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Search Results (524)

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15 pages, 1527 KiB  
Systematic Review
Using Virtual Reality Simulators to Enhance Laparoscopic Cholecystectomy Skills Learning
by Irene Suh, Hong Li, Yucheng Li, Carl Nelson, Dmitry Oleynikov and Ka-Chun Siu
Appl. Sci. 2025, 15(15), 8424; https://doi.org/10.3390/app15158424 - 29 Jul 2025
Viewed by 145
Abstract
(1) Medical training is changing, especially for surgeons. Virtual reality simulation is an excellent way to train surgeons safely. Studies show that surgeons who train with simulation have demonstrated improved technical skills in fundamental surgical procedures. The purpose of this study is to [...] Read more.
(1) Medical training is changing, especially for surgeons. Virtual reality simulation is an excellent way to train surgeons safely. Studies show that surgeons who train with simulation have demonstrated improved technical skills in fundamental surgical procedures. The purpose of this study is to determine the overall impact of virtual reality training on laparoscopic cholecystectomy performance and to explore whether specific training protocols or the addition of feedback confer any advantages for future surgeons. (2) MEDLINE (PubMed), Embase (Ovid SP), Web of Science, Google Scholar, and Scopus were searched for the literature related to virtual reality training, immersive simulation, laparoscopic surgical skills training, and medical education. Study quality was assessed using the Cochrane Risk of Bias Tool and NIH Quality Assessment Tool. (3) A total of 55 full-text articles were reviewed. Meta-analysis showed that virtual reality training is an effective method for learning cholecystectomy surgical skills. (4) Conclusions: Performance, measured by objective structured assessments and time to task completion, is improved with virtual reality training compared with no additional training. Positive effects of simulation training were evident in global rating scores and operative time. Continuous feedback on movement parameters during laparoscopic cholecystectomy skills training impacts skills acquisition and long-term retention. Full article
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12 pages, 1891 KiB  
Article
Full-Space Three-Dimensional Holograms Enabled by a Reflection–Transmission Integrated Reconfigurable Metasurface
by Rui Feng, Yaokai Yu, Dongyang Wu, Qiulin Tan and Shah Nawaz Burokur
Nanomaterials 2025, 15(14), 1120; https://doi.org/10.3390/nano15141120 - 18 Jul 2025
Viewed by 265
Abstract
A metasurface capable of flexibly manipulating electromagnetic waves to realize holograms presents significant potential in millimeter-wave imaging systems and data storage domains. In this study, full-space three-dimensional holograms are realized from a reflection–transmission integrated reconfigurable metasurface, which can achieve nearly 360° phase coverage [...] Read more.
A metasurface capable of flexibly manipulating electromagnetic waves to realize holograms presents significant potential in millimeter-wave imaging systems and data storage domains. In this study, full-space three-dimensional holograms are realized from a reflection–transmission integrated reconfigurable metasurface, which can achieve nearly 360° phase coverage in reflection space and 180° phase coverage in transmission space. By adjusting the voltage applied to the constituting electronically tunable meta-atoms of the metasurface, an octahedron hologram constituted by three hologram images in different focal planes is generated in the reflection space at 6.25 GHz. Moreover, a diamond hologram, also composed of three hologram images in different focal planes, is achieved in the transmission space at 6.75 GHz. Both the numerical simulation and experimental measurement are performed to validate the full-space holograms implemented by the modified weighted Gerchberg–Saxton (WGS) algorithm with specific phase distribution in different imaging planes. The obtained results pave the way for a wide range of new applications, such as next-generation three-dimensional displays for immersive viewing experiences, high-capacity optical communication systems with enhanced data encoding capabilities, and ultra-secure anti-counterfeiting solutions that are extremely difficult to replicate. Full article
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15 pages, 289 KiB  
Project Report
Characteristics of Authentic Construction Learning Experiences to Enable Accurate Consideration of Cost-Effective Alternatives
by Karan R. Patil, Steven K. Ayer, Kieren H. McCord, Logan A. Perry, Wei Wu, Jeremi S. London and Andrew R. Kline
Buildings 2025, 15(14), 2446; https://doi.org/10.3390/buildings15142446 - 11 Jul 2025
Viewed by 237
Abstract
Authentic learning opportunities that simulate full-scale design and construction using real materials provide valuable experiential learning environments for construction and civil engineering students by challenging students to apply building concepts in practical settings. These activities challenge students to apply theoretical concepts in a [...] Read more.
