Search Results (355)

Vanadium extraction tailings, as a highly alkaline and hazardous solid waste, pose not only serious environmental risks but also severely hinder the large-scale recycling of secondary iron resources. This study proposes an innovative process of “mild alkali leaching for vanadium extraction coupled with deep calcification and dealkali removal”. The vanadium extraction slag from a steel plant in China was used as a raw material to carry out the experimental and pilot study of alkali leaching of vanadium and calcification dealkalization. Experimental results show that under the conditions of 120 °C, 1% NaOH solution, liquid-solid ratio of 4:1 to 6:1, and reaction time of 1 h, vanadium leaching rate can reach 50%, which can be effectively used as a high-value-added economic hedge. Subsequently, under the conditions of 200 °C, calcium oxide concentration of 19.29%, stirring speed of 800 rpm, liquid-solid ratio of 4:1, and reaction time of 1 h, the Na₂O content in the tailings was successfully reduced to below 1%. A large number of tailings can be converted into high-quality secondary iron ore resources, which are suitable for subsequent iron-bearing briquette preparation and blast furnace ironmaking. Furthermore, pilot-scale testing in a 200 L reactor verified the engineering scalability of this combined process, maintaining a vanadium extraction rate of over 50% and an alkali removal rate of over 80%. This study provides a robust, scalable, and highly profitable pathway for the comprehensive utilization of high-alkali metallurgical solid waste. Full article

Municipal solid waste incineration fly ash (MSWI FA) represents a significant environmental challenge due to its high content of toxic heavy metal (HM) and large-scale generation. This study demonstrates the feasibility pathway for converting hazardous MSWI FA into well-crystallized layered double hydroxide nanosheets (LDH-FA). Sodium dimethyl dithiocarbamate (SDD) was incorporated as a chelating stabilizer to enable synergistic HM immobilization during acid leaching and crystallization. High-resolution transmission electron microscopy (HRTEM) confirmed the characteristic two-dimensional nanosheet morphology with interlayer spacings consistent with LDH structures, while elemental mapping revealed homogeneous distribution of Pb and Zn within the nanosheet matrix. SDD dosages higher than 1.0 wt% effectively suppressed HM leaching, and Pb concentrations were controlled below 0.1 mg/L and Zn maintained at minimal levels. BCR sequential extraction analysis further demonstrated that SDD treatment effectively transformed HMs from bioavailable acid-soluble fractions to stable forms. This investigation establishes an innovative approach to MSWI FA resource utilization and provides mechanistic insights into HM stabilization within LDH nanostructures, offering a scientific basis for safer applications of waste-derived nanomaterials. Full article

Flotation tailings and metallurgical slags from mining often contain toxic Pb, Cd, and Zn. In this study, we evaluated the in situ immobilization of Pb, Cd, and Zn in a Pb–Zn flotation tailing and a smelting slag by adding representative amendments: phosphate-based (ammonium phosphate, phosphoric acid, glassy fertiliser), cementitious (Portland cement), and iron-based (bog iron ore) materials at 1–10% (w/w). Treated samples underwent EPA-TCLP and pH-dependent leaching tests (pH 3–10), with Pb, Cd, and Zn measured by atomic absorption spectroscopy. The untreated tailing leached hazardous Pb (~60 mg/L) and elevated levels of Cd (~0.7 mg/L) and Zn (~53 mg/L), whereas the untreated slag leached negligible metal concentrations. All amendments reduced metal release in a dose-dependent manner. Phosphate amendments were most effective (e.g., 10% H₃PO₄ cut tailing Pb by 80%, Cd by 60%, and Zn by 30%), while cement and iron additions had much weaker effects. Solid-phase XRD and SEM-EDS analyses indicated the formation of stable calcium–phosphate minerals on sulfide surfaces after phosphate treatment. These findings suggest that low-cost phosphate additives (~5–10%) can substantially immobilize Pb, Cd, and Zn in such wastes. However, under strongly acidic conditions (pH < 3), some remobilization occurred, highlighting the need for further validation. This work provides practical guidance for waste managers on selecting in situ stabilization strategies for Pb–Zn mine wastes. Full article

