Search Results (273)

UNS S41003 is a low-cost, low-carbon ferritic stainless steel that exhibits moderate corrosion resistance but limited mechanical performance. This study evaluates the electrochemical behavior of untreated and thermomechanically treated UNS S41003 samples. Corrosion tests were conducted in acidic electrolytes with varying pH to simulate aggressive environments relevant to industrial and structural applications where exposure to acidic media and corrosive pollutants occurs. Potentiodynamic polarization curves for all samples displayed passive regions typically associated with protective oxide film formation; however, localized pitting corrosion was detected post-test. Electrochemical impedance spectroscopy indicated a marked decrease in corrosion resistance as pH decreased. The corrosion resistance of the treated alloy remained comparable to that of the untreated condition, indicating that thermomechanical processing did not detrimentally affect passivity or corrosion performance under the tested conditions. The literature suggests that the applied treatment enhances mechanical properties, supporting the potential use of this alloy in structural components subjected to acidic environments requiring a balance of mechanical strength and corrosion resistance. Full article

The problem of protecting 7075 Al alloy trekking poles from corrosion in complex outdoor environments was addressed using a composite conversion coating system. This system comprised Na₂MoO₄, NaF, CoSO₄·7H₂O, ethylenediaminetetraacetic acid-2Na, and H₂(TiF₆). The influences of this system on the properties of the coating layer were systematically studied by adjusting the pH of the coating solution. The conversion temperature and pH were the pivotal parameters influencing the formation of the conversion coating. The pH substantially influenced the compactness of the coating layer, acting as a regulatory agent of the coating kinetics. When the conversion temperature and pH were set to 40 °C and 3.8, respectively, the prepared coating layer displayed optimal performance in terms of compactness and protective properties. Therefore, this parameter combination favours the synthesis of high-performance conversion coatings. Microscopy confirmed the formation of a continuous, dense composite oxide film structure under these conditions, effectively blocking erosion in corrosive media. Furthermore, the optimised process led to substantial enhancements in the environmental adaptabilities and service lives of the components of trekking poles, thus establishing a theoretical foundation and technical reference for use in the surface protection of outdoor equipment. Full article

A fungal strain with comparably high chitosan yield was isolated from the Shivaganga hills and identified as Aspergillus versicolor AD07 through molecular characterization. Later, the strain was cultivated on Sabouraud Dextrose Broth (SDB) and wild jackfruit-based media to evaluate its potential for chitosan production. Among the various media formulations, the highest chitosan yield (178.40 ± 1.76 mg/L) was obtained from the jackfruit extract medium with added peptone and dextrose. The extracted chitosan was characterized through FTIR, XRD (reported a crystallinity index of 55%), TGA/DTG, and DSC analysis, confirming the presence of key functional groups and high thermal resistance. The extracted chitosan was fabricated into a sheet incorporated with 1% lemongrass oil; the sheet exhibited strong antibacterial activity against Escherichia coli (30 mm) and Bacillus megaterium (48 mm). The biodegradation studies reported a weight loss of 38.93 ± 0.51% after 50 days of soil burial. Further, the chitosan film was tested as a packaging material for paneer, demonstrating better preservation by maintaining nutritional quality and reducing microbial load over a 14-day storage period. These findings highlight the potential of A. versicolor AD07-derived chitosan, cultivated on a waste substrate medium, as a sustainable biopolymer for food packaging applications. Full article

In high-pressure thermal power systems, corrosion-induced wall thinning in steam pipelines poses a significant threat to operational safety and efficiency. This study investigates the effects of gas–liquid two-phase flow on corrosion-induced wall thinning in pipe bends of high-pressure heaters in power plants, with particular emphasis on the mechanisms of void fraction and inner wall surface roughness. Research reveals that an increased void fraction significantly enhances flow turbulence and centrifugal effects, resulting in elevated pressure and Discrete Phase Model (DPM) concentration at the bend, thereby intensifying erosion phenomena. Simultaneously, the turbulence generated by bubble collapse at the bend promotes the accumulation and detachment of corrosion products, maintaining a cyclic process of erosion and corrosion that accelerates wall thinning. Furthermore, the increased surface roughness of the inner bend wall exacerbates the corrosion process. The rough surface alters local flow characteristics, leading to changes in pressure distribution and DPM concentration accumulation points, subsequently accelerating corrosion progression. Energy-Dispersive Spectroscopy (EDS) and Scanning Electron Microscopy (SEM) analyses reveal changes in the chemical composition and microstructural characteristics of corrosion products. The results indicate that the porous structure of oxide films fails to effectively protect against corrosive media, while bubble impact forces damage the oxide films, exposing fresh metal surfaces and further accelerating the corrosion process. Comprehensive analysis demonstrates that the interaction between void fraction and surface roughness significantly intensifies wall thinning, particularly under conditions of high void fraction and high roughness, where pressure and DPM concentration at the bend may reach extreme values, further increasing corrosion risk. Therefore, optimization of void fraction and surface roughness, along with the application of corrosion-resistant materials and surface treatment technologies, should be considered in pipeline design and operation to mitigate corrosion risks. Full article

