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Keywords = massive sulfide deposit (VMS)

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28 pages, 17232 KiB  
Article
Mafic VMS Mineralization in the Mesozoic Metavolcanic Rocks of the Evros Ophiolite, Xylagani Area, Greece
by Vasilios Melfos, Panagiotis Voudouris, Grigorios-Aarne Sakellaris, Christos L. Stergiou, Margarita Melfou, Eftychia Peristeridou, Lambrini Papadopoulou, Jaroslav Pršek and Anestis Filippidis
Minerals 2025, 15(4), 420; https://doi.org/10.3390/min15040420 - 17 Apr 2025
Viewed by 633
Abstract
The sulfide mineralization at Xylagani is hosted in metamorphosed mafic massive and pillow lava. It has an Early–Middle Jurassic age and belongs to the Makri unit, which represents the upper crustal section of the Evros ophiolite in the Circum Rhodope Belt, Northern Greece. [...] Read more.
The sulfide mineralization at Xylagani is hosted in metamorphosed mafic massive and pillow lava. It has an Early–Middle Jurassic age and belongs to the Makri unit, which represents the upper crustal section of the Evros ophiolite in the Circum Rhodope Belt, Northern Greece. The protolith of the host rock is basalt that has a boninitic-to-low-Ti tholeiitic composition and was formed in an intra-oceanic supra-subduction zone within a juvenile forearc-to-volcanic arc setting. The volcanic rocks were subjected to ocean-floor metamorphism at very low-grade prehnite–pumpellyite facies and low-grade greenschist facies at temperatures of up to 360 °C and pressures between 1 and 4 kbar. The mineralization shows typical features of a stratabound–stratiform deposit and occurs as silicified lenses and layers with disseminated and massive sulfides and gold. Based on host rock composition, geotectonic setting, and base metal content, the mineralization at Xylagani is classified as a Cu-rich mafic volcanic-associated deposit, i.e., Cyprus-type VMS (volcanogenic massive sulfide). The mineralization consists of pyrite, chalcopyrite, gold, pyrrhotite, sphalerite, galena, and tennantite-(Zn). It was formed at a subseafloor setting where hydrothermal fluids circulated through the host volcanic rocks, resulting in a pervasive alteration (silicification and chloritization) and the development of a replacement VMS deposit. The very low-to-low-grade orogenic metamorphism and related deformation during the Alpine collision in the Middle Jurassic to Early Cretaceous periods remobilized the mineralization and formed milky quartz veins with rare sulfides, crosscutting the metavolcanic rocks. Full article
(This article belongs to the Special Issue Ore Deposits Related to Metamorphism)
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20 pages, 14201 KiB  
Article
The Study of Gold Mineralization at the Polymetallic Dapingzhang VMS-Type Copper–Gold Deposit, Yunnan Province, China
by Shanshan Ru, Guo Li, Chuandong Xue, Feng Li, Shunhong Zou, Wei Wang and Honglin Zhou
Minerals 2025, 15(1), 54; https://doi.org/10.3390/min15010054 - 7 Jan 2025
Viewed by 998
Abstract
The Dapingzhang Cu-polymetallic deposit in Yunnan is a volcanic massive sulfide (VMS) deposit, located on the western edge of the Lanping–Simao block. Recently, gold-rich polymetallic orebodies with significant economic value have been discovered. However, the occurrence and enrichment mechanisms of the gold remain [...] Read more.
The Dapingzhang Cu-polymetallic deposit in Yunnan is a volcanic massive sulfide (VMS) deposit, located on the western edge of the Lanping–Simao block. Recently, gold-rich polymetallic orebodies with significant economic value have been discovered. However, the occurrence and enrichment mechanisms of the gold remain unclear. This study investigates the massive sulfide orebodies (V1) through detailed geological surveys. Techniques such as optical microscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and electron probe microanalysis (EPMA) were used to clarify the occurrence of gold, and to reveal the enrichment mechanisms. The genesis of the orebodies consists of three stages: (I) pyrite–quartz, (II) pyrite–chalcopyrite–sphalerite–galena–quartz, and (III) pyrite–chalcopyrite–sphalerite–galena–quartz–calcite. Gold precipitated during each of these mineralization stages, and it may be described as multiphase mineralization. Gold predominantly exists as invisible gold (≤0.1 μm), with minor visible gold as native gold and independent minerals (küstelite, electrum, calaverite). Invisible gold mainly occurs as gold microinclusions (Au+) in pyrite, chalcopyrite, and sphalerite. Combined with the previous research, comprehensive analysis determined that deep-circulating seawater, driven by a magmatic hydrothermal system, leaches and dissolves mineralizing materials from underlying volcanic rocks. The mineralizing fluid, mixed with magmatic fluid, migrates upward through volcanic conduits or is expelled to the seafloor. Changes in physicochemical conditions lead to the co-precipitation of gold and sulfides, forming a mineralization structure with lower channel facies and upper eruptive facies. Full article
(This article belongs to the Section Mineral Deposits)
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24 pages, 27545 KiB  
Article
Superimposed Mineralization in the Xiaorequanzi Cu Deposit, Xinjiang: Evidence from Fluid Inclusions, H-O-S Isotopes, and Pyrite Trace Elements
by Yongqi Hao, Shunda Li, Fang Xia, Chuan Chen, Lingling Gao, Wei Wang, Xiaofei Du and Chenmeng Li
Minerals 2024, 14(11), 1166; https://doi.org/10.3390/min14111166 - 17 Nov 2024
Viewed by 1055
Abstract
The Xiaorequanzi Cu deposit is located in the western part of the Dananhu–Tousuquan Island arc in eastern Tianshan, Xinjiang. It includes stratiform and epithermal-related veinlet mineralization. However, the genesis of this deposit remains controversial. Therefore, fluid inclusions, H–O isotopes, in situ S, and [...] Read more.
