Factors Influencing Gaseous Emissions in Constructed Wetlands: A Meta-Analysis and Systematic Review

Constructed wetlands (CWs) are an eco-technology for wastewater treatment and are applied worldwide. Due to the regular influx of pollutants, CWs can release considerable quantities of greenhouse gases (GHGs), ammonia (NH₃), and other atmospheric pollutants, such as volatile organic compounds (VOCs) and hydrogen sulfide (H₂S), etc., which will aggravate global warming, degrade air quality and even threaten human health. However, there is a lack of systematic understanding of factors affecting the emission of these gases in CWs. In this study, we applied meta-analysis to quantitatively review the main influencing factors of GHG emission from CWs; meanwhile, the emissions of NH₃, VOCs, and H₂S were qualitatively assessed. Meta-analysis indicates that horizontal subsurface flow (HSSF) CWs emit less CH₄ and N₂O than free water surface flow (FWS) CWs. The addition of biochar can mitigate N₂O emission compared to gravel-based CWs but has the risk of increasing CH₄ emission. Polyculture CWs stimulate CH₄ emission but pose no influence on N₂O emission compared to monoculture CWs. The influent wastewater characteristics (e.g., C/N ratio, salinity) and environmental conditions (e.g., temperature) can also impact GHG emission. The NH₃ volatilization from CWs is positively related to the influent nitrogen concentration and pH value. High plant species richness tends to reduce NH₃ volatilization and plant composition showed greater effects than species richness. Though VOCs and H₂S emissions from CWs do not always occur, it should be a concern when using CWs to treat wastewater containing hydrocarbon and acid. This study provides solid references for simultaneously achieving pollutant removal and reducing gaseous emission from CWs, which avoids the transformation of water pollution into air contamination.