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15 pages, 2695 KiB  
Article
Gelling Characteristics and Mechanisms of Heat-Triggered Soy Protein Isolated Gels Incorporating Curdlan with Different Helical Conformations
by Pei-Wen Long, Shi-Yong Liu, Yi-Xin Lin, Lin-Feng Mo, Yu Wu, Long-Qing Li, Le-Yi Pan, Ming-Yu Jin and Jing-Kun Yan
Foods 2025, 14(14), 2484; https://doi.org/10.3390/foods14142484 - 16 Jul 2025
Viewed by 217
Abstract
This study investigated the effects of curdlan (CUR) with different helical conformations on the gelling behavior and mechanisms of heat-induced soy protein isolate (SPI) gels. The results demonstrated that CUR significantly improved the functional properties of SPI gels, including water-holding capacity (0.31–5.06% increase), [...] Read more.
This study investigated the effects of curdlan (CUR) with different helical conformations on the gelling behavior and mechanisms of heat-induced soy protein isolate (SPI) gels. The results demonstrated that CUR significantly improved the functional properties of SPI gels, including water-holding capacity (0.31–5.06% increase), gel strength (7.01–240.51% enhancement), textural properties, viscoelasticity, and thermal stability. The incorporation of CUR facilitated the unfolding and cross-linking of SPI molecules, leading to enhanced network formation. Notably, SPI composite gels containing CUR with an ordered triple-helix bundled structure exhibited superior gelling performance compared to other helical conformations, characterized by a more compact and uniform microstructure. This improvement was attributed to stronger hydrogen bonding interactions between the triple-helix CUR and SPI molecules. Furthermore, the entanglement of triple-helix CUR with SPI promoted the formation of a denser and more homogeneous interpenetrating polymer network. These findings indicate that triple-helix CUR is highly effective in optimizing the gelling characteristics of heat-induced SPI gels. This study provides new insights into the structure–function relationship of CUR in SPI-based gel systems, offering potential strategies for designing high-performance protein–polysaccharide composite gels. The findings establish a theoretical foundation for applications in the food industry. Full article
(This article belongs to the Special Issue Natural Polysaccharides: Structure and Health Functions)
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19 pages, 292 KiB  
Article
Twentieth-Century Changes in Catholic Liturgy and the Place of Truth in Religious Culture: A Discussion with Chantal Delsol
by Tomasz Dekert
Religions 2025, 16(7), 867; https://doi.org/10.3390/rel16070867 - 3 Jul 2025
Viewed by 602
Abstract
This article explores the transformative changes in Catholic liturgy during the twentieth century and their implications for the stability of religious meaning and cultural identity in the West. In critical dialogue with Chantal Delsol’s diagnosis of the decline of Christianitas, this study [...] Read more.
This article explores the transformative changes in Catholic liturgy during the twentieth century and their implications for the stability of religious meaning and cultural identity in the West. In critical dialogue with Chantal Delsol’s diagnosis of the decline of Christianitas, this study argues that the reform of ritual following the Second Vatican Council, rather than political entanglements, played a decisive role in weakening the public credibility of Catholic truth claims. Drawing on Roy A. Rappaport’s theory of ritual as a stabilizer of cultural meaning, the author analyzes how this postconciliar liturgical reform altered the semiotic structure of Catholic worship—shifting communication from indexical to symbolic forms and reorienting the liturgy from a vertical–concentric order to a more decentralized horizontal dynamic. The chosen method combines theoretical reflection with liturgical anthropology to assess how changes in the Roman Missal, ritual posture, and spatial arrangement disrupted the transmission of canonical messages. The conclusion suggests that this semiotic transformation undermined the liturgy’s capacity to ritually confirm the truths of faith, contributing to the broader civilizational disintegration observed by Delsol. Ultimately, this article contends that any future revitalization of Catholic culture will depend less on political influence and more on recovering the liturgy’s ritual capacity to sustain belief in transcendent truth. Full article
(This article belongs to the Section Religions and Humanities/Philosophies)
32 pages, 5287 KiB  
Article
UniHSFormer X for Hyperspectral Crop Classification with Prototype-Routed Semantic Structuring
by Zhen Du, Senhao Liu, Yao Liao, Yuanyuan Tang, Yanwen Liu, Huimin Xing, Zhijie Zhang and Donghui Zhang
Agriculture 2025, 15(13), 1427; https://doi.org/10.3390/agriculture15131427 - 2 Jul 2025
Viewed by 347
Abstract
Hyperspectral imaging (HSI) plays a pivotal role in modern agriculture by capturing fine-grained spectral signatures that support crop classification, health assessment, and land-use monitoring. However, the transition from raw spectral data to reliable semantic understanding remains challenging—particularly under fragmented planting patterns, spectral ambiguity, [...] Read more.