The Xiaorequanzi Cu deposit is located in the western part of the Dananhu–Tousuquan Island arc in eastern Tianshan, Xinjiang. It includes stratiform and epithermal-related veinlet mineralization. However, the genesis of this deposit remains controversial. Therefore, fluid inclusions, H–O isotopes, in situ S, and trace elements in pyrite were employed in this study to constrain the origins of the deposit. The Xiaorequanzi Cu deposit’s mineralization stages can be categorized into the following three phases: I. volcanogenic massive sulfide (VMS) mineralization; II. quartz–chalcopyrite–pyrite; and III. quartz–chalcopyrite–sphalerite stages. Fluid inclusion studies suggest that Stage I is distinguished by high-temperature (peak: 320–360 °C) and moderate-salinity (peak: 7–9 wt%) fluids belonging to the H2O–NaCl ± CO2 system. Stages II–III only exhibit vapor–liquid inclusions, with mineralizing fluids belonging to the medium-to-low-temperature (Stage II peak: 160–180 °C; Stage III peak: 120–130 °C) and medium-to-low-salinity (Stage II peak: 5–7 wt%; Atage III peak: 4–6 wt%) H2O–NaCl system. The H–O isotopic data suggest that mineralizing fluid in Stage I is a blend of magmatic and paleo-seawater sources, while in Stages II–III, meteoric water predominates, accompanied by low mineralizing temperatures. In situ S isotope results indicate that the source of mineralizing materials in Stage I (2.52–4.48‰) were magmatic rocks, whereas the markedly higher δ34S values in stages II–III (4.68–6.60‰) suggest sulfur isotope leaching from sedimentary rocks by meteoric water as the main source. The LA–ICP–MS data of pyrite in the Xiaorequanzi Cu deposit suggest that Py1 was formed through volcanic processes, whereas Py2 and Py3 exhibited epithermal characteristics. Throughout the mineralization process, a trend in increasing oxygen and decreasing sulfur fugacity occurred, accompanied by a decreased mineralization temperature. This observation corresponds with the temperature data derived from the fluid inclusions. Additionally, the principal components of different generations of pyrite segregated as two clusters representing the VMS (Stage I) and epithermal mineralization (stages II–III). In summary, based on comprehensive research and previous geochronological studies, it is suggested that the Xiaorequanzi Cu deposit experienced two mineralization stages. The early stage is related to the volcanic activity of the Early Carboniferous (354 Ma), whereas the later stage is associated with Carboniferous–Permian (266–264 Ma) volcanic intrusions. Full article
(This article belongs to the Section Mineral Deposits)
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32 pages, 9777 KiB  
Article
Geochemical Characterization of and Exploration Guide for the World-Class Mafic–Siliciclastic-Hosted Touro VMS Cu Deposit, Northwestern Iberian Peninsula
by Pablo Nuñez, Alvaro Rubio, Daniel Arias, Jorge Fuertes-Blanco, Fernando Cortés, Fernando Díaz-Riopa and Agustin Martin-Izard
Minerals 2024, 14(11), 1159; https://doi.org/10.3390/min14111159 - 16 Nov 2024
Viewed by 1206
Abstract
A geochemical study was conducted on the Touro deposit, which is situated within the Iberian Variscan Massif on the allochthonous terrain of the Galicia–Tras-os-Montes Zone. This study encompassed both mineralogical and geochemical analyses of the host rocks, with a particular focus on the [...] Read more.
