Search Results (618)

Mining activity in Peru generates environmental liabilities with the potential to release toxic metals into the environment. This study conducted a comprehensive physical, chemical, mineralogical, and toxicological characterization of ten active and inactive tailings samples from the Arequipa region in southern Peru. Particle size distribution analysis, inductively coupled plasma atomic emission spectroscopy (ICP-AES), scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and the Toxicity Characteristic Leaching Procedure (TCLP) followed by ICP-MS were employed. The results revealed variable particle size distributions, with the sample of Secocha exhibiting the finest granulometry. Chemically, 8 out of 10 samples exhibited concentrations of at least two metals surpassing the Peruvian Environmental Quality Standards (EQS) for soils with values reaching >6000 mg/kg of arsenic (Paraiso), 193.1 mg/kg of mercury (Mollehuaca), and 2309 mg/kg of zinc (Paraiso). Mineralogical analysis revealed the presence of sulfides such as arsenopyrite, cinnabar, galena, and sphalerite, along with uraninite in the Otapara sample. In the TCLP tests, 5 out of 10 samples released at least two metals exceeding the environmental standards on water quality, with concentrations up to 0.401 mg/L for mercury (Paraiso), 0.590 mg/L for lead (Paraiso), and 9.286 mg/L for zinc (Kiowa Cobre). These results demonstrate elevated levels of Potentially Toxic Elements (PTEs) in both solid and dissolved states, reflecting a critical geochemical risk in the evaluated areas. Full article

The increasing demand for sustainable practices in road construction has prompted the search for environmentally friendly and cost-effective materials. This study explores the incorporation of reclaimed asphalt pavement (RAP) and Panasqueira mine waste (greywacke aggregates) as full replacements for virgin aggregates in hot mix asphalt (HMA), aligning with the objectives of UN Sustainable Development Goal 9. Three asphalt mixtures were prepared: a reference mixture (MR) with granite aggregates, and two modified mixtures (M15 and M20) with 15% and 20% RAP, respectively. All mixtures were evaluated through Marshall stability, stiffness modulus, water sensitivity, and wheel tracking tests. The results demonstrated that mixtures containing RAP and mine waste met Portuguese specifications for surface courses. Specifically, the M20 mixture showed the highest stiffness modulus, improved moisture resistance, and the best performance against permanent deformation. These improvements are attributed to the presence of stiff aged binder in RAP and the mechanical characteristics of the greywacke aggregates. Overall, the findings confirm that the combined use of RAP and mining waste provides a technically viable and sustainable alternative for asphalt pavement construction, contributing to resource efficiency and circular economy goals. Full article

Cement–Soil Mixing (CSM) Pile is an important technology for soft ground reinforcement, and its as-formed compressive strength directly affects engineering design and construction quality. To address the significant discrepancy between laboratory-tested strength and field as-formed strength arising from differing environmental conditions, this study conducted modified laboratory experiments simulating key field formation characteristics. A cement–soil preparation system considering actual immersion conditions was established, based on controlling the initial water content state of the foundation soil before pile formation and applying submerged conditions post-formation. Utilizing data mining on 84 sets of experimental data with various preparation parameter combinations, a prediction model for the as-formed strength of CSM Pile was developed based on the Particle Swarm Optimization-Extreme Gradient Boosting (PSO-XGBoost) algorithm. Engineering validation demonstrated that the model achieved an RMSE of 0.138, an MAE of 0.112, and an R² of 0.961. It effectively addresses the issue of large prediction deviations caused by insufficient environmental simulation in traditional mix proportion tests. The research findings establish a quantitative relationship between as-formed strength and preparation parameters, providing an effective experimental improvement and strength prediction method for the engineering design of CSM Pile. Full article

This study evaluates the potential health risks posed by geogenic arsenic in environments suitable for leisure activities, such as walking, bathing, and playing, for adults and children alike, as well as in neighbouring agricultural areas. The study includes an analysis of environmental characteristics and the main stream originating in the adjacent mining area, with water and sediment samples taken. The study area is representative of other areas in the vicinity of the Mar Menor Lagoon, which is one of the largest and most biodiverse coastal lagoons in the Mediterranean Sea. The general characteristics of the soil and water were determined for this study, as was the concentration of As in the soil and water samples. A granulometric separation was carried out into four different fractions (<2 mm, <250 µm, <100 µm, and <65 µm). The mineralogical composition, total As content, and bioaccessible As content are analysed in each of these fractions. This provides data with which to calculate the danger of arsenic (As) to human health by ingestion and to contribute to As bioaccessibility studies and the role played by the mineralogical composition and particle size of soil ingestion. The conclusions rule out residential use of this environment, although they allow for eventual tourist use and traditional agricultural use of the surrounding soils. Full article

