Search Results (35,315)

In the 1930s and 1940s, Kumbum Monastery (Tibetan: sku’ bum byams pa gling) emerged as a significant spatial node in visual culture during the period of war and modern nation-building in the Republic of China (1912–1949). Through photography, painting, and film, a diverse range of visual media depicted the monastery’s architectural layout, inscribed plaques and steles, Cham dance (Tibetan: འཆམ་, Wylie: ’cham) rituals, lamaic prayers, and scenes of temple fairs and marketplaces. These visual representations not only documented historical detail but also constructed a composite space in which sacredness, transcendence, and secularity intersected. Due to its unique geographical location, religious doctrines, historical narratives, and political entanglements, Kumbum functioned as both a spiritual center and a politically charged symbol. Within this visual discourse, cham rituals and collective prayers were imbued with wartime ideological meanings, aligning religious transcendence with the national aspiration for resistance and victory. The inscribed plaques by state officials visually asserted political authority over sacred religious spaces, while the depiction of temple fairs foregrounded the entanglement of religious practices with everyday secular life, becoming key arenas for ethnic integration and political mobilization. Artists and photographers actively engaged with and reproduced both the symbolic and the quotidian landscapes of the monastery. These visual materials contributed to the broader project of narrating the Republic’s frontier and constructing the nation’s image. By examining how both monastic actors and external observers visually constructed Kumbum Monastery’s political and spiritual space, this study illuminates the complex interplay between religion and state power, and shows how visual media articulated ideological meanings and negotiated spatial relationships as collective responses to the site within the conditions of modernity. Full article

Microfluidic paper-based analytical devices (µPADs) are promising for point-of-care testing, yet most operate in an open-format that is susceptible to solvent evaporation and reagent contamination, causing poor signal stability under changing environments. Here, we present an equipment-free sealing strategy to construct closed µPADs by electrostatically adsorbing two polymer films onto open chips, forming an enclosed microenvironment. Using the Griess colorimetric reaction for nitrite, we benchmarked the closed-format against an open counterpart. At a standard condition, the closed µPAD produced a higher grayscale signal, reached a stable peak within 10 min, and remained stable for >60 min. It also demonstrated superior environmental robustness, yielding consistently smaller relative standard deviations (RSDs) across varying humidity levels and temperatures. With the optimized readout time, nitrite exhibited linear calibration over 2.0–10 mg/L (R² = 0.998), with a detection limit of 0.75 mg/L. In synthetic urine A, spike–recovery tests at 2.0, 5.0, and 9.0 mg/L gave acceptable recoveries and precision across temperature–humidity conditions (RSD < 10%). Additional verification in synthetic urine B at 5.0 mg/L under an uncontrolled environment further confirmed the practicality of this sealed µPAD for environment-tolerant quantitative nitrite analysis. Full article

Color results from the interaction of objects with varying wavelengths of light and the human visual system’s perception under different illumination conditions. In this study, special emphasis was placed on examining how varying illumination conditions and measurement geometries affect the color appearance and optical properties of printed effect pigments. Two distinct groups of pigments were examined: three interference pigments (M-series) based on calcium–aluminum borosilicate substrates, and three multicolor pigments (C-series) based on silicon dioxide. To ensure comparability of the results, all pigments were printed using screen printing techniques onto black PVC film. Characterization involved using a multi-angle spectrophotometer to measure CIEL*a*b* values, chroma (C*), and hue (h*) under CIE standard illuminants D50, A2, and F2 at a fixed illumination angle of 45° and aspecular angles of −15°, 15°, 25°, 45°, 75°, and 110°. Furthermore, the research methodology included the evaluation of lightness difference (∆L*), color differences (∆E*), chroma difference (∆C*), and hue difference (∆H*), with the D50 illuminant chosen as the reference and A2 and F2 as sample illuminants. The flop index (FI), as the indicator of lightness change at different scattering angles, was calculated for all printed pigments under all three standard illuminations. This multidisciplinary approach provided a deeper understanding of the relationship between pigment structure, illumination conditions, and viewing angles in our visual perception of printed pigments, which is of great importance for the development and optimization of goniochromatic materials. The results showed that while A2 and F2 illuminants have a negligible impact on lightness differences across all pigments, they induce noticeable variations in color, chroma, and hue differences, particularly at near-specular angles (−15° and 15°). Conversely, these differences become negligible at far-aspecular angles (75° and 110°). Furthermore, flop index (FI) analysis revealed that despite the larger borosilicate flakes in the M-series, the silicon dioxide-based C-series pigments exhibited the highest overall flop effect, with pigment C1 maintaining consistently high FI values under all illuminants. Full article