A geochemical study was conducted on the Touro deposit, which is situated within the Iberian Variscan Massif on the allochthonous terrain of the Galicia–Tras-os-Montes Zone. This study encompassed both mineralogical and geochemical analyses of the host rocks, with a particular focus on the high-grade Fornás metamorphic unit of the Órdenes Complex. The deposit is composed of massive and semi-massive sulfides, the host rocks are amphibolites and paragneisses, and the ore is hosted in garnet amphibolites and mineralized paragneisses. A microscopic study of thin sections and over 300 electron probe microanalyses on various minerals were conducted with the objective of geochemical characterization. Furthermore, a study of approximately 6000 samples processed by mining companies for multielement analyses of over 1350 drill cores was conducted to geochemically characterize the host and mineralized rocks for use as exploration guides. Additionally, five samples underwent Sm-Nd isotope analysis. The data from the Touro Cu (Zn-Co) deposit are consistent with its classification as a mafic–siliciclastic (Besshi-type) VMS deposit constructed in a back-arc environment during the Ordovician period. Following burial and high-grade metamorphism during the Middle Devonian period, these rocks were subsequently exposed during the later Variscan deformation phases, resulting in the formation of the Arinteiro antiform. Full article
(This article belongs to the Special Issue Mineralization and Geochemistry of VMS Deposits)
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34 pages, 16162 KiB  
Review
Updating Geological Information about the Metallogenesis of the Iberian Pyrite Belt
by Reinaldo Sáez, Felipe González, Teodosio Donaire, Manuel Toscano, Lola Yesares, Gabriel Ruiz de Almodóvar and Carmen Moreno
Minerals 2024, 14(9), 860; https://doi.org/10.3390/min14090860 - 24 Aug 2024
Cited by 3 | Viewed by 3002
Abstract
The Iberian Pyrite Belt (IPB) represents one of the largest districts of volcanogenic massive sulfide (VMS) deposits in the world, and is a critical source of base metals (Cu, Pb, and Zn) for Europe. Confirmed resources exceed 1700 Mt of massive sulfides with [...] Read more.
The Iberian Pyrite Belt (IPB) represents one of the largest districts of volcanogenic massive sulfide (VMS) deposits in the world, and is a critical source of base metals (Cu, Pb, and Zn) for Europe. Confirmed resources exceed 1700 Mt of massive sulfides with grades of around 1.2% Cu, 1% Pb, and 3% Zn as well as more than 300 Mt of stockwork-type copper mineralization. Significant resources of Sn, precious metals (Au and Ag), and critical metals (Co, Bi, Sb, In, and Se) have also been evaluated. The genesis of these deposits is related to a complex geological evolution during the late Devonian and Mississippian periods. The geological record of such evolution is represented by three main lithological units: Phyllite–Quartzite Group, the volcano–sedimentary Complex (VSC), and the so-called Culm Group. The sulfide deposits are located in the VSC, associated with felsic volcanic rocks or sedimentary rocks such as black shales. The massive sulfide deposits occur as tabular bodies and replacement masses associated with both volcanic and sedimentary rocks. Their mineralogical composition is relatively simple, dominated by pyrite, chalcopyrite, sphalerite, and galena. Their origin is related to three evolutionary stages at increasing temperatures, and a subsequent stage associated with the Variscan deformation. The present paper summarizes the latest developments in the IPB and revises research areas requiring further investigation. Full article
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23 pages, 29604 KiB  
Article
Multi-Stage Metallogenesis and Fluid Evolution of the Hongtoushan Cu-Zn Volcanogenic Massive Sulfide Deposit, Liaoning Province, China: Constraints from Sulfur Isotopes, Trace Elements, and Fluid Inclusions
by Xinwei You, Ende Wang, Jianfei Fu and Yekai Men
Appl. Sci. 2024, 14(11), 4600; https://doi.org/10.3390/app14114600 - 27 May 2024
Cited by 1 | Viewed by 1086
Abstract
The Hongtoushan Cu-Zn volcanogenic massive sulfide (VMS) deposit, located in the Hunbei granite–greenstone terrane of the North China Craton, has undergone a complex, multi-stage metallogenic evolution. The deposit comprises three main types of massive ores: Type-1 ores, characterized by a sulfide matrix enclosing [...] Read more.
