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32 pages, 18410 KB  
Article
Fault Ride-Through Enhancement of a 9 MW DFIG Wind Farm Using a Dual-Layer STATCOM and Multi-Tier Protection Scheme: Detailed and Reduced-Order Modelling
by Muhammed Anaz Khan, Abdullatif Hakami, Abdulrahman Salem Ali Alghamdi, Abdullah Mohammad Saeed Altarqi and Suhail Abduallah Ihsan Emam
Wind 2026, 6(3), 39; https://doi.org/10.3390/wind6030039 - 5 Aug 2026
Viewed by 373
Abstract
The doubly fed induction generator (DFIG) dominates the wind energy market, yet its direct stator-to-grid connection makes it vulnerable to grid faults, creating a tension between hardware self-protection and grid-code fault ride-through (FRT) compliance. This paper presents the modelling and FRT analysis of [...] Read more.
The doubly fed induction generator (DFIG) dominates the wind energy market, yet its direct stator-to-grid connection makes it vulnerable to grid faults, creating a tension between hardware self-protection and grid-code fault ride-through (FRT) compliance. This paper presents the modelling and FRT analysis of a 9 MW DFIG wind farm combining a 20 MVA Static Synchronous Compensator (STATCOM) with a ten-tier algorithmic protection scheme. A detailed phasor-domain MATLAB/Simulink R2024b model is complemented by physics-based reduced-order models integrated in Python, separating calibration targets, calibration-dependent derived quantities and quantities independent of the DC-link calibration. The aerodynamic model reproduces the power coefficient maximum of 0.48 at a tip–speed ratio of 8.1. The energy-balance model uses two parameters identified per scenario from the detailed DC-link trajectory; its peak-voltage agreement within 0.4% is therefore a calibrated consistency check, while the derived arming times, slopes, chopper sizing and latency budget remain conditional on that calibration. A first-order Thevenin analysis shows that the STATCOM supports a weak 25 kV point of common coupling of order 53 MVA short-circuit level, not the 2500 MVA source. The approximate 0.50-to-0.78 p.u. recovery requires about 29.7 Mvar and 1.90 p.u. of STATCOM rated current for 150 ms, conditional on an assumed short-time envelope and adequate converter-voltage headroom; it is not attributable to continuous rated operation. FRT support for the selected recoverable dip is separated from converter survival during a zero-impedance fault, for which a 1700 V chopper pickup with a 1 ms gate delay, not the 10 ms isolation command, is the clamping mechanism. The assessment is explicitly conditional and requires electromagnetic-transient and hardware-in-the-loop confirmation. Full article
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28 pages, 931 KB  
Article
Disclosed Managerial Long-Term Orientation and Related Product-Application Extension in China’s Listed SRDI Little Giants
by Guobin Liu and Jie He
Sustainability 2026, 18(14), 7438; https://doi.org/10.3390/su18147438 - 21 Jul 2026
Viewed by 505
Abstract
Specialized firms face a strategic tension between extending established capabilities into new applications and preserving the coherence that underpins their competitive advantage. Integrating dynamic capability theory with research on managerial time orientation, this study examines whether disclosed action-based managerial long-term orientation is associated [...] Read more.
Specialized firms face a strategic tension between extending established capabilities into new applications and preserving the coherence that underpins their competitive advantage. Integrating dynamic capability theory with research on managerial time orientation, this study examines whether disclosed action-based managerial long-term orientation is associated with subsequent product-application extension and whether such extension remains related to the firm’s existing capability base. The analysis uses an unbalanced retrospective cohort of 1272 firm-year observations from 325 listed Chinese firms that subsequently attained specialized, refined, distinctive, and innovative (SRDI) Little Giant status in the first three national batches. A change from the 10th to the 90th percentile of the raw long-term-orientation score (2 to 3) is associated with a 0.050 increase in the extension score (95% confidence interval: 0.021–0.080), equivalent to 1.25% of the full coding range and 10.9% of the outcome standard deviation. Firm fixed-effects and Mundlak estimates locate this modest association primarily in persistent differences across firms. A direct coefficient comparison favors related product-application extension, although the rarity of unrelated-expansion events limits the precision of this contrast. Digital-depth interactions vary across specifications, and extension is not significantly associated with sales growth or return on assets over the available horizons. These findings refine dynamic-capability theory by locating capability redeployment within persistent firm-level configurations and extend research on strategic time orientation by linking managerial horizons to the direction of product-application extension. Full article
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30 pages, 13241 KB  
Article
Nanosilica Gel-Stabilized Phase-Change Materials Based on Epoxy Resin and Wood’s Metal
by Svetlana O. Ilyina, Irina Y. Gorbunova, Vyacheslav V. Shutov, Michael L. Kerber and Sergey O. Ilyin
Gels 2026, 12(1), 79; https://doi.org/10.3390/gels12010079 - 16 Jan 2026
Viewed by 778
Abstract
The emulsification of a molten fusible metal alloy in a liquid epoxy matrix with its subsequent curing is a novel way to create a highly concentrated phase-change material. However, numerous challenges have arisen. The high interfacial tension between the molten metal and epoxy [...] Read more.