Authentic learning opportunities that simulate full-scale design and construction using real materials provide valuable experiential learning environments for construction and civil engineering students by challenging students to apply building concepts in practical settings. These activities challenge students to apply theoretical concepts in a realistic, hands-on context. However, the excessive cost of real building materials required for this mode of education limits access to the vast majority of students. As a result, educational researchers have explored potential alternatives to provide cost-effective experiential learning through activities using mock-up materials (e.g., plastic straws and popsicle sticks) and a simulation of experiences using immersive technologies (e.g., virtual reality or augmented reality). While some of these alternatives approximate the environment and others provide physical interaction with mock-up materials, the lack of authenticity in the building materials used introduces some apparent differences between the “authentic” learning environments and their cost-effective approximations. Therefore, this research aims to identify the learning processes reported by students and faculty who participated in authentic learning experiences to understand the ways in which this mode of education offers unique value to construction education. Their interview responses illustrated characteristics of authentic learning experiences that were believed to be critical to the learning process, some of which included working in groups; interdisciplinary participants; and the use of real construction materials. Although some of these characteristics are intrinsically linked to the use of real materials, others do not explicitly refer to interaction with real materials. This may point to specific aspects of authentic learning that educational researchers can replicate or enhance to provide cost-effective learning environments, such as virtual or augmented reality. The contribution of this paper is in identifying the characteristics of authentic learning experiences that may guide educational investment and research innovations that aim to replicate some of these learning experiences through more accessible learning environments. Full article
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22 pages, 2561 KiB  
Article
Virtual Reality and Digital Twins for Catastrophic Failure Prevention in Industry 4.0
by Vicente Rojas Catalán, José Luis Valín, Felipe Muñoz-La Rivera, Julio Ortega, Nicolás Norambuena, Emanuel Ramirez and Cristóbal Ignacio Galleguillos Ketterer
Appl. Sci. 2025, 15(13), 7230; https://doi.org/10.3390/app15137230 - 27 Jun 2025
Viewed by 406
Abstract
This paper presents an integrated methodology for remote monitoring, technical training and early warning systems in virtual reality environments oriented towards Industry 4.0. The proposal incorporates an engine modeled as a digital twin in Unity 3D, connected to physical sensors, and transmitted through [...] Read more.
This paper presents an integrated methodology for remote monitoring, technical training and early warning systems in virtual reality environments oriented towards Industry 4.0. The proposal incorporates an engine modeled as a digital twin in Unity 3D, connected to physical sensors, and transmitted through an IoT platform. This architecture allows continuous monitoring and immersive visualization, in addition to generating alerts when operating conditions exceed critical limits, allowing users to simulate fault conditions in real time and perform interactive training without putting equipment or operators at risk. This work proposes a low-cost simulation platform, based on virtual reality and real-time digital twins, designed to support training and capacity building in industrial environments. This methodology seeks to propose general guidelines that allow the integration of these technologies in a general way to enrich both preventive and predictive maintenance mechanisms, as well as training processes. Full article
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11 pages, 1353 KiB  
Article
Adhesion of 3D-Printed Versus Milled Resin Posts to Composite Resin Core Build-Up Material: Influence of Surface Treatments
by Khalid K. Alanazi, Ali Robaian Alqahtani, Abdullah Mohammed Alshehri, Abdullah Ali Alqahtani, Abdulellah Almudahi, Omar Abdulaziz Al-Mansour, Nawaf Abdullah Al-Harbi, Sultan Sahman Abdulrahman Alqahtani, Eman Mohamed Raffat Hussein and Tarek Ahmed Soliman
Polymers 2025, 17(12), 1711; https://doi.org/10.3390/polym17121711 - 19 Jun 2025
Viewed by 478
Abstract
Background: There are very few studies in literature concerning the bonding between 3D-printed resin posts and the core build-up material. This study aimed to evaluate and compare the adhesion of 3D-printed and milled resin posts to composite resin core build-up material following different [...] Read more.
