Search Results (827)

This research evaluates the financial sustainability of a basic income (BI) model funded through carbon taxation in Türkiye. Unlike classical BI models that provide unconditional transfers to everyone, this study proposes an income support scheme targeted only at those below the poverty line. The model seeks to balance limited resources with the goal of social equity. In this scenario, sectoral carbon taxation evolves progressively. The tax starts with the energy sector, which has the highest emissions, and subsequently shifts to industry and other sectors. Emissions will be reduced by 1% each year, while a carbon tax that starts at USD 12 per ton will be dynamically converted to TL based on the increasing exchange rate year by year. The simulation looks at 2023–2050 and computes annual revenue and expenditure forecasts for the period. The findings indicate that the revenues from carbon taxation are not only sufficient to cover the prioritized expenditure in the targeted basic income (TBI) scheme but also will lead to fiscal surplus in the long run. The research proposes for the first time a framework which integrates social protection and the environmental taxation of carbon, synergizing policies aimed at alleviating income disparity and climate change within Türkiye’s context. Full article

International organizations have highlighted the importance of consistent and reliable environment, social and governance (ESG) disclosure and metrics to inform business strategy and investment decisions. Greater corporate disclosure is a positive signal to investors who prioritize sustainable investment. In this study, economic and climate sentiment are extracted from the integrated and sustainability reports of the top 40 corporates listed on the Johannesburg Stock Exchange, employing domain-specific natural language processing. The intention is to clarify the complex interactions between climate risk, corporate disclosures, financial performance and investor sentiment. The study provides valuable insights to regulators, accounting professionals and investors on the current state of disclosures and future actions required in South Africa. A time series analysis of the sentiment scores indicates a noticeable change in the corporates’ disclosures from climate-related risks in the earlier years to climate-related opportunities in recent years, specifically in the banking and mining sectors. The trends are less pronounced in sectors with good ESG ratings. An exploratory regression study reveals that climate and economic sentiments contain information that explain stock price movements over the longer term. The results have important implications for asset allocation and offer an interesting direction for future research. Monitoring the sentiment may provide early-warning signals of systemic risk, which is important to regulators given the impact on financial stability. Full article

This study evaluates and compares the sorption performance of natural zeolite (NZ) and Fe(III)-modified zeolite (FeZ) in removing Cu(II) ions from aqueous solutions, with the goal of assessing their potential for environmental remediation. NZ was modified with Fe(NO₃)₃, NaOH and NaNO₃ solutions to improve its sorption properties. The modification led to a slight decrease in crystallinity (XRD), increase in pore volume (BET), functional groups (FTIR) and negative surface charge (zeta potential), thereby improving the affinity of FeZ towards Cu(II). Batch sorption experiments were conducted to optimize key parameters including pH, solid/liquid ratio (S/L), contact time, and initial Cu(II) concentration. The pH_o and S/L ratio were identified as key factors significantly influencing Cu(II) sorption on both zeolites, with a particularly pronounced effect observed for FeZ. The optimal conditions determined were pH_o = 3–5 for NZ, pH_o = 3 for FeZ, S/L = 10 g/L and a contact time of 600 min. Experimental results confirmed that FeZ has almost twice the sorption capacity for Cu(II) compared to NZ (0.271 mmol/g vs. 0.156 mmol/g), as further supported by elemental analysis, SEM-EDS and mapping analysis of saturated samples. The sorption of Cu(II) followed a mechanism of physical nature driven by ion exchange, dominated by intraparticle diffusion as the rate-controlling step. Leaching of copper-saturated zeolites according to the standard leaching method, DIN 38414 S4, demonstrated the ability of both zeolites to fully retain Cu(II) within their structure over a wide pH range, 4.01 ≤ pH_o ≤ 10.06. These findings highlight the superior performance of FeZ and its potential as an effective material for the remediation of copper-contaminated environments. Full article

