Search Results (14)

This paper aims to consider the issue of increasing the environmental friendliness of shipping by using alternative fuels in marine diesel engines. It has been determined that marine diesel engines are not only the main heat engines used on ships of sea and inland waterway transport, but are also sources of emissions of toxic components with exhaust gases. The main compounds whose emissions are controlled and regulated by international organizations are sulfur oxides (SO_X) and nitrogen oxides (NO_X), as well as carbon dioxide (CO₂). Reducing NO_X and CO₂ emissions while simultaneously increasing the environmental friendliness of shipping is possible by using fuel mixtures in marine diesel engines that include biodiesel fuel. During the research carried out on Wartsila 6L32 marine diesel engines (Shanghai Wartsila Qiyao Diesel Co. Ltd., Shanghai, China), RMG500 and DMA10 petroleum fuels were used, as well as their mixtures with biodiesel fuel FAME. It was found that when using mixtures containing 10–30% of FAME biodiesel, NO_X emissions are reduced by 11.20–27.10%; under the same conditions, CO₂ emissions are reduced by 5.31–19.47%. The use of alternative fuels in marine diesel engines (one of which is biodiesel and fuel mixtures containing it) is one of the ways to increase the level of environmental sustainability of seagoing vessels and promote ecological shipping. This is of particular relevance when operating vessels in special ecological areas of the World Ocean. The relatively low energy intensity of the method of creating and using such fuel mixtures contributes to the spread of its use on many means of maritime transport. Full article

This study proposes a nitrogen recycling system that collects and recycles nitrogen compounds from waste gases in the industrial sector, such as those from stationary sources, from industrially processed wastewater containing livestock effluent, and from household wastewater. Multiple scenarios are set, and the potential global flows of anthropogenic nitrogen in 2050 are estimated and compared to assess the effects on the largest planetary boundary problem. In contrast to the business-as-usual (BAU) scenario, in which environmental conditions are worsened through a 47% increase in nitrogen emissions by 2050 above the 2010 levels, the agricultural countermeasures scenario produced a reduction in emissions which was less than the 2010 levels. The industrial countermeasures scenario proposed in this study achieved comfortable reductions in nitrogen production by constructing a nitrogen recycling system that installs the nitrogen compounds to ammonia (NTA) technologies. Combining the agricultural and industrial countermeasures achieves a 66% reduction in nitrogen emissions compared with the BAU scenario in 2050. The combination of both countermeasures with a high installation rate of NTA technologies can achieve the reduction of nitrogen emissions beneath the planetary boundary. Full article

Constructed wetlands (CWs) are an eco-technology for wastewater treatment and are applied worldwide. Due to the regular influx of pollutants, CWs can release considerable quantities of greenhouse gases (GHGs), ammonia (NH₃), and other atmospheric pollutants, such as volatile organic compounds (VOCs) and hydrogen sulfide (H₂S), etc., which will aggravate global warming, degrade air quality and even threaten human health. However, there is a lack of systematic understanding of factors affecting the emission of these gases in CWs. In this study, we applied meta-analysis to quantitatively review the main influencing factors of GHG emission from CWs; meanwhile, the emissions of NH₃, VOCs, and H₂S were qualitatively assessed. Meta-analysis indicates that horizontal subsurface flow (HSSF) CWs emit less CH₄ and N₂O than free water surface flow (FWS) CWs. The addition of biochar can mitigate N₂O emission compared to gravel-based CWs but has the risk of increasing CH₄ emission. Polyculture CWs stimulate CH₄ emission but pose no influence on N₂O emission compared to monoculture CWs. The influent wastewater characteristics (e.g., C/N ratio, salinity) and environmental conditions (e.g., temperature) can also impact GHG emission. The NH₃ volatilization from CWs is positively related to the influent nitrogen concentration and pH value. High plant species richness tends to reduce NH₃ volatilization and plant composition showed greater effects than species richness. Though VOCs and H₂S emissions from CWs do not always occur, it should be a concern when using CWs to treat wastewater containing hydrocarbon and acid. This study provides solid references for simultaneously achieving pollutant removal and reducing gaseous emission from CWs, which avoids the transformation of water pollution into air contamination. Full article