To study hydrogeological characteristics after the occurrence of abnormal water bursts from the weak water-rich (permeable) aquifer of the Changxing Formation limestone overlying deep working faces during production in Guizhou karst landform mining areas, hydrogeological data covering the exploration and production periods of the Xinhua mining region in Jinsha County, Guizhou Province, were collected. On the basis of surface and underground drilling, geophysical exploration techniques, empirical equations, and indoor material simulation methods, the hydrogeological evolution characteristics of the Changxing Formation limestone in the mining region after mining damage to coalbed 9 were studied. The research results indicated that the ratio of the height of the roof failure fracture zone (as obtained via numerical simulation and ground borehole detection) to the mining height exceeded 25.78, which is far greater than the empirical model calculation values (from 13.0 to 15.8). After mining the underlying coalbed 9, an abnormal water-rich area developed in the Changxing Formation limestone, and mining damage fractures led to the connection of the original dissolution fissures and karst caves within the limestone, resulting in the weak water-rich (permeable) aquifer of the Changxing Formation limestone becoming a strong water-rich (permeable) aquifer, which served as the water source for mine water bursts. Over time, after mining damage occurrence, the voids in the Changxing Formation limestone were gradually filled with various substances, yielding water storage space and connectivity decreases. The specific yield decreased with an increasing water burst time and interval after the cessation of mining in the supply area, and the correlation coefficient R was 0.964, indicating a high degree of correlation between the two parameters. Full article

The prevention and control of mine inrush water has always been a major challenge for safety. By identifying the type of water source and analyzing the real-time changes in water composition, sudden water inrush accidents can be monitored in a timely manner to avoid major accidents. This paper proposes a novel explainable machine learning model for source type identification of mine inrush water. The paper expands the original monitoring system into the XinJi No.2 Mine in Huainan Mining Area. Based on the online water composition data, using the Spearman coefficient formula, it analyzes the water chemical characteristics of different aquifers to extract key discriminant factors. Then, the Conv1D-GRU model was built to deeply connect factors for precise water source identification. The experimental results show an accuracy rate of 85.37%. In addition, focused on the interpretability, the experiment quantified the impact of different features on the model using SHAP (Shapley Additive Explanations). It provides new reference for the source type identification of mine inrush water in mine disaster prevention and control. Full article

The applicability of the in-situ pyrolysis of oil-rich coal is highly dependent on regional geological conditions. In this study, six major geological factors and 19 key parameters influencing the in-situ pyrolysis of oil-rich coal were systematically identified. An analytic hierarchy process incorporating index classification and quantification was employed in combination with the geological features of the Tiaohu mining area to establish a feasibility evaluation index system suitable for in-situ development in the study region. Among these factors, coal quality parameters (e.g., coal type, moisture content, volatile matter, ash yield), coal seam occurrence characteristics (e.g., seam thickness, burial depth, interburden frequency), and hydrogeological conditions (e.g., relative water inflow) primarily govern pyrolysis process stability. Surrounding rock properties (e.g., roof/floor lithology) and structural features (e.g., fault proximity) directly impact pyrolysis furnace sealing integrity, while environmental geological factors (e.g., hazardous element content in coal) determine environmental risk control effectiveness. Based on actual geological data from the Tiaohu mining area, the comprehensive weight of each index was determined. After calculation, the southwestern, central, and southeastern subregions of the mining area were identified as favorable zones for pyrolysis development. A constraint condition analysis was then conducted, accompanied by a one-vote veto index system, in which the thresholds were defined for coal seam thickness (≥1.5 m), burial depth (≥500 m), thickness variation coefficient (≤15%), fault proximity (≥200 m), tar yield (≥7%), high-pressure permeability (≥10 mD), and high-pressure porosity (≥15%). Following the exclusion of unqualified boreholes, three target zones for pyrolysis furnace deployment were ultimately selected. Full article