A new Schiff base, (E)-2-(((1,10-phenanthrolin-5-yl)imino)methyl)-4,6-di-tert-butylphenol (Fen-IHB), was designed to incorporate an intramolecular hydrogen bond (IHB) between the phenolic OH and the azomethine nitrogen with the goal of modulating its physicochemical and biological properties. Fen-IHB was synthesized by condensation of 5-amino-1,10-phenanthroline with 3,5-di-tert-butyl-2-hydroxybenzaldehyde and exhaustively characterized by HR-ESI-MS, FTIR, 1D/2D NMR (¹H, ¹³C, DEPT-45, HH-COSY, CH-COSY, D₂O exchange), and UV–Vis spectroscopy. Cyclic voltammetry in anhydrous CH₃CN revealed a single irreversible cathodic peak at −1.43 V (vs. Ag/Ag⁺), which is consistent with the intramolecular reductive coupling of the azomethine moiety. Density functional theory (DFT) calculations, including MEP mapping, Fukui functions, dual descriptor analysis, and Fukui potentials with dual descriptor potential, identified the exocyclic azomethine carbon as the principal nucleophilic site and the phenolic ring (hydroxyl oxygen and adjacent carbons) as the main electrophilic region. Noncovalent interaction (NCI) analysis further confirmed the strength and geometry of the intramolecular hydrogen bond (IHB). In vitro antimicrobial assays indicated that Fen-IHB was inactive against Gram-negative facultative anaerobes (Salmonella enterica serovar Typhimurium and Typhi, Escherichia coli) and strictly anaerobic Gram-positive species (Clostridioides difficile, Roseburia inulinivorans, Blautia coccoides), as any growth inhibition was indistinguishable from the DMSO control. Conversely, Fen-IHB displayed measurable activity against Gram-positive aerobes and aerotolerant anaerobes, including Bacillus subtilis, Streptococcus pyogenes, Enterococcus faecalis, Staphylococcus aureus, and Staphylococcus haemolyticus. Overall, these comprehensive characterization results confirm the distinctive chemical and electronic properties of Fen-IHB, underlining the crucial role of the intramolecular hydrogen bond and electronic descriptors in defining its reactivity profile and selective biological activity. Full article

The increasing complexity of modern space systems requires a more integrated and scalable approach to their design, analysis, and verification. Model-Based Systems Engineering (MBSE) has emerged as a powerful methodology for managing the complexity of systems through formalized modeling practices, but its integration with dynamic and domain-specific simulations remains limited. This paper presents the first version of the unified Modeling and Simulation (M&S) framework MOSAiC (Modeling and Simulation Architecture for integrated Complex systems), which connects MBSE with open source, multi-domain simulation environments, with the goal of improving traceability, reusability, and fidelity in the system lifecycle. The architecture proposed here leverages ARCADIA-based models as authoritative sources, interfacing with simulation tools through standardized data exchanges and co-simulation strategies. Using a representative space mission scenario, the framework ability to align functional and physical models with specialized simulations is demonstrated. Results show improved consistency between system models and simulation artifacts, reduced integration costs, and improved early validation of design choices. This work supports the broader vision of digital engineering for space systems, suggesting that a modular, standards-based approach to unifying MBSE and simulation can significantly improve system understanding and development efficiency. Full article

The main purpose of this paper is to explore the benefits of combining two radio interfaces onboard an unmanned aerial vehicle (UAV) to communicate with a ground control station (GCS) and other UAVs inside a swarm. The goals are to use the IEEE 802.11ah standard (Wi-Fi HaLow) combined with the IEEE 802.11ax specification (Wi-Fi 6/6E) to enable real-time video transmission from UAVs to the GCS. While airport runway inspection serves as the proof-of-concept use case, the proposed multi-hop architectures apply to other medium-range UAV operations (i.e., a few kilometers) requiring real-time video transmission, such as natural disaster relief and agricultural monitoring. Several scenarios in which a UAV swarm performs infrastructure inspection are emulated. During the missions, UAVs have to send real-time video to the GCS through a multi-hop network when some damage in the infrastructure is found. The different scenarios are studied by means of emulation. Emulated scenarios are defined using different network architectures and radio technologies. Once the emulations finish, different performance metrics related to time, energy and the multi-hop video transmission network are analyzed. The capacity of a multi-hop network is a limiting factor for the transmission of high-quality video. As a first contribution, an expression to find this capacity from distances between UAVs in the emulated scenario is found using the NS-3 simulator. Then, this expression is applied in the algorithms in charge of composing the multi-hop network to offer on-demand quality video. However, the main contribution of this work lies in the development of efficient mechanisms for exchanging control information between UAVs and the GCS, and for forming a multi-hop network to transmit video. Full article

