Search Results (226)

Marine deck coatings suffer from premature failures such as wear thinning, flaking, and brittle cracking under repeated rolling, abrupt stopping/steering, and high shear loads of heavy equipment due to the imbalance of hardness, strength, toughness, and wear resistance. To address this issue, a rolling load-resistant coating system with an epoxy–amine/epoxy–thiol dual-crosslinked network was constructed using liquid polysulfide rubber (Lp-3) as the key crosslinking modifier, and the effect of Lp-3 content (0–2 wt%) on the comprehensive performance of the coating was systematically investigated. The results showed that the coating achieved the optimal synergy of properties at 1 wt% Lp-3 loading: Shore hardness reached 88.7 HD with the pencil hardness maintained at 8H, adhesion strength increased to 7.2 MPa, Taber abrasion loss significantly decreased to 14.8 mg, tensile strength rose from 5.5 MPa to 12.4 MPa, elongation at break nearly doubled, shear strength reached 10.2 MPa, and the failure mode transformed from brittle cleavage to ductile shear. Mechanistic analysis revealed that the terminal thiol groups of Lp-3 underwent a click reaction with epoxy groups, covalently embedding flexible polysulfide segments into the rigid epoxy network and forming Fe–S interfacial chemical bonds to enhance adhesion. The microphase separation, chain relaxation, and energy dissipation mechanisms effectively blunted crack propagation and alleviated stress concentration, while maintaining sufficient surface hardness and the continuity of the load-bearing skeleton. This work realizes the synergistic optimization of high strength, high toughness, strong adhesion, and excellent wear resistance for marine deck coatings and provides a new strategy and critical technical parameters for the design of functional coatings under heavy-duty dynamic service environments. Full article

Under complex terrains and extreme environmental conditions such as high wind speeds, prestressed rock anchor foundations for onshore wind turbines are subjected to multiple coupled adverse effects during long-term service, including cyclic wind loading, temperature variation, groundwater intrusion, and rock mass weathering. These factors significantly affect structural performance and service life through corrosion and material degradation processes, while conventional design methods mainly focus on ultimate bearing capacity and lack a systematic consideration of corrosion-induced deterioration mechanisms and long-term performance evolution. Without changing the theoretical framework of current design codes, this study introduces a durability-oriented design concept and explicitly incorporates corrosion effects and material degradation into the analytical system of prestressed rock anchor foundations. First, from the perspective of anchor force evolution, a time-dependent analysis method for long-term prestress loss is established, considering the coupled effects of steel corrosion, material relaxation, and cyclic loading. Second, for the mechanical behavior of group anchor systems, a shear capacity model is proposed that accounts for rock mass strength degradation and grout–rock interface deterioration. Meanwhile, the coupling relationship between foundation void development and groundwater seepage is analyzed, revealing its critical role in the corrosion evolution process. On this basis, a coordinated design method for foundation dimensions and prestress parameters is developed to satisfy both load-bearing capacity and durability requirements. Finite element analysis is further conducted to verify the stress and deformation characteristics of the foundation–rock–anchor system under nonlinear conditions. Engineering case studies demonstrate that the proposed method not only meets bearing capacity requirements, but also effectively suppresses void development, reduces corrosion risk, delays structural performance degradation, and improves long-term service reliability. The findings provide a theoretical basis and engineering reference for the durability design and lifecycle performance optimization of prestressed rock anchor foundations for onshore wind power structures in extreme environments. Furthermore, the study underscores the critical role of advanced anti-corrosion coatings and surface protection systems in mitigating the coupled corrosion-degradation mechanisms, aligning with the scope of this Special Issue on corrosion protection and durability of infrastructure in harsh environments. Full article