The Hongtoushan Cu-Zn volcanogenic massive sulfide (VMS) deposit, located in the Hunbei granite–greenstone terrane of the North China Craton, has undergone a complex, multi-stage metallogenic evolution. The deposit comprises three main types of massive ores: Type-1 ores, characterized by a sulfide matrix enclosing granular quartz and dark mineral aggregates; Type-2 ores, distinguished by large pyrite and pyrrhotite porphyroblasts and a small amount of gangue minerals; and Type-3 ores, mainly distributed in the contact zone between the ore body and gneiss, featuring remobilized chalcopyrite and sphalerite filling the cracks of pyrite. The metallogenic process of the Hongtoushan deposit is divided into three main stages: (1) an early mineralization stage forming Type-1 massive ores; (2) a metamorphic recrystallization stage resulting in Type-2 massive ores with distinct textural features; and (3) a late-stage mineralization event producing Type-3 massive ores enriched in Cu, Zn, and other metals. This study integrates sulfur isotope, trace elements, and fluid inclusion data to constrain the sources of ore-forming materials, fluid evolution and metallogenic processes of the deposit. Sulfur isotope analyses of sulfide samples yield δ34S values ranging from −0.7 to 4.2 (mean: 1.8 ± 1.5, 1σ), suggesting a predominant magmatic sulfur source with possible contributions from Archean seawater. Trace element analyses of pyrite grains from different ore types reveal a depletion of rare earth elements, Cu, and Zn in Type-2 massive ores due to metamorphic recrystallization, and a subsequent re-enrichment of these elements in Type-3 massive ores. Fluid inclusion studies allowed for identifying three types of ore-forming fluids: Type-1 (avg. Th: 222.9; salinity: 6.74 wt.% NaCl eqv.), Type-2 (avg. Th: 185.72; salinity: 16.56 wt.% NaCl eqv.), and Type-3 (avg. Th: 184.81; salinity: 16.22 wt.% NaCl eqv.), representing a complex evolution involving cooling, water–rock interaction and fluid mixing. This multi-disciplinary study reveals the interplay of magmatic, hydrothermal and metamorphic processes in the formation of the Hongtoushan VMS deposit, providing new insights into the fluid evolution and metallogenic mechanisms of similar deposits in ancient granite–greenstone terranes. Full article
(This article belongs to the Special Issue Seafloor Magmatic and Hydrothermal Activity)
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38 pages, 36523 KiB  
Article
Application of Machine Learning to Research on Trace Elemental Characteristics of Metal Sulfides in Se-Te Bearing Deposits
by Xiaoxuan Zhang, Da Wang, Huchao Ma, Saina Dong, Zhiyu Wang and Zhenlei Wang
Minerals 2024, 14(6), 538; https://doi.org/10.3390/min14060538 - 23 May 2024
Cited by 3 | Viewed by 2039
Abstract
This study focuses on exploring the indication and importance of selenium (Se) and tellurium (Te) in distinguishing different genetic types of ore deposits. Traditional views suggest that dispersed elements are unable to form independent deposits, but are hosted within deposits of other elements [...] Read more.
This study focuses on exploring the indication and importance of selenium (Se) and tellurium (Te) in distinguishing different genetic types of ore deposits. Traditional views suggest that dispersed elements are unable to form independent deposits, but are hosted within deposits of other elements as associated elements. Based on this, the study collected trace elemental data of pyrite, sphalerite, and chalcopyrite in various types of Se-Te bearing deposits. The optimal end-elements for distinguishing different genetic type deposits were recognized by principal component analysis (PCA) and the silhouette coefficient method, and discriminant diagrams were drawn. However, support vector machine (SVM) calculation of the decision boundary shows low accuracy, revealing the limitations in binary discriminant visualization for ore deposit type discrimination. Consequently, two machine learning algorithms, random forest (RF) and SVM, were used to construct ore genetic type classification models on the basis of trace elemental data for the three types of metal sulfides. The results indicate that the RF classification model for pyrite exhibits the best performance, achieving an accuracy of 94.5% and avoiding overfitting errors. In detail, according to the feature importance analysis, Se exhibits higher Shapley Additive Explanations (SHAP) values in volcanogenic massive sulfide (VMS) and epithermal deposits, especially the latter, where Se is the most crucial distinguishing element. By comparison, Te shows a significant contribution to distinguishing Carlin-type deposits. Conversely, in porphyry- and skarn-type deposits, the contributions of Se and Te were relatively lower. In conclusion, the application of machine learning methods provides a novel approach for ore genetic type classification and discrimination research, enabling more accurate identification of ore genetic types and contributing to the exploration and development of mineral resources. Full article
(This article belongs to the Special Issue Selenium, Tellurium and Precious Metal Mineralogy)
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30 pages, 11641 KiB  
Article
Characterization of a Metamorphosed Volcanic Stratigraphy and VMS Alteration Halos Using Rock Chip Petrography and Lithogeochemistry: A Case Study from King North, Yilgarn Craton, Western Australia
by Jamie Kelly, Steven P. Hollis, Cendi D. P. Dana, Allan Kneeshaw, Darryl Podmore, Megan James, Riquan Azri, Conal Rodgers and Stephen Roberts
Minerals 2024, 14(5), 481; https://doi.org/10.3390/min14050481 - 30 Apr 2024
Cited by 3 | Viewed by 2362
Abstract
Despite countless advances in recent years, exploration for volcanogenic massive sulfide (VMS) deposits remains challenging. This is particularly the case in the Yilgarn Craton of Western Australia, where outcrop is limited, weathering is deep and extensive, and metamorphism is variable. At Erayinia in [...] Read more.
