Search Results (1,119)

This paper describes the comprehensive molecular characterisation and application of a commercially available, but structurally undefined, photochromic pigment for the development of textile sensors. The commercial pigment was successfully identified using a multianalytical approach, including analysis using nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC). The identified pigment, ethyl-3′-methyl-3′-phenyl-1′-(propan-2-yl)-1′,3′-dihydrospiro[[4,1,2]benzoxadiazine-3,2′-indole], was used to develop a textile sensor by screen printing on a natural fibre fabric surface. The developed sensor exhibited a reversible colour change from white to pink upon exposure to UVA radiation (369 nm). The sensor is characterised by high sensitivity with a linear dose–response of 0–0.005 J/cm² and a dynamic range of up to 0.05 J/cm². Furthermore, the sensor’s molecular safety profile was assessed, including elemental composition and cytotoxicity tests on human dermal fibroblasts, which confirmed the sensor’s biocompatibility with occasional skin contact. In addition to its use in decorative and security elements for product authentication, this study demonstrates the sensor’s ability to map the 2D UVA radiation dose distribution. This research highlights the importance of precise molecular identification in the design of functional, safe, and intelligent textile systems. Full article

Cotton is recognized as the primary source of essential natural fibers for the global textile industry, supporting its sustainability and development. However, adverse environmental conditions such as drought severely constrain cotton production; thus, developing stress-tolerant cultivars via molecular breeding is essential for maintaining yield stability. Here, a comprehensive functional dissection was conducted on GhGA2ox15, a gibberellin 2-oxidase gene derived from Gossypium hirsutum L. This gene encodes a key catabolic enzyme implicated in the deactivation of endogenous bioactive GAs and the modulation of stress adaptation. We characterized GhGA2ox15, a GA2ox gene from upland cotton that modulates endogenous bioactive GA levels and abiotic stress tolerance. Bioinformatics and sequence analyses confirmed that GhGA2ox15 is a canonical C₂₀-GA2ox subfamily member, with conserved DIOX_N and 2OG-FeII_Oxy domains and marked similarity to orthologs in Arabidopsis and rice. Tobacco subcellular localization assays indicated that GhGA2ox15 resides in both the nucleus and the cytoplasm. In transgenic Arabidopsis and Oryza sativa lines, GhGA2ox15 overexpression was shown to increase drought tolerance, while virus-induced gene silencing (VIGS) of GhGA2ox15 yielded significantly compromised drought resistance. Physiological assays linked GhGA2ox15 silencing to impaired reactive oxygen species (ROS) detoxification. The suppressed lines displayed markedly lower antioxidant enzyme activities, concomitant ROS accumulation in leaves, and attenuated transcription of drought-responsive marker genes. Our findings delineate the mechanistic role of GhGA2ox15 in drought adaptation and highlight its potential utility in breeding drought-tolerant cotton. Full article

This study investigates lignin as a renewable functional dye capable of simultaneously imparting coloration and multifunctional performance to cotton textiles, with particular emphasis on how chitosan polymorphs influence lignin-mediated silver nanoparticle (AgNP) systems. Cotton fabrics were pretreated with α- or β-chitosan crosslinked with glyoxal and subsequently dyed with lignin in the presence of silver ions to generate lignin-mediated AgNPs. Inductively coupled plasma optical emission spectrometry (ICP–OES) analysis showed that α-chitosan retained a higher silver content (40.7 mg/kg) than β-chitosan (14.7 mg/kg). Transmission electron microscopy (TEM) revealed that α-chitosan produced larger AgNPs (≈13.6 nm), whereas β-chitosan was associated with smaller measurable nanoparticles (≈4.3 nm). Despite lower silver loading, β-chitosan–modified fabrics exhibited higher antibacterial activity against Staphylococcus aureus (82.6%) than α-chitosan-modified fabrics (68.7%). These results suggest that antibacterial performance in lignin–silver coating systems may depend not only on silver loading, but also on the distribution and accessibility of active components within the coating layer. In addition, the coatings improved UV protection, tensile properties, and color strength. Overall, the findings demonstrate that chitosan polymorphism plays an important role in controlling nanoparticle characteristics and multifunctional performance in lignin-based textile systems. Full article