Hyperspectral imaging (HSI) plays a pivotal role in modern agriculture by capturing fine-grained spectral signatures that support crop classification, health assessment, and land-use monitoring. However, the transition from raw spectral data to reliable semantic understanding remains challenging—particularly under fragmented planting patterns, spectral ambiguity, and spatial heterogeneity. To address these limitations, we propose UniHSFormer-X, a unified transformer-based framework that reconstructs agricultural semantics through prototype-guided token routing and hierarchical context modeling. Unlike conventional models that treat spectral–spatial features uniformly, UniHSFormer-X dynamically modulates information flow based on class-aware affinities, enabling precise delineation of field boundaries and robust recognition of spectrally entangled crop types. Evaluated on three UAV-based benchmarks—WHU-Hi-LongKou, HanChuan, and HongHu—the model achieves up to 99.80% overall accuracy and 99.28% average accuracy, outperforming state-of-the-art CNN, ViT, and hybrid architectures across both structured and heterogeneous agricultural scenarios. Ablation studies further reveal the critical role of semantic routing and prototype projection in stabilizing model behavior, while parameter surface analysis demonstrates consistent generalization across diverse configurations. Beyond high performance, UniHSFormer-X offers a semantically interpretable architecture that adapts to the spatial logic and compositional nuance of agricultural imagery, representing a forward step toward robust and scalable crop classification. Full article
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13 pages, 820 KiB  
Article
An Efficient Algorithmic Way to Construct Boltzmann Machine Representations for Arbitrary Stabilizer Code
by Yuan-Hang Zhang, Zhian Jia, Yu-Chun Wu and Guang-Can Guo
Entropy 2025, 27(6), 627; https://doi.org/10.3390/e27060627 - 13 Jun 2025
Viewed by 406
Abstract
Restricted Boltzmann machines (RBMs) have demonstrated considerable success as variational quantum states; however, their representational power remains incompletely understood. In this work, we present an analytical proof that RBMs can exactly and efficiently represent stabilizer code states—a class of highly entangled quantum states [...] Read more.
Restricted Boltzmann machines (RBMs) have demonstrated considerable success as variational quantum states; however, their representational power remains incompletely understood. In this work, we present an analytical proof that RBMs can exactly and efficiently represent stabilizer code states—a class of highly entangled quantum states that are central to quantum error correction. Given a set of stabilizer generators, we develop an efficient algorithm to determine both the RBM architecture and the exact values of its parameters. Our findings provide new insights into the expressive power of RBMs, highlighting their capability to encode highly entangled states, and may serve as a useful tool for the classical simulation of quantum error-correcting codes. Full article
(This article belongs to the Special Issue Quantum Information and Quantum Computation)
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22 pages, 3526 KiB  
Article
Indirect Regulation of SOC by Different Land Uses in Karst Areas Through the Modulation of Soil Microbiomes and Aggregate Stability
by Haiyuan Shu, Xiaoling Liang, Lei Hou, Meiting Li, Long Zhang, Wei Zhang and Yali Song
Agriculture 2025, 15(11), 1220; https://doi.org/10.3390/agriculture15111220 - 3 Jun 2025
Viewed by 451
Abstract
Natural restoration of vegetation and plantation are effective land use measures to promote soil organic carbon (SOC) sequestration. How soil physicochemical properties, microorganisms, Glomalin-related soil proteins (GRSPs), and aggregates interact to regulate SOC accumulation and sequestration remains unclear. This study examined five land [...] Read more.
Natural restoration of vegetation and plantation are effective land use measures to promote soil organic carbon (SOC) sequestration. How soil physicochemical properties, microorganisms, Glomalin-related soil proteins (GRSPs), and aggregates interact to regulate SOC accumulation and sequestration remains unclear. This study examined five land uses in the karst region of Southwest China: corn field (CF), corn intercropped with cabbage fields (CICF), orchard (OR), plantation (PL), and natural restoration of vegetation (NRV). The results revealed that SOC, total nitrogen (TN), total phosphorus (TP), total GRSP (T-GRSP), and easily extractable GRSP (EE-GRSP) contents were significantly higher under NRV and PL than in the CF, CICF, and OR, with increases ranging from 10.69% to 266.72%. Land use significantly influenced bacterial α-diversity, though fungal α-diversity remained unaffected. The stability of soil aggregates among the five land uses followed the order: PL > NRV > CF > OR > CICF. Partial least-squares path modeling (PLS-PM) identified land use as the most critical factor influencing SOC. SOC accumulation and stability were enhanced through improved soil properties, increased microbial diversity, and greater community abundance, promoting GRSP secretion and strengthening soil aggregate stability. In particular, soil microorganisms adhere to the aggregates of soil particles through the entanglement of fine roots and microbial hyphae and their secretions (GRSPs, etc.) to maintain the stability of the aggregates, thus protecting SOC from decomposition. Natural restoration of vegetation and plantation proved more effective for soil carbon sequestration in the karst region of Southwest China compared to sloping cropland and orchards. Full article
(This article belongs to the Section Agricultural Soils)
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27 pages, 1612 KiB  
Article
Employing Quantum Entanglement for Real-Time Coordination of Distributed Electric Vehicle Charging Stations: Advancing Grid Efficiency and Stability
by Dawei Wang, Hanqi Dai, Yuan Jin, Zhuoqun Li, Shanna Luo and Xuebin Li
Energies 2025, 18(11), 2917; https://doi.org/10.3390/en18112917 - 2 Jun 2025
Viewed by 482
Abstract
The widespread deployment of electric vehicles (EVs) has introduced substantial challenges to electricity pricing, grid stability, and renewable energy integration. This paper presents the first real-time quantum-enhanced electricity pricing framework for large-scale EV charging networks, marking a significant departure from existing approaches based [...] Read more.