Interfacial bond failure is a common form of distress in rigid–flexible composite pavements, especially in tunnel environments with harsh service conditions. Epoxy-emulsified asphalt (EEA) is widely used as a high-performance interlayer bond coat, but its dynamic damage evolution under coupled thermomechanical loading remains insufficiently characterised. In this work, 45° static oblique shear tests and stress-controlled dynamic shear fatigue tests were performed on a C40 concrete-EEA-asphalt mixture composite system. Tests covered a temperature range of −10 °C to 45 °C, loading frequencies of 1 to 15 Hz, and three stress levels (0.3, 0.4, 0.5). An optimised geometric tangent method (GTM) was adopted to objectively locate the fatigue failure inflexion point, reducing the empirical bias inherent in traditional stiffness degradation analysis. Test results showed that an EEA application rate of 0.8 kg/m² yielded the best overall interface performance, balancing mechanical interlocking and cohesive strength. At this application rate, the interfacial peak shear strength reached 1.72 MPa, with improved interfacial deformation compatibility and energy dissipation capacity. Fatigue damage followed a distinct three-stage stiffness degradation pattern. High temperatures and low loading frequencies accelerated rheological behaviour of the asphalt phase, shortened the stable damage propagation phase, and promoted premature interlayer slippage. Based on the experimental data, a phenomenological fatigue life prediction model was established, incorporating temperature, loading frequency and stress level. The model supports quantitative assessment of progressive interfacial damage and provides practical reference for structural durability design and life-cycle maintenance of composite tunnel pavements. Full article

A lubricant protective film (LP) formed on automotive Zn-coated steel sheets is a functional surface layer that controls shear resistance at the die–sheet interface while also affecting the electrical contact state during resistance spot welding and the surface reactivity during paint pretreatment. In this study, the effect of LP coating weight on surface friction, interfacial electrical resistance, and degreasing–phosphate reactivity was analyzed for 340 MPa-grade galvannealed (GA) steel sheets within a unified surface-governed framework. The LP coating weight was controlled in the range of 0–1008 mg/m² on a single-sided basis. The friction coefficient, cup-drawing limit blank holding force (BHF), resistance spot welding current range, resistance–time product obtained by integrating dynamic resistance with respect to time, residual LP after degreasing, phosphate coating formation behavior, and forming simulation results using experimentally measured friction coefficients as input were comparatively evaluated. With increasing LP coating weight, the friction coefficient decreased from approximately 0.163 to 0.130 and then increased again to approximately 0.145 in the high-coating-weight regime. This surface-state change increased the limit BHF during cup drawing, whereas it narrowed the current range and increased the resistance–time product during resistance spot welding. In addition, under conditions above approximately 550 mg/m², residual LP after degreasing increased, and local no-growth regions of the phosphate coating were identified. These results show that, within the present test conditions, LP coating weight is not merely the amount of lubricant applied but a surface-state variable that concurrently influences frictional, electrical, and chemical responses. Therefore, within the scope of the present laboratory-scale framework, an LP coating weight of approximately 300–550 mg/m² should be interpreted not as a universal optimum, but as an operational surface window derived by balancing formability, the RSW process window, and phosphate reactivity under the present experimental conditions. Full article

This work introduces a Targeted Emulsified-Solvent Injection (TESI) process for extracting bitumen from oil sands. In TESI, a solvent is emulsified near the emulsion phase inversion point (PIP), where the interfacial tension and the emulsion stability are very low. This allows the solvent to be easily emulsified and then deposited onto the bitumen-coated porous media (under lower shear conditions, where the emulsion breaks), mixing with bitumen, decreasing bitumen viscosity, and enabling mobilization and diluted bitumen recovery. The design of the surfactant-solvent formulation was guided by the Hydrophilic-Lipophilic-Difference and Net-Average-Curvature (HLD-NAC) frameworks. The HLD-NAC was used to identify a formulation with less than 1% surfactant exhibiting ultralow interfacial tension (~10⁻³ mJ/m²), at the PIP, where HLD = 0. This formulation was injected into columns packed with bitumen-coated sands at varying salinities and water-to-solvent ratios. Using optimal conditions, bitumen recoveries of up to 83% can be obtained at room temperature, without the need for steam or high-pressure injection, a condition suitable for intermediate-depth reservoirs. The effluent emulsion of diluted bitumen can be gravity-separated, allowing for the recycling of the aqueous solution containing the surfactant. The recovery curves were modeled using a continuous stirred tank reactor (CSTR) model coupled with a Capillary number model for thin viscous films that allowed the prediction of effluent diluted bitumen viscosities and an estimation of the pressure drops in the column that were consistent with experimental observations. Full article