Background: There are very few studies in literature concerning the bonding between 3D-printed resin posts and the core build-up material. This study aimed to evaluate and compare the adhesion of 3D-printed and milled resin posts to composite resin core build-up material following different surface treatments. Methods: Three types of resin posts were utilized in this study: ready-made glass-reinforced fiber post (3M ESPE, Germany), milled PEEK POST (Bredent, Germany), and 3D-printed resin post (CROWNTEC, Saremco Dental AG, Switzerland). Each type of post was categorized into three groups based on surface treatments: C: untreated surfaces; SB: Air abrasion with 50 μm aluminum oxide particles was applied to the posts’ surfaces.; HO: the posts’ surfaces were immersed in 30% H2O2 for 5 min. A dual-cured composite resin (Grandio DC; VOCO) was utilized for core build-up in each group to evaluate adhesion through the push-out bond strength test. The modes of failure were analyzed, and the surface morphology of the post was characterized using SEM. Data were analyzed using a two-way analysis of variance (ANOVA) along with Tukey’s test. Results: The two-way ANOVA indicated a significant effect for surface treatment (F = 583.54, p < 001), post type (F = 79.96, p < 0.001), and their interactions (F = 265.74, p < 0.001). Regarding 3D-printed resin post, 30% H2O2 for 5 min recorded the highest statistically significant bond strength value (13.11 ± 1.61) compared to other groups. Regarding the milled PEEK post, the air particle abrasion recorded the highest statistically significant value (23.88 ± 1.66) compared to other groups. Adhesive failure was the predominant failure type, with an occurrence rate of 70.35%. Mixed failure was noted in 24.07% of the cases, with a significant prevalence in the PEEK post within the air particle abrasion group (58.3%). Cohesive failure was noted in 5.54% of cases, with a significant prevalence in the air particle abrasion group, occurring at rates of 16.6% in the resin fiber post group and 33.3% in PEEK posts. Conclusions: Air particle abrasion significantly improved the push-out bond strength of milled PEEK posts, but it did not have a similar effect on the 3D-printed resin posts. The application of 30% H2O2 for 5 min to 3D-printed resin post enhanced the adhesion to core build-up material. The manufacturing method of posts, the surface treatments utilized, and their interactions affect the interfacial bond strength between posts and the composite resin core build-up material. Full article
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35 pages, 1794 KiB  
Article
Challenge/Competence Appraisal by Swiss Two-Way Immersion Teachers of the “Cursus bilingue/Bilingualer Studiengang” in Their Professionalization Process and Career-Entry Stage Implications
by Melanie Buser
Educ. Sci. 2025, 15(6), 773; https://doi.org/10.3390/educsci15060773 - 18 Jun 2025
Viewed by 312
Abstract
The growing number of public one-way and two-way immersion schools (French/German) in the Swiss cantons of Bern, Jura, and Neuchâtel has resulted in an increased need for teachers who are explicitly prepared for those schools. This need led to the thoughtfully conceptualized two-way [...] Read more.
The growing number of public one-way and two-way immersion schools (French/German) in the Swiss cantons of Bern, Jura, and Neuchâtel has resulted in an increased need for teachers who are explicitly prepared for those schools. This need led to the thoughtfully conceptualized two-way immersion curriculum “Cursus bilingue/Bilingualer Studiengang,” jointly offered by two universities of teacher education located in the French- and German-speaking areas of Switzerland. This study explores the professionalization process of future primary teachers from Bern, Jura, and the bilingual program who are confronted with professional requirements. A scientific tool, used in a longitudinal perspective (2020–2023), documents how students of the two-way immersion and the French and German programs (n = 1021) weigh these requirements in the competence and challenge dimensions. A linear mixed-effects model was used to analyze their appraisal within each dimension across time and context. Independently of the context, the competence weighting increases for all students between t1 and t3. However, the challenge weighting exhibits a peak at t2 in all contexts, maybe due to the consciousness-raising of faced challenges after half of the program. With teaching internships in two linguistic regions, two-way immersion students demonstrate a capacity for adaptability. Research-based and practitioner-informed implications for an induction program aiming to foster the further professionalization needed to master the new complexities during the career-entry stage are presented. Full article
(This article belongs to the Special Issue Bilingual Education in a Challenging World: From Policy to Practice)
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23 pages, 5352 KiB  
Article
Durability Performance of Alkali-Activated Natural Pozzolan and Limestone Powder Mortar in Sulfate Environments
by Adeshina Adewale Adewumi, Babatunde Abiodun Salami, Mohd Azreen Bin Mohd Ariffin, Moruf Olalekan Yusuf, Khaled A. Alawi Al-Sodani and Mohammed Ibrahim
Sustainability 2025, 17(12), 5611; https://doi.org/10.3390/su17125611 - 18 Jun 2025
Viewed by 371
Abstract
The pressing need for sustainable construction materials has identified alkali-activated materials (AAMs) as eco-friendly alternatives to conventional Portland cement. This study explores the synergistic performance of alkaline-activated natural pozzolan and limestone powder (AANL) blends against sulfate attack, evaluating mortar specimens immersed in sodium [...] Read more.