The constantly growing number of vehicles sold and operated has resulted in greater contribution of automobiles to global pollution. One way to reduce emissions of carbon dioxide (CO₂) and toxic compounds, including the particulates and nitrogen oxides (NO_x) contained in exhaust gases, is to use alternative fuels. Within this group of fuels, those of plant origin, mainly alcohols, are attracting more and more attention because of their high oxygen content (around 35%), low viscosity, and good atomisation. However, alternative fuels have different physicochemical properties than diesel fuel, and these may affect the formation of the fuel spray, which, in turn, impacts the operation of the internal combustion engine, operating parameters, and the purity of the exhaust gases emitted into the environment. To make sure this type of fuel can be used in compression ignition engines, it is necessary to gain a thorough understanding of the phenomena and relationships occurring during fuel injection. The study investigated the effect of ethanol added to diesel fuel on the range of fuel spray. Firstly, the kinematic viscosity was determined for diesel fuel, and for diesel–ethanol blends with varying proportional contents of ethanol, up to 30% v/v. The viscosity test was carried out at 40 °C in compliance with the normative requirements. At the next stage, the range of the spray tip was measured for the same fuels in which kinematic viscosity was assessed. A visualisation chamber and a high-speed camera were applied for this purpose. The test was carried out under reproducible conditions, in line with the test methodology used to determine the range of fuel spray. The analyses assessed the effect of ethanol addition on kinematic viscosity and the range of fuel spray. The findings show that the increase in ethanol content corresponds to a decrease in kinematic viscosity by about 4% on average. The results were inconclusive for the lowest injection pressure tested (75 MPa), since some of the mixtures investigated were found with a lower spray range, compared to diesel fuel with no ethanol added. The greatest increase in the spray range (by approximately 39%) was found in the fuel with 30% content of ethanol at an injection pressure of 125 MPa. Full article

Two new alkaline earth metal–organic frameworks (AE-MOFs) containing Sr(II) (UPJS-15) or Ba(II) (UPJS-16) cations and extended tetrahedral linker (MTA) were synthesized and characterized in detail (UPJS stands for University of Pavol Jozef Safarik). Single-crystal X-ray analysis (SC-XRD) revealed that the materials are isostructural and, in their frameworks, one-dimensional channels are present with the size of ~11 × 10 Ų. The activation process of the compounds was studied by the combination of in situ heating infrared spectroscopy (IR), thermal analysis (TA) and in situ high-energy powder X-ray diffraction (HE-PXRD), which confirmed the stability of compounds after desolvation. The prepared compounds were investigated as adsorbents of different gases (Ar, N₂, CO₂, and H₂). Nitrogen and argon adsorption measurements showed that UPJS-15 has S_BET area of 1321 m² g⁻¹ (Ar) / 1250 m² g⁻¹ (N₂), and UPJS-16 does not adsorb mentioned gases. From the environmental application, the materials were studied as CO₂ adsorbents, and both compounds adsorb CO₂ with a maximum capacity of 22.4 wt.% @ 0 °C; 14.7 wt.% @ 20 °C and 101 kPa for UPJS-15 and 11.5 wt.% @ 0°C; 8.4 wt.% @ 20 °C and 101 kPa for UPJS-16. According to IAST calculations, UPJS-16 shows high selectivity (50 for CO₂/N₂ 10:90 mixture and 455 for CO₂/N₂ 50:50 mixture) and can be applied as CO₂ adsorbent from the atmosphere even at low pressures. The increased affinity of materials for CO₂ was also studied by DFT modelling, which revealed that the primary adsorption sites are coordinatively unsaturated sites on metal ions, azo bonds, and phenyl rings within the MTA linker. Regarding energy storage, the materials were studied as hydrogen adsorbents, but the materials showed low H₂ adsorption properties: 0.19 wt.% for UPJS-15 and 0.04 wt.% for UPJS-16 @ −196 °C and 101 kPa. The enhanced CO₂/H₂ selectivity could be used to scavenge carbon dioxide from hydrogen in WGS and DSR reactions. The second method of applying samples in the area of energy storage was the use of UPJS-15 as an additive in a lithium-sulfur battery. Cyclic performance at a cycling rate of 0.2 C showed an initial discharge capacity of 337 mAh g⁻¹, which decreased smoothly to 235 mAh g⁻¹ after 100 charge/discharge cycles. Full article

