Search Results (11)

Gelled fuels are rheologically complex, non-Newtonian fluids. They combine the benefits of both liquid and solid states, reducing risks of leakage, spilling, and sloshing during storage while maintaining the ability to be sprayed inside a combustion chamber. Additionally, suspending energetic particles, such as metal powders of aluminum and boron, can significantly enhance their energy density compared to conventional liquid fuels. In this study, several kerosene-based and ethanol-based formulations were experimentally investigated, using both organic and inorganic gelling agents. The compositions were optimized in terms of the gellant amount and manufacturing process. Some of the most promising gellants for kerosene include fatty acids, such as Thixcin^® R or THIXATROL^® ST, and metallic soaps, such as aluminum stearate and zinc stearate. The effects of various co-solvents were assessed, including ketones (methyl isoamyl ketone, methyl ethyl ketone, and acetone) and alcohols (ethanol and octadecanol). Sugar polymers like hydroxypropyl cellulose were tested as gelling agents for ethanol. A preliminary rheological analysis was conducted to characterize their behavior at rest and under shear stress. Finally, a novel approach was introduced to study the stability of the gels under vibration, which was derived from a realistic mission profile of a ramjet. Finally, the ideal gravimetric specific impulse was evaluated through ideal thermochemical computations. The results showed that promising formulations can be found in both kerosene-based and ethanol-based gels. Such compositions are of interest in practical airbreathing applications as they have demonstrated excellent stability under vibration, ideal combustion properties, and pronounced shear-thinning behavior. Full article

(N-Alkyloxalamido)-amino acid amides 9–12 exhibit excellent gelation capacities toward some lipophilic solvents as well as toward the commercial fuels, petrol and diesel. Gelator 10 exhibits an excellent phase-selective gelation (PSG) ability and also possesses the highest gelation capacity toward petrol and diesel known to date, with minimum gelation concentration (MGC) values (%, w/v) as low as 0.012 and 0.015, respectively. The self-assembly motif of 10 in petrol and toluene gel fibres is determined from xerogel X-ray powder diffraction (XRPD) data via the simulated annealing procedure (SA) implemented in the EXPO2014 program and refined using the Rietveld method. The elucidated motif is strongly supported by the NMR (NOE and variable temperature) study of 10 toluene-d₈ gel. It is shown that the triple unidirectional hydrogen bonding between gelator molecules involving oxalamide and carboxamide groups, together with their very low solubility, results in the formation of gel fibres of a very high aspect ratio (d = 10–30 nm, l = 0.6–1.3 μm), resulting in the as-yet unprecedented capacity of gelling commercial fuels. Rheological measurements performed at low concentrations of 10 confirmed the strength of the self-assembled network with the desired thixotropic properties that are advantageous for multiple applications. Instantaneous phase-selective gelation was obtained at room temperature through the addition of the 10 solution to the biphasic mixture of diesel and water in which the carrier solvent was congealed along with the diesel phase. The superior gelling properties and PSG ability of 10 may be used for the development of more efficient marine and surface oil spill recovery and waste water treatment technologies as well as the development of safer fuel storage and transport technologies. Full article

Gelled fuels have promising applications in the aerospace field. Higher density and calorific value can be achieved with the addition of energetic metal particles to gelled fuels, which can also effectively improve the combustion efficiency of the fuel and thus enhance the engine performance. However, the addition of metal particles can also make the rheological properties of gelled fuels more complex, which introduces difficulties regarding their atomization and combustion. In order to investigate the effect of the concentration of metal particles on the rheological and atomization characteristics of gelled fuels, the gelled fuel was prepared with three metal particle concentrations of 0%, 15%, and 30%. In this paper, the rheological properties of the gelled fuel were tested by a rotational rheometer, and the atomization properties (spray cone angle, Sauter mean diameter (SMD), and droplet size distribution) of the gelled fuel were measured experimentally. In this paper, three nozzle structures were designed, including a DC nozzle, a swirl nozzle, and a self-excited oscillation nozzle. The effects of different nozzle structures and metal particle concentrations on the atomization of gelled fuels are compared and discussed. Full article