The separation of copper and arsenic from spent copper electrolyte plays a pivotal role in electrolyte recirculation and arsenic-bearing solid hazardous waste minimization. In this study, the deep copper removal process in high arsenic and low copper spent copper electrolyte by gas–liquid sulfidation is studied. Thermodynamic analysis indicates that under strongly acidic conditions, regulating the oxidation-reduction potential enables the selective precipitation of Cu²⁺ as CuS while inhibiting the formation of As₂S₃. The influence of hydrogen sulfide excess coefficient and gas–liquid sulfidation temperature on copper and arsenic co-precipitation behavior is investigated. Under the optimal gas–liquid sulfidation conditions with the sulfide excess coefficient of 47 and gas–liquid sulfidation for 60 min at 328.15 K, the copper concentration can be reduced from 0.312 g/L to 1.25 mg/L, while arsenic co-precipitation can be effectively suppressed. The copper gas–liquid sulfidation process is chemical reaction and diffusion mix controlled with an activation energy of 33.47 kJ/mol, while arsenic sulfidation is chemical reaction controlled with an activation energy of 51.22 kJ/mol. The copper–arsenic co-precipitated sludge predominantly consists of As₂S₃, CuS, and Cu₂S. Arsenic precipitation involves a multi-step process: As(V) is first reduced to As(III) and subsequently sulfurized. However, the majority of cupric ions are directly precipitated as sulfides, whereas a minor fraction is firstly reduced by hydrogen sulfide and subsequently precipitated. The present study clarifies the intrinsic mechanism and external regulatory factors for the gas–liquid sulfidation deep copper removal process, providing a theoretical basis for optimizing sulfidation processes to synergistically achieve valuable metal recovery and arsenic pollution control. Full article

A quaternary solid-waste-based binder was prepared from low-titanium slag, municipal solid waste incineration (MSWI) fly ash, steel slag, and flue-gas desulfurization gypsum (FGDG) to clarify the activating effect of MSWI fly ash on low-titanium slag and its influence on hydrate evolution. Unlike conventional solid-waste-based binders in which MSWI fly ash is mainly regarded as a hazardous residue requiring stabilization, this study demonstrates its specific role as a Ca-rich alkaline activator for promoting low-titanium slag depolymerization and coordinated hydrate formation. The results showed that the compressive strength first increased and then decreased with increasing MSWI fly ash content. Considering both strength development and MSWI fly ash utilization, the optimum mixture was identified as low-titanium slag:MSWI fly ash:steel slag:FGDG = 43.0:17.2:25.8:14.0, with compressive strengths of 9.51 and 46.32 MPa at 3 and 90 d, respectively. These values corresponded to 5.66 and 1.04 times those of the reference mixture without MSWI fly ash, respectively. Ettringite and C-(A)-S-H gel were the main strength-contributing hydration products, while Friedel’s salt was identified as a chloride-bearing AFm phase. Moderate MSWI fly ash addition promoted alkaline activation and low-titanium slag depolymerization, leading to increased formation of ettringite, C-(A)-S-H gel, and Friedel’s salt, which contributed to improved compressive strength. In contrast, excessive MSWI fly ash disturbed the Ca-Si-Al balance and inhibited effective hydrate formation. These results demonstrate that MSWI fly ash can serve as an effective Ca-rich activator for low-titanium-slag-based low-carbon cementitious materials and provide a feasible route for the synergistic utilization of multiple solid wastes. Full article

The global challenge of effectively using and treating solid wastes in an environmentally sustainable way is significant. This study explores the creation of ternary low-carbon gelling materials made from red mud (RM), mineral powder (MP), and soda residue (SR). Using techniques such as SEM-ED, XRD, and FTIR, the microstructure of the red mud–mineral powder–alkaline slag (RM-MP-SR) mixture was analyzed, and the mechanical and physical properties of the material, as well as the leaching behavior of heavy metals, were investigated. The MRS16 sample, containing a 16% SR replacement, exhibited the best properties: compared with the control sample MRS0 (without replacement), its 28-day compressive strength increased by 43.7% to 51.3 MPa, the drying shrinkage rate decreased by 43.2%, and the mass loss rate reduced by 73.9%. After 100 freeze–thaw cycles, the mass loss was only 3.7%. The addition of SR can decrease the porosity in ternary materials, enhancing their mechanical properties; this is mainly due to SR promoting the increase in C-S-H, C-A-S-H gel, and ettringite. Meanwhile, MRS16 showed excellent freeze–thaw resistance, and the leaching levels of Cu, As, Pb, Cr, and Ni were within China’s non-hazardous limits. This study emphasizes the potential of combining RM, MP, and SR, providing useful scientific and theoretical insights for the joint use of alkaline, silica–aluminum, and calcium-based solid wastes. Full article

