstructure characterization and a series of mechanical tests of 12Cr1MoV welded joint after the stress relief annealing (SRA) and tempering heat treatment (THT) were conducted. The effect of heat treatment on mechanical properties is analyzed based on the comparison between stress relief annealing and tempering heat treatment in terms of tensile properties, impact toughness, and impact fracture morphology. The results indicate that, after the tempering heat treatment, the evolution of mechanical properties in each subzone of the joint is consistent, i.e., the hardness and tensile strength decreased while the toughness increased. Notably, the most substantial enhancement in toughness is observed in the weld zone, primarily due to a significant reduction in the presence of pre-eutectoid ferrite. Furthermore, it is proved that hardness is an indicator to reflect changes in tensile strength related to the microstructure evolution, which indicates it can be employed to evaluate the effectiveness of post-weld heat treatment in practical engineering. Full article

The effects of Fe-bearing phases on the structure, mechanical properties, and fracture mechanism of a non-heat-treatable model sheet alloy (wt.%: Al–2%Cu–1.5%Mn(-Mg,Zn)), designed for Al₂₀Cu₂Mn₃ dispersoids, was investigated. This involved a combination of thermodynamic modeling in the Thermo-Calc program and experimental studies of structure and mechanical properties. It has been shown that the addition of 0.5 and 0.4% iron and silicon leads to the formation of eutectic inclusions in the Al₁₅(Mn,Fe)₃Si₂ phase. In addition to the Fe- bearing inclusions, the formation of the eutectic Al₂Cu and Al₂CuMg phases can be expected in the as-cast structure of the experimental alloys. Despite their relatively high fraction of eutectic particles, non-homogenized alloy ingots demonstrated sufficiently high deformation processability during the hot (400 °C) and cold rolling, which made it possible to obtain high-quality sheet alloys (with reduction degrees of 80 and 75%, respectively). The results of the tensile tests revealed that, after cold rolling, the addition of 1% Mg significantly increased the tensile and yield strengths, whereas the effect of 1% Zn was negligible. At the same time, the uniform distribution of Fe-bearing phases in the structure of the cold-rolled sheets contributes to the preservation of the dimple mechanism of the fracture toughness. This helps to maintain the same level of ductility for the cold-rolled sheet Fe-containing alloys as for Fe-free alloys. It has been shown, based on the data obtained, that adding Fe, Si, Mg, and Zn to the base Al–2%Cu–1.5%Mn alloy in a total amount of more than 3% makes it possible to retain the ductile fracture patterns of the base alloy and obtain a fairly higher level of mechanical properties. This suggests the fundamental possibility of using a variety of secondary raw materials (containing the main elements present in aluminum alloys of different alloying systems) to prepare a base alloy that does not require homogenization or thermal hardening. Full article

The helicoidal laminate is a kind of nature inspired fiber reinforced polymer, and the ply orientation affects their mechanical properties for engineering structural applications. A variety of helicoidal laminates with uniform and non-linear pitch angles mixed with additional 0° plies are fabricated to investigate the impact resistance through low-velocity impact and after-impact compression tests. Additionally, helicoidal laminates with constant pitch angles, quasi-isotropic laminate, and cross-ply laminates are also fabricated for a comparative study. The impact characteristics and the compressive strength are analyzed in view of the impact model, shear stress distribution, and fracture toughness. The results suggest that 10° or 20° are the better basic pitch angles before mixing 0° orientation plies. The 0° orientation plies may affect the contact stiffness, bending stiffness, damage extent, and compressive modulus. The compressive strength reaches the highest in tests on two samples with different percentages of 0° orientation plies and ply setups. Bending stiffness also dominates the impact response. The analysis on the laminate parameters provides ideas to improve the residual strength of helicoidal laminate. Full article

This paper presents the research results on the mechanical behavior of the low-carbon rolled steel of a sea portal crane after a 33-year operation depending on the operational stresses and rolling direction in order to assess its serviceability. The tensile properties of steels were investigated using rectangular cross-section specimens with different thicknesses and the same width. Strength indicators were slightly dependent on the considered factors (operational conditions, the cutting direction, and thickness of specimens). However, a clear trend of higher ultimate strength for thinner specimens was noticed, especially in the case of more brittle material due to its operational degradation. Plasticity of the tested steel specimens was more sensitive to the influence of the above-mentioned factors than strength but less sensitive than impact toughness. Uniform elongation was slightly less for thinner specimens regardless of the investigated steel state or the orientation of specimens relative to the rolling direction. The post-necking elongation was lower for transversal specimens compared with longitudinal ones, and the effect was more significant when testing steel with the lowest brittle fracture resistance. Among the tensile properties, non-uniform elongation was demonstrated to be the most effective for assessing the operational changes in the state of rolled steels. Full article