To achieve energy conservation, emission reduction, and green low-carbon goals for gas storage facilities, it is crucial to efficiently recover and utilize waste heat during gas injection while maintaining natural gas cooling rates. However, existing sensible and latent heat storage technologies cannot sustain long-term thermal storage or seasonal utilization of waste heat. Thermal chemical energy storage, with its high energy density and low thermal loss during prolonged storage, offers an effective solution for efficient recovery and long-term storage of waste heat in gas storage facilities. This study proposes a novel heat recovery method by combining a moving bed with mixed hydrated salts (CaCl₂·6H₂O and MgSO₄·7H₂O). By constructing both small-scale and full-scale three-dimensional models in Fluent, which couple the desorption and endothermic processes of hydrated salts, the study analyzes the temperature and flow fields within the moving bed during heat exchange, thereby verifying the feasibility of this approach. Furthermore, the effects of key parameters, including the inlet temperatures of hydrated salt particles and natural gas, flow velocity, and mass flow ratio on critical performance indicators such as the outlet temperatures of natural gas and hydrated salts, the overall heat transfer coefficient, the waste heat recovery efficiency, and the mass fraction of hydrated salt desorption are systematically investigated. The results indicate that in the small-scale model (1164 × 312 × 49 mm) the outlet temperatures of natural gas and mixed hydrated salts are 79.8 °C and 49.3 °C, respectively, with a waste heat recovery efficiency of only 33.6%. This low recovery rate is primarily due to the insufficient residence time of high-velocity natural gas (10.5 m·s⁻¹) and hydrated salt particles (2 mm·s⁻¹) in the moving bed, which limits heat exchange efficiency. In contrast, the full-scale moving bed (3000 × 1500 × 90 mm) not only accounts for variations in natural gas inlet temperature during the three-stage compression process but also allows for optimized operational adjustments. These optimizations ensure a natural gas outlet temperature of 41.3 °C, a hydrated salt outlet temperature of 82.5 °C, a significantly improved waste heat recovery efficiency of 94.2%, and a hydrated salt desorption mass fraction of 69.2%. This configuration enhances the safety of the gas injection system while maximizing both natural gas waste heat recovery and the efficient utilization of mixed hydrated salts. These findings provide essential theoretical guidance and data support for the effective recovery and seasonal utilization of waste heat in gas storage reservoirs. Full article

Background: Spectacle independence is a key goal in refractive lens exchange (RLE), especially in younger, high-expectation patients. This study evaluates a novel extended monovision approach combining a monofocal aspheric intraocular lens (IOL) in the dominant eye with a rotationally asymmetric bifocal extended-depth-of-focus (EDOF) IOL in the non-dominant eye. The strategy aims to optimize full-range visual performance while minimizing photic phenomena. Methods: In this retrospective cohort study, presbyopic patients underwent bilateral RLE with a monofocal IOL (Hoya Vivinex XC1-SP; target: 0 diopters [D]) in the dominant eye and a rotationally asymmetric bifocal EDOF IOL (LENTIS LS-313 MF15; addition: +1.5 D; target: −1.25 D) in the non-dominant eye. Uncorrected distance visual acuity (UDVA, at 6 m), uncorrected intermediate visual acuity (UIVA, at 66 cm), and uncorrected near visual acuity (UNVA, at 36 cm) were assessed. Additional evaluations included binocular defocus curves, contrast sensitivity, stereoacuity, and photic phenomena. Spectacle independence and satisfaction were measured using the PRSIQ and NEI-RQL-42 questionnaires. Results: A total of 38 patients (76 eyes) were included. The mean postoperative binocular UDVA, UIVA, and UNVA were −0.03 ± 0.08, −0.08 ± 0.09, and 0.04 ± 0.08 logMAR, respectively. The defocus curve peaked at 0.0 D (6 m) with a mean visual acuity of −0.03 ± 0.08 logMAR. Functional vision better than 0.2 logMAR extended over defocus steps from +1.00 to −3.25 D. All patients were spectacle-independent for distance and intermediate vision, and 84% reported complete spectacle independence. Contrast sensitivity was within normal limits for age. Minimal photic phenomena were reported, and stereoacuity was preserved in 97% of patients (≤100 arcseconds). Conclusions: This innovative extended monovision approach, combining two different IOLs in a mini-monovision setup, provides excellent uncorrected visual acuity at all distances, high spectacle independence, and minimal side effects. It represents a compelling alternative to multifocal IOL implantation in presbyopic RLE candidates. Full article