For propulsion systems using gel fuels, reducing the gel fuel viscosity is essential for achieving better atomization and combustion. In this paper, we investigate the flow and heat transfer in a water-gel with a temperature and shear dependent viscosity. We consider several different channels, mimicking the transport of gelled fuels in propulsion systems, and we also look at corrugation, which is a way of enhancing fluid mixing and thus improving the heat transfer characteristics. The rheological parameters in the constitutive model of the gel are fitted with experimental data. The influence of different corrugation profiles, corrugation configuration parameters and the Reynolds number on the mean apparent viscosity and the pressure drop are investigated. It was found that the flow recirculation formed in the valley of the corrugations enhances the heat transfer and thus the temperature of the main flow. We also noticed an increase in the pressure drop due to the stronger viscous dissipation. Furthermore, it was observed that the sinusoidal corrugation can achieve lower viscosity with a lower pressure drop compared with triangular and trapezoidal corrugations. A shorter wavelength and a deeper wave amplitude of the corrugation seemed to be better for reducing the gel fuel viscosity, while we must consider the adverse consequence of increased pressure drop. A larger Reynolds number was helpful for both lowering the pressure drop and for reducing the viscosity. In addition, compared with a smooth straight pipe, a Y-shape corrugated channel with a constant inlet velocity reduced the mean apparent viscosity by 70.8%, and this value increased to 72.6% by further applying a pulsed inlet velocity, which can greatly enhance the gel fuel atomization and thus improve the combustion efficiency. Full article

Corrosion testing with gel electrolytes gained attention in the past decade due to the advantage of almost non-destructive and in situ electrochemical measurements of bulk materials. Regarding thermal spray coatings, gel electrolytes offered the opportunity to prevent the infiltration of the typical microstructural features such as pores and microcracks. Using the example of stainless-steel AISI 316L coatings deposited by high velocity air fuel (HVAF) spraying on mild and stainless-steel substrates, the electrochemical corrosion behavior was analyzed in 3.5% NaCl electrolytes in an aqueous and gelled state. In this context, potentiodynamic polarization tests were carried out in a three-electrode corrosion cell, which was adapted for gel electrolyte testing. Gelling was realized with a technical gelatin. The characteristic corrosion values, such as open circuit potential, corrosion potential, and corrosion current density, revealed for the gelled state that the influence of the substrate material used could be eliminated and thus, the coatings itself could be characterized. In contrast, the coating specific microstructure and substrate material significantly affected the potentiodynamic polarization curve in the 3.5% NaCl aqueous electrolyte. Optical microscopy of the coating surfaces and cross-sections proved that the corrosion attack caused by aqueous electrolytes could be mimicked with the gel electrolyte. Full article

A reversible gelation–release system was developed for safe storage of toxic hydrazine solution based on gelation at lower critical solution temperature (LCST). Poly(N-isopropylacrylamide) (PNIPAM) and its copolymer could form gels of 35wt% hydrazine by dissolution under low temperature and storage at ambient temperatures. For example, PNIPAM gelled a 63 fold heavier amount of 35wt% hydrazine. Aqueous hydrazine was released from the gels by compression or heating, and the gelation–release cycles proceeded quantitatively (> 95%). The high gelation ability and recyclability are suitable for rechargeable systems for safe storage of hydrazine fuels. Full article

In general, rheological properties of gelled fuels change dramatically when temperature changes. In this work, we investigate flow and heat transfer of water-gel in a straight pipe and a tapered injector for non-isothermal conditions, which mimic the situations when gelled fuels are used in propulsion systems. The gel-fluid is modeled as a non-Newtonian fluid, where the viscosity depends on the shear rate and the temperature; a correlation fitted with experimental data is used. For the fully developed flow in a straight pipe with heating, the mean apparent viscosity at the cross section when the temperature is high is only 44% of the case with low temperature; this indicates that it is feasible to control the viscosity of gel fuel by proper thermal design of pipes. For the flow in the typical tapered injector, larger temperature gradients along the radial direction results in a more obvious plug flow; that is, when the fuel is heated the viscosity near the wall is significantly reduced, but the effect is not obvious in the area far away from the wall. Therefore, for the case of the tapered injector, as the temperature of the heating wall increases, the mean apparent viscosity at the outlet decreases first and increases then due to the high viscosity plug formed near the channel center, which encourages further proper design of the injector in future. Furthermore, the layer of low viscosity near the walls plays a role similar to lubrication, thus the supply pressure of the transport system is significantly reduced; the pressure drop for high temperature is only 62% of that of low temperature. It should be noticed that for a propellent system the heating source is almost free; therefore, by introducing a proper thermal design of the transport system, the viscosity of the gelled fuel can be greatly reduced, thus reducing the power input to the supply pressure at a lower cost. Full article