Substoichiometric molybdenum oxide is widely utilized as a hole transport layer (HTL) in polymer solar cells and perovskite solar cells. In this study, the possibility of developing MoOx layers applicable as HTLs with different characteristics by magnetron sputtering from a MoO₃ target and annealing in dry nitrogen or air is explored. The optical transmission and reflection, optical band gap, FTIR and Raman spectra, crystallinity, conductivity, and work function of the films are studied depending on deposition and annealing conditions. The results demonstrate that it is possible to tune the properties of the obtained films with a view toward their application in solar cells. Full article

Background: Soil mulching is a widely adopted agricultural practice known to regulate soil microclimate and enhance crop productivity; yet the biochemical mechanisms by which intact plastic and biodegradable mulch films influence soil nitrogen (N) cycling at the metabolic pathway level remain largely unexplored. Understanding these nitrogen transformation pathways is critical for assessing the long-term impacts of mulching materials on soil microbial communities, soil health, and sustainable agricultural management. This study focuses on the biochemical effects of intact mulch film application on soil N metabolism. Methods: N cycle-related soil metabolites were profiled using GC‒MS/MS and MALDI TOF/TOF MS and then integrated with multivariate statistical modelling and pathway-level metabolic network perturbation analysis to compare conventional plastic and biodegradable plastic mulch film application against unmulched controls. Results: A panel of 62 KEGG-annotated N-cycle metabolites was profiled, and material-dependent metabolome separation was confirmed by OPLS-DA (R²Y 0.893–0.956; Q² 0.546–0.786). Both mulching materials significantly perturbed soil N-metabolite pools but differed in terms of pathway identity, magnitude, and directionality. Conventional plastic mulching caused the greatest disruption—near-complete suppression of N-storage and stress-adaptation pools (NES of −1.16; impact score of 10.01) and severe impairment of aspartate-centred metabolism—with L-aspartate identified as a critical stoichiometric hub. Biodegradable mulching material imposed a distinct profile dominated by inhibition of branched-chain amino acid catabolism and lysine degradation, with L-pipecolate as a treatment-specific critical impact node. Conclusions: These findings support that mulching material choice is a primary determinant of soil N-cycling biochemistry. The observed metabolite-level perturbations are suggestive of potential consequences for nitrogen retention. Though this inference is based on metabolite pool size differences and network topology metrics rather than directly measured process rates, it should therefore be interpreted with appropriate caution. Full article

Neutral salt spray tests were conducted on assemblies comprising H59 brass and either electrogalvanized or hot-dip galvanized bolts. The polarization curves, electrochemical impedance spectroscopy (EIS), corrosion morphology, elemental distribution, and corrosion product composition of the H59 brass were systematically characterized. The results demonstrated that upon coupling with galvanized bolts, the formation of a protective Cu₂O film on the H59 brass is significantly weakened, leading to accelerated corrosion. After coupling with electrogalvanized bolts, the i_corr reached a maximum value of 0.21 mA/cm². A corrosion layer predominantly composed of ZnO formed on the sample surface with a thickness of approximately 13 μm, and no penetration or enrichment of Cl was observed in the matrix. More seriously, when the brass was assembled with hot-dip galvanized bolts, the i_corr never dropped below 0.2 mA/cm². A porous and complex Zn-Cu-O-Cl mixed corrosion layer developed on its surface. This loose structure allows Cl⁻ to reach a depth of 55 μm into the matrix and continue causing corrosion. The mechanisms underlying the different corrosion behaviors of H59 brass caused by different galvanizing bolt processes require further investigation. Full article