Plastics are indispensable to modern life, yet pose a double-edged sword as their escalating production threatens human health and ecosystems. This urgent reality drives intensive efforts to develop recycling technologies that convert waste plastics into valuable feedstocks. Herein, we develop an efficient organocatalytic strategy for the depolymerization and closed-loop chemical recycling of poly(butylene succinate) (PBS). The strong organic base TBD demonstrated the highest catalytic activity for the methanolysis depolymerization of PBS, achieving a yield of 93.1% under mild conditions (100 °C, 2 h). GC and MS analyses identified dimethyl succinate (DMS) and 1,4-butanediol (1,4-BDO) as the major products. Investigation into the depolymerization behavior and mechanism revealed that the process proceeds via random chain scission, facilitated by a dual hydrogen-bonding activation mechanism mediated by TBD. Closed-loop chemical recycling was achieved by repolymerizing the recovered monomers into PBS. The reproduced polymer exhibited properties comparable to commercial virgin PBS. Moreover, this strategy could be extended to other commercial polyester systems, establishing an eco-friendly and viable pathway for sustainable polymer recycling. Full article

Zinc oxide nanoparticles (ZnO NPs) exhibit strong and broad-spectrum antibacterial properties, making them a promising agent for textile applications. However, their weak adhesion to fibers and poor washing durability have hindered practical use. In this work, we report zinc/catechol resin-based microspheres (Zn/CFRs) synthesized via a one-pot hydrothermal route and applied to cotton fabric through a pad-dry-cure process. The resulting Zn/CFRs exhibit a monodisperse spherical morphology, with zinc ions concentrated on the surface and ZnO NPs encapsulated within the resin matrix. The finished fabric demonstrates potent, non-leaching antibacterial activity, achieving over 99.99% inhibition against S. aureus, E. coli, and C. albicans, with excellent performance retention even after 50 laundering cycles. Furthermore, we observed that catechol oxidation in the Zn/CFRs proceeds slowly under UV light, which may contribute to the durable adhesion of the coating. Moreover, the functional finishing does not compromise the fabric’s tensile strength, hand feel, or breathability, which positions it favorably for scalable adoption in functional textile manufacturing. Full article

The increasing complexity of textile waste, particularly blended fibers, represents a major challenge for conventional recycling approaches. This study proposes a selective valorization strategy for mixed textile waste streams by applying tailored chemical recycling routes to individual fiber type. Preliminary tests identified suitable methodologies for each fiber type: dissolution–precipitation for acrylic (poly(acrylonitrile)—PAN), acidolysis for nylon, glycolysis for polyester (PeS) and acetylation for cotton. Structural characterization confirmed that the incorporation of recycled products did not significantly change the chemical structure or crystallinity of the resulting materials. Furthermore, thermal analysis revealed comparable or slightly improved thermal stability in most recycled systems. Additionally, mechanical performance was observed to vary depending on the polymer type. Recycled acrylic and cellulose acetate showed reduced ductility, while nylon exhibited increased stiffness due to possible recrystallization effects. In contrast, PeS displayed enhanced elongation at break, suggesting increased chain mobility or plasticization effects. Overall, the results demonstrate that selective chemical valorization is a promising route for the efficient recycling of complex textile waste, enabling the recovery of high-quality materials with retained functional properties. Full article

Ballistic para-aramid fabrics are widely used in personal protection and defense applications due to their high strength-to-weight ratio, thermal stability, and durability. This study investigates the influence of laser-based surface modification on graphene-modified Kevlar^® KM2-600 (600 dtex) fabrics, with a particular focus on surface morphology and topographical characteristics of para-aramid fabrics used in ballistic applications. The deposition of graphene onto para-aramid fibers introduces new opportunities for surface engineering, while laser processing enables localized and controlled modification of the fiber surface without compromising the integrity of the bulk material. In this work, graphene-modified Kevlar^® KM2-600 fabrics were subjected to controlled laser processing under various parameter settings, and the resulting surface modifications were systematically analyzed. Three-dimensional laser microscopy was employed to characterize surface morphology and roughness, providing detailed insight into laser-induced topographical changes. The results demonstrate that optimized laser processing enables controlled surface restructuring while avoiding severe thermal damage, particularly when appropriate mechanical stabilization and focal conditions are maintained. Under identical laser processing conditions (Matrix II, q = 3.65 × 10⁴ W/cm²), the mean arithmetic roughness increased from 4.57 ± 1.04 µm for the unmodified fabric to 5.54 ± 1.05 µm for the graphene-modified fabric, while the mean root mean square roughness increased from 5.76 ± 1.41 µm to 6.95 ± 1.39 µm. These findings contribute to an improved understanding of laser–graphene–aramid interactions and provide a foundation for future studies addressing the potential functional implications of surface modification in lightweight protective textiles. Full article

