Search Results (27)

In the context of the deep geological disposal of high-level and intermediate-level long-lived radioactive waste in France, the Callovian–Oxfordian (Cox) clay formation has been selected as a natural barrier. Thus, understanding the corrosion phenomena between the carbon steel used (API 5L X65) for the waste lining tubes and the Cox pore water, as well as its possible future evolutions, is of great importance. A controlled laboratory experiment was conducted using robust handmade API 5L X65 carbon steel electrodes in synthetic Cox pore water under equilibrium with three distinct gas atmospheres, simulating oxic, anoxic, and sulfide-rich environments at 25 °C and 80 °C, in a batch-type electrochemical cell. The experimental methodology involved linear polarization resistance (LPR) cycles, electrochemical impedance spectroscopy (EIS), and Tafel extrapolation at regular intervals over a period of 70 to 100 h to elucidate corrosion mechanisms and obtain corrosion current densities. At the same time, the fluid’s key geochemical parameters (temperature, pH, and redox potential) were monitored for temporal variation. This study, with results showing high corrosion rates under the three conditions investigated at two temperatures, underscores the importance of controlling the immediate environment of the containment materials to prevent exposure to variable conditions and to ensure that corrosion remains controlled over the long term. Full article

In this study, we investigated the morphology, chemical composition and pH measurement performance of MoO_x electrodes prepared via thermal oxidation and submitted to hydration in milliQ water. Surface analysis using SEM-EDS and XPS revealed that the hydrated MoO_x film is composed of different oxidation states of Mo (Mo (IV), Mo (V) and Mo (VI)), influencing its electrochemical behavior. A hydration period of 45 days was required for the electrode to achieve a response approaching the Nernstian model (−58 mV/pH), while extended hydration of up to 70 days enhanced its stability and sensitivity. The electrode’s performance was assessed under various conditions, including in the presence and absence of oxygen and in anaerobic conditions with the presence of sulfides. Oxygen absence increased sensitivity and lowered the experimental standard potential (E⁰_Exp) due to the effect of oxygen vacancies. Low sulfide concentrations had minimal impact on electrode performance, although higher concentrations may slightly decrease the electron transfer efficiency due to the complex formation. The pH sensing mechanisms of MoO_x electrodes are also discussed. Full article

High-speed railways are critical infrastructure in many countries, but their construction generates substantial spoil, particularly in mountainous regions dominated by tunnels and slopes, necessitating the establishment and monitoring of spoil disposal areas. Inadequate monitoring of spoil disposal areas can lead to significant environmental issues, including soil erosion and geological hazards such as landslides and debris flows, while also hindering the recycling and reuse of construction spoil, thereby impeding the achievement of circular economy and sustainable development goals for high-speed railways. Although the potential of geographic information systems, remote sensing, and global positioning systems in waste monitoring is increasingly recognized, there remains a critical research gap in their application to spoil disposal areas monitoring within high-speed railway projects. This study proposes an innovative framework integrating geographic information systems, remote sensing, and global positioning systems for monitoring spoil disposal areas during high-speed railway construction across three key scenarios: identification of disturbance boundaries (scenario 1), extraction of soil and water conservation measures (scenario 2), and estimation of spoil volume changes (scenario 3). In scenario 1, disturbance boundaries were identified using Gaofen-1 satellite data through processes such as imagery fusion, unsupervised classification, and spatial analysis. In scenario 2, unmanned aerial vehicle data were employed to extract soil and water conservation measures via visual interpretation and overlay analysis. In scenario 3, Sentinel-1 data were used to analyze elevation changes through the differential interferometric synthetic aperture radar method, followed by the estimation of spoil volume changes. The effectiveness of this integrated framework was validated through a case study. The results demonstrate that the framework can accurately delineate disturbance boundaries, efficiently extract soil and water conservation measures, and estimate dynamic changes in spoil volume with an acceptable error margin (15.5%). These findings highlight the framework’s capability to enhance monitoring accuracy and efficiency. By integrating multi-source data, this framework provides robust support for sustainable resource management, reduces the environmental impact, and advances circular economy practices. This study contributes to the efficient utilization of construction spoil and the sustainable development of high-speed railway projects. Full article