The emulsification of a molten fusible metal alloy in a liquid epoxy matrix with its subsequent curing is a novel way to create a highly concentrated phase-change material. However, numerous challenges have arisen. The high interfacial tension between the molten metal and epoxy resin and the difference in their viscosities hinder the stretching and breaking of metal droplets during stirring. Further, the high density of metal droplets and lack of suitable surfactants lead to their rapid coalescence and sedimentation in the non-cross-linked resin. Finally, the high differences in the thermal expansion coefficients of the metal alloy and cross-linked epoxy polymer may cause cracking of the resulting phase-change material. This work overcomes the above problems by using nanosilica-induced physical gelation to thicken the epoxy medium containing Wood’s metal, stabilize their interfacial boundary, and immobilize the molten metal droplets through the creation of a gel-like network with a yield stress. In turn, the yield stress and the subsequent low-temperature curing with diethylenetriamine prevent delamination and cracking, while the transformation of the epoxy resin as a physical gel into a cross-linked polymer gel ensures form stability. The stabilization mechanism is shown to combine Pickering-like interfacial anchoring of hydrophilic silica at the metal/epoxy boundary with bulk gelation of the epoxy phase, enabling high metal loadings. As a result, epoxy shape-stable phase-change materials containing up to 80 wt% of Wood’s metal were produced. Wood’s metal forms fine dispersed droplets in epoxy medium with an average size of 2–5 µm, which can store thermal energy with an efficiency of up to 120.8 J/cm3. Wood’s metal plasticizes the epoxy matrix and decreases its glass transition temperature because of interactions with the epoxy resin and its hardener. However, the reinforcing effect of the metal particles compensates for this adverse effect, increasing Young’s modulus of the cured phase-change system up to 825 MPa. These form-stable, high-energy-density composites are promising for thermal energy storage in building envelopes, radiation-protective shielding, or industrial heat management systems where leakage-free operation and mechanical integrity are critical. Full article
(This article belongs to the Special Issue Energy Storage and Conductive Gel Polymers)
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19 pages, 4490 KB  
Article
Classification of Tight Sandstone Gas Reservoirs and Evaluation of Aqueous-Phase Trapping Damage Using Mercury Intrusion Porosimetry
by Yuanyuan Tian, Yu Lu, Xin Zhou, Ying Liu, Qin Bie and Nan Zhang
Processes 2025, 13(11), 3682; https://doi.org/10.3390/pr13113682 - 14 Nov 2025
Cited by 1 | Viewed by 1081
Abstract
Diagnosing water-phase damage remains challenging because routine petrophysical parameters do not capture capillary hysteresis and pressure-transmission effects. In this study, a standardized, auditable workflow was established to link laboratory descriptors to field-relevant cleanup. Full-curve mercury injection capillary pressure data were acquired and converted [...] Read more.