Despite countless advances in recent years, exploration for volcanogenic massive sulfide (VMS) deposits remains challenging. This is particularly the case in the Yilgarn Craton of Western Australia, where outcrop is limited, weathering is deep and extensive, and metamorphism is variable. At Erayinia in the southern Kurnalpi terrane, intercepts of VMS-style mineralization occur along ~35 km strike length of stratigraphy, and a small Zn (-Cu) deposit has been defined at King (2.15 Mt at 3.47% Zn). An extensive aircore and reverse circulation drilling campaign on the regional stratigraphy identified additional VMS targets, including the King North prospect. Through a combination of detailed rock chip logging, petrography (inc. SEM imaging), and lithogeochemistry, we have reconstructed the volcanic stratigraphy and alteration halos associated with the King North prospect. Hydrothermal alteration assemblages and geochemical characteristics at King North (Mg-Si-K enrichment, Na depletion, and high Sb, Tl, Eu/Eu*, alteration index, CCPI, and normative corundum abundance values) are consistent with an overturned VMS system. The overturned footwall stratigraphy at King North is dominated by metamorphosed volcanic rocks, namely the following: garnet amphibolite (tholeiitic, basaltic), biotite amphibolite (andesitic, calc-alkaline), chlorite–quartz schist (dacitic), and narrow horizons of muscovite–quartz schist (dacitic to rhyolitic, HFSE-enriched). The hanging-wall to the Zn-bearing sequence is characterized by quartz–albite schists (metasedimentary rocks) and thick sequences of amphibolite (calc-alkaline, basaltic andesite). An iron-rich unit (>25% Fe2O3) of chlorite–actinolite–quartz schist, interpreted as a meta-exhalite, is associated with significant Cu-Au mineralization, adjacent to a likely syn-volcanic fault. Extensive Mg metasomatism of the immediate felsic footwall is represented by muscovite–chlorite schist. Diamond drilling into the deep hanging-wall stratigraphy at both King North and King has also revealed the potential for additional, stacked VMS prospective horizons in the greenstone belt stratigraphy. The discovery of HFSE-enriched rhyolites, zones of muscovite–chlorite schist, presence of abundant sulfide-rich argillaceous metasedimentary rocks, and a second upper meta-exhalite horizon further expand the exploration potential of the King–King North region. Our combined petrographic and lithogeochemical approach demonstrates that complex volcanic lithologies and VMS alteration signatures can be established across variably metamorphosed greenstone belts. This has wider implications for more cost-effective exploration across the Yilgarn Craton, utilizing RC drilling to reconstruct the local geology and identify proximal halos, and limiting more costly diamond drilling to key areas of complex geology and deeper EM targets. Full article
(This article belongs to the Special Issue Mineralization and Geochemistry of VMS Deposits)
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26 pages, 9058 KiB  
Article
Trace Element and Sulfur Isotope Signatures of Volcanogenic Massive Sulfide (VMS) Mineralization: A Case Study from the Sunnhordland Area in SW Norway
by Sabina Strmic Palinkas, Trond Fjellet, Håvard Hallås Stubseid, Xuan Liu, Jorge Enrique Spangenberg, Andrea Čobić and Rolf Birger Pedersen
Minerals 2024, 14(4), 384; https://doi.org/10.3390/min14040384 - 7 Apr 2024
Cited by 3 | Viewed by 2586
Abstract
The Sunnhordland area in SW Norway hosts more than 100 known mineral occurrences, mostly of volcanogenic massive sulfide (VMS) and orogeny Au types. The VMS mineralization is hosted by plutonic, volcanic and sedimentary lithologies of the Lower Ordovician ophiolitic complexes. This study presents [...] Read more.
The Sunnhordland area in SW Norway hosts more than 100 known mineral occurrences, mostly of volcanogenic massive sulfide (VMS) and orogeny Au types. The VMS mineralization is hosted by plutonic, volcanic and sedimentary lithologies of the Lower Ordovician ophiolitic complexes. This study presents new trace element and δ34S data from VMS deposits hosted by gabbro and basalt of the Lykling Ophiolite Complex and organic-rich sediments of the Langevåg Group. The Alsvågen gabbro-hosted VMS mineralization exhibits a significant Cu content (1.2 to >10 wt.