Single-use plastic residues persist in agricultural and peri-urban soils of the Ecuadorian Andes. Regionally sourced starch-based films are a plausible local replacement for short-lifetime petroleum plastics, yet field-relevant degradation data for tropical high-altitude soils remain scarce. This study evaluated the soil biodegradability of bioplastic films produced from Colocasia esculenta (malanga blanca) and Manihot esculenta (yuca) across three contrasting soils from Chimborazo, Ecuador (ESPOCH, San Andrés and Río Chimborazo; 2825–3249 m a.s.l.) as a function of their physicochemical properties and bibliographically inferred microbial context. The films were prepared by citric acid starch extraction, glycerol plasticization and carboxymethylcellulose reinforcement; the gravimetric weight loss was tracked on days 0, 11, 18, 27, 40 and 47 on n = 20–21 film replicates per soil × feedstock combination, with the soils characterized by their pH, electrical conductivity and organic matter. After 47 days, the malanga films reached 42.3 ± 13.6%, 22.9 ± 10.7% and 54.1 ± 19.3% mean (±standard deviation, SD) weight loss in the ESPOCH, San Andrés and Río Chimborazo soils, respectively; the yuca films reached 24.4 ± 6.5%, 21.1 ± 6.8% and 49.4 ± 18.7%. The between-soil differences were statistically significant at 47 days according to the analysis of variance (ANOVA) (malanga: F = 22.17, p < 0.001; yuca: F = 34.08, p < 0.001; Tukey’s Honestly Significant Difference (HSD)), with the results corroborated by the Kruskal–Wallis method (H = 29.16 and 37.05; both p < 0.001), given the partial departure from normality identified by the Shapiro–Wilk test. The ordering of degradation departed from the bulk organic matter ranking, indicating that microbial community composition, rather than organic matter quantity alone, was the proximal driver. These findings extend the scarce evidence base on cassava/taro film degradation under high-Andean conditions. Full article

Residual film recovery is a crucial approach to mitigating agricultural “white pollution” and ensuring sustainable land use. Currently, the development of residual film recovery machines relies primarily on theoretical analysis and field performance tests. The lack of support from computational simulation models often leads to suboptimal mechanical performance, severely restricting the design and optimization of recovery equipment. To address this, this study proposes a method for constructing and experimentally validating a discrete element model of plow-layer residual film using EDEM software. First, field tests were conducted to measure soil compaction and residual film distribution at various depths. The ultimate tensile force of the residual film was also evaluated to provide fundamental data for model development. Using the Hertz–Mindlin with bonding contact model in EDEM, the intrinsic parameters of the residual film were selected and optimized. Combined with a Box–Behnken experimental design, a quadratic regression model relating normal stiffness per unit area, critical normal stress, and bond radius to the ultimate tensile force of the film was constructed. The optimal parameter combination was determined as follows: normal stiffness = 1.11 × 10⁶ N·m⁻³, critical normal stress = 2.45 × 10⁶ Pa, and bond radius = 0.03 mm. Under these parameters, the theoretically predicted ultimate tensile force was 1.18 N, and the simulated value yielded a relative error of only 1.69%, validating the effectiveness of the single-film model. Furthermore, using the field-measured data, a coupled film–soil model was established via the “rainfall” method to conduct simulated penetration tests. Parameter calibration was executed using the multivariate Newton–Raphson iteration method. The optimal bonding parameters for soil particles were identified as follows: normal stiffness per unit area = 9.6 × 10⁵ N/m², shear stiffness per unit area = 9.6 × 10⁵ N/m², critical normal stress = 5.38 × 10⁵ Pa, critical shear stress = 5.38 × 10⁵ Pa, and bond radius = 4.3 mm. The average simulated penetration resistance was 59.61 N, showing a relative error of 5.91% compared to the field-measured value of 56.28 N. These results demonstrate that the developed coupled film–soil DEM can be effectively applied to simulate the lifting and throwing processes of plow-layer residual film recovery machines, thereby providing vital modeling support for the design and optimization of residual film recovery mechanisms. Full article