In mining areas with high groundwater levels, intensive coal mining has led to the accumulation of substantial surface water and significant alterations in regional landscape patterns. Reconstructing the ecological security pattern (ESP) has emerged as a critical focus for ecological restoration in coal mining subsidence areas with high groundwater levels. This study employed the patch-generating land use simulation (PLUS) model to predict the landscape evolution trend of the study area in 2032 under three scenarios, combining environmental characteristics and disturbance features of coal mining subsidence areas with high groundwater levels. In order to determine the differences in ecological network changes within the study area under various development scenarios, morphological spatial pattern analysis (MSPA) and landscape connectivity analysis were employed to identify ecological source areas and establish ecological corridors using circuit theory. Based on the simulation results of the optimal development scenario, potential ecological pinch points and ecological barrier points were further identified. The findings indicate that: (1) land use changes predominantly occur in urban fringe areas and coal mining subsidence areas. In the land reclamation (LR) scenario, the reduction in cultivated land area is minimal, whereas in the economic development (ED) scenario, construction land exhibits a marked increasing trend. Under the natural development (ND) scenario, forest land and water expand most significantly, thereby maximizing ecological space. (2) Under the ND scenario, the number and distribution of ecological source areas and ecological corridors reach their peak, leading to an enhanced ecological network structure that positively contributes to corridor improvement. (3) By comparing the ESP in the ND scenario in 2032 with that in 2022, the number and area of ecological barrier points increase substantially while the number and area of ecological pinch points decrease. These areas should be prioritized for ecological protection and restoration. Based on the scenario simulation results, this study proposes a planning objective for a “one axis, four belts, and four zones” ESP, along with corresponding strategies for ecological protection and restoration. This research provides a crucial foundation for decision-making in enhancing territorial space planning in coal mining subsidence areas with high groundwater levels. Full article

Sustainability in the construction sector has become a fundamental objective for mitigating escalating environmental challenges; given that concrete is the most widely used man-made material, extending its service life is therefore critical. Among durability concerns, magnesium sulfate (MgSO₄) attack is particularly deleterious to concrete structures. Therefore, this study investigates the short- and long-term performance of concrete produced with copper slag (CS)—a massive waste generated by copper mining activities worldwide—employed as a supplementary cementitious material (SCM), together with recycled coarse aggregate (RCA), obtained from concrete construction and demolition waste, when exposed to MgSO₄. CS was used as a 15 vol% cement replacement, while RCA was incorporated at 0%, 20%, 50%, and 100 vol%. Compressive strength, bulk density, water absorption, and porosity were measured after water curing (7–388 days) and following immersion in a 5 wt.% MgSO₄ solution for 180 and 360 days. Microstructural characteristics were assessed using scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis with its differential thermogravimetric derivative (TG-DTG), and Fourier transform infrared spectroscopy (FTIR) techniques. The results indicated that replacing 15% cement with CS reduced 7-day strength by ≤10%, yet parity with the reference mix was reached at 90 days. Strength losses increased monotonically with RCA content. Under MgSO₄ exposure, all mixtures experienced an initial compressive strength gain during the short-term exposures (28–100 days), attributed to the pore-filling effect of expansive sulfate phases. However, at long-term exposure (180–360 days), a clear strength decline was observed, mainly due to internal cracking, brucite formation, and the transformation of C–S–H into non-cementitious M–S–H gel. Based on these findings, the combined use of CS and RCA at low replacement levels shows potential for producing environmentally friendly concrete with mechanical and durability performance comparable to those of concrete made entirely with virgin materials. Full article

Underground pumped storage hydropower stations (UPSH) are of great significance for energy structure adjustment, and coal mine underground reservoirs are an integral part of UPSH. This study investigates the fracture mechanics behavior of coal in mine water immersion environments with varying loading rates and layer direction. Three types of samples were analyzed: Crack-arrester, Crack-splitter, and Crack-divider types. The immersion duration extended up to 120 days. The results indicate that, after immersion in mine water for 120 days, the fracture toughness (K_IC), fracture modulus (E_S), and absorbed energy (U_T) of coal decreased by 60.87%, 53.38%, and 63.21%, respectively, compared to the unsaturated coal samples. An immersion period of 30 days significantly weakens the mechanical properties of coal fractures. The K_IC, E_S, and U_T of coal demonstrate a positive correlation with loading rate, primarily influenced by the duration of coal damage. At the same loading rate, the order of fracture toughness among the three coal types is as follows: Crack-divider > Crack-arrester > Crack-splitter. This hierarchy is determined by the properties of the coal matrix and bedding planes, as well as the mechanical structures composed of them. This study holds significant implications for the safe construction and operational design of underground water reservoirs in coal mines. Full article