%), with chalcopyrite and cubanite being the main Cu-bearing minerals. The enrichment of pyrite in Co, Se, and Te and the high Se/As and Se/Tl ratios indicate elevated formation temperatures, while the high Se/S ratio indicates a contribution of magmatic volatiles. The δ34S values of the sulfide phases also support a substantial influx of magmatic sulfur. Chalcopyrite from the Alsvågen VMS mineralization shows significant enrichment in Se, Ag, Zn, Cd and In, while pyrrhotite concentrates Ni and Co. The Lindøya basalt-hosted VMS mineralization consists mainly of pyrite and pyrrhotite. Pyrite is enriched in As, Mn, Pb, Sb, V, and Tl. The δ34S values of sulfides and the Se/S ratio in pyrite suggest that sulfur was predominantly sourced from the host basalt. The Litlabø sediment-hosted VMS mineralization is also dominated by pyrite and pyrrhotite. Pyrite is enriched in As, Mn, Pb, Sb, V and Tl. The δ34S values, which range from −19.7 to −15.7 ‰ VCDT, point to the bacterial reduction of marine sulfate as the main source of sulfur. Trace element characteristics of pyrite, especially the Tl, Sb, Se, As, Co and Ni concentrations, together with their mutual ratios, provide a solid basis for distinguishing gabbro-hosted VMS mineralization from basalt- and sediment-hosted types of VMS mineralization in the study area. The distinctive trace element features of pyrite, in conjunction with its sulfur isotope signature, have been identified as a robust tool for the discrimination of gabbro-, basalt- and sediment-hosted VMS mineralization. Full article
(This article belongs to the Special Issue Submarine Volcanism, Related Hydrothermal Systems and Mineralizations)
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30 pages, 31932 KiB  
Article
The Zircon U-Pb Age, Hf Isotopes, and Lithogeochemistry of Ore-Bearing Rocks from the Archean Hongtoushan Volcanogenic Massive Sulfide Deposit in the North China Craton: Implications for Tectonic Setting
by Xinwei You, Ende Wang, Yekai Men, Jianfei Fu, Kun Song and Sishun Ma
Minerals 2024, 14(4), 367; https://doi.org/10.3390/min14040367 - 29 Mar 2024
Viewed by 1443
Abstract
Volcanogenic massive sulfide (VMS) deposits are globally significant sources of metals. The Hongtoushan VMS deposit is the only large Archean Cu-Zn VMS deposit in the North China Craton, carrying substantial economic value. Significant deformation and metamorphism have made the tectonic setting of the [...] Read more.
Volcanogenic massive sulfide (VMS) deposits are globally significant sources of metals. The Hongtoushan VMS deposit is the only large Archean Cu-Zn VMS deposit in the North China Craton, carrying substantial economic value. Significant deformation and metamorphism have made the tectonic setting of the Hongtoushan VMS deposit the subject of extensive debate. This study investigates the petrogenesis and chronology of the ore-bearing host rocks from the Hongtoushan Cu-Zn VMS deposit in the North China Craton. By utilizing whole-rock geochemical analyses and zircon dating, this research sheds light on the origin and evolution of the ore-bearing rocks within the deposit. The whole-rock geochemical analysis data indicate that the Hongtoushan ore-bearing rock series is mainly composed of amphibole plagioclase gneiss (basalt protolith) and biotite plagioclase gneiss (andesite and rhyolite protolith), suggesting a complete volcanic cycle from basic to medium-acidic volcanic rocks. The amphibole plagioclase gneiss has slight LREE enrichment patterns with unremarkable depletions of Nb, Ta, and Ti and belongs to contaminated ocean plateau basalt (OPB) in terms of composition, which is generally interpreted as being generated from the mantle plume head. Meanwhile, the biotite plagioclase gneiss has relatively steep LREE enrichment distribution patterns with remarkable negative Ta, Nb, and Ti anomalies and a wide range of Zr/Y ratios, indicating their classification as FI- and FII-type felsic rocks; they were likely formed through the fractional crystallization of basic magma combined with crustal assimilation. When combined with the zircon dating results, the ore-bearing host rocks of the Hongtoushan VMS deposit were generated via a continuous magmatic evolution process. The zircon dating of the host rocks indicates a formation age of between 2609 and 2503 Ma, with metamorphic events between 2540 and 2466 Ma, which is consistent with the 2.5 Ga-related global mantle plume event. Further research shows that the ore-bearing host rocks are more likely to have been formed in a mantle plume-related stretching environment, possibly a margin rift. Full article
(This article belongs to the Special Issue Mineral Resources in North China Craton)
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16 pages, 8451 KiB  
Article
Electrical Prospecting of Gold Mineralization in Exhalites of the Digo-Digo VMS Occurrence, Central Brazil
by Pedro Augusto Costa do Amaral, Welitom Rodrigues Borges, Catarina Labouré Bemfica Toledo, Adalene Moreira Silva, Hygor Viana de Godoy and Marcelo Henrique Leão Santos
Minerals 2023, 13(12), 1483; https://doi.org/10.3390/min13121483 - 24 Nov 2023
Cited by 2 | Viewed by 1563
Abstract
The greenstone belts of the Crixás-Goiás Domain are economically important due to significant epigenetic gold deposits and the potential for under-researched syngenetic deposits. The gold occurrences associated with the volcanogenic massive sulfide (VMS) deposits in the region are documented only in the volcanoclastic [...] Read more.
