Search Results (5,920)

The solid electrolyte interphase (SEI) is a passive layer, typically a few hundred angstroms thick, that forms on the electrode surface in the first few battery cycles when the electrode is in contact with the electrolyte in lithium-metal batteries. Composed of a combination of lithium salts and organic compounds, the SEI plays a critical role in battery performance, serving as a channel for Li-ion shuttling. Its structure typically comprises an inorganic component-rich sublayer near the electrode and an outer organic component-rich sublayer. Understanding heat transport through the SEI is crucial for improving battery pack safety, particularly since the Li-ion diffusion coefficient exhibits an exponential temperature dependence. This study employs first-principles calculations to investigate phonon-mediated temperature-dependent lattice thermal conductivity across the inorganic components of the SEI, including, LiF, Li₂O, Li₂S, Li₂CO₃, and LiOH. This study is also extended to the dependence of the grain size on thermal conductivity, considering the mosaic-structured nature of the SEI. Full article

Negative air ions (NAI) represent an important ecological value indicator for green tree species. Flow of sap is a crucial indicator for water utilization and physiological state of trees. Although there have been some advancements in studies on the correlation between the release of NAI by plants and sap flow in recent years, it is still unclear how the release of NAI by plants changes during drought stress and recovery processes, as well as the coupling effect between the release of NAI by plants and sap flow under drought stress. In this context, four typical green tree species, Robinia pseudoacacia, Quercus variabilis, Pinus tabulaeformis, and Platycladus orientalis, were selected as experimental materials. A drought stress and recovery control experiment was conducted based on OTC. The dynamic data of negative air ion concentration (NAIC) and sap flow rate during the process of drought stress and recovery were monitored to clarify the characteristics and correlations of NAI and sap flow changes in the experimental tree species under drought stress and recovery. The main research results are as follows: (1) At the end of the drought period, the NAI and sap flow in the drought treatment group significantly decreased (p < 0.01), compared with the control group (CK), and the reduction rate of sap flow (77.73 ± 4.96%) for each tree species was higher than that of NAI (47.78% ± 4.96%). (2) At 1 day after rehydration, the recovery amplitudes of NAI and sap flow for all tree species were the greatest; at 7 days after rehydration, the NAI and sap flow of the drought treatment group recovered to the levels of the control group (p > 0.05). (3) During different stages of drought rehydration, the response degree of NAI to sap flow varied. The study found that in the drought-rehydration stage, the correlation between the NAI released by each tree species and sap flow was the lowest at the drought endpoint. In conclusion, this research clarifies the changing patterns of plant NAI release and sap flow during drought-rehydration, as well as the response changes of NAI to sap flow. It provides a theoretical basis for selecting drought-tolerant tree species in arid regions. Full article

Against the backdrop of accelerating global energy transition, developing high-performance energy-storage systems is crucial for achieving carbon neutrality. Traditional electrode materials are limited by a single densification storage mechanism and low conductivity, struggling to meet demands for high energy/power density and a long cycle life. Carbon/high-entropy alloy nanocomposites provide an innovative solution through multi-component synergistic effects and cross-scale structural design: the “cocktail effect” of high-entropy alloys confers excellent redox activity and structural stability, while the three-dimensional conductive network of the carbon skeleton enhances charge transfer efficiency. Together, they achieve synergistic enhancement via interfacial electron coupling, stress buffering, and dual storage mechanisms. This review systematically analyzes the charge storage/attenuation mechanisms and performance advantages of this composite material in diverse energy-storage devices (lithium-ion batteries, lithium-sulfur batteries, etc.), evaluates the characteristics and limitations of preparation techniques such as mechanical alloying and chemical vapor deposition, identifies five major challenges (including complex and costly synthesis, ambiguous interfacial interaction mechanisms, lagging theoretical research, performance-cost trade-offs, and slow industrialization processes), and prospectively proposes eight research directions (including multi-scale structural regulation and sustainable preparation technologies, etc.). Through interdisciplinary perspectives, this review aims to provide a theoretical foundation for deepening the understanding of carbon/high-entropy alloy composite energy-storage mechanisms and guiding industrial applications, thereby advancing breakthroughs in electrochemical energy-storage technology under the energy transition. Full article