The durable enzyme functionalisation of cellulosic fibres is often limited by enzyme deactivation under alkaline processing and insufficient wash resistance. Here, a cold pad–batch (CPB)-compatible route integrates reactive dyeing and lysozyme anchoring by using the commercial bifunctional dye C.I. Reactive Red 195 (MCT/VS) as an interfacial mediator to build a cellulose–dye–lysozyme ternary layer. The dye is first fixed on cotton, and residual electrophilic motifs are proposed to facilitate subsequent coupling with nucleophilic residues in lysozyme. A nine-run, four-factor/three-level orthogonal design was used to identify a practical processing window; under the selected condition, an ELISA-equivalent releasable lysozyme level of 53.8 U/L was achieved together with moderate colour strength (K/S = 6.5). The treated fabrics exhibited 96.5% inhibition against Escherichia coli and >99.9% against Staphylococcus aureus and retained antibacterial functionality after five ISO 105-C06 laundering cycles. Textile-relevant properties were preserved, including colour fastness (Grade 4–5), tensile strength retention (~86%), and capillary wicking close to pristine cotton. This dye-mediated strategy offers a practical route to wash-resistant bioactive interfaces on cellulose fibres and is extendable to regenerated cellulose and wood-pulp-derived cellulosics. Full article

This research paper examines the environmental impact of natural and synthetic fur coats, focusing exclusively on the processing and manufacturing stages. Using one coat weighing approximately 5 kg as the functional unit, a comparative Life Cycle Assessment (LCA) is conducted from raw material processing to final garment production, explicitly excluding animal farming. The analysis includes key processes such as cleaning, tanning, dyeing, and sewing for natural fur, and polymer production, fabric formation, dyeing, and finishing for synthetic fur. Data from international academic literature (Google Scholar and Scopus) are used to evaluate CO₂ emissions, energy and water consumption, chemical inputs, and waste generation. Results indicate that synthetic fur production is energy-intensive but requires relatively low water use, whereas natural fur processing involves high water consumption and chemical treatments, resulting in significantly higher emissions—often reaching hundreds to thousands of kg CO₂e per coat. The study further investigates the role of embedded IoT systems in improving efficiency within tanneries and textile manufacturing. Real-time monitoring and automated dosing systems can reduce emissions and chemical use by approximately 10–20%. Case studies of a smart tannery and an IoT-enabled synthetic fur production line illustrate potential implementation pathways. Although such optimizations can reduce environmental impacts, the findings clearly show that natural fur processing remains considerably more carbon-intensive than synthetic alternatives. This research highlights the importance of integrating digital technologies into industrial processes and suggests directions for future work based on real-world operational data. Full article

The textile and clothing industry has historically exerted a significant negative impact on the environment. Excessive water consumption, chemical pollution, and soil degradation are just a few of the pressing environmental concerns linked to this sector. Addressing these issues has become a priority not only for regulatory bodies, at the National and European levels, but also for the industry itself. More recently, growing attention has turned to reducing the huge volume of waste generated by consumers’ unbridled purchase of clothing. In this context, the Circular Economy (CE) and the Digital Product Passport (DPP) have emerged as complementary approaches for improving product circularity, transparency, and traceability. However, in the textile and clothing sector, their effective implementation also depends on consumer participation in practices such as prolonged use, repair, reuse, and responsible end-of-life management. This article presents EcoProve, a gamified platform designed to encourage consumer engagement with CE practices through smart wardrobe management. The platform allows users to register garments, track usage, record maintenance and repair actions, and document sharing, donation, remaking, and recycling activities. These functionalities aim both to promote more sustainable clothing-related behaviours and to support the structured recording of use phase data relevant to DPP-oriented lifecycle information. This study reports the development and pilot validation of the platform with end users. The results suggest positive effects on environmental awareness, perceived understanding of sustainable textile-related practices, and initial self-reported changes in habits associated with clothing use and disposal. The findings support the potential of gamified digital platforms to foster consumer participation in CE systems in the textile and clothing sector while also indicating the need for broader and longer-term evaluations. Full article

The escalating energy crisis and global warming drive the demand for all-season self-regulating functional textiles. This study presents a Janus smart textile that combines phase change energy storage with active and passive heating modes, electromagnetic interference shielding, and self-cleaning capabilities. The front surface incorporates phase change temperature regulation and thermochromic properties, while the back surface is spray-coated with a transition metal carbide to establish a continuous conductive network. In the low-temperature state, the black surface enhances solar absorption for efficient heating; as the temperature rises, the surface turns white to increase solar reflection and suppress overheating. This mechanism, combined with phase change energy storage, enables the textile to mitigate environmental temperature fluctuations. The MXene layer on the back provides efficient Joule heating and cycling stability under driving voltages of 3 to 5 volts, along with electromagnetic interference shielding dominated by absorption loss. The front hybrid coating further imparts hydrophobic self-cleaning performance. This study offers a strategy for synergistic active and passive thermal management, demonstrating application potential in intelligent outdoor gear and specialized protective outer layers. Full article