From the perspective of organizational legitimacy acquisition, this study elucidates the sources and formation pathways of resource-based enterprises’ resilience in the face of institutional shocks. It explores the evolution of resilience with the improvement of the resource-based enterprises’ legitimacy under institutional constraints. Using the new mining rights of the resource-based enterprises as the measured variable of organizational resilience under institutional shocks, this study describes the adaptability of the resource-based enterprises to institutional change from the subdivision dimension of pragmatic legitimacy and moral legitimacy. A multi-period fuzzy-set Qualitative Comparative Analysis (fsQCA) approach is adopted, which takes Chinese mining enterprises listed on the Shanghai Stock Exchange as samples to obtain the formation pathways and dynamic evolution characteristics of the resilience of the resource-based enterprises under the institutional shocks of the “supply-side structural reforms” (2016–2019) and the “dual-carbon” goals (2020–2022). The results indicate that the differences of institutional shock strength and constraint degree promote different resilience formation mechanisms. The high intensity and hard constraints of the supply-side structural reforms promote the high-resilience pathways of the enterprises based on pragmatic legitimacy. The guiding and incentive orientation of the “dual-carbon” goals promote more improvement in the moral legitimacy of the enterprises, forming high-resilience pathways of “pragmatic legitimacy + moral legitimacy”. Under continuous institutional shocks, influence legitimacy has a universal effect on the formation of high resilience by the resource-based enterprises, and structural legitimacy, as the core condition of the high-resilience pathways, demonstrates continuity. By increasing the subdivision dimension of moral legitimacy and mitigating the limitations of pragmatic legitimacy, resource-based enterprises can achieve breakthroughs in their pathways to high resilience. This study provides valuable insights and guidance for resource-based enterprises seeking to overcome future institutional shocks and achieve resilient growth. Full article

With growing public concern over environmental issues, organizations are facing increasing pressure to demonstrate a genuine and measurable commitment to environmental sustainability. In this context, understanding how corporate environmental responsibility (CER) shapes employee engagement (EE) is essential. This understanding helps align organizational behavior with both internal goals and broader societal expectations. Although the impact of corporate social responsibility (CSR) on EE has been widely studied, the specific role of CER—a key subdimension of CSR—remains underexplored. To address this gap, we developed a moderated mediation model grounded in social exchange theory, social identity theory, and signaling theory. This model aims to reveal how CER influences EE and through which mechanisms. Based on survey data from 418 employees in large Chinese manufacturing firms, our results show that perceived CER significantly enhances EE. This effect occurs primarily through the strengthening of organizational pride. Furthermore, online media coverage reinforces the relationship between perceived CER and organizational pride. It also amplifies the indirect impact of perceived CER on EE via this pride. These findings contribute to the corporate sustainability literature by showing how credible and visible environmental actions can enhance employee alignment and engagement. Practical implications are discussed for organizations seeking to connect managerial priorities with society’s call for transparent and authentic environmental initiatives. Full article

The fraction of absorbed photosynthetically active radiation (FAPAR) stands as a pivotal parameter within the Earth system, quantifying the energy exchange between vegetation and solar radiation. Accordingly, there is an urgent need for comprehensive validation studies to accurately quantify uncertainties and improve the reliability of FAPAR-based applications. This study validated five global FAPAR products, MOD15A2H, MYD15A2H, VNP15A2H, GEOV2, and GEOV3, over four boreal forest sites in North America. Qualitative quality flags (QQFs) and quantitative quality indicators (QQIs) of each product were analyzed. Time series high-resolution reference FAPAR maps were developed using the Harmonized Landsat and Sentinel-2 dataset. The reference FAPAR maps revealed a strong agreement with the in situ FAPAR from AmeriFlux (correlation coefficient (R) = 0.91; root mean square error (RMSE) = 0.06). The results revealed that global FAPAR products show similar uncertainties (RMSE: 0.16 ± 0.04) and moderate agreement with the reference FAPAR (R = 0.75 ± 0.10). On average, 34.47 ± 6.91% of the FAPAR data met the goal requirements of the Global Climate Observing System (GCOS), while 54.41 ± 6.89% met the threshold requirements of the GCOS. Deciduous forests perform better than evergreen forests, and the products tend to underestimate the reference data, especially for the beginning and end of growing seasons in evergreen forests. There are no obvious quality differences at different QQFs, and the relative QQI can be used to filter high-quality values. To enhance the regional applicability of global FAPAR products, further algorithm improvements and expanded validation efforts are essential. Full article

This study investigates the impact of environmental, social, and governance (ESG) disclosure on value creation in a balanced panel of 100 non-financial Sharia-compliant firms listed on the Saudi Stock Exchange over the period 2014–2023. The analysis employs a combination of econometric techniques, including fixed effects models with Driscoll–Kraay standard errors, Pooled Ordinary Least Squares (POLS) with Driscoll–Kraay standard errors and industry and year dummies, and two-step system generalized method of moments (GMM) estimation to address potential endogeneity and omitted variable bias. Value creation is measured using Tobin’s Q (TBQ), Return on Assets (ROA), and Return on Equity (ROE). The models also control for firm-specific variables such as firm size, leverage, asset tangibility, firm age, growth opportunities, and market capitalization. The findings reveal that ESG disclosure has a positive and statistically significant effect on firm value across all three performance measures. Furthermore, firm size significantly moderates this relationship, with larger Sharia-compliant firms experiencing greater value gains from ESG practices. These results align with agency, stakeholder, and signaling theories, emphasizing the role of ESG in enhancing transparency, reducing information asymmetry, and strengthening stakeholder trust. The study provides empirical evidence relevant to policymakers, investors, and firms striving to achieve Saudi Arabia’s Vision 2030 sustainability goals. Full article