This study evaluates the quality and vulnerability of groundwater within the Nakivale Sub-catchment of the transboundary Lake Victoria Basin in Southwestern Uganda. Groundwater quality assessment focuses on its suitability for both drinking and agricultural uses. Hydrochemical analysis of 19 groundwater samples revealed that 90% comply with World Health Organization drinking water standards, although localized contamination was noted, particularly in terms of total iron, nitrate, potassium, magnesium, and sulfates. The drinking groundwater quality index shows that over 90% of the samples fall within the good-to-excellent quality categories. Elevated nitrate levels and chloride–bromide ratios indicate human impacts, likely due to agricultural runoff and wastewater disposal. For irrigation, Sodium Adsorption Ratio analysis revealed medium-to-high salinity hazards in the region, while Sodium Percentage and other parameters indicated low-to-moderate risks of soil degradation. DRASTIC vulnerability assessments identified low contamination risks due to impermeable geological layers, steep terrain, slow groundwater recharge, deep aquifer depth, and clayey soil cover. These findings emphasize the need for conjunctive water resource management, including improved groundwater quality monitoring, public education on sustainable practices, and protective measures for recharge zones and areas highly susceptible to contamination. By addressing these issues, this study aims to preserve groundwater resources for domestic and agricultural use, ensuring long-term sustainability in the region. Full article

Assessing reservoir subsidence due to depletion involves understanding the geological and geophysical processes that lead to ground subsidence as a result of reservoir fluid extraction. Subsidence is a gradual sinking or settling of the Earth’s surface, and it can occur when hydrocarbons are extracted from underground reservoirs. In this study, a time-integrated 3D coupled geomechanical modeling incorporating the fourth dimension—time—into traditional 3D geomechanical models has been constructed utilizing seismic inversion volumes and a one-dimensional mechanical Earth model (1D MEM). The 3D geomechanical model was calibrated to the 1D MEM results. Geomechanical rock properties were derived from the density and sonic log data that was distributed with conditioning to the seismic inversion volumes obtained from running pre-stack inversion. The standard elastic parameter equations were used to generate estimates of the elastic moduli. These properties are dynamic but have been converted to static values using additional equations used in the 1D MEM study. This included estimating the Unconfined Compressive Strength. In situ stresses were matched using different minimum horizontal principal stress gradients and horizontal principal stress ratios. The match is good except where the weak carbonate faults are close to the wells, where the Shmin magnitudes tend to decrease. The SHmax orientations were assessed from image log data and indicated to be 110° in the reservoir section. A time-integrated 3D coupled simulation was created using the finite-element method (FEM). The effective stresses increase while there is depletion in all directions, especially in the Z direction. The predicted compaction in the reservoir and overburden was 350 mm. Most of the compaction occurs at the reservoir level and dissipates towards the surface (seabed). Furthermore, the case displayed no shear failure that might cause or fault reactivation in the reservoir interval (Kangan–Dalan Formations) located in the simulated area. In this study, we applied an integrated and comprehensive geomechanical approach to evaluate subsidence, fault reactivation and stress alteration, while reservoir depletion was assessed using seismic inversion, well logs, and experiment data. The deformation monitoring of geological reservoirs, whether for gas storage or hazardous gas disposal, is essential due to the economic value of the stored assets and the hazardous nature of the disposed materials. This monitoring is vital for ensuring the sustainability of the reservoir by maintaining operational success and detecting integrity issues. Full article