This study evaluates and compares the sorption performance of natural zeolite (NZ) and Fe(III)-modified zeolite (FeZ) in removing Cu(II) ions from aqueous solutions, with the goal of assessing their potential for environmental remediation. NZ was modified with Fe(NO₃)₃, NaOH and NaNO₃ solutions to improve its sorption properties. The modification led to a slight decrease in crystallinity (XRD), increase in pore volume (BET), functional groups (FTIR) and negative surface charge (zeta potential), thereby improving the affinity of FeZ towards Cu(II). Batch sorption experiments were conducted to optimize key parameters including pH, solid/liquid ratio (S/L), contact time, and initial Cu(II) concentration. The pH_o and S/L ratio were identified as key factors significantly influencing Cu(II) sorption on both zeolites, with a particularly pronounced effect observed for FeZ. The optimal conditions determined were pH_o = 3–5 for NZ, pH_o = 3 for FeZ, S/L = 10 g/L and a contact time of 600 min. Experimental results confirmed that FeZ has almost twice the sorption capacity for Cu(II) compared to NZ (0.271 mmol/g vs. 0.156 mmol/g), as further supported by elemental analysis, SEM-EDS and mapping analysis of saturated samples. The sorption of Cu(II) followed a mechanism of physical nature driven by ion exchange, dominated by intraparticle diffusion as the rate-controlling step. Leaching of copper-saturated zeolites according to the standard leaching method, DIN 38414 S4, demonstrated the ability of both zeolites to fully retain Cu(II) within their structure over a wide pH range, 4.01 ≤ pH_o ≤ 10.06. These findings highlight the superior performance of FeZ and its potential as an effective material for the remediation of copper-contaminated environments. Full article

Aquaporins (AQPs) are membrane proteins that facilitate the transport of water and solutes. Among AQPs, plasma membrane intrinsic proteins (PIPs) play a critical role in maintaining water balance between the internal and external cell environments. This study focuses on the tomato due to its economic importance and cultivation under moderate salinity conditions in Japan. A swelling assay using X. laevis oocyte confirmed that all five examined tomato SlPIP2 isoforms showed water transport activity. Among them, two-electrode voltage clamp (TEVC) experiments showed that only SlPIP2;1, SlPIP2;4, and SlPIP2;8 transport Na⁺ and K⁺, with no transport activity for Cs⁺, Rb⁺, Li⁺, or Cl⁻. CaCl₂ (1.8 mM) reduced ionic currents by approximately 45% compared to 30 µM free-Ca²⁺. These isoforms function as very low-affinity Na⁺ and K⁺ transporters. Expression analysis showed that SlPIP2;4 and SlPIP2;8 had low, stable expression, while SlPIP2;1 was strongly upregulated in roots NaCl treatment (200 mM, 17days), suggesting distinct physiological roles for these ion-conducting AQPs (icAQPs). These data hypothesized that tomato icAQPs play a critical role in ion homeostasis, particularly under salinity stress. In conclusion, the first icAQPs have been identified in the dicotyledonous crop. These icAQPs are essential for plant resilience under salt stress. Full article

Lanthanide hydrogen-bonded organic frameworks (Ln-HOFs) integrating luminescent and proton-conductive properties hold significant promise for multifunctional sensing and energy applications, yet their development remains challenging due to the difficulty of balancing structural stability and functional diversity. In this context, this study successfully synthesized a novel neodymium(III)-based hydrogen-bonded framework material, formulated as {Nd(H₂O)₃(4-CPCA)[H(4-CPCA)]∙H₂O}ₙ (SNUT-15), via hydrothermal assembly using 1-(4-carboxyphenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylic acid (H₂(4-CPCA)) as the ligand. Single-crystal X-ray diffraction analysis revealed a rare two-dimensional hydrogen-bonded bilayer structure stabilized by π-π stacking interactions and intermolecular hydrogen bonds. Hirshfeld surface analysis further corroborated the structural characteristics of this material. Moreover, leveraging the superior luminescent properties of lanthanide elements, this crystalline material exhibits dual functionality: selective fluorescence quenching toward Fe³⁺, La³⁺, and Mn²⁺ (with detection limits of 1.74 × 10⁻⁴, 1.88 × 10⁻⁴, and 3.57 × 10⁻⁴ mol·L⁻¹, respectively), as well as excellent proton conductivity reaching 7.92 × 10⁻³ S cm⁻¹ under conditions of 98% relative humidity and 353 K (80 °C). As a multifunctional neodymium(III)-based HOF material, SNUT-15 demonstrates its potential for applications in environmental monitoring and solid-state electrolytes, providing valuable insights into the rational design of lanthanide-containing frameworks. Full article