The amniotic membrane is widely recognized in regenerative medicine due to its rich content of extracellular matrix proteins and growth factors that confer anti-inflammatory and pro-regenerative properties. However, its rapid degradation restricts its standalone clinical use. To overcome these limitations, we developed biofilms by incorporating decellularized human amniotic membrane matrix (dHAM) into polycaprolactone (PCL) and polyvinylpyrrolidone (PVP) matrices using spin-coating. Bone marrow-derived mesenchymal stem cells (BM-MSCs) were used to evaluate film biocompatibility through cell viability, proliferation, and wound healing migration assays. Surface characterization was performed using contact angle measurements, Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) spectroscopy, and scanning electron microscopy. Soluble dHAM extracts (4–6 mg/mL) significantly enhanced BM-MSC proliferation at 48 h compared to controls (p ≤ 0.01 and p ≤ 0.0001). Both PCL-dHAM and PVP-dHAM biofilms exhibited high cell viability (>90%) and improved initial adhesion. Notably, dHAM incorporation significantly increased wound closure rates at 24 h, reaching 98.47% for PCL-dHAM and 93.13% for PVP-dHAM, compared to 76.56% and 64.20% for pure polymers (p = 0.0001). All scaffolds maintained hydrophilic surfaces (<90°), favorable for cell interaction. The integration of dHAM into PCL and PVP by spin-coating produces biofilms biocompatible with enhanced regenerative potential, representing promising candidates for wound healing applications. In conclusion, these coatings support BM-MSC adhesion, proliferation, and migration, while significantly accelerating wound closure, underscoring their value as advanced bioactive coatings for regenerative medicine. Full article

Visual freshness monitoring is challenging in intelligent seafood packaging. This study developed low-acyl gellan gum (LGG)-based intelligent films incorporating anthocyanin (BRE), carboxymethyl chitosan (CMCh), and black rice starch (BRS) and evaluated their effects on film structure, physical–mechanical properties, and shrimp freshness-monitoring performance. Films prepared via solution casting were evaluated using structural, mechanical, and barrier analyses, alongside shrimp spoilage trials at 25 °C. Structural analyses revealed an integrated polysaccharide network. CMCh reinforced the matrix and increased tensile strength, whereas partially retained BRS granules introduced microstructural heterogeneity, reducing strength and increasing water vapor permeability, highlighting a trade-off between mechanical performance and moisture transport. Consequently, BRS-containing films reduced BRE release, improved pigment retention, and resulted in less intense color changes associated with total volatile basic nitrogen (TVB-N) accumulation during shrimp spoilage. Overall, these results suggest that CMCh and BRS composition-dependently modulate the structure, water vapor transport, pigment retention, and colorimetric response of LGG-based films for visual monitoring of shrimp freshness under accelerated spoilage conditions. Full article

Nickel ferrite (NiFe₂O₄) is one of the most studied inverse-spinel ferrites because it combines moderate saturation magnetization, comparatively high electrical resistivity, chemical stability, and broad synthesis flexibility. Yet the literature shows that the measured structure and magnetism of NiFe₂O₄ are not intrinsic constants; they evolve strongly with dimensionality, size, thickness, strain state, cation distribution, surface spin disorder, and synthesis pathway. This review develops a unified theoretical and literature-based interpretation of how dimensionality reshapes the structural and magnetic behavior of NiFe₂O₄ across bulk ceramics, nanoparticles, one-dimensional nanostructures, polycrystalline thin films, and ultrathin epitaxial films. The review is anchored in the two uploaded nickel ferrite attachments and expanded using internet-sourced journal literature on spinel inversion, surface effects, mechanochemical synthesis, sputtered and pulsed laser deposited thin films, and epitaxial ultrathin-film anomalies. The central novelty of this article is the formulation of a dimensionality-dependent framework in which the observed magnetic response is governed by a competition among three coupled factors: (i) the cation-distribution function, which controls the A–B superexchange balance and therefore the net ferrimagnetic moment; (ii) the microstructural coherence function, which measures how crystallinity, strain, defects, and anti-phase boundaries preserve or degrade exchange continuity; and (iii) the surface/interface spin-order parameter, which quantifies the loss or reconfiguration of magnetic order at free surfaces and buried interfaces. Within this framework, bulk NiFe₂O₄ behaves as a near-equilibrium inverse spinel with relatively stable magnetization, whereas nanoscale NiFe₂O₄ experiences strong spin canting and finite-size suppression due to the growing fraction of disordered surface spins. Thin films introduce a distinct regime in which strain, texture, anti-phase boundaries, substrate mismatch, and growth kinetics determine both anisotropy and magnetization. In ultrathin epitaxial films, off-equilibrium cation redistribution and interface-controlled electronic reconstruction may even generate magnetization values far above bulk expectations. The review also compares major synthesis routes—solid-state reaction, sol–gel, co-precipitation, hydrothermal growth, reactive milling, combustion, pulsed laser deposition, and radio-frequency sputtering—and explains why each route biases the final dimensionality-dependent properties differently. A set of word-style equations is provided to formalize spinel inversion, finite-size suppression, anisotropy scaling, coercivity trends, and superparamagnetic crossover. Beyond summarizing the field, the review proposes a regime map linking dimensionality to characteristic structural defects and magnetic signatures, and it identifies unresolved questions concerning the true origin of enhanced magnetization in ultrathin NiFe₂O₄, the interplay between anti-phase boundaries and strain, and the distinction between intrinsic inversion changes and extrinsic substrate artifacts. The resulting article offers a submission-ready, originality-focused review that positions dimensionality as the master variable governing structure–magnetism correlations in nickel ferrite. Full article