This study investigates the nanomechanical response of aluminum substrates coated with crystalline or amorphous equiatomic FeNiCrCo compositionally complex alloy (CCA) layers using molecular dynamics nanoindentation. We evaluated the influence of coating microstructure and pre-relaxation via Monte Carlo/molecular dynamics (MC/MD) on deformation behavior at shallow (35 Å) and deep (65 Å) indentation depths. The relaxation process is critical for equilibrating internal stresses and homogenizing the initial stress field in amorphous phases, while preventing chaotic defect multiplication in crystalline lattices, yet it simultaneously promotes Fe and Cr surface segregation consistent with the equilibrium chemical short-range ordering of the alloy. The results reveal distinct deformation mechanisms: crystalline coatings exhibit higher peak indentation forces of about 300 ± 16 eV/Å characterized by discrete force fluctuations indicative of localized plastic events, while amorphous coatings show lower peak loads (~170–220 ± 12 eV/Å), corresponding to a reduction in load-bearing capacity of roughly 25%–40%, and smooth, continuous deformation governed by shear transformation zones. Notably, in amorphous systems, pressure-induced local crystallization occurs under load, with ordered FCC/HCP regions persisting after unloading, indicating partial irreversibility of the phase transition. Upon deep indentation into the substrate, the amorphous system exhibits a sharp increase in stiffness due to substrate compaction, whereas the crystalline system maintains high load-bearing capacity with reduced defect density in the relaxed state compared to the non-relaxed counterpart. Relaxation significantly reduces force-curve fluctuations in both systems, enhancing the stability of the mechanical response. Compared with uncoated aluminum, which exhibits extensive twin propagation and deep defect penetration, the FeNiCrCo-coated systems approximately halve the defect penetration depth and reduce the defective-atom volume fraction in the substrate by about a factor of two, thereby more effectively confining plastic deformation and preserving substrate integrity under the simulated conditions. These findings demonstrate that the synergy between coating crystallinity and rigorous relaxation protocols governs stress distribution patterns—localized hotspots in amorphous phases versus extended networks in crystalline ones—providing key insights for designing advanced protective coating–substrate systems with optimized mechanical performance. Full article

Octopus maya is a fast-growing species from the Yucatán Peninsula with high economic relevance, accounting for a major share of regional fishery production. However, a significant fraction of the organism, rich in type I collagen, is discarded as by-products, representing a promising and underutilized source for sustainable biomaterials. This study evaluated, through a 3² factorial design, the effect of two factors on the rheological and dynamic mechanical properties of film-forming solutions (FFS). The first factor was the type of food-grade polysaccharide: chitosan (Ch), hydroxypropyl methylcellulose (HPMC), or starch (S). The second factor was the proportion of each polysaccharide blended with ultrasound-extracted Octopus maya insoluble collagen (CIPM), using polysaccharide ratios of 30:70, 50:50, and 70:30 (w/w). This approach aims to valorize octopus by-products through the recovery and functional utilization of collagen. Rheological properties were determined by rotational and oscillatory rheometry at 25 °C, with flow curves fitted to the Carreau-Yasuda model. All formulations exhibited pseudoplastic behavior (n < 1), with viscosity decreasing as shear rate increased. Pure CIPM showed high viscosity (190.36 Pa·s at 1 s⁻¹), which decreased (0.3–10.44 Pa·s) in HPMC and chitosan systems, suggesting their potential suitability for applications requiring fluidity, such as spray coatings or film-forming solutions, based on their rheological properties. In contrast, starch-based systems exhibited higher viscosities (33.54–197.53 Pa·s) and a more structured viscoelastic profile (G′ > G″), suggesting potential suitability for thick coatings or gels requiring structural stability, although these applications were not experimentally validated. These results demonstrate that CIPM-polysaccharide systems enable tunable rheological properties, supporting the use of Octopus maya collagen as a sustainable functional material for advanced food and biomaterial design. Full article