Personal cooling garments are designed to help individuals manage excess heat in high-temperature environments. The thermal effects of these garments are typically evaluated through thermal manikin experiments or human subject tests. However, there remains an insufficient understanding of the correlation between the cooling efficacy of garments tested with thermal manikins and the thermal responses observed in the human body. This study seeks to establish thermal correspondence by integrating a novel thermal manikin-based testing protocol with physiological simulation software and controlled human-subject trials. A phase change material (PCM) cooling vest serves as a representative textile system for comparison. The results indicate that the manikin-based protocol effectively replicates the non-linear skin temperature drop and thermal stabilisation phases evident in humans, demonstrating a maximum deviation of only 0.2 °C in skin temperature (T_sk) across varying metabolic loads. These findings provide specific experimental evidence on the minimal deviation between the manikin’s skin temperature and human trials, demonstrating that the established novel testing protocol is capable of accurately detecting the heat-flux saturation points and latent heat discharge of the textile system. The proposed approach endorses this protocol as a robust, reproducible methodology for assessing thermal comfort and serves as a starting point for future international standardised protocols in personal cooling textiles, especially where human safety cannot be guaranteed. Full article

Food waste fashion—garments produced from agricultural and food industry by-products, such as fruit peels, coffee grounds, and grape marc—represents a radical yet understudied innovation within the circular economy. This study proposes the Fashion Innovation Adoption Model, a novel framework that organizes consumer adoption of fashion innovations across three hierarchical levels: a distal level comprising sociodemographic characteristics, an intermediate cognitive–evaluative level comprising consumer decision-making styles and functional product attribute evaluations, and a proximal psychosocial level comprising attitudes, static and dynamic social norms, and past fashion purchasing behavior. The model is applied for the first time to food waste fashion as a paradigmatic case of radical circular innovation in the textile sector. Hypotheses were tested via structural equation modeling on a sample of 396 Italian consumers. Purchase intention was directly predicted by attitudes, static and dynamic norms, and general fashion purchasing, whereas sustainable fashion purchasing showed no effect. Among product attributes, only sustainability information influenced both attitudes and intentions. Perfectionism and hedonism were positively associated with intention through sustainability information, while impulsivity and habit were negatively associated with intention. Sociodemographics influenced intention only indirectly, via cognitive and normative mechanisms. These findings reveal complex pathways linking psychological profiles and perceived product attributes to circular fashion adoption, with implications for communication strategies emphasizing sustainability information and targeting heterogeneous consumer motivations. Full article

One of the challenges to sustainability is the management of textile waste. Effective technologies for recycling this type of waste are still lacking. Currently, textile waste is most often landfilled or incinerated. Pyrolysis offers a more advantageous solution, as it enables partial recovery of raw materials along with energy recovery from the remaining mass, thereby aligning with the circular economy. The kinetics of volatile matter release play an important role in the pyrolysis and combustion of solid substances. This paper presents research related to this issue. The study concerns three waste textile materials (cotton, silk, and polyamide) and the following process parameters: temperatures from 400 to 800 °C and time from 0 to 900 s. The results of the study are characteristics, i.e., functions describing the kinetics of volatile matter release as a function of process parameters. The general forms of these functions were determined taking into account fundamental physical and chemical laws. In addition to process parameters, the functions include coefficients whose values were determined on the basis of experimental measurements. The characteristics were determined for isothermal processes as well as for generalized processes, additionally accounting for temperature variability, which represents an original contribution of this study. Kinetic coefficients were derived from the obtained characteristics. The studies revealed mass fractions of volatile matter exceeding even 90%. The obtained characteristics may serve as tools for improving the sustainable management of textile waste by enabling more rational control of thermal processes. Full article

Because the environmental pollution arising from microplastics and carbon emissions continues to intensify, biodegradable alginate fibers have become green candidates to relieve the environmental crisis. However, the facile fabrication of alginate fibers with excellent mechanical strength and specific functionalities remains challenging. This study incorporates titanium dioxide (TiO₂) nanoparticles into pre-crosslinked sodium alginate (SA) spinning solutions to fabricate multifunctional alginate composite fibers by a one-step wet-spinning strategy. Due to the pre-crosslinking of calcium ions (Ca²⁺), the spinning solution shows favorable rheological performance for wet spinning, ensuring the continuous fabrication of the fibers. By optimizing the TiO₂ content, SA/TiO₂ composite fibers exhibit oriented and uniform morphology, as well as enhanced mechanical performance (breaking stress of 400 MPa and Young’s modulus of 17.2 GPa). The incorporation of TiO₂ also endows the fibers with excellent formaldehyde degradation and quick self-extinguished capacity, expanding their applications in formaldehyde-removal and flame-retardant textiles. Full article