Search Results (8)

Numerical simulations reveal the combustion dynamics of hydrogen-blended natural gas (H-BNG) in semi-open spaces. In the typical semi-open space scenario, increasing the hydrogen blending ratio from 0% to 60% elevates peak internal pressure by 107% (259.3 kPa → 526.0 kPa) while reducing pressure rise time by 56.5% (95.8 ms → 41.7 ms). A vent size paradox emerges: 0.5 m openings generate 574.6 kPa internal overpressure, whereas 2 m openings produce 36.7 kPa external overpressure. Flame propagation exhibits stabilized velocity decay (836 m/s → 154 m/s, 81.6% reduction) at hydrogen concentrations ≥30% within 2–8 m distances. In street-front restaurant scenarios, 80% H-BNG leaks reach alarm concentration (0.8 m height) within 120 s, with sensor response times ranging from 21.6 s (proximal) to 40.2 s (distal). Forced ventilation reduces hazard duration by 8.6% (151 s → 138 s), while door status shows negligible impact on deflagration consequences (412 kPa closed vs. 409 kPa open), maintaining consistent 20.5 m hazard radius at 20 kPa overpressure threshold. These findings provide crucial theoretical insights and practical guidance for the prevention and management of H-BNG leakage and explosion incidents. Full article

The natural combustion of underground coal seams leads to the formation of gas, which contains molecular hydrogen and carbon monoxide. In places where hot coal gases are released to the surface, specific thermal ecosystems are formed. Here, 16S rRNA gene profiling and shotgun metagenome sequencing were employed to characterize the taxonomic diversity and genetic potential of prokaryotic communities of the near-surface ground layer near hot gas vents in an open quarry heated by a subsurface coal fire. The communities were dominated by only a few groups of spore-forming Firmicutes, namely the aerobic heterotroph Candidatus Carbobacillus altaicus, the aerobic chemolitoautotrophs Kyrpidia tusciae and Hydrogenibacillus schlegelii, and the anaerobic chemolithoautotroph Brockia lithotrophica. Genome analysis predicted that these species can obtain energy from the oxidation of hydrogen and/or carbon monoxide in coal gases. We assembled the first complete closed genome of a member of uncultured class-level division DTU015 in the phylum Firmicutes. This bacterium, ‘Candidatus Fermentithermobacillus carboniphilus’ Bu02, was predicted to be rod-shaped and capable of flagellar motility and sporulation. Genome analysis showed the absence of aerobic and anaerobic respiration and suggested chemoheterotrophic lifestyle with the ability to ferment peptides, amino acids, N-acetylglucosamine, and tricarboxylic acid cycle intermediates. Bu02 bacterium probably plays the role of a scavenger, performing the fermentation of organics formed by autotrophic Firmicutes supported by coal gases. A comparative genome analysis of the DTU015 division revealed that most of its members have a similar lifestyle. Full article

In a volcanic area, the composition of air is influenced by the interaction between fluids generated from many different environments (magmatic, hydrothermal, meteoric, and marine). Any physical and chemical variation in one of these subsystems is able to modify the outgassing dynamic. The increase of natural gas hazard, related to the presence of unhealthy components in air, may depend on temporary changes both in the pressure and chemical gradients that generate transient fluxes of gases and can have many different causes. Sometimes, the content of unhealthy gases approaches unexpected limits, without clear warning. In this case, an altered composition of the air can be only revealed after accurate sampling procedures and laboratory analysis. The investigations presented here are a starting point to response to the demand for a new monitoring program in the touristic area of Baia di Levante at Vulcano Island (Aeolian archipelago, Italy). Three multiparametric geochemical surveys were carried in the touristic area of Baia di Levante at Vulcano Island (Aeolian archipelago, Italy) in 2011, 2014, and 2015. Carbon dioxide (CO₂) and hydrogen sulfide (H₂S) are the main undesired components, usually present at the local scale. Anomalous CO₂ and H₂S outputs from soil and submarine bubbling vents were identified; the thermal anomaly of the ground was mapped; atmospheric concentrations of CO₂ and H₂S were measured in the air 30 cm above the ground surface. Atmospheric concentrations above the suggested limits for the wellbeing of human health were retrieved in open areas where tourists stay and where CO₂ can accumulate under absence of wind. Full article