The disposal of high-water-content bentonite slurry generated from underground construction presents prominent environmental and technical challenges, calling for low-carbon and efficient consolidation technologies. This study proposes an integrated flocculation–preloading–electro-osmosis (FPE) method using anionic polyacrylamide (APAM) combined with ground granulated blast furnace slag to strengthen dewatering and stabilization of bentonite slurry. Settlement column experiments were conducted to determine the optimal APAM dosages. A series of FPE consolidation experiments were performed to monitor drainage, settlement, electrical current, temperature and post-treatment soil properties, combined with microstructural analysis to reveal the synergistic mechanism. The results show that APAM creates abundant seepage channels via adsorption bridging and flocculation, significantly accelerating early-stage drainage and settlement rates without obviously increasing total drainage and final settlement. The polymer hydrogel homogenizes soil structure, leading to a gradual increase in moisture content and decrease in shear strength from anode to cathode, and effectively eliminates cracking during electro-osmosis. The temporary seepage channels induce a faster initial current rise, while the polymer coating increases apparent resistivity after free water discharge, thereby reducing current and temperature during the electro-osmotic consolidation stage. Appropriate APAM dosage thickens the electric double layer to raise the free swell ratio, whereas excessive dosage restricts swelling by particle coating. Microscopic observations confirm that chain-structured APAM and flocculent C-(A)-S-H hydration products cement soil particles and fill pores, improving soil integrity and shear strength. Overall, APAM improves early-stage efficiency and soil uniformity/integrity. In addtion, its combined effect with slag on bentonite shear strength increase is relatively higher than that of 0% slag condition. The integrated FPE technique realizes synchronous high-efficiency dewatering and low-carbon stabilization of high-water-content bentonite slurry, providing a novel and practical solution for engineering slurry disposal. Full article

High-velocity oxy-fuel (HVOF) spraying was used to deposit WC-Co and WC-Co-Cr coatings on high-speed steel in order to determine how binder chemistry and coating thickness jointly control load support, friction, and dry sliding wear resistance. Nominal 50 and 100 µm coatings were compared within the same substrate framework by XRD, FT-IR, SEM/EDX, cross-sectional image analysis, Vickers hardness testing, dry sliding wear testing, and post-wear SEM/EDX. The coatings retained WC as the dominant crystalline phase, while weak overlapping features were associated with binder-rich regions and limited decarburization products. Cross-sectional observations confirmed continuous coating build-up close to the nominal thicknesses and low apparent dark-feature/porosity fractions. All WC-based coatings increased the effective hardness and reduced mass loss relative to uncoated HSS. Among the tested conditions, WC-Co-Cr-100 provided the highest effective hardness and the lowest mass loss after 1000 m sliding, whereas WC-Co-100 produced the lowest mean coefficient of friction. The results show that low friction and high wear resistance are not governed by identical mechanisms: WC-Co favours interfacial shear reduction, while the thicker Cr-containing coating provides superior resistance to material removal through improved carbide retention, binder stability, and coating-scale load support. Full article

Aluminum alloys are attractive for oil production, refining, and hydrocarbon-processing equipment because of their low density, high specific strength, and heat-transfer properties; however, their use is limited by localized corrosion in chloride-, sulfur-, and water-containing environments. This review analyzes combined anodic oxide/polymer and anodic oxide/fluoropolymer coating systems as surface-engineering approaches for improving corrosion resistance, adhesion, and durability of aluminum alloys under such conditions. The reviewed data show that coating performance is governed by anodic oxide morphology, pore sealing or polymer impregnation, and oxide/polymer interfacial stability. Quantitative results indicate that anodizing and pore widening can increase aluminum/polyamide lap-shear strength from 5.0 to 17.4 MPa, while optimized interfacial treatment can provide 22.5 ± 0.5 MPa before aging and 18.1 ± 0.2 MPa after humid aging. Corrosion data show that anodizing can increase the polarization resistance of aluminum alloy 6061 in seawater from 17.2 kΩ·cm² to 2.24 MΩ·cm². For wear-related durability, optimized anodizing can increase the critical scratch load from 37.3 to 118.9 N. These values provide practical benchmarks for designing anodic oxide/polymer systems for complex oilfield and hydrocarbon-processing environments. Full article