The greenstone belts of the Crixás-Goiás Domain are economically important due to significant epigenetic gold deposits and the potential for under-researched syngenetic deposits. The gold occurrences associated with the volcanogenic massive sulfide (VMS) deposits in the region are documented only in the volcanoclastic rocks of the Digo-Digo Formation, Serra de Santa Rita greenstone belt. The objective of this work is to discuss the efficiency of the induced polarization methods in the time and frequency domains for differentiating and identifying potentially mineralized zones in the exhalites associated with the VMS-type gold of the Digo-Digo Formation. Data were acquired using a multielectrode resistivity meter with the dipole–dipole array and 10 m spacing between electrodes, as well as different current injection times (250, 1000, and 2000 ms). After the electrical data processing and inversion, the sections were integrated into ternary red-green-blue and cyan-magenta-yellow models to highlight areas of high chargeability, low resistivity, and high metal factor (frequency domain) and, thus, map the higher potential zones to host polarizable metallic minerals. The geological–geophysical model elaborated from the correlation of electrical and surface geological data allowed us to identify four anomalous areas related to potential mineralized zones. The geological data confirm that two targets are associated with the geological contacts between metamafic and intermediate metavolcanic units and the exhalative horizon. One of the targets coincides with a sulfide-rich exhalative horizon (VMS), while the last target occurs in the occurrence area of metaultramafic rocks, where gold mineralization occurrences have not been previously described, being a promising target for future investigations. Full article
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19 pages, 3127 KiB  
Article
Comparison of Handheld and Echelle Spectrometer to Assess Copper in Ores by Means of Laser-Induced Breakdown Spectroscopy (LIBS)
by Pia Brinkmann, Nicole Köllner, Sven Merk, Toralf Beitz, Uwe Altenberger and Hans-Gerd Löhmannsröben
Minerals 2023, 13(1), 113; https://doi.org/10.3390/min13010113 - 11 Jan 2023
Cited by 5 | Viewed by 3052
Abstract
Its properties make copper one of the world’s most important functional metals. Numerous megatrends are increasing the demand for copper. This requires the prospection and exploration of new deposits, as well as the monitoring of copper quality in the various production steps. A [...] Read more.
Its properties make copper one of the world’s most important functional metals. Numerous megatrends are increasing the demand for copper. This requires the prospection and exploration of new deposits, as well as the monitoring of copper quality in the various production steps. A promising technique to perform these tasks is Laser Induced Breakdown Spectroscopy (LIBS). Its unique feature, among others, is the ability to measure on site without sample collection and preparation. In this work, copper-bearing minerals from two different deposits are studied. The first set of field samples come from a volcanogenic massive sulfide (VMS) deposit, the second part from a stratiform sedimentary copper (SSC) deposit. Different approaches are used to analyze the data. First, univariate regression (UVR) is used. However, due to the strong influence of matrix effects, this is not suitable for the quantitative analysis of copper grades. Second, the multivariate method of partial least squares regression (PLSR) is used, which is more suitable for quantification. In addition, the effects of the surrounding matrices on the LIBS data are characterized by principal component analysis (PCA), alternative regression methods to PLSR are tested and the PLSR calibration is validated using field samples. Full article
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22 pages, 7042 KiB  
Article
New Mineral Occurrences in Massive Sulfide Deposits from Mănăilă, Eastern Carpathians, Romania
by Gheorghe Damian, Andrei Ionuț Apopei, Andrei Buzatu, Andreea Elena Maftei and Floarea Damian
Minerals 2023, 13(1), 111; https://doi.org/10.3390/min13010111 - 10 Jan 2023
Cited by 1 | Viewed by 2891
Abstract
The massive sulfide deposits (VMS) from Mănăilă are associated with the metamorphic formations of the Tulgheș Lithogroup from the Bucovinian Nappes of the Crystalline-Mesozoic Zone in the Eastern Carpathians, Romania. The following types of ore were identified: pyrite-polymetallic, pyrite copper, compact and precompact [...] Read more.
The massive sulfide deposits (VMS) from Mănăilă are associated with the metamorphic formations of the Tulgheș Lithogroup from the Bucovinian Nappes of the Crystalline-Mesozoic Zone in the Eastern Carpathians, Romania. The following types of ore were identified: pyrite-polymetallic, pyrite copper, compact and precompact copper, and quartz-precompact copper. The polymetallic mineralization consists of pyrite, chalcopyrite, sphalerite, galena, and subordinately arsenopyrite and tennantite. The copper, especially the quartz-copper mineralizations, have a distinct mineralogical composition compared to the other metamorphosed mineralizations of the Tulgheș Lithogroup. These types of deposits from Mănăilă contain large amounts of bornite and chalcocite along with chalcopyrite. Tennantite is abundant and has up to a 3.57 wt.% of bismuth. Wittichenite was identified for the first time in the metamorphic mineralizations and mawsonite was identified as the first occurrence in Romania. An unnamed mineral with the formula: Cu,Fe11Pb,AgS7 was also identified, belonging to the sulfides group. The compact and precompact pyrite-rich ores, located in sericite ± quartzite schists and covered by rhyolitic metatuffs, are of hydrothermal-sedimentary type metamorphosed in the greenschist facies. The source of the quartz-copper mineralization would be the retromorphic or metasomatic hydrothermal solutions that circulated through major fractures. Full article
(This article belongs to the Special Issue Sulfide Mineralogy and Geochemistry)
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18 pages, 3445 KiB  
Article
Tracing the Source of Hydrothermal Fluid in Ophiolite-Related Volcanogenic Massive Sulfide Deposits: A Case Study from the Italian Northern Apennines
by Gabriella B. Kiss, Kata Molnár, Zsolt Benkó, Péter Skoda, Zsuzsanna Kapui, Giorgio Garuti, Federica Zaccarini, László Palcsu and György Czuppon
Minerals 2023, 13(1), 8; https://doi.org/10.3390/min13010008 - 21 Dec 2022
Cited by 4 | Viewed by 2178
Abstract
The Italian Northern Apennines contain several Fe-Cu-Zn-bearing, Cyprus-type volcanogenic massive sulfide (VMS) deposits, which significantly contribute to the Cu resources of Italy. The massive sulfide lenses and related stockwork mineralizations are hosted by several levels (from basalt to serpentinite) of the unmetamorphosed ophiolitic [...] Read more.