This study aims to develop environmentally friendly soil-stabilization materials by investigating the synergistic enhancement mechanism of industrial by-product lignin fibers (LFs) and sodium sulfate (Na₂SO₄) on the mechanical and micro-structural properties of cement-stabilized soil. A systematic evaluation was conducted through unconfined compressive strength (UCS), splitting tensile strength, and capillary water absorption tests, supplemented by microscopic analyses including XRD and SEM. The results indicate that the optimal synergistic effect occurs at 1.0% LF and 0.10% Na₂SO₄, which increases UCS and splitting tensile strength by 9.23% and 18.37%, respectively, compared to cement-stabilized soil. Meanwhile, early strength development is accelerated. Microscopically, LF physically bridges soil particles, forming aggregates, reducing porosity, and enhancing cohesion. Chemically, Na₂SO₄ acts as an activator, accelerating cement hydration and stimulating pozzolanic reactions to form calcium aluminosilicate hydrate and gypsum, which fill pores and densify the matrix. The synergistic mechanism lies in Na₂SO₄ enhancing the interaction between the LFs and clay minerals through ion exchange, facilitating the formation of a stable spatial network structure that inhibits particle sliding and crack propagation. This technology offers substantial sustainability benefits by utilizing paper-making waste LF and low-cost Na₂SO₄ to improve soil strength, toughness, and impermeability. Full article

Despite notable advancements in lithium-ion battery (LIB) technology, growing industrialization, rising energy demands, and evolving consumer electronics continue to raise performance requirements. As the primary determinant of battery performance, cathode materials have become a central research focus. Among emerging candidates, iron-based fluorides show great promise due to their high theoretical specific capacities, elevated operating voltages, low cost (owing to abundant iron and fluorine), and structurally diverse crystalline forms such as pyrochlore and tungsten bronze types. These features make them strong contenders for next-generation high-energy, low-cost LIBs. This review highlights recent progress in iron-based fluoride cathode materials, with an emphasis on structural regulation and performance enhancement strategies. Using pyrochlore-type hydrated iron trifluoride (Fe₂F₅·H₂O), synthesized via ionic liquids like BmimBF₄, as a representative example, we discuss key methods for tuning physicochemical properties—such as electronic conductivity, ion diffusion, and structural stability—via doping, compositing, nanostructuring, and surface engineering. Advanced characterization tools (XRD, SEM/TEM, XPS, Raman, synchrotron radiation) and electrochemical analyses are used to reveal structure–property–performance relationships. Finally, we explore current challenges and future directions to guide the practical deployment of iron-based fluorides in LIBs. This review provides theoretical insights for designing high-performance, cost-effective cathode materials. Full article

The flammability and volatility of conventional lithium hexafluorophosphate (LiPF₆)-based electrolytes with organic carbonate solvents remain critical issues to the safety and thermal stability of lithium-ion batteries (LIBs). This study investigates the incorporation of phosphate-based additives including ammonium dihydrogen phosphate (ADP), trimethyl phosphate (TMP), and trimethyl phosphite (TMPi) into LiPF₆ electrolytes for improving the ionic conductivity, safety, and electrochemical performance of LIBs. Self-extinguishing time (SET) measurements demonstrated that the ADP-based LiPF₆ electrolyte significantly reduced flammability, achieving a shorter SET of 04 min 53 s, compared to 12 min for the pristine LiPF₆ electrolyte. The ADP-based LiPF₆ electrolyte possessed the highest ionic conductivity (14.08 mS·cm⁻¹) with an excellent lithium-ion transference number of 0.0076. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (C-V) analyses demonstrated that ADP lowered interfacial resistance and stabilized long-term cycling behavior. In particular, the 1% ADP-based LiPF₆ electrolyte maintained improved charge-discharge profiles and Coulombic efficiency over 200 cycles. These results highlight ADP’s dual functionality in suppressing gas-phase flammability and enhancing condensed-phase electrochemical stability, making it a promising candidate for next-generation, high-safety, high-performance LIB electrolytes. Full article