Diagnosing water-phase damage remains challenging because routine petrophysical parameters do not capture capillary hysteresis and pressure-transmission effects. In this study, a standardized, auditable workflow was established to link laboratory descriptors to field-relevant cleanup. Full-curve mercury injection capillary pressure data were acquired and converted using consistent Washburn parameters, from which withdrawal efficiency was computed on the withdrawal branch. A pressure-transmission coefficient was evaluated under unified boundary conditions to complement permeability and porosity. After preprocessing and partial least-squares regression (PLSR) screening, MICP descriptors were clustered by k-means (k = 5) to obtain reservoir Types I–V. Regressions relating WE to permeability and flowback behavior were then used to assess engineering relevance. The results indicate that WE capture hysteretic trapping/back-pressure not contained in permeability or porosity and, when interpreted jointly with PTC, differentiates reservoir types by cleanup propensity. This framework provides a reproducible bridge from laboratory MICP hysteresis to field-scale flowback interpretation. Practical implications include prioritization of gas–wet wettability modification, low-surface-tension systems, and minimized early liquid loading for clusters exhibiting higher WE and lower PTC. Full article
(This article belongs to the Section Energy Systems)
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16 pages, 6806 KB  
Article
Considering a Non-Constant Anisotropicity Parameter in the Giesekus Model
by Fatemeh Karami and Pavlos S. Stephanou
Polymers 2025, 17(18), 2510; https://doi.org/10.3390/polym17182510 - 17 Sep 2025
Cited by 2 | Viewed by 1057
Abstract
The Giesekus model has proven to be one of the most successful constitutive rheological models. Although Giesekus introduced the anisotropicity parameter as a constant, recent evidence suggests that it should not be. We elaborate herein on the implications of having a variable anisotropicity [...] Read more.
The Giesekus model has proven to be one of the most successful constitutive rheological models. Although Giesekus introduced the anisotropicity parameter as a constant, recent evidence suggests that it should not be. We elaborate herein on the implications of having a variable anisotropicity coefficient; to our knowledge, this is only the second such model. We find that the modification leads to important differences in the predictions of the second normal stress coefficient in simple shear flow, of which the most significant is the shift of the linear viscoelastic envelope of the second normal stress coefficient to higher values in the case of start-up simple shear flow, which is more in line with experimental data in the literature. Full article
(This article belongs to the Section Polymer Physics and Theory)
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24 pages, 5303 KB  
Article
Preliminary Documentation and Radon Tracer Studies at a Tourist Mining Heritage Site in Poland’s Old Copper Basin: A Case Study of the “Aurelia” Gold Mine
by Lidia Fijałkowska-Lichwa and Damian Kasza
Appl. Sci. 2025, 15(17), 9743; https://doi.org/10.3390/app15179743 - 4 Sep 2025
Viewed by 1306
Abstract
This study presents the results of preliminary documentation and radon tracer investigations conducted at the “Aurelia” Mine in Złotoryja. Measurements of 222Rn activity concentrations were carried out between 17 March and 26 August 2023, while terrestrial laser scanning (TLS) for mapping purposes [...] Read more.
This study presents the results of preliminary documentation and radon tracer investigations conducted at the “Aurelia” Mine in Złotoryja. Measurements of 222Rn activity concentrations were carried out between 17 March and 26 August 2023, while terrestrial laser scanning (TLS) for mapping purposes was performed on 16 November 2024. The radon data exhibited a consistently right-skewed distribution, with skewness coefficients ranging from 0.9 to 8.2 and substantial standard deviations, indicating significant data dispersion. Outliers and extreme outliers were identified as key factors influencing average radon activity concentrations from April through August, whereas data from March displayed homogeneity, with no detected anomalies. The average 222Rn activity concentrations recorded from March to July ranged from 51.4 Bq/m3 to 65.9 Bq/m3. In contrast, July and August showed elevated average values (75.8 Bq/m3 and 5784.8 Bq/m3, respectively) due to the presence of outliers and extreme values. Upon removal of these anomalies, the adjusted means were 73.8 Bq/m3 and 1003.6 Bq/m3, respectively, resulting in reduced skewness and improved representativeness. These findings suggest that the annual average radon concentrations at the “Aurelia” Mine remain compliant with the regulatory threshold of 300 Bq/m3 set by the Atomic Law Act, with exceedances likely related to atypical or rare geophysical phenomena requiring further statistical validation. August exhibited a significant occurrence of outliers and extreme outliers in 222Rn activity concentration data, particularly concentrated between the 13th and 17th days of the month. This anomaly is hypothesized to be associated with geological processes, notably mining-induced seismic events within the LGOM (Legnica–Głogów Copper District) region. It is proposed that periodic transitions between tensional and compressional phases within the rock mass, triggered by mining activity, may lead to abrupt increases in radon exhalation, potentially occurring before or after seismic events with a magnitude exceeding 2.5. Although the presented data provide preliminary evidence supporting the influence of tectonic kinematic changes on subsurface radon dynamics, further systematic observations are required to confirm this relationship. At the current stage, the hypothesis remains speculative but may contribute to the broader understanding of radon behavior in geologically active underground environments. Complementing the geochemical analysis, TLS enabled detailed geological mapping and 3D spatial modeling of the mine’s underground tourist infrastructure. The resulting simplified linked data model—integrating radon activity concentrations, geological structures, and spatial parameters—provides a foundational framework for developing a comprehensive GIS database. This integrative approach highlights the feasibility of combining tracer studies with spatial and cartographic data to improve radon risk assessment models and ensure regulatory compliance in underground occupational settings. Full article
(This article belongs to the Special Issue Advances in Environmental Monitoring and Radiation Protection)
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17 pages, 9781 KB  
Article
Research on the Tensile-Bending Dynamic Response of the Half-Through Arch Bridge Short Suspender Considering Vehicle-Bridge Coupling Vibration
by Lianhua Wang, Guowen Yao and Xuanbo He
Vibration 2025, 8(3), 51; https://doi.org/10.3390/vibration8030051 - 4 Sep 2025
Viewed by 980
Abstract
The half-through arch bridge short suspender is more prone to damage due to its high linear stiffness and special force characteristics. To analyze the vehicle-induced vibration characteristics of the short suspender during service, a half-through arch bridge finite element model and a three-axis [...] Read more.