In recent years, global warming and climate change associated with emissions of CO₂ from fossil fuel-fired power systems are a big worry for authorities in many countries worldwide. The utilization of biomass as an alternative, carbon-neutral fuel can reduce emissions of CO₂ and other greenhouse gases. Furthermore, the coupling of oxy-combustion of biomass with CO₂ capture is an option for carbon-negative power generation technology. In this study, emissions of NO_x, SO₂, and CO from the air- and oxy-combustion of three energy crops (Miscanthus giganteus, Sida hermaphrodita, and Salix viminalis) are presented and compared with emissions from other biomass fuels and reference coal. Combustion tests in air and O₂/CO₂ mixtures were conducted in a 12-kW bench-scale CFB combustor at 850 °C. Measurements of flue gas compositions were taken using an FTIR spectrometer. In all tested atmospheres, emissions of SO₂, N₂O, and CO for biomass were lower than those for the reference coal. The oxidation of volatile nitrogen compounds was behind high emissions of NO_x from biomass burned in air and O₂/CO₂ mixtures. The lowest concentrations of NO were found in the 21% O₂/70% CO₂ mixture. Combustion in mixtures containing more oxygen (30% and 40% O₂) led to a decrease in emissions of N₂O and CO and an increase in emissions of NO and SO₂. Full article

Nitrogen (N) is a gas and the fifth most abundant element naturally found in the atmosphere. N’s role in agriculture and plant metabolism has been widely investigated for decades, and extensive information regarding this subject is available. However, the advent of sequencing technology and the advances in plant biotechnology, coupled with the growing interest in functional genomics-related studies and the various environmental challenges, have paved novel paths to rediscovering the fundamentals of N and its dynamics in physiological and biological processes, as well as biochemical reactions under both normal and stress conditions. This work provides a comprehensive review on multiple facets of N and N-containing compounds in plants disseminated in the literature to better appreciate N in its multiple dimensions. Here, some of the ancient but fundamental aspects of N are revived and the advances in our understanding of N in the metabolism of plants is portrayed. It is established that N is indispensable for achieving high plant productivity and fitness. However, the use of N-rich fertilizers in relatively higher amounts negatively affects the environment. Therefore, a paradigm shift is important to shape to the future use of N-rich fertilizers in crop production and their contribution to the current global greenhouse gases (GHGs) budget would help tackle current global environmental challenges toward a sustainable agriculture. Full article

The effect of a controlled oxygen admixture to a plasma nitrocarburizing process using active screen technology and an active screen made of carbon was investigated to control the carburizing potential within the plasma-assisted process. Laser absorption spectroscopy was used to determine the resulting process gas composition at different levels of oxygen admixture using O₂ and CO₂, respectively, as well as the long-term trends of the concentration of major reaction products over the duration of a material treatment of ARMCO^® iron. The short-term studies of the resulting process gas composition, as a function of oxygen addition to the process feed gases N₂ and H_2, showed that a stepwise increase in oxygen addition led to the formation of oxygen-containing species, such as CO, CO₂, and H₂O, and to a significant decrease in the concentrations of hydrocarbons and HCN. Despite increased oxygen concentration within the process gas, no oxygen enrichment was observed in the compound layer of ARMCO^® iron; however, the diffusion depth of nitrogen and carbon increased significantly. Increasing the local nitrogen concentration changed the stoichiometry of the ε-Fe₃(N,C)_1+x phase in the compound layer and opens up additional degrees of freedom for improved process control. Full article