Four alloy coatings were deposited via laser cladding on EH40 steel: a Co-based coating (HG), a Ni-based coating (P0), and two Ni-based composite coatings containing 15 wt.% WC (P15) and 30 wt.% WC (P30). Their low-temperature mechanical properties—hardness, tensile strength, shear strength, and impact toughness—were systematically investigated. Hardness increased with WC content, with P30 being the hardest. HG exhibited the highest tensile strength (577 MPa), exceeding the EH40 substrate baseline. Shear tests revealed strong anisotropy: P0 was stronger longitudinally, but WC addition reversed this trend. P30 showed critically low longitudinal shear strength (187.1 MPa), while HG demonstrated high, nearly isotropic shear performance. Impact toughness decreased for all coatings at lower temperatures (−40 °C to −80 °C). P30 maintained good impact energy at −40 °C and −60 °C but suffered severe embrittlement at −80 °C, correlating with its poor longitudinal shear strength. HG offered the best balance of high strength and isotropic properties. P15 provided a reasonable compromise between enhanced hardness and retained toughness. This study highlights the critical trade-off between surface strength and bulk impact toughness for laser claddings on high-strength steel in low-temperature service. Full article

Traditional research was mostly focused on the effects of emulsions on the mechanical properties and durability of cement mortar, while studies on the regulation mechanism of emulsions on the rheological properties of cement-based materials and the coupling mechanism with the hydration process were rarely conducted. In this paper, a novel core–shell structured emulsion was prepared by free radical polymerization. The regulation of cement mortar yield stress, creep recovery, dynamic viscosity, and thixotropy by different dosages (0–10%) of the emulsion admixture was systematically investigated, and combined with characterization by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR), the microscopic action mechanism of the emulsion was elucidated. It was demonstrated that the Bingham fluid behavior of cement mortar was not altered by the core–shell emulsion, whereas a significant dosage-dependent regulatory effect on its rheological parameters was observed, and a critical regulation interval of 4–6% was identified. At an emulsion dosage of 10%, the yield stress of the mortar was increased by 937.0% compared to that of the control group. At dosages of 2–4%, the static structural stability and construction flowability of the mortar were synergistically optimized, and the weakest thixotropy and the best structural stability were exhibited at an emulsion dosage of 4%. A more pronounced shear-thinning behavior was shown by all modified mortars, and their high-shear flowability was not affected. Microstructural analysis confirmed that no chemical reaction occurred between the emulsion and the cement hydration products. Through the triple effects of “hydration retardation by physical coating, pore filling and densification, and composite network enhancement”, a film was formed on the surface of cement particles by the emulsion, which hindered the diffusion of water and ions, thereby regulating the cement hydration process and microstructural evolution. Full article

The antimicrobial effect of Eucalyptus radiata essential oil nanoemulsion (EON) on Staphylococcus aureus and spoilage microorganisms was evaluated on fresh beef chunks during cold storage at days 0, 2, 4, 6, and 8. For this purpose, nanoemulsion was prepared using 2% eucalyptus oil combined with high methoxyl pectin, glycerol, and Tween 80, employing high shear force. Then the following were evaluated: (1) the essential oil’s chemical profile and in vitro antioxidant and antimicrobial capacities; (2) the nanoemulsion characteristics; and (3) the microbial counts of the beef treatments. The results showed that the essential oil’s primary components were o-cymene (45.4%), 2-bornene (26.29%), 1,8-cineole (11.31%), and α-pinene (9.25%). The EON had a particle size of 52.04 nm and a zeta potential of −9.16 mV. The in vitro studies revealed that both the essential oil and its nanoemulsion demonstrated significant antibacterial activity. Similarly, in in situ examinations, when the meat samples were spiked with S. aureus (0.1 × 10⁸ CFU/mL), the EON-treated meat samples had significantly (p ≤ 0.05) lower microbial counts than the untreated meat samples throughout the storage period; the difference between the treatments ranged between 1.62 and 2.44 log CFU/g. Additionally, the EON exhibited excellent antimicrobial efficacy against spoilage microorganisms on beef pieces during shelf life. On day 4, the maximum inhibitory activity was observed against total coliform, Pseudomonas spp., and yeast in reductions of 1.96, 2.09, and 2.18 log CFU/g in microbial counts, respectively. Moreover, application of meat samples with the EON delayed spoilage by 4 days. Therefore, the results of this study showed that coating beef chunks with the EON enhanced both product safety and shelf life. Full article