The pressing need for sustainable construction materials has identified alkali-activated materials (AAMs) as eco-friendly alternatives to conventional Portland cement. This study explores the synergistic performance of alkaline-activated natural pozzolan and limestone powder (AANL) blends against sulfate attack, evaluating mortar specimens immersed in sodium sulfate, magnesium sulfate, and a combined sulfate solution over 12 months. The samples were synthesized using natural pozzolan (NP) and limestone powder (LSP) in three distinct binder combinations to evaluate the influence of varying precursor ratios on the material’s performance, as follows: NP: LSP = 40:60 (AN40L60), 50:50 (AN50L50), and 60:40 (AN60L40). At the same time, the alkaline activators of 10 M NaOH(aq) and Na₂SiO3(aq) were combined in a ratio of 1:1 and cured at 75 °C. The research examines the weight variations of the samples, their residual compressive strength, and microstructural characteristics under exposure to magnesium sulfate, sodium sulfate, and a combined sulfate solution. In terms of weight change, samples exposed to Na2SO4 gained weight slightly, with AN40L60 recording the highest gain (3.2%) due to the ingress of sulfate ions and pore filling. Under MgSO4, AN60L40 had the lowest weight gain (29%), while AN40L60 reached 54%. In mixed sulfate, AN60L40 showed negligible weight gain (0.11%); whereas, AN50L50 and AN40L60 gained 2.43% and 1.81%, respectively. Compressive strength retention after one year indicated that mixes with higher NP content fared better. AN60L40 exhibited the highest residual strength across all solutions—16.12 MPa in Na2SO4, 12.5 MPa in MgSO4, and 19.45 MPa in the mixed solution. Conversely, AN40L60 showed the highest strength degradation, losing 47.22%, 58.11%, and 55.89%, respectively. SEM-EDS and FTIR analyses confirm that LSP’s vulnerability to sulfate attack diminishes with increased NP incorporation, highlighting a synergistic interaction that mitigates degradation and retains structural integrity. The combination of 60% NP and 40% LSP demonstrated superior resistance to all sulfate environments, as evidenced by visual durability, minimized weight gain, and retained compressive strength. This study highlights the potential of tailored NP-LSP combinations in developing durable and sustainable AAMs, paving the way for innovative solutions in sulfate-prone environments, while reducing environmental impact and promoting economic efficiency. Full article
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11 pages, 1281 KiB  
Article
Effect of Thermal Aging on Color Stability and Mechanical Properties of High-Density CAD/CAM Polymers Utilized for Provisional Restorations
by Rasha Alharthi, Ali Robaian Alqahtani, Abdullah Mohammed Alshehri, Abdulrahman Almalki, Heba Wageh Abozaed, Eman Mohamed Raffat Hussein and Tarek Ahmed Soliman
J. Funct. Biomater. 2025, 16(6), 223; https://doi.org/10.3390/jfb16060223 - 15 Jun 2025
Viewed by 751
Abstract
Background: This study evaluated and compared the effects of thermal aging on the color stability and mechanical properties of CAD/CAM polymers utilized for provisional restorations. Material and Methods: Three CAD/CAM polymers in this study: CAD-Temp (CAT), Everest C-Temp (CT), and PEEK (PK). Forty [...] Read more.