With the large-scale closure of coal mines leading to groundwater pollution, in order to systematically identify the sources of major chemical ions in surface water and groundwater. This study comprehensively applied methods such as Piper’s trilinear diagram, linear fitting, and correlation analysis to quantitatively analyze the hydrochemical characteristics of closed coal mining areas in southwest Shandong and to clarify the sources of geochemical components in surface water and groundwater, and the PMF model was used to analyze the sources of chemical components in mine water and karst water. The results show that the concentrations of TDS ( Total Dissolved Solids), SO₄²⁻, Fe, and Mn in the mine water of the closed coal mine area are higher than in the karst water. Both water bodies are above groundwater quality standards. Ca²⁺, SO₄²⁻, and HCO₃⁻ dominate the ionic components in surface water and different types of groundwater. The hydrochemical types of surface, pore, and mine waters are mainly SO₄-HCO₃-Ca, whereas SO₄-HCO₃-Ca and HCO₃-SO₄-Ca dominate karst waters. SO₄²⁻ is the leading ion in the TDS of water bodies. The mineralization process of surface water is mainly controlled by the weathering of silicate minerals, while that of the groundwater is mainly controlled by the dissolution of carbonate minerals. The impact of mining activities on surface water and groundwater is significant, while the impact of agricultural activities on surface water and groundwater is relatively small. The degree of impact of coal mining activities on SO₄²⁻ concentrations in surface water, pore water, and karst water, in descending order, is karst water, surface water, and pore water. The PMF (Positive Matrix Factorization) model analysis results indicate that dissolution of carbonate minerals with sulphate and oxidation dissolution of sulfide minerals are the main sources of chemical constituents in mine waters. Carbonate dissolution, oxidation dissolution of sulfide minerals, domestic sewage, and dissolution of carbonate minerals with sulphate are ranked as the main sources of chemical constituents in karst water from highest to lowest. These findings provide a scientific basis for the assessment and control of groundwater pollution in the areas of closed coal mines. Full article

Sulfate as a potential pollution source in the water environment of the basin, identifying sulfate sources and migration mechanisms is essential for protecting the water environment and ensuring sustainable water management. Liuyang River is a primary tributary of the Xiangjiang River. It has experienced progressively intensifying anthropogenic influences in recent decades, manifested by sustained sulfate concentration increases. However, the sulfate sources and their contributions were not clear. This study used hydrochemistry and multi-isotopes methods combined with Simmr model to study the hydrochemical characteristics, sulfate sources, and migration–transformation processes of surface water and groundwater. The results showed that the hydrochemical types of surface water were HCO₃-Ca and HCO₃·SO₄-Ca·Mg, and groundwater were HCO₃-Ca, HCO₃-Ca·Mg, and HCO₃·SO₄-Ca. Ions in the water primarily originated from carbonate and silicate rocks dissolution and sulfide oxidation, augmented by mining operations, sewage discharge, and chemical production. The analyses of hydrochemistry, isotopes, and Simmr model revealed that surface water sulfate originated from soil sulfate (35.70%), sulfide oxidation (26.56%), sewage (16.58%), and atmospheric precipitation (12.45%). Groundwater sulfate was derived predominantly from sewage (34.96%), followed by soil sulfate (28.09%), atmospheric precipitation (17.35%), and sulfide oxidation (12.25%). Sulfate migration and transformation were controlled by the natural environment and anthropogenic impacts. When unaffected by human activities, sulfate mainly originated from soil and atmospheric precipitation, relating to topography, geological conditions, agricultural activities, and precipitation intensity. However, in regions with intense human activities, contributions from sewage and sulfide oxidation significantly increased due to the influences of mining and industrial activities. Full article