The half-through arch bridge short suspender is more prone to damage due to its high linear stiffness and special force characteristics. To analyze the vehicle-induced vibration characteristics of the short suspender during service, a half-through arch bridge finite element model and a three-axis vehicle model were established to realize the coupled vibration of the suspender axle under bridge deck unevenness excitation. The suspender was simulated using LINK element and BEAM element and separated along its axial and radial directions, and its tension-bending response characteristics was studied. The study found that the short suspender’s amplitude and frequency are higher than those of the long suspender as vehicle critical duration increases. Influenced by the tensile bending effect, the vibration, cross-section equivalent force amplitude, and impact coefficient at the anchorage end are larger than those at the center, and the lower anchorage end’s cross-section peak stress is biased towards the direction of the side column. The internal force of the short suspender is consistent with the deformation trend; its internal force coincides with the deformation trend; and its axial alternating load is generated by the axial relative deformation between the arch rib and the bridge deck, while the bending alternating load originates from the rotational deformation of the short suspender. Full article
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14 pages, 4787 KB  
Article
Study on Contact Characteristics of Cold Rolled Deformation Zone of Ultra-High-Strength Steel
by Jianhui Wang, Zhenhua Bai, Yuan Gao, Zhourun Shi, Zifei Guo and Xuetong Li
Metals 2025, 15(3), 311; https://doi.org/10.3390/met15030311 - 13 Mar 2025
Cited by 3 | Viewed by 1896
Abstract
This study investigates the longitudinal deformation behavior of ultra-high-strength steel (UHSS) during the cold rolling process. First, rolling experiments were conducted on UHSS, and longitudinal surface coordinates of the deformation zone were collected using a probe-type profiler to obtain the actual profile. The [...] Read more.
This study investigates the longitudinal deformation behavior of ultra-high-strength steel (UHSS) during the cold rolling process. First, rolling experiments were conducted on UHSS, and longitudinal surface coordinates of the deformation zone were collected using a probe-type profiler to obtain the actual profile. The forward slip value was derived from production data. An elastic–plastic finite element model of the UHSS rolling process was then established using the nonlinear finite element method. The model calculated the contact arc shape and forward slip within the deformation zone, with errors of less than 15% for the contour and 10% for forward slip. The model was further used to analyze the impact of rolling parameters on contact profile, stress, and forward slip. The results indicate that reducing plate thickness and tension, along with increasing depression and yield strength, promotes the formation of a neutral zone in the deformation zone. The peak contact stress is linked to increased elastic compression of the rolls and the expansion of the roll exit. Additionally, increases in roll diameter, friction coefficient, and yield strength lead to a gradual increase in forward slip in the deformation zone. Full article
(This article belongs to the Special Issue Plastic and Plastic Processing of Metallic Materials)
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16 pages, 4023 KB  
Article
A Decoupling Module Based on a Geometrical-Balance Mechanism for Mitigating Cable Length Variation in Cable-Driven Applications
by Van Pho Nguyen, Sunil Bohra Dhyan and Wai Tuck Chow
Machines 2024, 12(11), 755; https://doi.org/10.3390/machines12110755 - 25 Oct 2024
Cited by 2 | Viewed by 2814
Abstract
Cable-driven mechanisms are increasingly popular in applications requiring low-inertia operation. However, issues like cable loosening, which leads to reduced durability and stability with long-term use, have not been fully addressed in previous studies. This paper presents a novel design for a decoupling mechanism [...] Read more.