Promoting social equity is a global issue, and common prosperity is an important goal for human society’s sustainable development. This study is the first to examine climate risks’ impacts on common prosperity from the perspective of corporate employees, providing micro-level evidence for the coordinated development of climate governance and social equity. Employing data from companies listed on the Shanghai and Shenzhen stock exchanges from 2016 to 2023, a fixed-effects model analysis was conducted, and the results showed the following: (1) Climate risks are positively associated with the common prosperity of corporate employees in a significant way, and this effect is mainly achieved through employee guarantees, rather than employee remuneration or employment. (2) Climate risk will increase corporate financing constraints, but it will also force companies to improve their ESG performance. (3) The mechanism tests show that climate risks indirectly promote improvements in employee rights and interests by forcing companies to improve the quality of internal controls and audits. (4) The results of the moderating effect analysis show that corporate size and performance have a positive moderating effect on the relationship between climate risk and the common prosperity of corporate employees. This finding may indicate the transmission path of “climate pressure—governance upgrade—social equity” and suggest that climate governance may be transformed into social value through institutional changes in enterprises. This study breaks through the limitations of traditional research on the financial perspective of the economic consequences of climate risks, incorporates employee welfare into the climate governance assessment framework for the first time, expands the micro research dimension of common prosperity, provides a new paradigm for cross-research on ESG and social equity, and offers recommendations and references for different stakeholders. Full article

Direct air capture (DAC), as a complementary strategy to carbon capture and storage (CCS), offers a scalable and sustainable pathway to remove CO₂ directly from the ambient air. This study presents a detailed evaluation of the amine-functionalised metal-organic framework (MOF) sorbent, mmen-Mg₂(dobpdc), for DAC using a temperature–vacuum swing adsorption (TVSA) process. While this sorbent has demonstrated promising performance in point-source CO₂ capture, this is the first dynamic simulation-based study to rigorously assess its effectiveness for low-concentration atmospheric CO₂ removal. A transient one-dimensional TVSA model was developed in Aspen Adsorption and validated against experimental breakthrough data to ensure accuracy in capturing both the sharp and gradual adsorption kinetics. To enhance process efficiency and sustainability, this work provides a comprehensive parametric analysis of key operational factors, including air flow rate, temperature, adsorption/desorption durations, vacuum pressure, and heat exchanger temperature, on process performance, including CO₂ purity, recovery, productivity, and specific energy consumption. Under optimal conditions for this sorbent (vacuum pressure lower than 0.15 bar and feed temperature below 15 °C), the TVSA process achieved ~98% CO₂ purity, recovery over 70%, and specific energy consumption of about 3.5 MJ/KgCO₂. These findings demonstrate that mmen-Mg₂(dobpdc) can achieve performance comparable to benchmark DAC sorbents in terms of CO₂ purity and recovery, underscoring its potential for scalable DAC applications. This work advances the development of energy-efficient carbon removal technologies and highlights the value of step-shape isotherm adsorbents in supporting global carbon-neutrality goals. Full article

This study investigates how Greek professionals formulate upward requests and simultaneously manage rapport and workplace identity within hierarchical exchanges. The data comprise 400 written requests elicited through a discourse–completion task from 100 participants, supplemented by follow-up interviews. Integrating pragmatic perspectives on request mitigation with Spencer-Oatey’s Rapport-Management model and a social constructionist perspective on identity, the analysis reveals a distinctive “direct-yet-mitigated” style: syntactically direct head acts (typically want- or need-statements) various mitigating devices. This mitigation enables speakers to preserve superiors’ face, assert entitlement, and invoke shared corporate goals in a single move. Crucially, rapport work is intertwined with identity construction. Strategic oscillation between deference and entitlement projects four recurrent professional personae: the deferential subordinate, the competent and deserving employee, the cooperative team-player, and the rights-aware negotiator. Speakers shift among these personae to calibrate relational distance, demonstrating that rapport management functions not merely as a politeness calculus but as a resource for dynamic identity performance. This study thus bridges micro-pragmatic choices and macro social meanings, showing how linguistic mitigation safeguards interpersonal harmony while scripting desirable workplace selves. Full article