Silicon oxynitrides (SiO_xN_y) have many advantageous properties for modern ceramic applications that justify a development of their new and efficient preparation methods. In the paper, we show the possibility of preparing amorphous SiO_xN_y-based materials from selected liquid organosilicon compounds, methyltrimethoxysilane CH₃Si(OCH₃)₃ and methyltriethoxysilane CH₃Si(OC₂H₅)₃, by a convenient spray pyrolysis method. The precursor mist is transported with an inert gas or a mixture of reactive gases through a preheated tube reactor to undergo complex decomposition changes, and the resulting powders are collected in the exhaust filter. The powders are produced in the tube at temperatures of 1200, 1400, and 1600 °C under various gas atmosphere conditions. In the first option, argon Ar gas is used for mist transportation and ammonia NH₃ gas serves as a reactive medium, while in the second option nitrogen N₂ is exclusively applied. Powder X-Ray Diffraction (XRD) results confirm the highly amorphous nature of all products except those made at 1600 °C in nitrogen. SEM examination shows the spheroidal particle morphology of powders, which is typical for this method. Fourier Transform Infrared (FT-IR) spectroscopy reveals the presence of Si–N and Si–O bonds in the powders prepared under Ar/NH₃, whereas those produced under N₂ additionally contain Si–C bonds. Raman spectroscopy measurements also support some turbostratic free carbon C in the products prepared under nitrogen. The directly determined O- and N-contents provide additional data linking the process conditions with specific powder composition, especially from the point of view of oxygen replacement in the Si–O moieties formed upon initial precursor decomposition reactions by nitrogen (from NH₃ or N₂) or carbon (from the carbonization of the organic groups). Full article

SCR still represents the most widely applied technique to remove nitrogen oxides from flue gas from both stationary and mobile sources. The catalyst lifetime is greatly affected by the presence of poisoning compounds in the exhaust gas that deactivate the catalysts over time on stream. The progressive and widespread transition towards bio-derived fuels is pushing research efforts to deeply understand and contrast the deactivating effects of some specific poisons among those commonly found in the emissions from combustion processes. In particular, exhaust gases from the combustion of bio-fuels, as well as from municipal waste incineration plants and marine engines, contain large amounts of alkali and alkaline earth metals that can severely affect the acid, redox, and physical properties of the SCR catalysts. This review analyzes recent studies on the effects of alkali and alkaline earth metals on different types of SCR catalysts divided into three main categories (conventional V₂O₅-WO₃/TiO₂, supported non-vanadium catalysts and zeolite-based catalysts) specifically focusing on the impact of poisons on the reaction mechanism while highlighting the different type of deactivation affecting each group of catalysts. An overview of the different regeneration techniques aimed at recovering as much as possible the original performance of the catalysts, highlighting the pros and cons, is given. Finally, current research trends aiming to improve the tolerance towards alkali-poisoning of SCR catalysts are reported. Full article

Microalgae and cyanobacteria are unicellular microorganism that contain high-added-value compounds. To make their extraction economically feasible, the biorefinery concept is the only solution. In this study, the residues resulting from lipid or protein extraction from Arthrospira platensis biomass were valorized by catalytic pyrolysis using ZSM5 zeolite or amorphous silica–alumina as catalyst. The reaction was performed in a quartz reactor, and the catalysts were placed in a fixed bed, to force the reaction gases to pass through it. The reaction products were analyzed by FTIR and GC–MS analyses. The reaction gases and liquids obtained from the extraction residues had higher hydrocarbon contents compared with the untreated biomass. Moreover, the pyrolysis of biomass after protein extraction led to fractions with lower nitrogenated component contents, while that after lipid extraction to fractions with lower oxygenated component contents. This study showed that the pyrolysis process could be used to valorize the microalgae extraction residues, aiming to make biofuels production and extraction of high-added-value products more economically feasible. Full article