Background/Objectives: Cocaine is a widely used illicit stimulant with significant toxicity. Despite its clinical relevance, the broader metabolic alterations associated with cocaine use remain incompletely characterized. This study aims to identify novel biomarkers for cocaine exposure by applying untargeted metabolomics to retrospective urine drug screening data. Methods: We conducted a retrospective analysis of a raw mass spectrometry (MS) dataset from urine comprehensive drug screening (UCDS) from 363 patients at the University of Pittsburgh Medical Center Clinical Toxicology Laboratory. The liquid chromatography–quadrupole time-of-flight mass spectrometry (LC-qToF-MS) data were preprocessed with MS-DIAL and subjected to multiple statistical analyses to identify features significantly associated with cocaine-enzyme immunoassay (EIA) results. Significant features were further evaluated using MS-FINDER for feature annotation. Results: Among 14,883 features, 262 were significantly associated with cocaine-EIA results. A subset of 37 more significant features, including known cocaine metabolites and impurities, nicotine metabolites, norfentanyl, and a tryptophan-related metabolite (3-hydroxy-tryptophan), was annotated. Cluster analysis revealed co-varying features, including parent compounds, metabolites, and related ion species. Conclusions: Features associated with cocaine exposure, including previously underrecognized cocaine metabolites and impurities, co-exposure markers, and alterations in an endogenous metabolic pathway, were identified. Notably, norfentanyl was found to be significantly associated with cocaine -EIA, reflecting current trends in illicit drug use. This study highlights the potential of repurposing real-world clinical toxicology data for biomarker discovery, providing a valuable approach to identifying exposure biomarkers and expanding our understanding of drug-induced metabolic disturbances in clinical toxicology. Further validation and exploration using complementary analytical platforms are warranted. Full article

In this work, (NaBi)_0.5−x(LiSm)_xBi₂Nb₂O₉ (NBN-xLS, x = 0.00–0.06) ceramics were fabricated by co-doping of LiSm into Na_0.5Bi_2.5Nb₂O₉. The traditional solid-phase technique was employed for the entire synthesis process. The impact of LiSm doping on the crystal structure, dielectric, ferroelectric, and piezoelectric properties, as well as the underlying conduction mechanisms in the NBN-xLS ceramics, was analyzed systematically. The XRD patterns and the Rietveld refinement revealed that lattice distortion reduced with an increase in the LiSm doping amount. The decrease in lattice distortion significantly contributed to its improved ferroelectric and piezoelectric characteristics. The results showed that the NBN-xLS ceramics were primarily p-type materials due to their bulk-limited conduction, with oxygen holes and vacancies acting as the conducting species, and the appearance of weak ion conduction at high temperatures. The NBN-0.04LS ceramic, in particular, displayed the highest performance, with P_r, T_c, and d₃₃ values of 9.05 μC/cm², 777 °C, and 25.2 pC/N, respectively. Additionally, the ceramic displayed remarkable thermal stability, with its d₃₃ retaining 95.0% of its original value after annealing at 760 °C. These results demonstrate that LiSm co-doped Na_0.5Bi_2.5Nb₂O₉ ceramics have potential for use in high-temperature sensors. Full article

Gel-type electrofluorochromic (EFC) devices, which reversibly modulate photoluminescence under electrical stimuli, have emerged as versatile platforms for advanced optoelectronic applications. By integrating redox-active luminophores with soft, ion-conductive gel matrices, these systems combine the structural robustness of solids with the ionic mobility of liquids, enabling a high-contrast, flexible, and multifunctional operation. This review provides a comprehensive overview of gel-based EFC technologies, outlining fundamental working principles, device architectures, and key performance metrics such as contrast ratio, switching time, and cycling stability. Gel matrices are categorized into ionogels, organogels, and hydrogels, and their physicochemical properties are discussed in relation to EFC device performance. Recent advances are highlighted across applications ranging from flexible displays and rewritable electronic paper to strain and biosensors, data encryption, smart windows, and hybrid energy-interactive systems. Finally, current challenges and emerging strategies are analyzed to guide the design of next-generation adaptive, intelligent, and energy-efficient optoelectronic platforms. Full article