Serpentinization produces molecular hydrogen (H₂) and hydrocarbons that can feed the colonies of microbes in hydrothermal vent fields, and therefore serpentinization may be important for the origins of life. However, the mechanisms that control molecular hydrogen (H₂) production during serpentinization remain poorly understood. Here the effect of pyroxene minerals and spinel on molecular hydrogen (H₂) generation during serpentinization is experimentally studied at 311–500 °C and 3.0 kbar, where olivine, individually and in combinations with pyroxene and/or spinel, is reacted with saline solutions (0.5 M NaCl). The results show a contrasting influence of spinel and pyroxeneon molecular hydrogen (H₂) production. At 311 °C and 3.0 kbar, spinel promotes H₂ generation by around two times, and pyroxene minerals decrease molecular hydrogen (H₂) production by around one order of magnitude. Spinel leaches aluminum (Al) and chromium (Cr) during hydrothermal alteration, and Al and Cr enhance molecular hydrogen (H₂) production. This is confirmed by performing experiments on the serpentinization of olivine with the addition of Al₂O₃ or Cr₂O₃ powders, and an increase in molecular hydrogen (H₂) production was observed. Pyroxene minerals, however, not only leach Al and Cr, but they also release silica (SiO₂) during serpentinization. The sharp decline in molecular hydrogen (H₂) production in experiments with a combination of olivine and pyroxene minerals may be attributed to releases of silica from pyroxene minerals. With increasing temperatures (e.g., 400–500 °C), the effect of spinel and pyroxene minerals on molecular hydrogen (H₂) production is much less significant, which is possibly related tothe sluggish kinetics of olivine serpentinization under these T-P conditions. In natural geological settings, olivine is commonly associated with spinel and pyroxene, and molecular hydrogen (H₂) during serpentinization can be greatly affected. Full article

We report a natural wind cycle, the Antarctic Centennial Wind Oscillation (ACWO), whose properties explain milestones of climate and human civilization, including contemporary global warming. We explored the wind/temperature relationship in Antarctica over the past 226 millennia using dust flux in ice cores from the European Project for Ice Coring in Antarctica (EPICA) Dome C (EDC) drill site as a wind proxy and stable isotopes of hydrogen and oxygen in ice cores from EDC and ten additional Antarctic drill sites as temperature proxies. The ACWO wind cycle is coupled 1:1 with the temperature cycle of the Antarctic Centennial Oscillation (ACO), the paleoclimate precursor of the contemporary Antarctic Oscillation (AAO), at all eleven drill sites over all time periods evaluated. Such tight coupling suggests that ACWO wind cycles force ACO/AAO temperature cycles. The ACWO is modulated in phase with the millennial-scale Antarctic Isotope Maximum (AIM) temperature cycle. Each AIM cycle encompasses several ACWOs that increase in frequency and amplitude to a Wind Terminus, the last and largest ACWO of every AIM cycle. This historic wind pattern, and the heat and gas exchange it forces with the Southern Ocean (SO), explains climate milestones including the Medieval Warm Period and the Little Ice Age. Contemporary global warming is explained by venting of heat and carbon dioxide from the SO forced by the maximal winds of the current positive phase of the ACO/AAO cycle. The largest 20 human civilizations of the past four millennia collapsed during or near the Little Ice Age or its earlier recurrent homologs. The Eddy Cycle of sunspot activity oscillates in phase with the AIM temperature cycle and therefore may force the internal climate cycles documented here. Climate forecasts based on the historic ACWO wind pattern project imminent global cooling and in ~4 centuries a recurrent homolog of the Little Ice Age. Our study provides a theoretically-unified explanation of contemporary global warming and other climate milestones based on natural climate cycles driven by the Sun, confirms a dominant role for climate in shaping human history, invites reconsideration of climate policy, and offers a method to project future climate. Full article