Chromium slag, a chromium-bearing solid waste characterized by substantial environmental hazards yet with appreciable resource potential, has become a focal topic in solid-waste pollution control and the circular economy. Centered on the overarching logic of “evidence chain–system boundary–scalable and verifiable acceptance,” this review systematically synthesizes recovery technologies, industrial-scale utilization pathways, and the key challenges associated with the detoxification and resource utilization of chromium slag. From the perspective of recovery technologies, we examine pyrometallurgical and hydrometallurgical routes, solidification/stabilization (S/S), and bioelectrochemical coupling approaches, elucidating their fundamental principles, applicability boundaries, and critical nodes where environmental burdens may be transferred across media. We emphasize that process design should concurrently consider detoxification efficiency, resource recovery performance, and whole-process pollution control. Regarding utilization pathways, this review highlights three major routes with strong scale-up relevance—metallurgical process co-treatment (CAP–sintering–blast furnace), bulk utilization in construction materials, and high-value utilization—and analyzes their industrial potential and engineering constraints. Particular attention is given to the lack of long-term leaching and durability evidence, which represents a central bottleneck limiting product-side credibility. Furthermore, we discuss cross-cutting challenges including the long-term stabilization of Cr(VI), the verifiability of “green utilization” concepts, cost and economic feasibility, and standardized acceptance criteria. We propose that future research should shift from single-process optimization toward multi-objective, system-level evaluation, and establish a full-chain evidence system covering “speciation/mineral phases–process mechanisms–environmental behavior–risk assessment–engineering scale-up–standardized acceptance.” This review aims to provide a systematic analytical framework and practical reference for improving comparability across resource-utilization technologies and supporting engineering decision-making for chromium slag management. Full article

Biogas from municipal solid waste is a promising pathway for renewable energy production while mitigating environmental pollution and public health risks. In this study, biogas emissions from a sanitary landfill in Maringá, southern Brazil, were evaluated using three models (IPCC, LandGEM, and CETESB tool) to estimate methane generation and energy recovery potential. Experimental analysis revealed methane concentrations from 51.10 ± 8.89% to 57.06 ± 1.19% across collection drains, indicating favorable conditions for energy utilization. Methane generation was estimated under different scenarios, reaching up to 1.30 × 10⁴ tonnes of CH₄, with peak production projected over 25–26 years depending on the model. Beyond energetic relevance, controlled biogas recovery can substantially reduce methane emissions, a key precursor of tropospheric ozone, and limit hazardous trace gas release, improving air quality and reducing population exposure to harmful pollutants. These findings are particularly relevant in developing countries, where insufficient waste management infrastructure leads to uncontrolled emissions, posing elevated environmental and health risks. This study supports integrating landfill biogas recovery into waste management and climate strategies, contributing to Sustainable Development Goals related to clean energy (SDG 7), climate action (SDG 13), and health (SDG 3), demonstrating it as a scalable solution for sustainable urban development. Full article

This study proposes the development of a recycling process for the reintegration of dental zirconia waste into CAD/CAM systems for rapid prototyping, with the objective of demonstrating the feasibility of manufacturing functional products from recycled zirconia obtained from a commercial dental laboratory. The proposed methodology aims to explore a simple and economically viable process, which involves the purification and processing of a heterogeneous zirconia powder, followed by the fabrication of pre-sintered blocks suitable for CAD/CAM applications. The recycled bulk ceramic was characterized and compared with commercial zirconia through density measurements, X-ray diffraction, scanning electron microscopy, Vickers hardness, flexural strength testing, and sintering shrinkage analysis. The results indicated that, although recycled zirconia exhibits lower property values than the commercial reference material, it retains adequate characteristics for specific practical applications. Consequently, to demonstrate industrial feasibility, four components were designed using CAD and machined using CAM from the recycled blocks, simulating a rapid prototyping process. The fabricated components exhibited a smooth and flawless surface, were mechanically robust and solid to the touch, and showed well-defined contours with sharp edges. Dimensional analysis demonstrated high accuracy, with an average percentage error of 0.53% ± 0.14. These findings demonstrate that high-value ceramic waste can be reintegrated into the production chain as functional industrial components through a process that is closely aligned with the real conditions of industrial recycling, while also mitigating environmental contamination from hazardous industrial waste. Full article

