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1,827 Results Found

  • Feature Paper
  • Review
  • Open Access
92 Citations
15,810 Views
44 Pages

Metal–Organic Frameworks (MOFs) and Covalent Organic Frameworks (COFs) Applied to Photocatalytic Organic Transformations

  • Alberto López-Magano,
  • Alicia Jiménez-Almarza,
  • Jose Alemán and
  • Rubén Mas-Ballesté

27 June 2020

Among the different alternatives for catalysis using metal–organic frameworks (MOFs) or covalent organic frameworks (COFs), photocatalysis has remarkably evolved during the last decade. Photocatalytic reticular materials allowed recyclability a...

  • Review
  • Open Access
3 Citations
4,456 Views
35 Pages

Advances in Metal-Organic Frameworks (MOFs) for Rechargeable Batteries and Fuel Cells

  • Christos Argirusis,
  • Niyaz Alizadeh,
  • Maria-Εleni Katsanou,
  • Nikolaos Argirusis and
  • Georgia Sourkouni

The growing demand for energy, coupled with the unsustainable nature of fossil fuels due to global warming and the greenhouse effect, have led to the advancement of renewable energy production concepts. Innovations such as photovoltaics, wind energy,...

  • Review
  • Open Access
58 Citations
17,474 Views
29 Pages

Copper-Based Metal–Organic Frameworks (MOFs) as an Emerging Catalytic Framework for Click Chemistry

  • Riddima Singh,
  • Gurleen Singh,
  • Nancy George,
  • Gurjaspreet Singh,
  • Sofia Gupta,
  • Harminder Singh,
  • Gurpreet Kaur and
  • Jandeep Singh

6 January 2023

In the extensive terrain of catalytic procedures for the synthesis of organic molecules, metal–organic frameworks (MOFs) as heterogenous catalysts have been investigated in a variety of chemical processes, including Friedel–Crafts reactio...

  • Review
  • Open Access
59 Citations
12,399 Views
31 Pages

Fe-Based Metal Organic Frameworks (Fe-MOFs) for Bio-Related Applications

  • Rongyue Zhu,
  • Mengru Cai,
  • Tingting Fu,
  • Dongge Yin,
  • Hulinyue Peng,
  • Shilang Liao,
  • Yuji Du,
  • Jiahui Kong,
  • Jian Ni and
  • Xingbin Yin

Metal–organic frameworks (MOFs) are porous materials composed of metal ions and organic ligands. Due to their large surface area, easy modification, and good biocompatibility, MOFs are often used in bio-related fields. Fe-based metal–orga...

  • Article
  • Open Access
2 Citations
2,761 Views
10 Pages

Synthesis and Characterization of Highly Fluorinated Hydrophobic Rare–Earth Metal–Organic Frameworks (MOFs)

  • Muhammad Abbas,
  • Bhargavasairam Murari,
  • Simin Sheybani,
  • Monu Joy and
  • Kenneth J. Balkus

26 August 2024

Tuning a material’s hydrophobicity is desirable in several industrial applications, such as hydrocarbon storage, separation, selective CO2 capture, oil spill cleanup, and water purification. The introduction of fluorine into rare-earth (RE) met...

  • Article
  • Open Access
18 Citations
2,848 Views
14 Pages

16 February 2024

For hydrogen-powered vehicles, the efficiency cost brought about by the current industry choices of hydrogen storage methods greatly reduces the system’s overall efficiency. The physisorption of hydrogen fuel onto metal–organic frameworks...

  • Article
  • Open Access
15 Citations
3,337 Views
20 Pages

Microwave-Responsive Metal-Organic Frameworks (MOFs) for Enhanced In Vitro Controlled Release of Doxorubicin

  • Syeda Fiza Fatima,
  • Rana Sabouni,
  • Ghaleb Husseini,
  • Vinod Paul,
  • Hassan Gomaa and
  • Remya Radha

24 June 2024

Metal-organic frameworks (MOFs) are excellent candidates for a range of applications because of their numerous advantages, such as high surface area, porosity, and thermal and chemical stability. In this study, microwave (MW) irradiation is used as a...