Brittle geomaterials such as coal and rock are prone to unstable failure under high stress and dynamic disturbances, where rapid release of stored elastic strain energy can trigger dynamic disasters. Polyurea, a high-strength and high-ductility elastomer, can form a continuous flexible coating on the surface of coal/rock to regulate their deformation–fracture behavior. Here, uniaxial compression tests were performed on coal specimens coated with polyurea layers of different thicknesses (0–1.25 mm). Acoustic emission (AE) and digital image correlation (DIC) were jointly employed to characterize macroscopic deformation, microcrack evolution, fracture-mode transition, and energy partitioning. The results show that polyurea provides passive lateral confinement that suppresses lateral expansion and shifts macroscopic failure from brittle splitting to progressive ductile damage. AE-based AF–RA analysis indicates that thicker coatings increase the normal stress and shear resistance along potential fracture planes, promoting a microfracture transition from shear-dominated to tension-dominated cracking. Energy analysis demonstrates that the coating enhances pre-peak energy dissipation via coordinated deformation with the coal, while thicker coatings (≥1.00 mm) exhibit pronounced post-peak elastic tensile deformation to absorb and buffer fracture-released energy, impeding the instantaneous energy release typical of bare coal. Moreover, the elastic energy index shows that polyurea markedly reduces impact tendency, with an appropriate thickness stabilizing specimens from strong to weak/non-impact propensity. These findings clarify the coupled confinement–fracture–energy regulation mechanisms of polyurea coatings and provide quantitative guidance for coating-thickness design to mitigate dynamic failure hazards in brittle materials. Full article

Near-fault pulse-like ground motions (NFPLGMs) impose concentrated energy demands that can severely damage bridges, yet their scarcity and the influence of structural parameter uncertainties are often neglected in seismic fragility assessments. This study proposed a synthesis method for NFPLGMs by superposing low-frequency pulse components (extracted via the Gabor wavelet transform and low-pass filtering) with high-frequency stochastic components based on an evolutionary power spectrum. A three-span reinforced concrete bridge was modeled in OpenSeesPy, and Incremental Dynamic Analysis (IDA), together with a quadratic response surface model, were used to plot seismic fragility curves. The damping ratio (ξ), elastic modulus of steel reinforcement (E_s), yield strength of steel reinforcement (f_y), diameter of longitudinal reinforcement (D), and peak ground acceleration (PGA) were treated as random variables. Sensitivity indices were computed using Monte Carlo sampling (n = 10,000). Results show that ξ most strongly affects the displacement ductility ratio of the bridge pier (u_d) (variation of up to 32.6%), while E_s dominates the shear deformation of the bridge bearing (d) (variation of up to 43.8%). Neglecting structural parameter uncertainties overestimates median PGA thresholds (m_R) for different damage states by 1.5%–36.1%, and replacing NFPLGMs with ordinary ground motions overestimates seismic capacity by 1.7%–36.6%. The bridge bearing is consistently more vulnerable than the pier, with a collapse probability of 0.9566 at PGA = 1.0 g. These findings highlight the necessity of incorporating both NFPLGM characteristics and structural parameter uncertainties into bridge seismic fragility assessment. On the other hand, when seismic retrofitting of bridges is carried out using coating materials, priority should be given to more vulnerable components, such as bridge bearings, to improve the utilization efficiency of limited resources. Full article