As China’s primary grain-producing area, the Luxi Plain is rich in groundwater resources, which serves as the main water supply source in this region. Investigating the evolution of hydrochemical characteristics and influencing factors of groundwater in this region is crucial for maintaining the safety of groundwater quality and ensuring the high-quality development of the water supply. This study took Liaocheng City in the hinterland of the Luxi Plain as the study area. To clarify the hydrochemical characteristics evolution trend of groundwater in the area, the hydrochemical characteristics of shallow groundwater in recent years were systematically analyzed. The methods of ion ratio, correlation analysis, Gibbs and Gaillardet endmember diagrams, as well as the application of the absolute principal component scores–multiple linear regression (APCS-MLR) receptor model were used to determine the contribution rates of different ion sources to groundwater and to elucidate the driving factors behind the evolution of groundwater chemistry. Results showed significant spatiotemporal variations in the concentrations of major ions such as Na⁺, SO₄²⁻, and Cl⁻ in groundwater in the study area, and these variations demonstrated an overall increasing trend. Notably, the increases in total hardness (THRD), SO₄⁻, and Cl⁻ concentrations were particularly pronounced, while the variations in Na⁺, Mg²⁺, Ca²⁺ and other ions were relatively gradual. APCS-MLR receptor model analysis revealed that the ions such as Na⁺, Ca²⁺, Mg²⁺, SO₄²⁻, Cl⁻, HCO₃⁻ and NO₃⁻ all have a significant influence on the hydrochemical composition of groundwater due to the high absolute principal component scores of them. The hydrochemical characteristics of groundwater in the study area were controlled by multiple processes, including evaporites, silicates and carbonates weathering, evaporation-concentration, cation alternating adsorption and human activities. Among the natural driving factors, rock weathering had a greater influence on the evolution of groundwater hydrochemical characteristics. Moreover, mining activities were the most important anthropogenic factor, followed by agricultural activities and living activities. Full article

Unveiling the relationship between the “Water–Carbon–Ecology” (W-C-E) footprints embodied in regional trade and resource flows is crucial for enhancing the synergistic benefits between economic development and environmental protection. This study constructs an association framework based on the Multi-Regional Input–Output (MRIO) model to systematically evaluate the “W-C-E” footprints and resource flow characteristics of the Yangtze River Economic Belt and the Yellow River Basin. By integrating import and export trade data, this study reveals the patterns of resource flows within and outside these regions. This research delineates the connection patterns between the “W-C-E” footprints and resource flows across three dimensions: spatial, sectoral, and environmental–economic factors. The results indicate that the Yangtze River Economic Belt has gained significant economic benefits from regional trade but also bears substantial environmental costs. Import and export trade further exacerbate the imbalance in regional resource flows, with the Yangtze River Economic Belt exporting many embodied resources through high-energy-consuming products, while the Yellow River Basin increases resource input by importing products such as food and tobacco. Sectoral analysis reveals that agriculture, electricity and water supply, and mining are the sectors with the highest net output of “W-C-E” footprints in both regions, whereas services, food and tobacco, and construction are the sectors with the highest net input. The comprehensive framework of this study can be extended to the analysis of resource–environment–economic systems in other regions, providing methodological support for depicting complex human–land system linkage patterns. Full article

The overtopping-induced lateral erosion breaching of tailings dams represents a critical disaster mechanism threatening structural safety, particularly in reinforced fine-grained tailings dams where erosion behaviors demonstrate pronounced water–soil coupling characteristics and material anisotropy. Through physical model tests and numerical simulations, this study systematically investigates lateral erosion failure patterns of reinforced fine-grained tailings under overtopping flow conditions. Utilizing a self-developed hydraulic initiation test apparatus, with aperture sizes of reinforced geogrids (2–3 mm) and flow rates (4–16 cm/s) as key control variables, the research elucidates the interaction mechanisms of “hydraulic scouring-particle migration-geogrid anti-sliding” during lateral erosion processes. The study revealed that compared to unreinforced specimens, reinforced specimens with varying aperture sizes (2–3 mm) demonstrated systematic reductions in final lateral erosion depths across flow rates (4–16 cm/s): 3.3–5.8 mm (15.6−27.4% reduction), 3.1–7.2 mm (12.8–29.6% reduction), 2.3–11 mm (6.9–32.8% reduction), and 2.5–11.4 mm (6.2–28.2% reduction). Smaller-aperture geogrids (2 mm × 2 mm) significantly enhanced anti-erosion performance through superior particle migration inhibition. Concurrently, a pronounced positive correlation between flow rate and lateral erosion depth was confirmed, where increased flow rates weakened particle erosion resistance and exacerbated lateral erosion severity. The numerical simulation results are in basic agreement with the lateral erosion failure process observed in model tests, revealing the dynamic process of lateral erosion in the overtopping breach of a reinforced tailings dam. These findings provide critical theoretical foundations for optimizing reinforced tailings dam design, construction quality control, and operational maintenance, while offering substantial engineering applications for advancing green mine construction. Full article