  • Review
  • Open Access
17 Citations
5,584 Views
27 Pages

20 February 2023

Decarbonization has become an urgent affair to restrain global warming. CO2 hydrogenation coupled with H2 derived from water electrolysis is considered a promising route to mitigate the negative impact of carbon emission and also promote the applicat...

  • Article
  • Open Access
9 Citations
3,456 Views
22 Pages

Investigation of the Sensing Properties of Lanthanoid Metal–Organic Frameworks (Ln-MOFs) with Terephthalic Acid

  • Denitsa Elenkova,
  • Yana Dimitrova,
  • Martin Tsvetkov,
  • Bernd Morgenstern,
  • Maria Milanova,
  • Dimitar Todorovsky and
  • Joana Zaharieva

5 August 2024

The solvothermal synthesis of LnCl3.nH2O with terephthalic acid (benzene-1,4-dicarboxylic acid, H2BDC) produced metal–organic frameworks (LnBDC), [Ln2(BDC)3(H2O)4]∞, where Ln = Sm, Eu, Tb, and Dy. The materials obtained were characterized...

  • Review
  • Open Access
318 Citations
27,606 Views
53 Pages

21 April 2014

Metal-organic frameworks (MOFs) are a new class of microporous materials that possess framework flexibility, large surface areas, “tailor-made” framework functionalities, and tunable pore sizes. These features empower MOFs superior performances and b...

  • Review
  • Open Access
4 Citations
5,004 Views
37 Pages

2 August 2025

Metal–Organic Frameworks (MOFs) have emerged as advanced porous crystalline materials due to their highly ordered structures, ultra-high surface areas, fine-tunable pore sizes, and massive chemical diversity. These features, arising from the co...

  • Review
  • Open Access
5 Citations
3,606 Views
20 Pages

30 November 2024

Boron nitride nanostructures (BNNs), including nanotubes, nanosheets, and nanoribbons, are renowned for their exceptional thermal stability, chemical inertness, mechanical strength, and high surface area, making them suitable for advanced material ap...

  • Review
  • Open Access
19 Citations
7,590 Views
39 Pages

The ability to measure and monitor the concentration of specific chemical and/or gaseous species (i.e., “analytes”) is the main requirement in many fields, including industrial processes, medical applications, and workplace safety managem...

  • Perspective
  • Open Access
89 Citations
8,066 Views
10 Pages

Metal–Organic Frameworks (MOFs) for Cancer Therapy

  • Mohammad Reza Saeb,
  • Navid Rabiee,
  • Masoud Mozafari,
  • Francis Verpoort,
  • Leonid G. Voskressensky and
  • Rafael Luque

28 November 2021

MOFs exhibit inherent extraordinary features for diverse applications ranging from catalysis, storage, and optics to chemosensory and biomedical science and technology. Several procedures including solvothermal, hydrothermal, mechanochemical, electro...

  • Review
  • Open Access
153 Citations
19,137 Views
16 Pages

Metal-Organic Framework (MOF)/Epoxy Coatings: A Review

  • Farzad Seidi,
  • Maryam Jouyandeh,
  • Mohsen Taghizadeh,
  • Ali Taghizadeh,
  • Henri Vahabi,
  • Sajjad Habibzadeh,
  • Krzysztof Formela and
  • Mohammad Reza Saeb

26 June 2020

Epoxy coatings are developing fast in order to meet the requirements of advanced materials and systems. Progress in nanomaterial science and technology has opened a new era of engineering for tailoring the bulk and surface properties of organic coati...

  • Proceeding Paper
  • Open Access
2,381 Views
5 Pages

Synthesis of a Novel Porphyrin-Based Metal–Organic Framework (Co-Por MOF)

  • Leyla Tayebi,
  • Rahmatollah Rahimi and
  • Mahboubeh Rabbani

14 November 2019

In this study, a novel porphyrin-based metal–organic framework (Co-Por MOF) was successfully synthesized by a simple one-step solvothermal method. We report a metal–organic framework based on the covalent interaction of an organic linker, 5,10,15,20-...

  • Feature Paper
  • Article
  • Open Access
13 Citations
5,950 Views
20 Pages

MOF@chitosan Composites with Potential Antifouling Properties for Open-Environment Applications of Metal-Organic Frameworks

  • Christian Jansen,
  • Nam Michael Tran-Cong,
  • Carsten Schlüsener,
  • Alexa Schmitz,
  • Peter Proksch and
  • Christoph Janiak

27 January 2022

Metal-organic frameworks (MOFs) are promising materials for a myriad of applications because of their easy synthesis and large variability through the organic linker. For open-environment applications, the organic content can, however, give rise to f...