Flotation tailings, the primary solid waste generated during gold extraction, may pose issues such as land occupation, environmental pollution, and geological hazards in open-pit mining areas. This study systematically investigated the environmental characteristics, long-term pollutant release patterns, and migration risks associated with flotation tailings by taking a specific backfill project as a case study and employing short-term leaching tests, long-term column leaching experiments, and multi-model numerical simulations. Short-term leaching tests indicated that tailings leachate exhibited weak alkalinity (pH 8.21−8.45) with low pollutant leaching concentrations, meeting the fundamental requirements for open-pit backfilling. Notably, leaching characteristics varied significantly among tailings from different sources, and an extended storage duration enhanced chemical stability. Long-term leaching tests identified nine characteristic pollutants, including fluoride and sulfate, with their release patterns categorized into three types: continuous slow release, initial rapid leaching, and delayed/complex release. Furthermore, simulation results from the HYDRUS and MODFLOW/MT3DMS models indicated that the maximum predicted concentrations of characteristic pollutants in the surrounding soil and groundwater will remain at low levels for 50 years post-backfilling. The site’s “micro-to-weakly permeable” strata exhibited significant pollutant retention capabilities. Based on these experimental and simulation results, a three-tier risk management system—”source control, process monitoring, and end-point surveillance”, was developed to provide technical support for the long-term environmental safety of the flotation tailings backfill project. This study revealed the environmental risk characteristics associated with the storage of flotation tailings, including land occupation, environmental pollution, and the potential for geological hazards in open pits. Furthermore, the leaching characteristics, long-term release patterns, and migration mechanisms of tailings used to backfill open pits have been elucidated, providing theoretical references and practical guidance for similar solid waste resource recovery and backfilling projects. Full article

Elemental mercury (Hg⁰) in coal-fired flue gas has become a focal yet challenging issue in mercury pollution control due to its high toxicity, bioaccumulation potential, and high volatility. There is an urgent need to develop a technology of Hg⁰ catalytic oxidation that is both low-cost and highly efficient. On the other hand, waste fluid catalytic cracking (WFCC) catalysts generated from the petroleum refining industry are classified as hazardous solid waste, necessitating effective harmless disposal and resource recovery. Herein, a composite support (A-P) was constructed by combining an activated WFCC catalyst (AFCC) with the natural mineral palygorskite, followed by the loading of VO_x active species to prepare a Vx/A-P catalyst for Hg⁰ removal from flue gas. Moreover, the effects of the preparation process and conditions of the Vx/A-P catalyst on the Hg⁰ removal performance were systematically studied. This work aims to provide a theoretical basis and technical support for the development of low-cost, high-performance mercury removal catalysts, while also promoting the green recycling and value-added utilization of waste catalysts. Full article

Southern New Jersey faces increasing flood risk due to several factors including rapid development, climate change, and aging infrastructure. This study evaluated the flood vulnerability of two municipal solid waste landfills located in Gloucester and Cumberland Counties. These sites are located near rural communities that rely on shallow groundwater for drinking water, which may be contaminated by floods. To assess these challenges, this research applies a hydrologic–hydraulic model to evaluate future flood vulnerability at the Cumberland County Improvement Authority (CCIA) landfill and the Gloucester County Solid Waste Complex (GCSWC) landfill. The method uses HEC-HMS and HEC-RAS 2D model simulations with climate-adjusted precipitation data derived from global climate models. Model performance was evaluated using Hurricane Ida (31 August–2 September 2021) by comparing HEC-RAS-simulated inundation extents with independently derived Sentinel-1 SAR flood maps generated in Google Earth Engine. Climate forcing was developed by deriving climate-adjusted 24 h precipitation–frequency (PF) design depths for 50-year and 100-year design storms under the Shared Socioeconomic Pathway (SSP) emissions pathways SSP2-4.5 (moderate) and SSP5-8.5 (high) for mid-century (2025–2050) and late-century (2070–2100) periods. These PF storm totals were converted to rainfall hyetographs using a fixed alternating variability method (AVM) temporal pattern within the coupled HEC-HMS/HEC-RAS modeling chain. Hazard amplification was primarily expressed through lateral inundation expansion and longer persistence of shallow flooding in low-relief operational zones, rather than uniform increases in peak depth across landfill interiors. Across both facilities, the landfill toe and adjacent access corridors were consistently identified as the most sensitive operational areas. Full article

Municipal solid waste disposed of in open dumpsites and unlined landfills contaminates groundwater, soils, and air across urban areas of low- and middle-income countries. Nevertheless, impacts across all three environmental media have not been systematically assessed together. We conducted a PRISMA 2020-compliant systematic review of 286 peer-reviewed studies from PubMed, Dimensions, and OpenAlex, applying structured eligibility screening and quality appraisal using an adapted JBI checklist. Heavy metals—lead, cadmium, chromium, and zinc—were the most frequently detected contaminants in leachate and groundwater, commonly exceeding WHO drinking water guidelines by one to three orders of magnitude. Soil contamination by potentially toxic elements was documented at virtually all open dumpsites studied, persisting for decades after site closure. Particulate matter at South Asian MSW sites reached up to 41 times the WHO 2021 annual guideline. Microplastics acting as heavy metal carriers and dumpsite leachate as a source of antimicrobial resistance genes were identified as emerging risks outside standard monitoring frameworks. Non-carcinogenic hazard indices exceeded acceptable thresholds in the majority of health risk studies reviewed. Engineered containment was the strongest predictor of contamination severity across all sites. Phytoremediation, constructed wetlands, and biofiltration showed promise as mitigation approaches. Critical evidence gaps remain for Central Asia, harmonized reporting standards, and longitudinal monitoring data. Full article