The mining of deep underground coal seams induces the movement, failure, and collapse of the overlying rock–soil body, and the development of this damaging effect on the surface causes ground fissures and ground subsidence on the surface. To ensure safety throughout the life cycle of the mine, fully distributed, real-time, and continuous sensing and early warning is essential. However, due to mining being a dynamic process with time and space, the overburden movement and collapse induced by mining activities often have a time lag effect. Therefore, how to find a new way to resolve the issue of the existing discontinuous monitoring technology of overburden deformation, obtain the spatiotemporal continuous information of the overlying strata above the coal seam in real time and accurately, and clarify the whole process of deformation in the compression–tensile strain transition zone of overburden has become a key breakthrough in the investigation of overburden deformation mechanism and mining subsidence. On this basis, firstly, the advantages and disadvantages of in situ observation technology of mine rock–soil body were compared and analyzed from the five levels of survey, remote sensing, testing, exploration, and monitoring, and a deformation and failure perception technology based on spatiotemporal continuity was proposed. Secondly, the evolution characteristics and deformation failure mechanism of the compression–tensile strain transition zone of overburden were summarized from three aspects: the typical mode of deformation and collapse of overlying rock–soil body, the key controlling factors of deformation and failure in the overburden compression–tensile strain transition zone, and the stability evaluation of overburden based on reliability theory. Finally, the spatiotemporal continuous perception technology of overburden deformation based on DFOS is introduced in detail, and an integrated coal seam mining overburden safety guarantee system is proposed. The results of the research can provide an important evaluation basis for the design of mining intensity, emergency decisions, and disposal of risks, and they can also give important guidance for the assessment of ground geological and ecological restoration and management caused by underground coal mining. Full article

Geological reservoirs are widely used for storing or disposing of various fluids and gases, including groundwater, wastewater, carbon dioxide, air, gas, and hydrogen. Monitoring these sites is essential due to the stored assets’ economic value and the disposed materials’ hazardous nature. Reservoir pressure monitoring is vital for ensuring operational success and detecting integrity issues, but it presents challenges due to the difficulty of obtaining comprehensive pressure distribution data. While direct pressure measurement methods are costly and localized, indirect techniques offer a viable alternative, such as inferring reservoir pressure from surface deformation data. This inversion approach integrates a forward model that links pressure distribution to deformation with an optimization algorithm to account for the ill-posed nature of the inversion. The application of forward models for predicting subsidence, uplift, and seismicity is well-established, but using deformation data for monitoring underground activity through inversion has yet to be explored. Previous studies have used various analytical, semi-analytical, and numerical models integrated with optimization tools to perform efficient inversions. However, analytical or semi-analytical solutions are impractical for complex reservoirs, and advanced numerical models are computationally expensive. These studies often rely on prior information, which may only sometimes be available, highlighting the need for innovative approaches. This study addresses these challenges by leveraging advanced numerical models and genetic algorithms to estimate pressure distribution from surface deformation data without needing prior information. The forward model is based on a discrete Green matrix constructed by integrating the finite element method with Python scripting. This matrix encapsulates the influence of reservoir properties and geometry on the displacement field, allowing for the rapid evaluation of displacement due to arbitrary pressure distributions. Precomputing Green’s matrix reduces computational load, making it feasible to apply advanced optimization methods like GA, which are effective for solving ill-posed problems with fewer observation points than unknown parameters. Testing on complex reservoir cases with synthetic data showed less than 5% error in predicted pressure distribution, demonstrating the approach’s reliability. Full article

Landslide is a typical geological disaster distributed in most countries worldwide. Due to long-term natural weathering and human engineering disturbances, the instability of landslides is prone to occur. Once monitoring and disposal methods are implemented inappropriately, they can lead to landslide hazards, seriously threatening the safety of people’s lives and property. For a long time, extensive research on landslide monitoring has been conducted from various countries, providing crucial technical support for reducing the incidence and severity of landslide hazards. However, considering the complex geological conditions of actual landslides and the direct impact of internal and external factors such as rainfall, storms, and earthquakes, the early warning accuracy of landslide hazards is still relatively low. Therefore, based on advanced research achievements, it is significant to carry out research on the current status and development trends of landslide monitoring technology. Based on the Web of Science core database, this study quantitatively analyzes the advanced research achievements in global landslide monitoring in the past decade using bibliometric analysis. A systematic analysis of landslide monitoring technology development is conducted according to each study’s publication time, keywords, and countries. On this basis, a multi-dimensional monitoring system for landslides was proposed, which utilizes the complementary advantages of multi-dimensional monitoring technology to achieve all-round, high-precision, and real-time monitoring of landslides. Finally, taking the Xinpu landslide in the Three Gorges Region of China as an example, a multi-source and multi-field-monitoring experiment was conducted. The application of landslide multi-field-monitoring technology provides an essential reference for monitoring, early warning, as well as the scientific prevention and control of landslide hazard. Full article