  • Article
  • Open Access
7 Citations
5,366 Views
21 Pages

Synthesis of Aluminum-Based Metal–Organic Framework (MOF)-Derived Carbon Nanomaterials and Their Water Adsorption Isotherm

  • Dasom Jeong,
  • Seong Cheon Kim,
  • Taeseop An,
  • Dongho Lee,
  • Haejin Hwang,
  • Siyoung Q. Choi and
  • Jeasung Park

16 August 2023

The characteristics of water vapor adsorption depend on the structure, porosity, and functional groups of the material. Metal–organic framework (MOF)-derived carbon (MDC) is a novel material that exhibits a high specific area and tunable pore s...

  • Article
  • Open Access
10 Citations
4,787 Views
22 Pages

Enhanced Solid-State Fluorescence of Flavin Derivatives by Incorporation in the Metal-Organic Frameworks MIL-53(Al) and MOF-5

  • Dietrich Püschel,
  • Simon Hédé,
  • Iván Maisuls,
  • Simon-Patrick Höfert,
  • Dennis Woschko,
  • Ralf Kühnemuth,
  • Suren Felekyan,
  • Claus A. M. Seidel,
  • Constantin Czekelius and
  • Oliver Weingart
  • + 2 authors

22 March 2023

The flavin derivatives 10-methyl-isoalloxazine (MIA) and 6-fluoro-10-methyl-isoalloxazine (6F-MIA) were incorporated in two alternative metal-organic frameworks, (MOFs) MIL-53(Al) and MOF-5. We used a post-synthetic, diffusion-based incorporation int...

  • Review
  • Open Access
17 Citations
5,491 Views
16 Pages

Application of Metal–Organic Frameworks (MOFs) in Environmental Biosystems

  • Lu Zhang,
  • Qingwen Zheng,
  • Zheng Zhang,
  • Huidong Li,
  • Xue Liu,
  • Jinzhi Sun and
  • Ruiwen Wang

21 January 2023

Metal–organic frameworks (MOFs) are crystalline materials that are formed by self-assembling organic linkers and metal ions with large specific areas and pore volumes. Their chemical tunability, structural diversity, and tailor-ability make the...

  • Article
  • Open Access
13 Citations
4,241 Views
21 Pages

Thermodynamic Investigation and Study of Kinetics and Mass Transfer Mechanisms of Oily Wastewater Adsorption on UIO-66–MnFe2O4 as a Metal–Organic Framework (MOF)

  • Abdelfattah Amari,
  • Heba Saed Kariem Alawameleh,
  • Mubeen Isam,
  • Mohammed Abdul Jaleel Maktoof,
  • Haitham Osman,
  • Balamurugan Panneerselvam and
  • Maciej Thomas

30 January 2023

Hitherto, a considerable amount of research has been carried out to investigate the equilibrium condition of adsorption process; nevertheless, there is no comprehensive study to evaluate the surface adsorption properties of MOFs. Therefore, the adsor...

  • Review
  • Open Access
19 Citations
6,455 Views
27 Pages

21 September 2021

Metal–organic-frameworks (MOFs) are emerging materials used in the environmental electrochemistry community for Faradaic and non-Faradaic water remediation technologies. It has been concluded that MOF-based materials show improvement in performance c...

  • Review
  • Open Access
28 Citations
9,930 Views
23 Pages

Metal–Organic Frameworks (MOFs) and Materials Derived from MOFs as Catalysts for the Development of Green Processes

  • Gonzalo Valdebenito,
  • Marco Gonzaléz-Carvajal,
  • Luis Santibañez and
  • Patricio Cancino

22 January 2022

This review will be centered around the work that has been reported on the development of metal–organic frameworks (MOFs) serving as catalysts for the conversion of carbon dioxide into short-chain hydrocarbons and the generation of clean energi...