Cable-driven mechanisms are increasingly popular in applications requiring low-inertia operation. However, issues like cable loosening, which leads to reduced durability and stability with long-term use, have not been fully addressed in previous studies. This paper presents a novel design for a decoupling mechanism based on the geometrical-balance principle. The mechanism incorporates three pulleys—main, minor, and guiding—mounted on a parallelogram structure. The cable passes over these pulleys and an elbow pulley with constant tension, maintained through a balance between the pulleys’ radii and the cable’s thickness and radius. A theoretical model was developed to estimate deviations in the cable tension within this design, considering general geometric parameters and friction coefficients. In the experimental setup, the main pulley had a radius of 15 mm, while the minor, guiding, and elbow pulleys had radii of 7 mm, and a 1 mm radius Dyneema cable was used. The results demonstrated that the decoupling mechanism maintained a consistent cable length and tension with minimal deviation as the two links rotated from small to large angles. Furthermore, a strong correlation between the theoretical estimates and experimental validation confirmed that the cable tension remained stable at both ends when the decoupling mechanism was integrated into the original system. This research improves the stability and durability of cable-driven mechanisms while offering a compact, accurate solution adaptable to a wide range of applications, including robotics, machinery, and other devices. Full article
(This article belongs to the Section Electrical Machines and Drives)
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11 pages, 1148 KB  
Article
Relationship between Femur Mineral Content and Local Muscle Strength and Mass
by Bruno V. R. Ramos, Danilo A. Massini, Tiago A. F. Almeida, Eliane A. Castro, Mário C. Espada, Cátia C. Ferreira, Ricardo A. M. Robalo, Anderson G. Macedo and Dalton M. Pessôa Filho
J. Funct. Morphol. Kinesiol. 2024, 9(2), 69; https://doi.org/10.3390/jfmk9020069 - 9 Apr 2024
Cited by 2 | Viewed by 2381
Abstract
Among the stimuli able to prevent early decreases in bone mineralization, exercise has a noticeable role per se as the source of mechanical stimulus or through lean tissue enlargement by its increasing of tensional stimulus. However, prevention strategies, including exercise, generally do not [...] Read more.
Among the stimuli able to prevent early decreases in bone mineralization, exercise has a noticeable role per se as the source of mechanical stimulus or through lean tissue enlargement by its increasing of tensional stimulus. However, prevention strategies, including exercise, generally do not establish the moment in life when attention should begin to be paid to bone integrity, according to age group- and sex-related differences. Thus, this study analyzed the relationship between variables from the diagnosis of total and regional body composition, muscle strength, and bone mineral content (BMC) of femurs in young adult males. Thirty-four young Caucasian men (24.9 ± 8.6 years) had their body composition and bone density assessed by dual X-ray absorptiometry. The subjects performed a one-repetition maximum test (1-RM) in a bench press, front pulley, seated-row, push press, arm curl, triceps pulley, leg flexion, leg extension, and 45° leg press for the assessment of muscle strength in upper and lower limbs in single- and multi-joint exercises. Lean tissue mass in the trunk and upper and lower limbs were related to femoral BMC (Pearson coefficient ranging from 0.55 to 0.72, p < 0.01), and 1-RM values for different exercises involving both upper and lower limbs also correlated with femoral BMC (Pearson coefficients ranging from 0.34 to 0.46, p < 0.05). Taken together, these correlations suggest that muscle mass and strength are positively linked with the magnitude of femoral mass in men, even in early adulthood. Hence, the importance of an enhanced muscle mass and strength to the health of femoral bones in young adults was highlighted. Full article
(This article belongs to the Special Issue Skeletal Muscle Mechanics)
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14 pages, 3626 KB  
Article
Effects of Mechanical Stress on the Life and Insulation Performance of DC-Link Capacitors
by Xiaowu Sun, Ying Qiao, Yinda Li, Xiangming Guo and Chongfeng Cao
Energies 2024, 17(3), 699; https://doi.org/10.3390/en17030699 - 1 Feb 2024
Cited by 5 | Viewed by 2624
Abstract
Mechanical stress is a crucial factor affecting the life and insulation performance of DC-link capacitors (DCLCs). However, at present, there is a lack of long-term experimental observations on the effects of mechanical stress on the life and insulation performance of DCLCs. The element-winding [...] Read more.