Background: This study evaluated and compared the effects of thermal aging on the color stability and mechanical properties of CAD/CAM polymers utilized for provisional restorations. Material and Methods: Three CAD/CAM polymers in this study: CAD-Temp (CAT), Everest C-Temp (CT), and PEEK (PK). Forty specimens of each material were randomly assigned to two subgroups. Subgroup A was immersed in distilled water for 24 h, whereas Subgroup B was subjected to 5000 thermal cycles. The color stability, flexural strength (FS), survival probability, and microstructures were evaluated following thermal cycling. Data analysis was conducted utilizing two-way ANOVA along with Tukey’s test. Results: The CAT (3.74 ± 0.39) and CT (3.51 ± 0.54) groups exhibited the highest color variations, while PEEK (2.95 ± 0.45) showed the lowest color change. The baseline groups showed that the CT group had the highest flexural strength value (p < 0.05). The flexural strength values of CAT and CT groups significantly decreased (p < 0.05) following thermal cycling. No significant decrease in FS was observed following thermal cycling in the Pk group (p = 0.16). Conclusions: The color measurement and flexural strength outcomes were significantly influenced by CAD/CAM materials and thermal cycling. The CT group demonstrated superior flexural strength compared to the other groups, both before and after thermal cycling. The PK group shows the lowest color change compared to other groups. Regardless of aging condition, C-Temp and PEEK materials recorded the highest survival probability, a 95% significance level compared to CAD-Temp. Full article
(This article belongs to the Special Issue Advanced Dental Restorative Composite Materials)
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13 pages, 895 KiB  
Article
Perspectives on Generative Sound Design: A Generative Soundscapes Showcase
by Grzegorz Samson
Arts 2025, 14(3), 67; https://doi.org/10.3390/arts14030067 - 12 Jun 2025
Viewed by 680
Abstract
Recent advancements in generative neural networks, particularly transformer-based models, have introduced novel possibilities for sound design. This study explores the use of generative pre-trained transformers (GPT) to create complex, multilayered soundscapes from textual and visual prompts. A custom pipeline is proposed, featuring modules [...] Read more.
Recent advancements in generative neural networks, particularly transformer-based models, have introduced novel possibilities for sound design. This study explores the use of generative pre-trained transformers (GPT) to create complex, multilayered soundscapes from textual and visual prompts. A custom pipeline is proposed, featuring modules for converting the source input into structured sound descriptions and subsequently generating cohesive auditory outputs. As a complementary solution, a granular synthesizer prototype was developed to enhance the usability of generative audio samples by enabling their recombination into seamless and non-repetitive soundscapes. The integration of GPT models with granular synthesis demonstrates significant potential for innovative audio production, paving the way for advancements in professional sound-design workflows and immersive audio applications. Full article
(This article belongs to the Special Issue Sound, Space, and Creativity in Performing Arts)
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10 pages, 1611 KiB  
Proceeding Paper
Access to Digital Cultural Heritage: Exploring Future Perspectives Through Open Tools of Research
by Veronica Casadei and Giuseppe Di Modica
Eng. Proc. 2025, 96(1), 10; https://doi.org/10.3390/engproc2025096010 - 9 Jun 2025
Viewed by 376
Abstract
In line with the research objectives of the SCORPiò-NIDI project, we aim to implement a software platform showcasing the digital models developed during the project. The goal is to develop dynamic and interactive user experiences, expanding access to cultural heritage through digital means, [...] Read more.
In line with the research objectives of the SCORPiò-NIDI project, we aim to implement a software platform showcasing the digital models developed during the project. The goal is to develop dynamic and interactive user experiences, expanding access to cultural heritage through digital means, which become spaces for engaging and educational experiences. Using open-source frameworks, users can explore the complexity of Roman siege machines in an immersive way, interacting directly with the digital models. We will focus on the 3D model of the scorpion created by Dr. Claudio Formicola (University of Campania Luigi Vanvitelli), using the 3D modeling software Rhinoceros. Full article
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24 pages, 1119 KiB  
Article
Experiential Programming for Resorts
by Matthew Miller and Jannatul Rafia-Tracy
Tour. Hosp. 2025, 6(2), 105; https://doi.org/10.3390/tourhosp6020105 - 6 Jun 2025
Viewed by 598
Abstract
This study investigates the influence of experiential programs (EPs) on enhancing consumer experience offerings at luxury resorts. EPs encompass a variety of activities, amenities, and services designed to immerse consumers in the local culture, scenery, and authenticity. The research focuses explicitly on EPs [...] Read more.