The DIGIT experiment was launched at the Tournemire Underground Research Laboratory URL with the aim of determining the effects of temperature on the transfer of analogues of most mobile radionuclides (i.e., ³⁶Cl, ¹²⁹I and ⁷⁹Se) in the Toarcian clay rock, the properties of which are close to host rocks being considered for future deep geological disposal of high-level (HL) radioactive wastes. The experimental principle involves the monitoring of an exchange between a test water traced with stable halides and deuterium at constant concentration and the porewater of the Toarcian clay rock submitted to various temperatures. This experiment seeks to partially address questions regarding the potential spread of contaminants during the thermal phase of High Level Waste (HLW) waste packages. Specifically, the in situ experiment aims to evaluate the role of scale effects and thermodiffusion, a process that combines Fick’s law and the Soret effect, in the transfer of radionuclides. This paper presents the first steps of the study, including the scoping calculations, the experimental set-up and the first results obtained during the unheated phase. The study started with the acquisition of the initial parameters, including the rock thermal properties, the concentrations of the four tracers (chloride, bromide, iodide and deuterium) naturally present in the clay porewater and their diffusive transport parameters by using four diffusion exchange techniques (phase 0). A model coupling heat and mass transfers was then developed using Comsol Multiphysics^®, integrating data acquired so far with existing literature data. A test water with a tracer concentration around 1000 times higher than those in the pore water was proposed with a temperature imposed at the test section wall of 70 °C. A large test zone of 50 cm height and 1 m in diameter and installed in a 3 m deep vertical well located in a sound zone at the URL was then proposed. The installation of the experiments required the realization of one shaft and of nine peripheral boreholes for the monitoring of temperature, water pressure and deformation. The experiment started with phase 1, involving a traced, unheated water start-up for a period of 5 months. Then, a core sampling was conducted in the emptied well, and the same diffusion exchange techniques were applied. The results of anionic tracers were compared to simulations based on initial parameters (phase 0), revealing that tracer penetration at the end of phase 1 exceeded simulated values by approximately 2 cm. This result is interpreted as an increase in the accessible porosity to tracers, possibly due to the excavation damaged zone. Future simulations should incorporate these adjusted diffusive transport parameters. Following phase 1, the heating system was activated, applying a temperature of 70 °C to the test zone. New data will enable the comparison of tracer penetration and assess the actual impact of temperature on tracer transfer. Full article

Due to various historical events, in the Russian Federation, in addition to the radioactive waste storage facilities used in world practice, there are various nuclear and radiation hazardous facilities that require special procedures for monitoring and decommissioning. One of these facilities is the disposal site for LRW on the territory of the JSC Siberian Chemical Plant, where specially prepared waste is injected into sand reservoirs lying at depths of 300–350 m between clayey strata. This study examines in detail the features of the lithological and mineral composition of reservoir sands and aquitards. The processes of environmental transformation in reservoir sands, which lead to changes in the composition and structure of rocks, were characterized. These processes manifest themselves in the form of the development of leaching zones and their “healing” with newly formed smectite, the destruction of terrigenous grains, including the development of cracks, and the growth of newly formed smectite in the pore space of reservoirs. The forms of occurrence and localization of authigenic smectite formed as a result of technogenic impact are described. It has been shown that, despite the obvious impact of highly reactive solutions accompanying liquid radioactive waste, the insulating properties of the geological environment are maintained and even improved to some extent. Full article