Next-generation wastewater treatment and recycling rely on membrane-based processes, but they face a trade-off among permeability, selectivity, and fouling resistance. In the present study, thin-film nanocomposite (TFN) membranes were fabricated by incorporating a ternary TiO₂-SiO₂-biochar nanofiller into a polysulfone (PSf) support using nonsolvent-induced phase separation, after which m-phenylenediamine and trimesoyl chloride were used via interfacial polymerization to produce a selective polyamide layer. The membrane compositions were M1 (22 wt.% PSf), M2 (22 wt.% PSf/0.5 wt.% TiO₂/0.5 wt.% SiO₂/0.5 wt.% biochar), and M3 (polyamide-coated M2). FTIR, XRD, SEM, contact-angle, porosity, and mechanical analyses supported successful membrane formation and changes in morphology, wettability, and structural strength after nanofiller incorporation and TFC coating. The addition of a nanofiller increased the hydrophilicity of the membranes by decreasing the water contact angle from 98.6 ± 0.8° for pristine PSf to 35.6 ± 1.5° for the nanocomposite membrane. Consequently, the pure-water permeability increased from 21 to 37 L m⁻² h⁻¹ bar⁻¹. After polyamide layer formation, the optimized TFN membrane maintained a contact angle of 55.4 ± 3.8° and achieved a high Congo red rejection of 98% with permeate flux of 7–9 L m⁻² h⁻¹ bar⁻¹. The membrane also showed good antifouling performance, with flux recovery ratios exceeding 90%. For heavy-metal-containing solutions, the optimized membrane showed apparent removal efficiencies of 78–98% for multivalent heavy metals (Pb²⁺, Hg²⁺, Cd²⁺, Mn²⁺, Zn²⁺, Cu²⁺, Ni²⁺, Fe³⁺, As³⁺, and Cr⁶⁺). Static adsorption tests showed the order M2 > M3 > M1, confirming that exposed TiO₂-SiO₂-biochar sites contribute to pollutant uptake, while the superior filtration performance of M3 is attributed to the combined effect of the polyamide selective layer and adsorption-assisted interactions. Overall, the TiO₂-SiO₂-biochar-based TFN membrane provides a promising platform for dye removal and preliminary heavy-metal attenuation from contaminated water. Full article