This paper explores how sound design in the Harry Potter film series shapes the symbolic significance of written words within the magical world. Sound mediates between language and meaning; while characters gain knowledge by reading and seeing, viewers are guided emotionally and thematically by how these written texts are framed through sound. For example, Harry’s magical identity is signalled to viewers through the score long before he fully understands himself—first through music when he speaks to a snake, then more explicitly when he receives his letter from Hogwarts. Throughout the series, characters engage with a wide array of written media—textbooks, letters, newspapers, diaries, maps, and inscriptions—that gradually shift in narrative function, from static props to dynamic, multi-sensory agents of transformation. Using a close analysis of selected scenes to examine layers of utterances, diegetic sounds, underscore, and sound design, this study draws on metaphor theory and adaptation theory to examine how sound design gives writing a metaphorical voice, sometimes framing it as character, landscape, or moral authority. As the series progresses, becoming more autonomous from the literary source, written words take on greater symbolic significance, and sound increasingly determines which texts are granted narrative power, whose voices are trusted, and how viewers interpret truth and agency across media. Ultimately, written words in the films are animated through sound into agents of growth, memory, resistance, and transformation. Thus, the audio-visual treatment of written magic reveals not just what is written, but what matters. Full article

Meme studies that evaluate specific media characters are growing in popularity, and with the twenty-fifth anniversary of The Mummy (1999) in 2024, the scholarly gap involving memes related to The Mummy narratives became apparent. This article, therefore, focuses on memes depicting the character of Evelyn “Evie” Carnahan, who has been played by Rachel Weisz and Maria Bello. Through the analysis, which takes librarianship and gender perspectives due to Evie’s character, four meme categories emerge: (1) general librarian stereotypes, (2) the ‘dangerous/harmful book’ trope, (3) gender issues, and (4) the choosing of the ’real’ (better) Evie. This study finds that the professional and personal issues experienced by Evie in the films—and in the memes—are the same ones that remain problematic for women, librarians, and female librarians in the contemporary world. Moreover, rather than trying to choose between Evies, it is more useful to interpret Weisz’s and Bello’s renderings as critical parts of a whole—a complete woman, librarian, scholar, and adventurer—especially since both iterations of the character face stereotypes involving gender, maternal status, and career aspects. Full article

Many studies have examined the ability of polymer-based gels or hydrogels to serve various purposes, particularly as absorbents. Several studies have reported that polyvinyl alcohol (PVA), with specific compositions and additives, is an absorbent and a decontamination material usable for heavy metals and radioactive substances. PVA has a high cost and is slowly degradable under anaerobic conditions. This study investigated the potential of natural materials, namely cassava starch, which is an environmentally friendly, non-toxic, and readily available gel-forming polymer that, notably, is inexpensive in Indonesia. The FTIR analysis showed a bond and polymer formation between cassava starch and glycerol. The cassava starch–glycerol–water mixture was applied to media such as glass, aluminum plates, and ceramics contaminated with heavy-metal stable ions which correspond to a radionuclide. The media, stored at room temperature for 24 h, becomes a film. According to the SEM and XRF results, the gel becomes a film that binds and absorbs metals when dried. The SEM results showed the presence of metals corresponding with the sources of contamination, and the XRF results showed that the quantity of metals absorbed was large. The cassava starch gel absorption results indicated the formation of an amorphous compound, as indicated by the XRF results. Based on all the analyses, the cassava starch–glycerol gel has enormous potential. It is almost equivalent to a PVA gel as an absorbent material and heavy-metal decontamination material, when used for radioactive decontamination on the material’s surface. Full article