The Italian Northern Apennines contain several Fe-Cu-Zn-bearing, Cyprus-type volcanogenic massive sulfide (VMS) deposits, which significantly contribute to the Cu resources of Italy. The massive sulfide lenses and related stockwork mineralizations are hosted by several levels (from basalt to serpentinite) of the unmetamorphosed ophiolitic series; therefore, this region offers perfect locations to study the ore-forming hydrothermal system in detail. A combination of fluid inclusion microthermometry, Raman spectroscopy, electron probe analyses (chlorite thermometry) and stable and noble gas isotope geochemistry was used to determine the fluid source of the VMS system at Bargone, Boccassuolo, Campegli, Casali–Monte Loreto, Corchia, Reppia and Vigonzano. This question of the fluid source is the focus of modern VMS research worldwide, as it has a direct influence on the metal content of the deposit. The obtained temperature and compositional data are both in the typical range of VMS systems and basically suggest evolved seawater origin for the mineralizing fluid. Modification of seawater was most commonly due to fluid–rock interaction processes, which happened during long-lasting circulation in the crust. The role of a small amount of magmatic fluid input was traced only at the lower block of Boccassuolo, which may be responsible for its higher ore grade. This fluid origin model is evidenced by O, H and C stable isotopic as well as He, Ne and Ar noble gas isotopic values. Full article
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21 pages, 10984 KiB  
Article
Neuro-Fuzzy-AHP (NFAHP) Technique for Copper Exploration Using Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and Geological Datasets in the Sahlabad Mining Area, East Iran
by Aref Shirazi, Ardeshir Hezarkhani, Amin Beiranvand Pour, Adel Shirazy and Mazlan Hashim
Remote Sens. 2022, 14(21), 5562; https://doi.org/10.3390/rs14215562 - 4 Nov 2022
Cited by 39 | Viewed by 1187495
Abstract
Fusion and analysis of thematic information layers using machine learning algorithms provide an important step toward achieving accurate mineral potential maps in the reconnaissance stage of mineral exploration. This study developed the Neuro-Fuzzy-AHP (NFAHP) technique for fusing remote sensing (i.e., ASTER alteration mineral [...] Read more.
Fusion and analysis of thematic information layers using machine learning algorithms provide an important step toward achieving accurate mineral potential maps in the reconnaissance stage of mineral exploration. This study developed the Neuro-Fuzzy-AHP (NFAHP) technique for fusing remote sensing (i.e., ASTER alteration mineral image-maps) and geological datasets (i.e., lithological map, geochronological map, structural map, and geochemical map) to identify high potential zones of volcanic massive sulfide (VMS) copper mineralization in the Sahlabad mining area, east Iran. Argillic, phyllic, propylitic and gossan alteration zones were identified in the study area using band ratio and Selective Principal Components Analysis (SPCA) methods implemented to ASTER VNIR and SWIR bands. For each of the copper deposits, old mines and mineralization indices in the study area, information related to exploration factors such as ore mineralization, host-rock lithology, alterations, geochronological, geochemistry, and distance from high intensity lineament factor communities were investigated. Subsequently, the predictive power of these factors in identifying copper occurrences was evaluated using Back Propagation Neural Network (BPNN) technique. The BPNN results demonstrated that using the exploration factors, copper mineralizations in Sahlabad mining area could be identified with high accuracy. Lastly, using the Fuzzy-Analytic Hierarchy Process (Fuzzy-AHP) method, information layers were weighted and fused. As a result, a potential map of copper mineralization was generated, which pinpointed several high potential zones in the study area. For verification of the results, the documented copper deposits, old mines, and mineralization indices in the study area were plotted on the potential map, which is particularly appearing in high favorability parts of the potential map. In conclusion, the Neuro-Fuzzy-AHP (NFAHP) technique shows great reliability for copper exploration in the Sahlabad mining area, and it can be extrapolated to other metallogenic provinces in Iran and other regions for the reconnaissance stage of mineral exploration. Full article
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