Monitoring the activity of the autonomic nervous system, including the sympathetic and parasympathetic divisions, plays a crucial role in studying emotional processing. However, few methods allow the dynamic tracking of parasympathetic activity. Here, we propose a testable hypothesis that ear thermography may serve as a dynamic index of sympathetic and parasympathetic activity, with a time resolution of seconds. Anatomical and physiological evidence suggests that the vascular structures of the ear may be innervated in a region-specific manner by the autonomic nervous system, with the posterior regions (e.g., the helix) predominantly influenced by sympathetic activity and the anterior regions (e.g., the tragus) potentially affected by parasympathetic mechanisms. Recent thermographic studies during emotional film viewing have demonstrated distinct spatial and functional patterns: posterior regions showed a linear negative association between temperature and emotional arousal, consistent with sympathetic vasoconstriction, whereas anterior regions exhibited a non-linear (inverted-U-shaped) relationship, resembling the known non-monotonic characteristics of parasympathetic activity. These findings suggest that ear thermography may be used to assess sympathetic- and parasympathetic-related dynamic processes, although direct evidence remains to be established. Full article

$\mathrm{T}{\mathrm{i}}_{70}\mathrm{Z}{\mathrm{r}}_{20}\mathrm{T}{\mathrm{a}}_{10}$ alloy is a $\beta$-titanium based shape memory alloy with a high martensitic transformation temperature and large recoverable strain. It is thought to be to develop into a new generation of high-performance high-temperature shape memory alloy materials. By partially replacing the Ta element in the $\mathrm{T}{\mathrm{i}}_{70}\mathrm{Z}{\mathrm{r}}_{20}\mathrm{T}{\mathrm{a}}_{10}$ alloy with Al, Ti-Zr-Ta-Al alloys with different Al contents were prepared. In this study, isothermal oxidation tests at 900 °C were conducted on Ti-Zr-Ta-Al alloys with different Al contents to investigate the effect of Al content on the high-temperature oxidation behavior of the $\mathrm{T}{\mathrm{i}}_{70}\mathrm{Z}{\mathrm{r}}_{20}\mathrm{T}{\mathrm{a}}_{10}$ alloy. The results show that the isothermal oxidation kinetics curves of $\mathrm{T}{\mathrm{i}}_{70}\mathrm{Z}{\mathrm{r}}_{20}\mathrm{T}{\mathrm{a}}_{10-\mathrm{x}}\mathrm{A}{\mathrm{l}}_{\mathrm{x}}$ (x = 0, 0.5, 1, 3 at.%) at 900 °C all follow a parabolic law. The oxide films formed on the alloy surface are mainly composed of $\mathrm{Ti}{\mathrm{O}}_2$, $\mathrm{T}{\mathrm{a}}_2{\mathrm{O}}_5$ and $(\mathrm{Ti},\mathrm{Zr}){\mathrm{O}}_2$. However, the surface of the oxide films is relatively rough. The films are not dense and there are pores and cracks, leading to spallation during the oxidation process. After the addition of Al, the high-temperature oxidation resistance of the Ti-Zr-Ta alloy is improved. When the Al content is 1 at.%, $\mathrm{T}{\mathrm{i}}_{70}\mathrm{Z}{\mathrm{r}}_{20}\mathrm{T}{\mathrm{a}}_9\mathrm{A}{\mathrm{l}}_1$ exhibits the best high-temperature oxidation resistance. Full article

Accelerated carbonation of cement-based materials offers a promising route for CO₂ sequestration driven by waste heat co-emitted from cement and power plants; however, existing kinetic models typically describe the low-temperature gas–liquid–solid regime near 100 °C and the high-temperature gas–solid regime near 600 °C in isolation, limiting their applicability to plant-scale reactor design. This study proposes a unified dual-regime kinetic framework spanning 20–700 °C. The low-temperature branch couples Henry’s-law CO₂ solubility, a sigmoidal water-film stability function, and an Arrhenius ionic reaction term, whereas the high-temperature branch integrates shrinking-core surface reaction and product-layer diffusion with an attenuation term near the CaCO₃ decomposition onset. Seven parameters were calibrated by bounded least squares against a 51-point temperature dataset compiled from the author’s previously published carbonation experiments. The calibrated model reproduced the bimodal temperature dependence of the carbonation degree (R² = 0.62; RMSE = 0.083), with peaks near 100 °C and 640 °C, and predicted reactor volumes of order-of-magnitude 150–200 m³ for a 1 Mt/y cement plant under three waste-heat operating points. The framework bridges particle-scale kinetic and plant-scale design, and identifies mixing as the dominant operational sensitivity at the clinker-cooler condition. Full article