As solid waste generated from shield tunnel construction, shield muck is characterized by its massive volume, high water content, and poor engineering properties. Large-scale stockpiling not only occupies precious land resources but also poses potential environmental risks. This has become one of the key bottlenecks hindering the green, low-carbon, and sustainable development of rail transit construction. Efficient dewatering is a key prerequisite for its subsequent disposal or reutilization. Lime, cement, phosphogypsum, nano-SiO₂, and ground granulated blast furnace slag were employed in this research as composite conditioning agents to dewater shield tunnel muck. A range of water content, pH, and total organic carbon analyses tests were conducted to explore the roles of lime, cement, phosphogypsum, nano-SiO₂, and ground granulated blast furnace slag on the dewatering effect of shield tunnel muck. Furthermore, microstructures and elemental distribution of typical mixes were analyzed by scanning electron microscopy and energy-dispersive X-ray spectroscopy tests. Results indicate that a composite agent consisting of 3.5% lime, 4% cement, 1% phosphogypsum, 0.2% nano-SiO₂, and 4% ground granulated blast furnace slag exhibits optimal performance, reducing water content from 50% to 29.8% within 24 h. Phosphogypsum significantly decreased pH and reduced TOC to below 1 g/kg after 15 days, effectively mitigating the environmental hazards associated with muck disposal. The formation of cementitious products, including calcium aluminate hydrate, calcium aluminosilicate hydrate gels, and calcium silicate hydrate, effectively bonds soil particles. Additionally, ettringite crystals produced by the reaction between phosphogypsum and calcium aluminate phases filled interparticle voids. These processes were identified as the primary mechanisms for water reduction. Although nano-SiO₂ exerted a limited direct influence on water content, it acted as a pozzolanic catalyst that accelerated hydration reactions of lime and cement, rapidly reducing muck fluidity. The synergistic effect of the composite dewatering agent components establishes a multi-mechanism dewatering system characterized by “hydration gel + AFt filling + nano-catalysis.” The dewatering system developed in this study achieves both high efficiency and environmental friendliness for shield tunnel muck. This provides technical support for subsequent resource utilization, such as subgrade filling, while promoting the recycling of industrial solid wastes like phosphogypsum and blast furnace slag, ultimately contributing to green, low-carbon, and sustainable development. Full article

Pyrolysis of refuse-derived fuel (RDF) is a promising waste-to-energy route, but its use in higher-value applications remains limited by tar carryover, benzene, toluene, ethylbenzene, and xylenes (BTEX), heteroatom-containing compounds, and pollutant accumulation in recirculated scrubber water. This study evaluated operating windows for RDF pyrolysis coupled with direct wet scrubbing and closed-loop water reuse, with the aim of identifying regimes suitable for different end-use tiers. A Taguchi L27 design of experiments (DOE), i.e., an orthogonal array comprising 27 experimental runs, was applied to evaluate the effects of pyrolysis temperature, residence time, scrubber liquid-to-gas ratio, and scrubber-water temperature, while sequential reuse of the same scrubber-water inventory was evaluated at 5, 10, and 15 cycles. Cleaned-gas pollutants were quantified by compound-resolved gas chromatography–mass spectrometry (GC–MS) after solid-phase adsorption (SPA) sampling, while phenolics and polycyclic aromatic hydrocarbons (PAHs) in scrubber water were determined by extraction followed by GC–MS. Feasibility within each end-use tier was defined as simultaneous satisfaction of tier-specific cleaned-gas thresholds (C_tar, C_BTEX, I_N, and I_S) and the corresponding water-loop hazard limit (I_tox), using literature-informed engineering screening criteria. The results showed that stronger scrubbing reduced gas-phase tar and BTEX burdens, whereas extended water reuse caused systematic accumulation of phenolics and PAHs and increased the composite water-loop hazard index. Boiler-grade operation remained feasible across a broad operating range, with 23 of the 27 tested conditions remaining robust, whereas internal combustion engine combined heat and power (ICE-CHP) feasibility was restricted to a narrow robust regime, and no robust microturbine-grade condition was identified. These findings show that operating windows for RDF pyrolysis must be defined jointly by gas cleanliness and water-loop management constraints. Full article