The electric field enhancement effect induced by localized surface plasmon resonance (LSPR) plays a critical role in imaging and sensing applications. In particular, nanocube structures with narrow gaps provide large hotspot areas, making them highly promising for high-sensitivity applications. This study predicts the electric field enhancement effect of structures combining silver nanocubes and a 10 nm thick silver thin film using the finite-difference time-domain (FDTD) method. We demonstrate that the interaction between the silver nanocubes and silver thin film allows control over sharp LSPR peaks in the visible wavelength range. Specifically, the structure with a spacer layer between the silver nanocubes and the silver thin film is suitable for multimodal imaging, while the direct contact structure of the silver nanocubes and the silver thin film shows potential as a highly sensitive refractive index sensor. The 10 nm thick silver thin film enables backside illumination due to its transparency in the visible wavelength region, making it compatible with inverted microscopes and allowing for versatile applications, such as living cell imaging and observations in liquid media. These structures are particularly expected to contribute to advancements in bioimaging and biosensing. Full article

SiAlCN coatings were first obtained by the method of reactive evaporation of aluminum and plasma chemical activation of an organosilicon precursor in a hollow cathode arc discharge. The spectrum of discharge plasma was studied by optical emission spectroscopy under conditions of evaporation of Al in an Ar+N₂+hexamethyldisilazane vapor/gas medium, and it was shown that in the presence of a metal component in the plasma, not only did intensive activation of various components of the media occur but also an increased ionic effect on the surface of the coating was provided, with a deposition rate of up to 10.1 µm/h. The films had a dense and homogeneous structure and had a hardness of up to 31 GPa and good adhesion on stainless steel. The results of SEM, FTIR, and XRD showed that their structure was a nanocomposite consisting of an amorphous matrix based on SiCN and AlN with inclusions of AlCN nanocrystals. Full article

The migration and driving factors of microplastics (MPs), as an emerging pollutant, have been reported in plateau lakes. However, whether MPs can accumulate to an extreme degree in the local aquatic organisms of plateau lakes remains unclear. Therefore, the present study mainly aims to investigate the MPs accumulated in tissues of grass carp as well as reveal their migration processes and driving factors in the Caohai watershed, a typical plateau lake in southwest China. Density flotation (saturated NaCl solution) and laser direct infrared imaging spectrometry were used to analyze the relative abundance and morphological characteristics of MPs, respectively. The results showed that the MPs’ abundance in soil, water, and sediments ranged from 1.20 × 10³ to 1.87 × 10⁴ n/kg, from 9 to 223 n/L, and from 5.00 × 10² to 1.02 × 10⁴ n/kg, respectively. The contents and composition of MPs in forestland soils were more plentiful in comparison with cultivated land soils and marshy grassland soils. Polyethylene (PE), polyvinylchloride (PVC), PA from caprolactam (PA6), and PA from hexamethylene diamine and adipic acid (PA66) were detected in grass carp, and PE was detected in all organs of grass carp. MP concentrations in the stomach, intestines, tissue, skin, and gills of grass carp ranged from 54.94 to 178.59 mg/kg. MP pollution probably mainly originated from anthropogenic factors (road traffic, farming activities, the habits of residents scattered around the study area, etc.) due to the Caohai watershed’s considerable proximity to Weining city. In addition, wind, land runoff, rivers, and atmospheric deposition in the locality directly and indirectly promoted MP migration. Our results suggested that although there is moderate MP pollution in soil, water, sediment, and grass carp in comparison with other areas, it is necessary to pay attention to PE and PVC migration via the various environmental media and the risks associated with consuming the local grass carp. The local government can make several policies to reuse and recycle agricultural film to alleviate local PE and PVC pollution. Full article

This article examines the audiovisual representation of violence during the armed takeover of the Ecuadorian television channel TC Television on 9 January 2024, an unprecedented event in the country’s recent media history. Employing a film analysis methodology, the study deconstructs the live broadcast by segmenting it into visual sequences and analyzing elements such as narrative content, shot composition, camera movement, sound design, and editing techniques. The interpretive phase includes narratological, iconic, and psychoanalytic readings. From a psychoanalytic perspective, the study explores the emotional impact of the broadcast on viewers, focusing on responses such as fear, anxiety, identification, projection, and the activation of psychological defense mechanisms. It also reflects on the broader sociocultural consequences of such representations of violence in public media. The article concludes by emphasizing the need for public investment in inclusive and high-quality education as a structural response to youth vulnerability, school dropout, and the risk of recruitment by organized criminal groups in Ecuador. Full article