Hydrogen cyanide (HCN)-derived polymers have been recognized as sources of relevant organic molecules in prebiotic chemistry and material sciences. However, there are considerable gaps in the knowledge regarding the polymeric nature, the physicochemical properties, and the chemical pathways along polymer synthesis. HCN might have played an important role in prebiotic hydrothermal environments; however, only few experiments use cyanide species considering hydrothermal conditions. In this work, we synthesized an HCN-derived thermal polymer simulating an alkaline hydrothermal environment (i.e., HCN (l) 0.15 M, 50 h, 100 °C, pH approximately 10) and characterized its chemical structure, thermal behavior, and the hydrolysis effect. Elemental analysis and infrared spectroscopy suggest an important oxidation degree. The thermal behavior indicates that the polymer is more stable compared to other HCN-derived polymers. The mass spectrometric thermal analysis showed the gradual release of several volatile compounds along different thermal steps. The results suggest a complicate macrostructure formed by amide and hydroxyl groups, which are joined to the main reticular chain with conjugated bonds (C=O, N=O, –O–C=N). The hydrolysis treatment showed the pH conditions for the releasing of organics. The study of the synthesis of HCN-derived thermal polymers under feasible primitive hydrothermal conditions is relevant for considering hydrothermal vents as niches of chemical evolution on early Earth. Full article

Proterozoic sedimentary basins very often emit natural hydrogen gas that may be a valuable part of a non-carbon energy infrastructure. Vents in the Sao Francisco Basin in Brazil release hydrogen to the atmosphere mainly during the daylight half of the day. Daily temperature and the regular daily tidal atmospheric pressure variations have been suggested as possible causes of the pulsing of H₂ venting. Here, we analyze a ~550 m-diameter depression that is barren of vegetation and venting hydrogen mainly at its periphery. We show that daily temperature changes propagated only ~1/2 m into the subsurface and are thus too shallow to explain the H₂ variations measured at 1-m depth. Pressure changes could propagate deeply enough, and at the depth at which the cyclic variations are measured hydrogen concentration will have the observed phase relationship to atmospheric pressure changes provided: (1) the pressure wave is terminated by geologic barriers at about 25% of its full potential penetration distance, and (2) the volume of gas in the vents is very small compared to the volume of gas tapped by the venting. These constraints suggest that there is a shallow gas reservoir above the water table under the ~550 m-diameter barren-of-vegetation depression. The 1D-analytical and finite-element calculations presented in this paper help define the hydrogen system and suggest the further steps needed to characterize its volume, hydrogen flux and resource potential. Full article

Rock–water–carbon interactions germane to serpentinization in hydrothermal vents have occurred for over 4 billion years, ever since there was liquid water on Earth. Serpentinization converts iron(II) containing minerals and water to magnetite (Fe₃O₄) plus H₂. The hydrogen can generate native metals such as awaruite (Ni₃Fe), a common serpentinization product. Awaruite catalyzes the synthesis of methane from H₂ and CO₂ under hydrothermal conditions. Native iron and nickel catalyze the synthesis of formate, methanol, acetate, and pyruvate—intermediates of the acetyl-CoA pathway, the most ancient pathway of CO₂ fixation. Carbon monoxide dehydrogenase (CODH) is central to the pathway and employs Ni⁰ in its catalytic mechanism. CODH has been conserved during 4 billion years of evolution as a relic of the natural CO₂-reducing catalyst at the onset of biochemistry. The carbide-containing active site of nitrogenase—the only enzyme on Earth that reduces N₂—is probably also a relic, a biological reconstruction of the naturally occurring inorganic catalyst that generated primordial organic nitrogen. Serpentinization generates Fe₃O₄ and H₂, the catalyst and reductant for industrial CO₂ hydrogenation and for N₂ reduction via the Haber–Bosch process. In both industrial processes, an Fe₃O₄ catalyst is matured via H₂-dependent reduction to generate Fe₅C₂ and Fe₂N respectively. Whether serpentinization entails similar catalyst maturation is not known. We suggest that at the onset of life, essential reactions leading to reduced carbon and reduced nitrogen occurred with catalysts that were synthesized during the serpentinization process, connecting the chemistry of life and Earth to industrial chemistry in unexpected ways. Full article