  • Article
  • Open Access
4 Citations
3,516 Views
14 Pages

13 October 2022

Modified γ-cyclodextrin metal organic frameworks (γ-CD-MOFs) are a promising eco-friendly sorbents for post-combustion CO2 capture. Polyethyleneimine (PEI) has been widely used for modifying MOFs to enhance their CO2 sorption capacity and...

  • Perspective
  • Open Access
11 Citations
4,444 Views
12 Pages

Metal-Organic Frameworks (MOFs) have emerged as a novel component in biomaterial formulations over the past 5 years. The bioactivity of MOFs in bone or cartilage tissue is mediated through the sustained delivery of metal ions, bioactive ligands, or d...

  • Review
  • Open Access
36 Citations
11,512 Views
27 Pages

Recent Advances in Polymeric Nanocomposites of Metal-Organic Frameworks (MOFs)

  • Jun Zhong,
  • Ranjith Kumar Kankala,
  • Shi-Bin Wang and
  • Ai-Zheng Chen

9 October 2019

Recently, metal-organic frameworks (MOFs) have garnered enormous attention from researchers owing to their superior physicochemical properties, which are of particular interest in various fields such as catalysis and the diverse areas of biomedicine....

  • Review
  • Open Access
5 Citations
8,175 Views
31 Pages

Metal–Organic Frameworks (MOFs) for Adsorption and Degradation of Microplastics

  • Thayna Campeol Marinho,
  • Almudena Gomez-Aviles and
  • Pilar Herrasti

Microplastics (MPs) are currently a serious environmental problem, primarily due to their persistence in the environment, low concentration, and difficulty in detection and disposal. MPs have also been detected in humans and have been shown to be har...

  • Review
  • Open Access
65 Citations
10,788 Views
28 Pages

2 November 2022

Volatile organic compounds (VOCs) are a major threat to human life and health. The technologies currently used to remove VOCs mainly include adsorption and photocatalysis. Adsorption is the most straightforward strategy, but it cannot ultimately elim...

  • Editorial
  • Open Access
3 Citations
1,710 Views
2 Pages

This Special Issue is dedicated to exploring various approaches and techniques for the preparation and modification of metal–organic frameworks (MOFs), as well as their applications, with a specific focus on molecular research [...]

  • Proceeding Paper
  • Open Access
2 Citations
1,868 Views
9 Pages

A Systematic Review of Metal–Organic Framework (MOF)-Based Nanocomposites and Their Application in Photocatalytic Degradation of Pharmaceutical Compounds

  • Kyle Angelique Bautista,
  • Eugene Josh D. C. Mata,
  • Chris Diane B. Mercado,
  • Ron Jasper C. Placio,
  • Vince Harvey O. Alano,
  • Allan N. Soriano and
  • Rugi Vicente C. Rubi

6 September 2024

Photocatalytic degradation has emerged as a promising and sustainable solution to the rising environmental concerns caused by the emergence of pharmaceutical contaminants in aquatic bodies. Given its sustainability, nontoxicity, and energy-efficient...

  • Article
  • Open Access
57 Citations
9,224 Views
25 Pages

An Inhalable Theranostic System for Local Tuberculosis Treatment Containing an Isoniazid Loaded Metal Organic Framework Fe-MIL-101-NH2—From Raw MOF to Drug Delivery System

  • Gabriela Wyszogrodzka-Gaweł,
  • Przemysław Dorożyński,
  • Stefano Giovagnoli,
  • Weronika Strzempek,
  • Edyta Pesta,
  • Władysław P. Węglarz,
  • Barbara Gil,
  • Elżbieta Menaszek and
  • Piotr Kulinowski

The theranostic approach to local tuberculosis treatment allows drug delivery and imaging of the lungs for a better control and personalization of antibiotic therapy. Metal-organic framework (MOF) Fe-MIL-101-NH2 nanoparticles were loaded with isoniaz...

  • Feature Paper
  • Review
  • Open Access
42 Citations
17,759 Views
31 Pages

Engineering Metal-Organic-Framework (MOF)-Based Membranes for Gas and Liquid Separation

  • Yutian Duan,
  • Lei Li,
  • Zhiqiang Shen,
  • Jian Cheng and
  • Kewu He

Separation is one of the most energy-intensive processes in the chemical industry, and membrane-based separation technology contributes significantly to energy conservation and emission reduction. Additionally, metal-organic framework (MOF) materials...