Laparoscopic lens fogging and contamination pose significant challenges, leading to a reduced surgical field of view. Intraoperative cleaning to address these issues extends the surgical duration and elevates the risk of surgical site infections. The authors propose that a hydrophilic diamond-like carbon (DLC) coating would effectively mitigate fogging and fouling, thereby eliminating the requirement for intraoperative cleaning, while the scratch-resistant nature of DLC would provide additional benefits. The present study investigates the efficacy of aluminum oxide (Al₂O₃) as a dopant in diamond-like carbon (DLC) films for antifogging applications. The authors hypothesized that adding oxygen to the DLC matrix would increase surface energy by increased hydrogen bonding, resulting in a highly hydrophilic coating. Varying dopant concentrations were tested to observe their effects on hydrophilicity, transparency, biocompatibility, and wear properties. The doped films displayed a notable improvement in transparency throughout the visible spectrum. Plasma-cleaned samples demonstrated a substantial reduction in contact angles, achieving values less than 8°. The biocompatibility of these films was analyzed with CellTiter-Glo assays; the films demonstrated statistically similar levels of cell viability when compared to the control media. The absence of adenosine triphosphate released by blood platelets in contact with the DLC coatings suggests in vivo hemocompatibility. These films, characterized by high transparency, biocompatibility, and biostability, could be valuable for biomedical applications necessitating transparent coatings. Full article

This study investigates the extraction, isolation, and chemical modification of cellulose from coffee ground residues using TEMPO-NaBr-NaClO oxidation. These residues represent a promising renewable source of cellulose, which is obtained after the removal of impurities such as lignin (24%), hemicellulose (42%), and other compounds. The TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl radical)-catalyzed oxidation selectively converts primary hydroxyl groups into carboxylate groups (-COOH) under mild conditions in aqueous media, achieving an oxidation yield of up to 67%. Structural and morphological analyses, including scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD), confirm the successful chemical modification of the cellulose. The results indicate a reduction in crystallinity index from native cellulose (80%) to oxidized cellulose (65%), reflecting partial disruption of the microfibril structure and the introduction of new chemical functionalities. FTIR analysis reveals the appearance of characteristic carboxylate bands, confirming the conversion of hydroxyl groups into carboxyl groups. Energy-dispersive X-ray (EDX) analysis further highlights a significant increase in oxygen content, indicating the efficiency of the oxidation process. The TEMPO-oxidized cellulose is water-soluble, enabling the production of valuable polyelectrolytes and intermediates. These chemical modifications improve the cellulose’s reactivity, broadening its potential applications in various fields, including biocomposites, sustainable packaging materials, and functional films. This work demonstrates the feasibility of utilizing coffee ground residues as a renewable, eco-friendly source of modified cellulose for high-value applications. Full article

When access to natural speech is limited or challenging, as is the case for people with complex communication needs, self-created digital film can be practical to use as one of the resources within a multimodal conversation about a personal experience. The detailed and contextual information such audiovisual media offers with today’s available technology may assist the utility of other communication modes, such as (computerized) spoken, written or signed language, to foster mutual understanding and story growth. To promote the use of self-created film, here named a personal-video-scene (PVS), in the practice of augmentative and alternative communication (AAC), a greater understanding is required of how such media can operate as a resource within social interactions, such as daily conversations. This study therefore introduces a multimodal coding model developed to study the employment of a PVS within a film-elicited conversational narrative, relating to four aspects of conversational control: (a) topic development, (b) conversational structure, (c) conversational repair and (d) conversational maintenance. A case study illustrates how the use of a PVS in story-sharing was instrumental in establishing common ground between narrators, boosting the frequency of comments and questions, mitigating instances of conversational repair and expanding topic development. Full article

Bacterial cellulose (BC) is a versatile biopolymer prized for its remarkable water absorption, nanoscale fiber architecture, mechanical robustness, and biocompatibility, making it suitable for diverse applications. Despite its potential, the high cost of conventional fermentation media limits BC’s scalability and wider commercial use. This study investigates an economical solution by utilizing fractions from fruit processing wastewater, refined through sequential membrane fractionation, as a supplement to commercial HS medium for BC production. BC films were thoroughly characterized using Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), X-ray diffraction (XRD), differential scanning calorimetry (DSC), and assessments of mechanical properties and water holding capacity (WHC). FTIR confirmed the BC structure, while TEM validated its nanofibrillar 3D network. XRD analysis revealed a slight increasing trend in crystallinity with the addition of wastewater fractions, and DSC revealed a slight increase in thermal stability for F#6. Adding these fractions notably improved the BC films’ tensile strength, Young’s modulus, and WHC. Overall, the results underscore that fruit processing wastewater fractions can serve as a cost-efficient, eco-friendly alternative to traditional fermentation media. This approach supports circular economy principles by lowering reliance on intensive wastewater treatments, promoting waste valorization, and advancing sustainable production methods for high-value biopolymers. Full article