This study used a digital imaging technique (DIC) to obtain the strain distribution at various locations in undermatching X80 pipe girth-weld joints under uniaxial tensile loading. In addition, the microstructure characteristics and deformation patterns in different regions were analyzed by scanning electron microscopy (SEM). The results showed that there was strain heterogeneity between the various regions of the welded joint. Strain concentration existed only in the 12.8 mm base metal heat-affected zone (HAZ) and only in the elastic deformation stage. There was strain concentration in the weld metal (WM) and both sides of the HAZ close to the near-fracture stage, and the maximum deformation was in the WM. When ${\epsilon }_M$ = 12.2%, the $K_C$ was 6.27 and the $K_F$ was 1.73, and the $K_F$ was 113% and 152% of the $K_C$ and the $K_G$, respectively. The large number of slip strips generated indicated serious damage in the WM near the fracture stage. In the elastic deformation stage, the strain concentration of the N1 HAZ was caused by the softened ferrite. The maximum deformation of the WM near the fracture stage was caused by the large grain size and the non-uniform martensite–austenite (M–A) islands, which may also lead to better local toughness of the cover weld and further affect the fracture mechanism of the welded joint. Full article

The multifracture competitive growth from a horizontal well is an essential issue in multi-cluster fracturing design. In recent years, extremely limited entry (ELE) fracturing has been implemented to promote uniform multifracture growth. However, the mechanism of multifracture growth and ELE design remain unclear. Based on the planar three-dimensional multifracture propagation model, a multi-cluster horizontal well fracturing model that considers ELE design has been developed. The model considers flow in the wellbore and fluid filtration loss in the fracture. The simulator enables the simulation and analysis of non-uniform in situ stress, filtration loss, and fracture properties. Using this program, we simulated the propagation process of multiple clusters of fractures in ELE fracturing of horizontal wells. The results show the following: The perforation friction in the ELE fracturing can counteract the difference in fluid allocation caused by stress interference, allowing all clusters of perforations to have even fluid allocation but to differ significantly in fracture geometry. The in situ stress profile and 3D fracture stress interference determine the fracture geometry, and the fracture of the middle cluster could cross through the layer with relatively higher in situ stress, resulting in a decrease in effective fracture area in the pay zone. Furthermore, an increase in perforation diameter causes the flow-limiting effect of the perforations to decrease. The fluid volumes entering different clusters of perforations become less uniform. The difference in fracture toughness within a perforated stage has a minor influence on the fluid allocation between different clusters, while the in situ stress distribution within a perforated stage has a significant impact on the fluid allocation between different perforation clusters in the stage. Fractures preferentially propagate at the perforation points with lower in situ stress and stress interference. This study can be helpful to understand multifracture competitive growth and the optimization of ELE fracturing design. Full article

In this paper, interlayer toughening composites were prepared by the z-directional injection RTM process (z-RTM), which has the advantage of increasing the interlaminar toughness and shortening the filling time and completely impregnating the fibers. The nonwoven fabrics and dot matrix structure material were used as ex situ interlayer toughening agents. The effect of the interlayer toughening agent structure on the resin flow behavior during the z-RTM process was investigated. The macro-flowing and micro-infiltration behaviors of the resin inside the preforms were deduced. The permeability of the fabric preforms with different toughening agents was investigated. The results show that the introduction of the nonwoven structure toughening agent makes the macro flow slow, and the flow front more uniform. The toughening agent with a dot matrix structure promotes the resin macro flow in the preforms, and shortens the injection time. The z-directional permeability of the preform with a dot matrix structural toughening agent is one order of magnitude lower than that of the non-toughened preform, while being higher than the preform toughened by the nonwoven fabric preforms, which is helpful for the further applicability of the z-RTM process. Furthermore, the mode II interlaminar fracture toughness of composites was evaluated. Full article

The effectiveness of the hydraulic fracturing procedure is crucially dependent on the stage of fracture planning and design. Forecasting fracture behavior in rock formations characterized by non-uniform toughness is a serious challenge. In the present paper, a planar-3D model considering the rock’s non-uniform fracture toughness has been developed for the uneven propagation of a hydraulic fracture. The series of numerical experiments were designed to study the effect of inhomogenous fracture toughness. The results show that the fracture toughness contract significantly controls the overall direction of fracture propagation, and a combination of toughness contrast and the proportion between the pay zone and barrier zone determine the fracture profile: from almost circular with or without a pair of narrow wedges when the proportion is small to almost rectangular otherwise. This paper also discusses the process of cleaning a fracture from hydraulic fracturing fluid by oil. Using numerical modeling on the basis of the constructed mathematical model, a relationship is established between the quality of hydraulic fracture cleaning and the geometrical parameters of the fracture and the region filled with the hydraulic fracturing fluid. The results of numerical experiments show that while fracturing fluid is more viscous than oil, the length of the fracture has a greater influence on the cleaning process than the viscosity of the fracturing fluid. Full article