  • Perspective
  • Open Access
84 Citations
7,714 Views
10 Pages

Metal-Organic Frameworks (MOFs)-Based Nanomaterials for Drug Delivery

  • Mohammad Reza Saeb,
  • Navid Rabiee,
  • Masoud Mozafari and
  • Ebrahim Mostafavi

30 June 2021

The composition and topology of metal-organic frameworks (MOFs) are exceptionally tailorable; moreover, they are extremely porous and represent an excellent Brunauer–Emmett–Teller (BET) surface area (≈3000–6000 m2·g−1). Nanoscale MOFs (NMOFs), as car...

  • Review
  • Open Access
50 Citations
11,031 Views
32 Pages

Application of Various Metal-Organic Frameworks (MOFs) as Catalysts for Air and Water Pollution Environmental Remediation

  • Sanha Jang,
  • Sehwan Song,
  • Ji Hwan Lim,
  • Han Seong Kim,
  • Bach Thang Phan,
  • Ki-Tae Ha,
  • Sungkyun Park and
  • Kang Hyun Park

6 February 2020

The use of metal-organic frameworks (MOFs) to solve problems, like environmental pollution, disease, and toxicity, has received more attention and led to the rapid development of nanotechnology. In this review, we discuss the basis of the metal-organ...

  • Article
  • Open Access
22 Citations
6,891 Views
33 Pages

Metal–Organic Frameworks (MOFs) Containing Adsorbents for Carbon Capture

  • Linda Ansone-Bertina,
  • Viesturs Ozols,
  • Lauris Arbidans,
  • Linda Dobkevica,
  • Kristaps Sarsuns,
  • Edgars Vanags and
  • Maris Klavins

9 May 2022

In this study, new composite materials of montmorillonite, biochar, or aerosil, containing metal–organic frameworks (MOF) were synthesized in situ. Overall, three different MOFs—CuBTC, UTSA-16, and UiO-66-BTEC—were used. Obtained ad...

  • Review
  • Open Access
151 Citations
15,473 Views
21 Pages

Cyclodextrin-Based Metal-Organic Frameworks (CD-MOFs) in Pharmaceutics and Biomedicine

  • Yaoyao Han,
  • Weicong Liu,
  • Jianjing Huang,
  • Shuowen Qiu,
  • Huarui Zhong,
  • Dong Liu and
  • Jianqiang Liu

Metal-organic frameworks (MOFs) show promising application in biomedicine and pharmaceutics owing to their extraordinarily high surface area, tunable pore size, and adjustable internal surface properties. However, MOFs are prepared from non-renewable...

  • Feature Paper
  • Review
  • Open Access
85 Citations
22,794 Views
23 Pages

Metal–Organic Framework Hybrid Materials and Their Applications

  • Joshua D. Sosa,
  • Timothy F. Bennett,
  • Katherine J. Nelms,
  • Brandon M. Liu,
  • Roberto C. Tovar and
  • Yangyang Liu

14 August 2018

The inherent porous nature and facile tunability of metal–organic frameworks (MOFs) make them ideal candidates for use in multiple fields. MOF hybrid materials are derived from existing MOFs hybridized with other materials or small molecules us...

  • Review
  • Open Access
32 Citations
6,400 Views
14 Pages

Metal–organic frameworks (MOFs) comprising metal ions or clusters coordinated to organic ligands have become a class of emerging materials in the field of biomedical research due to their bespoke compositions, highly porous nanostructures, larg...

  • Review
  • Open Access
68 Citations
9,604 Views
25 Pages

A Comprehensive Review on the Use of Metal–Organic Frameworks (MOFs) Coupled with Enzymes as Biosensors

  • José E. da S. Souza,
  • Gabriel P. de Oliveira,
  • Jeferson Y. N. H. Alexandre,
  • José G. L. Neto,
  • Misael B. Sales,
  • Paulo G. de S. Junior,
  • André L. B. de Oliveira,
  • Maria C. M. de Souza and
  • José C. S. dos Santos

1 February 2022

Several studies have shown the development of electrochemical biosensors based on enzymes immobilized in metal–organic frameworks (MOFs). Although enzymes have unique properties, such as efficiency, selectivity, and environmental sustainability...