Water gushing is a common engineering geological disaster in the process of foundation pit construction. Its successful judgment directly affects the safety of engineering construction. Taking the case of water gushing at the bottom of the foundation pitas as a research object, the mechanism and treatment of water gushing in foundation pits, the stability against water gushing, and its influencing factors are analyzed with a field investigation, field testing, and theoretical calculation. The calculation formula for the safety factor and critical thickness of the foundation pit against surges, considering the influence of multiple factors, is deduced. The influence of the height of the confined water level, the thickness of the water-resisting layer, the shear strength of the soil mass, the reinforcement depth of the soil mass in the pit, and the diameter of the bearing pile in the pit on the safety factor of the foundation pit surge are expounded. In addition, measures such as the reinforcement of the soil mass in the passive area in the pit, the increase in the thickness of the water-resisting layer, and the reduction in the confined water level are proposed to improve the anti-surge stability of the foundation pit. A new monitoring method is proposed for characterizing uplift deformation at the bottom of the pit without affecting normal construction. The research results show that: (1) the minimum safety factor against surges, considering multiple factors, is 1.455, and the critical thickness is 5.87 m, which is in line with specifications. (2) Measures such as reinforcing the soil in the passive zone of the pit, increasing the thickness of the water-insulating layer, and lowering the bearing pressure level are used to improve the stability of the pit against surges. (3) The pit, obtained by the pit bottom counter-pressure, pumping water out of the pit, and the timely construction of the pit bottom bedding to block the program, exhibits a measured maximum bottom plate pressure of 115.189 kPa, and the deformation corresponding to the method proposed in this paper is 1.406 mm, which is better disposed in the field. The research results provide a reference basis for the judgment of anti-surge stability of foundation pits and similar engineering applications. Full article

Underground coal mining can cause the deformation, failure, and collapse of the overlying rock mass of a coal seam. If the mining design, monitoring, early warning, or emergency disposal are improper, in that case, it can often lead to mining disasters such as roof falls, water inrush, surface collapse, and ground fissures, seriously threatening the safety of mine engineering and the geological environment protection in mining areas. To ensure the intrinsic security of the entire coal mining process, aspace–time continuous sensing system of overburden deformation and failure was developed, which breaks through the limitations of traditional monitoring methods that characterize the evolution process of overlying rock deformation and ground subsidence. This paper summarizes the classification of typical overburden deformation and failure modes. It researches the space–time continuous sensing of rock–soil mass above the coal seam based on Distributed Fiber Optic Sensing (DFOS). A multi-range strain optical fiber sensing neural series from micron to meter was developed to achieve synchronous sensing of overburden separation, internal micro–cracks, and large rock mass deformation. The sensing cable–rock mass coupling test verified the reliability of the optical fiber monitoring data. The sensing neural network of overburden deformation was constructed using integrated optical fiber layout technology on the ground and underground. Different sensing nerves’ performance and application effects in overburden deformation and failure monitoring were compared and analyzed with field monitoring examples. A physical model was used to carry out the experimental study on the overburden subsidence prediction during coal mining. The results showed that the optical fiber monitoring data were reliable and could be used to predict overburden subsidence. The reliability of the calculation model for overlying rock subsidence based on space–time continuous optical fiber sensing data was verified in the application of mining subsidence evaluation. A systematic review of the shortcomings of current overburden deformation observation technology during coal mining was conducted, and a space–time continuous sensing system for overburden deformation and failure was proposed. This system integrated sensing, transmission, processing, early warning, decision-making, and emergency response. Based on the fusion of multi-parameter sensing, multi-method transmission, multi-algorithm processing, and multi-threshold early warning, the system realized the real-time acquisition of space–time continuous information for the overburden above coal seams. This system utilizes long-term historical monitoring data from the research area for data mining and modeling, realizing the prediction and evaluation of the evolution process of overburden deformation as well as the potential for mining subsidence. This work provides a theoretical reference for the prevention and control of mining disasters and the environmental carrying capacity evaluation of coal development. Full article