This study investigates the influence of experiential programs (EPs) on enhancing consumer experience offerings at luxury resorts. EPs encompass a variety of activities, amenities, and services designed to immerse consumers in the local culture, scenery, and authenticity. The research focuses explicitly on EPs related to fitness, evening entertainment, children’s activities, and personalized experiences. By analyzing data from 30 resorts, significant trends and typologies within each category of EP emerged, highlighting the diverse ways in which resorts meet consumers’ desires for immersive and status-enhancing experiences. Valuable insights were gained through semi-structured interviews with two hoteliers, providing a deeper understanding of the strategic integration of EPs. Fitness EPs highlight activities, including hiking and yoga, whereas evening entertainment encompasses experiences like mixology, music, and astronomy education. For children, EPs prioritize cultural immersion through hands-on experiences, while personalized EPs—including romance packages and private dining—allow for consumer exclusivity. The research underscores how these EPs align with contemporary trends in conspicuous consumption, where luxury resorts leverage unique, high-quality, and culturally rich experiences to reinforce affluence and societal standing. The findings emphasize that EPs are a vital strategy for luxury resorts to differentiate themselves in a competitive market, enhancing consumer satisfaction, loyalty, and positive self-image. Full article
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21 pages, 1627 KiB  
Systematic Review
Immersive Tools in Engineering Education—A Systematic Review
by Vasco Reis, João Santos Baptista and Joana Duarte
Appl. Sci. 2025, 15(11), 6339; https://doi.org/10.3390/app15116339 - 5 Jun 2025
Cited by 1 | Viewed by 845
Abstract
Immersive tools are being adopted as an alternative to traditional education methods, especially in engineering curricula, where it is common to integrate various disciplines such as science, technology, engineering, and mathematics (STEM). This systematic review aimed to evaluate the effectiveness of immersive tools [...] Read more.
Immersive tools are being adopted as an alternative to traditional education methods, especially in engineering curricula, where it is common to integrate various disciplines such as science, technology, engineering, and mathematics (STEM). This systematic review aimed to evaluate the effectiveness of immersive tools and serious games in improving student engagement and knowledge retention in engineering education. This study follows the Preferred Reporting Items for Systematic Reviews and Meta-Analyses guidelines, analyzing 31 articles published between 2020 and 2025 across four databases (Scopus, Web of Science, Dimensions, and ScienceDirect). Articles were included if they complied with the following inclusion criteria: using (any) immersive tools, carrying out evaluation methods, and participation of students in STEM-related engineering courses. The data extracted encompassed sample characteristics, game attributes, evaluation methods, and results. The findings suggest that immersive tools positively impact students’ engagement and motivation. However, challenges such as potential motion sickness, complexity of serious games (SGs), and high implementation costs exist. SG design must balance engagement, immersion and pedagogical effectiveness to ensure viability. Future research should assess long-term impacts and promote methodological consistency across studies, particularly in subject areas and sample demographics, while determining a way to reduce motion sickness and alleviating SG complexity and difficulty. Full article
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18 pages, 25346 KiB  
Article
The Impact of Prophylactic Polishing Pastes on the Surface Roughness, Color, and Stain Resistance of CAD/CAM Restorative Materials
by Betul Arkan, Ipek Iscan and Neslihan Tinastepe
Dent. J. 2025, 13(5), 212; https://doi.org/10.3390/dj13050212 - 15 May 2025
Viewed by 488
Abstract
Background: Prophylactic polishing pastes (PPPs) are widely used to clean teeth and dental restorations; however, their effects on restorative materials are crucial for clinical outcomes. This study investigates the impact of PPPs on the susceptibility of CAD/CAM restorative materials to staining and the [...] Read more.
Background: Prophylactic polishing pastes (PPPs) are widely used to clean teeth and dental restorations; however, their effects on restorative materials are crucial for clinical outcomes. This study investigates the impact of PPPs on the susceptibility of CAD/CAM restorative materials to staining and the relationship between surface roughness and discoloration. Methods: Samples of tested materials (resin nanoceramic, hybrid ceramic, feldspathic ceramic, and lithium disilicate-reinforced glass ceramic) were treated with various PPPs (Cleanic, CleanJoy, Detartrine, Proxyt). Surface roughness and color parameters were recorded before and after the PPP application and following coffee immersion for 12 days. Initial measurements of surface roughness (Ra1) and color were taken. The specimens were divided into groups based on the PPP applied. After PPP application, secondary roughness (Ra2) and color values were measured. Changes in roughness (ΔRa), color (ΔE*ab, ΔE00), and whiteness index (ΔWID) were calculated post-application and after coffee immersion. Data normality was tested with the Shapiro–Wilks test. Two-way ANOVA evaluated the effects of material type and PPP on ΔE, ΔWID, and ΔRa. One-way ANOVA, Tukey HDS test, and Pearson correlation were used for further analysis, with significance set at p < 0.05. Results: The Vita Enamic–Detartrine group showed the highest ΔEab 1 and ΔE001 values, while Cerasmart–control showed the lowest. The Vita Enamic–Proxyt group had the lowest ΔWID1, and Vita Enamic–Cleanjoy exhibited the highest values of ΔEab 2, ΔE002, and ΔWID2. The E.MAX–control group had the lowest values for these metrics. No significant correlation was found between ΔRa and color changes (ΔE*ab 2, ΔE002, ΔWID2); however, a moderate positive correlation was found between values of ΔE1 and ΔE2. Conclusions: These findings indicate that PPPs significantly affect the discoloration and surface features of CAD/CAM materials, with both types of PPPs and materials. Full article
(This article belongs to the Section Dental Materials)
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14 pages, 2955 KiB  
Article
From Game to Concert: Exploratory Listening in ‘Stardew Valley: Festival of Seasons’ Concert Tour
by Natalie P. Miller and Elizabeth Hellmuth Margulis
Behav. Sci. 2025, 15(5), 667; https://doi.org/10.3390/bs15050667 - 13 May 2025
Viewed by 670
Abstract
Exploratory listening encompasses the various ways, contexts, and levels of attention with which listeners engage with their sonic environment. This paper presents findings from qualitative research conducted with audience members during the Stardew Valley: Festival of Seasons concert tour. During these events, attendees [...] Read more.