  • Review
  • Open Access
25 Citations
5,806 Views
29 Pages

Metal–Organic Frameworks (MOFs) Derived Materials Used in Zn–Air Battery

  • Dongmei Song,
  • Changgang Hu,
  • Zijian Gao,
  • Bo Yang,
  • Qingxia Li,
  • Xinxing Zhan,
  • Xin Tong and
  • Juan Tian

24 August 2022

It is necessary to develop new energy technologies because of serious environmental problems. As one of the most promising electrochemical energy conversion and storage devices, the Zn–air battery has attracted extensive research in recent year...

  • Review
  • Open Access
111 Citations
11,771 Views
28 Pages

The Chemistry and Applications of Metal–Organic Frameworks (MOFs) as Industrial Enzyme Immobilization Systems

  • Allison R. M. Silva,
  • Jeferson Y. N. H. Alexandre,
  • José E. S. Souza,
  • José G. Lima Neto,
  • Paulo G. de Sousa Júnior,
  • Maria V. P. Rocha and
  • José C. S. dos Santos

15 July 2022

Enzymatic biocatalysis is a sustainable technology. Enzymes are versatile and highly efficient biocatalysts, and have been widely employed due to their biodegradable nature. However, because the three-dimensional structure of these enzymes is predomi...

  • Review
  • Open Access
24 Citations
6,460 Views
20 Pages

24 December 2022

Metal–organic frameworks (MOFs) have been broadly applied to numerous domains with a substantial surface area, tunable pore size, and multiple unsaturated metal sites. Recently, hollow MOFs have greatly attracted the scientific community due to...

  • Article
  • Open Access
34 Citations
5,131 Views
10 Pages

13 February 2021

Metal-organic frameworks (MOFs) were usually synthesized in hydrothermal conditions; in this study, a more energy-saving, easier to control, and solvent-free mechanochemical method was firstly applied to synthesize MOFs with varied reactants as slow...

  • Article
  • Open Access
27 Citations
4,560 Views
31 Pages

Trends and Opportunities in Enzyme Biosensors Coupled to Metal-Organic Frameworks (MOFs): An Advanced Bibliometric Analysis

  • Misael Bessa Sales,
  • José Gadelha Lima Neto,
  • Ana Kátia De Sousa Braz,
  • Paulo Gonçalves De Sousa Junior,
  • Rafael Leandro Fernandes Melo,
  • Roberta Bussons Rodrigues Valério,
  • Juliana de França Serpa,
  • Ana Michele Da Silva Lima,
  • Rita Karolinny Chaves De Lima and
  • Artemis Pessoa Guimarães
  • + 5 authors

The unique properties of metal-organic frameworks (MOFs) such as their large surface area and high porosity have attracted considerable attention in recent decades. The MOFs are a promising class of materials for developing highly efficient biosensor...

  • Review
  • Open Access
17 Citations
4,183 Views
27 Pages

In recent years, with pressing needs such as diabetes management, the detection of glucose in various substrates has attracted unprecedented interest from researchers in academia and industry. As a relatively new glucose sensor, non-enzymatic target...

  • Review
  • Open Access
11 Citations
4,236 Views
34 Pages

13 January 2025

Metal–organic frameworks (MOFs) have become a highly usable system in various sectors because of their highly ordered structure and high porosity providing them with high storage capacity. However, their use is sometimes forbidden in the food i...

  • Review
  • Open Access
971 Views
45 Pages

10 November 2025

1,2,4-Triazoles, as heterocyclic compounds, represent an attractive class of ligands in the design of metal–organic frameworks (MOFs) due to their donor–acceptor character, thermal and chemical stability, and ability to form extended coor...

  • Review
  • Open Access
41 Citations
8,028 Views
27 Pages

24 January 2020

The determination of organic and inorganic pollutants in fish samples is a complex and demanding process, due to their high protein and fat content. Various novel sorbents including graphene, graphene oxide, molecular imprinted polymers, carbon nanot...

  • Article
  • Open Access
30 Citations
6,895 Views
13 Pages

9 December 2021

In metal-organic frameworks (MOFs), mixed-metal clusters have the opportunity to adsorb hydrogen molecules due to a greater charge density of the metal. Such interactions may subsequently enhance the gravimetric uptake of hydrogen. However, only a fe...

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