The consistent quality control of ultrapure water (UPW) in semiconductor manufacturing depends on removing trace organonitrogen compounds such as urea. Due to its high solubility, chemical stability, and neutral polarity, urea is inadequately removed by conventional processes. Even at low concentrations, it elevates total organic carbon (TOC) and reduces electrical resistivity. The use of reclaimed water as a sustainable feed stream amplifies this challenge because its nitrogen content is variable and persistent. Conventional methods such as reverse osmosis, ultraviolet oxidation, and ion exchange remain limited in treating urea due to its uncharged, low-molecular-weight nature. This review examines the performance and limitations of these processes and explores electrochemical oxidation (EO) as an alternative. Advances in EO are analyzed with attention to degradation pathways, electrode design, reaction selectivity, and operational parameters. Integrated systems combining EO with membrane filtration, adsorption, or chemical oxidation are also reviewed. Although EO shows promise for selectively degrading urea, its application in UPW production is still in its early stages. Challenges such as low conductivity, byproduct formation, and energy efficiency must be addressed. The paper first discusses urea in reclaimed water and associated removal challenges, then examines both conventional and emerging treatment technologies. Subsequent sections delve into the mechanisms and optimization of EO, including electrode materials and operational parameters. The review concludes with a summary of main findings and a discussion of future research directions, aiming to provide a comprehensive foundation for validating EO as a viable technology for producing UPW from reclaimed water. Full article

Phosphates are key pollutants involved in the eutrophication of water bodies, creating the need for efficient and low-cost strategies for their removal in order to meet environmental quality standards. This study presents a comparative thermodynamic evaluation of phosphate ion adsorption from aqueous solutions using two sustainable and readily available materials: autoclaved aerated concrete (AAC) and pumice stone (PS). Batch experiments were conducted under acidic (pH 3) and alkaline (pH 9) conditions to determine equilibrium adsorption capacities, and kinetic experiments were carried out for the best-performing adsorbent. Adsorption data were fitted to the Langmuir and the Freundlich isotherm models, while kinetic data were evaluated using pseudo-first-order and pseudo-second-order models. The Freundlich model showed the best correlation (R² = 0.90 − 0.97), indicating the heterogeneous nature of the adsorbent surfaces, whereas the Langmuir parameters suggested monolayer adsorption, with maximum capacities of 1006.69 mg/kg for PS and 859.20 mg/kg for AAC at pH 3. Kinetic results confirmed a pseudo-second-order behavior, indicating chemisorption as the main mechanism and the rate-limiting step in the adsorption process. To the best of our knowledge, this is the first study to compare the thermodynamic performance of AAC and PS for phosphate removal under identical experimental conditions. The findings demonstrate the potential of both materials as efficient, low-cost, and thermodynamically favorable adsorbents. Furthermore, the use of AAC, an industrial by-product, and PS, a naturally abundant volcanic material, supports resource recovery and waste valorization, aligning with the principles of the circular economy and sustainable water management. Full article

The state of the art in the thermodynamics of calix[4]resorcinarene derivatives and its metal ion complexes is briefly discussed in the introduction. This is followed by the synthesis and characterization of a recyclable calix[4]resorcinarene amide derivative (L). The 1H NMR analyses in CD3CN and CD3OD showed solvent-dependent conformational changes with a notable downfield chemical shift in the aromatic proton (H-2) in moving from deuterated methanol to acetonitrile, indicating an interaction of the solvent within the ligand cavity as suggested by molecular dynamic simulations. 1H NMR complexation in acetonitrile revealed that L forms relatively strong 1:1 complexes with cations, with selectivity for Ca(II) and, to lesser extent, with Pb(II) over other metal cations. The composition of the complexes is corroborated by conductance measurements. The thermodynamics of these systems indicate that the complexation process is predominantly enthalpy controlled in acetonitrile, while it is entropy controlled in methanol. A remarkable outcome of fundamental studies is found in its application as new material for the removal of Ca(II) from water. The capacity of L to remove Ca(II) from water is 24 mmol/g which exceeds by far the capacity of cation exchange resins. Full article