Gelled fuels combine the main advantages of liquid fuels (throttle ability) and solid fuels (easy handling, etc.) due to their non-Newtonian characteristics. In this paper, we study the flow characteristics of water-hydroxypropylcellulose (HPC) gel in converging tubes and tapered injectors which mimic the flow and injection of kerosene gel in typical geometries of propulsion systems. The water-HPC gel is modeled as a non-linear fluid, where the shear viscosity is assumed to depend on the local shear rate and modeled by the Carreau–Yasuda model; the model parameters are fitted with our experimental measurements done by a rotational rheometer. The numerical simulations indicate that for the converging tubes, increasing the convergence angle, causes the mean apparent viscosity at tube exit to decrease while the mass flow rate reduces at a constant pressure drop. Therefore, there is a balance between the lowering of the pressure loss and reducing mean apparent viscosity. In the tapered injectors, the straight pipe after the converging part has a detrimental effect on the viscosity reduction. Full article

Microscopic high-speed imaging is used to experimentally measure the velocity and size of droplets of gelled RP-1 based fuels with a solid particle additive. The gels are atomized using an air atomizing nozzle. The droplet diameter and velocity at a fixed position 20 cm from the nozzle on the centerline of the spray are measured at air mass flow rates of 1.5, 3 and 5 g/s. A parametric study is conducted to study the effect of gas mass flow rate, boron particle content, and species of the solid particle on the droplet characteristics. The results indicate that the droplet size decreases with the increasing of gas mass flow rate and boron particle content. Gel fuels with an aluminum particle are observed to produce smaller droplets at a low gas mass flow rate than that with a boron particle. The implication of these observations is that the atomization processes for gelled fuels with an additive of solid particles is controlled by the velocity difference between the gas and the droplets. Full article

Phase selective gelation (PSG) of organic phases from their non-miscible mixtures with water was achieved using tetrapeptides bearing a side-chain azobenzene moiety. The presence of the chromophore allowed PSG at the same concentration as the minimum gelation concentration (MGC) necessary to obtain the gels in pure organic phases. Remarkably, the presence of the water phase during PSG did not impact the thermal, mechanical, and morphological properties of the corresponding organogels. In the case of miscible oil/water mixtures, the entire mixture was gelled, resulting in the formation of quasi-hydrogels. Importantly, PSG could be triggered at room temperature by ultrasound treatment of the mixture or by adding ultrasound-aided concentrated solution of the peptide in an oil-phase to a mixture of the same oil and water. Moreover, the PSG was not affected by the presence of salts or impurities existing in water from natural sources. The process could be scaled-up, and the oil phases (e.g., aromatic solvents, gasoline, diesel fuel) recovered almost quantitatively after a simple distillation process, which also allowed the recovery and reuse of the gelator. Finally, these peptidic gelators could be used to quantitatively remove toxic dyes from aqueous solutions. Full article

The increasing demand for high energy density fuels and the concern for their safety have propelled research in the field of gelled propellants, where understanding the combustion of single gelled fuel droplets is the first stage to predict the spray combustion characteristics. The experiments utilized single-isolated freely falling gelled unsymmetrical dimethylhydrazine (UDMH) droplets instead of the conventional suspended droplet approach, in order to eliminate the perturbation associated with the suspension mechanism. Morphological transformations of the gelled droplet involved in the combustion processes were monitored by employing a high-speed digital camera, while the effects of ambient pressure and oxygen concentration on burning rate constants were also studied. The experimental results show that four main phenomena (droplet deformation, bubble formation and growth, vapor jetting and luminous jetting flame with “horn” shape) and three distinct phases were identified in the droplet combustion process; the high yield stress and polymer chain structure of polymer gellant are responsible for the appearance of bubbles with almost the same order of magnitude as the droplets. Increasing the ambient pressure can increase the burning rate, postpone the appearance of microexplosions, and weaken microexplosion intensity; while increasing the ambient oxygen concentration can promote the appearance of microexplosions, strengthen microexplosion intensity and increase the burning rate. Full article