Mechanical stress is a crucial factor affecting the life and insulation performance of DC-link capacitors (DCLCs). However, at present, there is a lack of long-term experimental observations on the effects of mechanical stress on the life and insulation performance of DCLCs. The element-winding process for DCLCs is carried out by winding metalized film on a reel and adjusting the various winding tensions and pressures according to performance requirements, usually with a winding tension coefficient (WTC) of kT = 1.5. The pull pressure of the winding machine on the film produces tension during the elements’ winding process, and the tension in the film grows after the heat-setting process. In this study, by adjusting the four tension coefficients of the elements in the winding process, which were 1.4, 1.5, 1.6, and 1.7, various winding tensions of the DCLC components were changed. Additionally, various heat-setting shrinkage tensions were appropriately generated by setting different heat-setting temperatures (HSTs). Relevant test platforms were established, and a life aging test, insulation resistance measurement, and withstand voltage test were performed on these DCLCs at different tension coefficients and HSTs. The obtained results reveal that the mechanical stress of DCLCs is affected by the parameters of the material itself, including the tension coefficient during the winding process and the HST. The winding tension affects the life of DCLCs, such that those with the highest tension (kT = 1.7) demonstrate the longest life at an HST of 105 °C, whereas samples with the lowest tension (kT = 1.4) exhibit the longest life at an HST of 110 °C. HSTs are capable of improving the lifetime of DCLCs. HSTs are also able to improve the withstand voltage capability of DCLCs, but the tension is not proportional to the withstand voltage capability of DCLCs. This research provides a suitable basis for further explorations of the life and insulation performance of DCLCs. Full article
(This article belongs to the Section F: Electrical Engineering)
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20 pages, 4852 KB  
Article
Complex Nanowrinkling in Chiral Liquid Crystal Surfaces: From Shaping Mechanisms to Geometric Statistics
by Ziheng Wang, Phillip Servio and Alejandro D. Rey
Nanomaterials 2022, 12(9), 1555; https://doi.org/10.3390/nano12091555 - 4 May 2022
Cited by 3 | Viewed by 3095
Abstract
Surface wrinkling is closely linked to a significant number of surface functionalities such as wetting, structural colour, tribology, frictions, biological growth and more. Given its ubiquity in nature’s surfaces and that most material formation processes are driven by self-assembly and self-organization and many [...] Read more.
Surface wrinkling is closely linked to a significant number of surface functionalities such as wetting, structural colour, tribology, frictions, biological growth and more. Given its ubiquity in nature’s surfaces and that most material formation processes are driven by self-assembly and self-organization and many are formed by fibrous composites or analogues of liquid crystals, in this work, we extend our previous theory and modeling work on in silico biomimicking nanowrinkling using chiral liquid crystal surface physics by including higher-order anisotropic surface tension nonlinearities. The modeling is based on a compact liquid crystal shape equation containing anisotropic capillary pressures, whose solution predicts a superposition of uniaxial, equibiaxial and biaxial egg carton surfaces with amplitudes dictated by material anchoring energy parameters and by the symmetry of the liquid crystal orientation field. The numerical solutions are validated by analytical solutions. The blending and interaction of egg carton surfaces create surface reliefs whose amplitudes depend on the highest nonlinearity and whose morphology depends on the anchoring coefficient ratio. Targeting specific wrinkling patterns is realized by selecting trajectories on an appropriate parametric space. Finally, given its importance in surface functionalities and applications, the geometric statistics of the patterns up to the fourth order are characterized and connected to the parametric anchoring energy space. We show how to minimize and/or maximize skewness and kurtosis by specific changes in the surface energy anisotropy. Taken together, this paper presents a theory and simulation platform for the design of nano-wrinkled surfaces with targeted surface roughness metrics generated by internal capillary pressures, of interest in the development of biomimetic multifunctional surfaces. Full article
(This article belongs to the Section Theory and Simulation of Nanostructures)
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22 pages, 1690 KB  
Article
Theoretical Study on Thermal Stresses of Metal Bars with Different Moduli in Tension and Compression
by Ying Guo, Si-Rui Wen, Jun-Yi Sun and Xiao-Ting He
Metals 2022, 12(2), 347; https://doi.org/10.3390/met12020347 - 16 Feb 2022
Cited by 8 | Viewed by 4312
Abstract
Extensive studies have shown that engineering materials, including metals and their oxides, will present different mechanical properties in tension or compression; however, this difference is generally neglected due to the complexity of the analysis. In this study, we theoretically analyze the thermal stress [...] Read more.