Exploratory listening encompasses the various ways, contexts, and levels of attention with which listeners engage with their sonic environment. This paper presents findings from qualitative research conducted with audience members during the Stardew Valley: Festival of Seasons concert tour. During these events, attendees encountered music from the widely successful indie video game, reorchestrated in a new context. Just as the game encourages exploration through open-ended gameplay, the concerts prompt listeners to explore how the rearranged music refers to and diverges from its use in the game. Findings suggest that attendees deployed their attention to divergent aspects of the music. While some attendees focused on specific musical aspects like recognizable melodies and instrumentation, others focused on the broader audiovisual and community aspects of the performance. Results also indicate that highly immersed listeners experience diverse thoughts, including those not directly about the immediate musical content. Positioning music-evoked imaginings as a way listeners become immersed in musical experiences, we report on how exploratory listening shapes the dynamics of attention, immersion, and enjoyment within musical and audiovisual contexts. Full article
(This article belongs to the Special Issue Music Listening as Exploratory Behavior)
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16 pages, 8075 KiB  
Article
Spent LiFePO4 to High-Value LiF: Enhanced Mechanical Chlorination Coupled with a Fluorination Reaction Mechanism
by Chao Liang, Nengwu Zhu, Fei Li, Pengfei Zhang, Pingxiao Wu and Yaxi Hu
Processes 2025, 13(5), 1478; https://doi.org/10.3390/pr13051478 - 12 May 2025
Viewed by 504
Abstract
LiFePO4 (LFP) batteries are among the earliest commercialized and most discarded lithium-ion batteries. Although existing recovery technologies focus on the conversion of LiFePO4 to Li2CO3, challenges associated with achieving near-full recovery and high-value products remain. This study [...] Read more.
LiFePO4 (LFP) batteries are among the earliest commercialized and most discarded lithium-ion batteries. Although existing recovery technologies focus on the conversion of LiFePO4 to Li2CO3, challenges associated with achieving near-full recovery and high-value products remain. This study proposes a strategy for the conversion of spent LiFePO4 to LiF by mechanical chlorination coupled with a fluorination reaction. The optimum conditions were determined to be a ball-to-powder ratio (BPR) = 15, NH4Cl:LFP = 3, H2O2 = 2.0 mL, rotation speed = 600 rpm, and grinding time = 12 h. Results showed that 97.14% Li was converted into LiCl by H2O2–NH4Cl mechanical chlorination. When chlorinated intermediates were immersed in water, FePO4 could be harvested, and 96.79% Li could be recovered as LiF with a purity of 99.50% after adding NH4F. When Cl-functionalized renewable resin was used to exchange 99.89% F, 0.63 g NH4Cl per litre of LiF conversion residual liquid was derived. The favourable results were attributed to the 1O2 generated by H2O2, which had a strong electron affinity to break Li–O bonds and provided superior conditions for the combination of Li and Cl. During fluorination, the formation of LiF reduced the ion concentration, and the entropy decreased, contributing to the spontaneous reaction. Therefore, the proposed method paves the way for near-full recovery and high-value products of spent LiFePO4. Full article
(This article belongs to the Section Chemical Processes and Systems)
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