Near-neutral pH and a low redox potential are considered favorable conditions for immobilizing radionuclides in deep repository systems within clay formations. Cigeo is the future French Industrial Center for Geological Disposal for high- and intermediate-level long-lived radioactive waste, to be built at a depth of 500 m within the Callovian–Oxfordian clay. In-depth knowledge of the mechanisms and kinetics of corrosion occurring on the surface of API 5L X65 (X65) carbon steel tubing is essential for the reversible nuclear waste management of the Cigeo site. By using all-solid and robust handmade electrodes in addition to electrochemical and gravimetric techniques, we determined the corrosion phenomenology and kinetics of X65 in contact with natural Cox pore water in equilibrium with its rock gases, flowing continuously through a multi-parameter probe device and placed at a depth of 500 m at the Bure Underground Research Laboratory, for over 180 days. Two iron oxidants were encountered, namely, depleted dioxygen (O₂) and proton H^(I), accompanied by hydrogen sulfide. Corrosion mechanisms and kinetics were well established for the two X65 electrodes, whether electrochemically perturbed or not. The corrosion thickness loss rates, determined by both electrochemical and gravimetric techniques, were between 0.016 and 0.032 mm/year. This study demonstrates, on site, the reliability of a developed methodology for continuous monitoring of the corrosion kinetics of the API 5L X65 carbon steel at the same time as the temporal variation of the key geochemical parameters of the fluid was assessed. Full article

Open-pit unclassified cemented paste backfilling (OPUCPB) methods have not only addressed the disposal problems of tailings but also eliminated geological hazards of high and steep open pit slopes and created conditions for ecological restoration of the open pit in the future. In this paper, slope safety simulations, heavy metal leaching, groundwater monitoring, and pollutant diffusion predictions were examined to evaluate the slope safety pattern and environmental protection enabled by OPUCPB. The results showed that: (1) The safety factor of the open pit slope was proportional to the height of OPUCPB operation. Under the condition of seismic force and seepage field, the safety factor of slope B was increased from 1.188 to 1.574 by OPUCPB. (2) The toxic and harmful components in tailings were significantly stabilized by the OPUCPB. Under the conditions of acid leaching and water leaching, the quality of the leaching solution met the requirements of the class III limit of groundwater (GB/T14848-2017). (3) The monitoring results of groundwater quality around the open pit showed that the OPUCPB had no effect on groundwater, and the water quality met the requirements of the class III limit of groundwater (GB/T14848-2017). (4) Considering the diffusion prediction of pollutants and groundwater under extreme conditions, it was found that the pollution process is slow, and the shortest time required for pollutants to reach the standard limit is 232 d at a distance of 50 m from the leakage point. Therefore, the influence of OPUCPB can be controlled, and this method can achieve improved reclamation of open pits and safety treatment of tailings. It was worth popularizing and applying in mining enterprises. Full article

Within the context for deep geological disposal (DGD) of high-level radioactive waste (HLW), thermo-hydro-mechanical (THM) coupled numerical modeling has become significantly important for studying the safe disposal of HLW. In this work, a 3D mechanical module is incorporated into the thermal–hydraulic (TH) coupled code TOUGH2, thus forming an integrated THM coupled simulator referred to as TOUGH2Biot. The Galerkin finite element method is used to discretize the space for rock mechanical calculation. The mechanical process is sequentially coupled with the fluid and heat flow processes, which further gives feedback to the flow through stress-dependent hydraulic properties (e.g., porosity and permeability). Based on the available geological data at the Meuse/Haute-Marne Underground Research Laboratory (MHM URL) in France, the improved simulator is used to analyze the coupled THM behaviors of the Callovo-Oxfordian claystone (COx) induced by thermal loading. The anisotropy of material parameters (e.g., permeability and thermal conductivity) caused by the bedding and of in-situ stresses are well considered in our model. The numerical simulation can reasonably reproduce the field observations, including changes in temperature and pore pressure at monitoring boreholes during the ALC1604 experiment. The modeling results indicate that the anisotropic effects are remarkable, and temperature, pore pressure, and effective stress along the bedding increase more rapidly than in the vertical direction. Insight into numerical results through the visual model is beneficial for helping us to interpret the field observations and to understand the complex THM problem in the COx claystone formation. The numerical method and the modeling results presented in this work can be effectively used in support of performance assessment studies of HLW disposal sites to build confidence in the safety of future applications of nuclear energy systems. Full article