Extensive studies have shown that engineering materials, including metals and their oxides, will present different mechanical properties in tension or compression; however, this difference is generally neglected due to the complexity of the analysis. In this study, we theoretically analyze the thermal stress of a metal bar with a bimodular effect. First, the common strain suppression method is used to obtain a one-dimensional thermal stress expression. As a contrast with the one-dimensional solution, a two-dimensional thermoelasticity solution is also derived, based on the classical Duhamel theorem concerning body force analogy. Results indicate an important phenomenon that the linear temperature rise mode will produce thermal stress in a bimodular metal bar, whereas there is no thermal stress in the case of singular modulus. If the equilibrium relation is needed to be satisfied, the variation trend between different moduli and different thermal expansion coefficients in tension and compression should be opposite. In addition, the amplitude of stress variation, from the maximum tensile stress to the maximum compressive stress, increases dramatically. There exists an inevitable link between one- and two-dimensional solutions. These results are helpful to the refined analysis and measurements of the thermophysical properties of metals and their oxides. Full article
(This article belongs to the Special Issue Thermo-Physical Properties of Metals and Oxides)
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15 pages, 2177 KB  
Article
Highly Hydrophilic and Lipophilic Derivatives of Bile Salts
by M. Pilar Vázquez-Tato, Julio A. Seijas, Francisco Meijide, Francisco Fraga, Santiago de Frutos, Javier Miragaya, Juan Ventura Trillo, Aida Jover, Victor H. Soto and José Vázquez Tato
Int. J. Mol. Sci. 2021, 22(13), 6684; https://doi.org/10.3390/ijms22136684 - 22 Jun 2021
Cited by 12 | Viewed by 3681
Abstract
Lipophilicity of 15 derivatives of sodium cholate, defined by the octan-1-ol/water partition coefficient (log P), has been theoretically determined by the Virtual log P method. These derivatives bear highly hydrophobic or highly hydrophilic substituents at the C3 position of the [...] Read more.
Lipophilicity of 15 derivatives of sodium cholate, defined by the octan-1-ol/water partition coefficient (log P), has been theoretically determined by the Virtual log P method. These derivatives bear highly hydrophobic or highly hydrophilic substituents at the C3 position of the steroid nucleus, being linked to it through an amide bond. The difference between the maximum value of log P and the minimum one is enlarged to 3.5. The partition coefficient and the critical micelle concentration (cmc) are tightly related by a double-logarithm relationship (VirtuallogP=−(1.00±0.09)log(cmcmM)+(2.79±0.09)), meaning that the Gibbs free energies for the transfer of a bile anion from water to either a micelle or to octan-1-ol differ by a constant. The equation also means that cmc can be used as a measurement of lipophilicity. The demicellization of the aggregates formed by three derivatives of sodium cholate bearing bulky hydrophobic substituents has been studied by surface tension and isothermal titration calorimetry. Aggregation numbers, enthalpies, free energies, entropies, and heat capacities, ΔCP,demic, were obtained. ΔCP,demic, being positive, means that the interior of the aggregates is hydrophobic. Full article
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19 pages, 3338 KB  
Article
Assessment of the Tumbling-Snake Model against Linear and Nonlinear Rheological Data of Bidisperse Polymer Blends
by Pavlos S. Stephanou and Martin Kröger
Polymers 2019, 11(2), 376; https://doi.org/10.3390/polym11020376 - 20 Feb 2019
Cited by 6 | Viewed by 4911
Abstract
We have recently solved the tumbling-snake model for concentrated polymer solutions and entangled melts in the academic case of a monodisperse sample. Here, we extend these studies and provide the stationary solutions of the tumbling-snake model both analytically, for small shear rates, and [...] Read more.
We have recently solved the tumbling-snake model for concentrated polymer solutions and entangled melts in the academic case of a monodisperse sample. Here, we extend these studies and provide the stationary solutions of the tumbling-snake model both analytically, for small shear rates, and via Brownian dynamics simulations, for a bidisperse sample over a wide range of shear rates and model parameters. We further show that the tumbling-snake model bears the necessary capacity to compare well with available linear and non-linear rheological data for bidisperse systems. This capacity is added to the already documented ability of the model to accurately predict the shear rheology of monodisperse systems. Full article
(This article belongs to the Special Issue Theory and Simulations of Entangled Polymers)
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