N-containing gaseous compounds, such as trimethylamine (TMA), triethylamine (TEA), ammonia (NH₃), nitrogen monoxide (NO), and nitrogen dioxide (NO₂) exude irritating odors and are harmful to the human respiratory system at high concentrations. In this study, we investigated the sensing responses of five sensor materials—Al-doped ZnO (AZO) nanoparticles (NPs), Pt-loaded AZO NPs, a Pt-loaded WO₃ (Pt-WO₃) thin film, an Au-loaded WO₃ (Au-WO₃) thin film, and N-doped graphene—to the five aforementioned gases at a concentration of 10 parts per million (ppm). The ZnO- and WO₃-based materials exhibited n-type semiconducting behavior, and their responses to tertiary amines were significantly higher than those of nitric oxides. The N-doped graphene exhibited p-type semiconducting behavior and responded only to nitric oxides. The Au- and Pt-WO₃ thin films exhibited extremely high responses of approximately 100,000 for 10 ppm of triethylamine (TEA) and approximately −2700 for 10 ppm of NO₂, respectively. These sensing responses are superior to those of previously reported sensors based on semiconducting metal oxides. On the basis of the sensing response results, we drew radar plots, which indicated that selective pattern recognition could be achieved by using the five sensing materials together. Thus, we demonstrated the possibility to distinguish each type of gas by applying the patterns to recognition techniques. Full article

There are two dominant and contrasting classes of origin of life scenarios: those predicting that life emerged in submarine hydrothermal systems, where chemical disequilibrium can provide an energy source for nascent life; and those predicting that life emerged within subaerial environments, where UV catalysis of reactions may occur to form the building blocks of life. Here, we describe a prebiotically plausible environment that draws on the strengths of both scenarios: surface hydrothermal vents. We show how key feedstock molecules for prebiotic chemistry can be produced in abundance in shallow and surficial hydrothermal systems. We calculate the chemistry of volcanic gases feeding these vents over a range of pressures and basalt C/N/O contents. If ultra-reducing carbon-rich nitrogen-rich gases interact with subsurface water at a volcanic vent they result in ${10}^{-3}$ – $1\mathrm{M}$ concentrations of diacetylene (C₄H₂), acetylene (C₂H₂), cyanoacetylene (HC₃N), hydrogen cyanide (HCN), bisulfite (likely in the form of salts containing HSO₃⁻), hydrogen sulfide (HS⁻) and soluble iron in vent water. One key feedstock molecule, cyanamide (CH₂N₂), is not formed in significant quantities within this scenario, suggesting that it may need to be delivered exogenously, or formed from hydrogen cyanide either via organometallic compounds, or by some as yet-unknown chemical synthesis. Given the likely ubiquity of surface hydrothermal vents on young, hot, terrestrial planets, these results identify a prebiotically plausible local geochemical environment, which is also amenable to future lab-based simulation. Full article

Gas and vapor transport properties were studied in mixed matrix membranes containing elastomeric ethylene-octene copolymer (EOC or poly(ethylene-co-octene)) with three types of carbon fillers: virgin or oxidized multi-walled carbon nanotubes (CNTs) and carbon fibers (CFs). Helium, hydrogen, nitrogen, oxygen, methane, and carbon dioxide were used for gas permeation rate measurements. Vapor transport properties were studied for the aliphatic hydrocarbon (hexane), aromatic compound (toluene), alcohol (ethanol), as well as water for the representative samples. The mechanical properties and homogeneity of samples was checked by stress-strain tests. The addition of virgin CNTs and CFs improve mechanical properties. Gas permeability of EOC lies between that of the more permeable PDMS and the less permeable semi-crystalline polyethylene and polypropylene. Organic vapors are more permeable than permanent gases in the composite membranes, with toluene and hexane permeabilities being about two orders of magnitude higher than permanent gas permeability. The results of the carbon-filled membranes offer perspectives for application in gas/vapor separation with improved mechanical resistance. Full article