The widespread deployment of electric vehicles (EVs) has introduced substantial challenges to electricity pricing, grid stability, and renewable energy integration. This paper presents the first real-time quantum-enhanced electricity pricing framework for large-scale EV charging networks, marking a significant departure from existing approaches based on mixed-integer programming (MILP) and deep reinforcement learning (DRL). The proposed framework incorporates renewable intermittency, demand elasticity, and infrastructure constraints within a high-dimensional optimization model. The objective is to dynamically determine spatiotemporal electricity prices that reduce system peak load, improve renewable utilization, and minimize user charging costs. A rigorous mathematical formulation is developed, integrating over 40 system-level constraints, including power balance, transmission limits, renewable curtailment, carbon targets, voltage regulation, demand-side flexibility, social participation, and cyber-resilience. Real-time electricity prices are treated as dynamic decision variables influenced by station utilization, elasticity response curves, and the marginal cost of renewable and grid electricity. The model is solved across 96 time intervals using a quantum-classical hybrid method, with benchmark comparisons against MILP and DRL baselines. A comprehensive case study is conducted on a 500-station EV network serving 10,000 vehicles, coupled with a modified IEEE 118-bus grid and 800 MW of variable renewable energy. Historical charging data with ±12% stochastic demand variation and real-world solar/wind profiles are used to simulate realistic conditions. Results show that the proposed framework achieves a 23.4% average peak load reduction per station, a 17.9% gain in renewable utilization, and up to 30% user cost savings compared to flat-rate pricing. Network congestion is mitigated at over 90% of high-traffic stations. Pricing trajectories align low-price windows with high-renewable periods and off-peak hours, enabling synchronized load shifting and enhanced flexibility. Visual analytics using 3D surface plots and disaggregated bar charts confirm structured demand-price interactions and smooth, stable price evolution. These findings validate the potential of quantum-enhanced optimization for scalable, clean, and adaptive EV charging coordination in renewable-rich grid environments. Full article
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21 pages, 1309 KiB  
Article
Quantum-Inspired Spatio-Temporal Inference Network for Sustainable Car-Sharing Demand Prediction
by Nihad Brahimi, Huaping Zhang and Zahid Razzaq
Sustainability 2025, 17(11), 4987; https://doi.org/10.3390/su17114987 - 29 May 2025
Viewed by 491
Abstract
Accurate car-sharing demand prediction is a key factor in enhancing the operational efficiency of shared mobility systems. However, mobility data often exhibit temporal, spatial, and spatio-temporal interdependencies that pose significant challenges for conventional models. These models typically struggle to capture nonlinear and high-dimensional [...] Read more.
Accurate car-sharing demand prediction is a key factor in enhancing the operational efficiency of shared mobility systems. However, mobility data often exhibit temporal, spatial, and spatio-temporal interdependencies that pose significant challenges for conventional models. These models typically struggle to capture nonlinear and high-dimensional patterns. Existing methods struggle to model entangled relationships across these modalities and lack scalability in dynamic urban environments. This paper presents the Quantum-Inspired Spatio-Temporal Inference Network (QSTIN), an enhanced approach that builds upon our previously proposed Explainable Spatio-Temporal Inference Network (eX-STIN). QSTIN integrates a Quantum-Inspired Neural Network (QINN) into the fusion module, generating complex-valued feature representations. This enables the model to capture intricate, nonlinear dependencies across heterogeneous mobility features. Additionally, Quantum Particle Swarm Optimization (QPSO) is applied at the final prediction stage to optimize output parameters and improve convergence stability. Experimental results indicate that QSTIN consistently outperforms both conventional baseline models and the earlier eX-STIN in predictive accuracy. By enhancing demand prediction, QSTIN supports efficient vehicle allocation and planning, reducing energy use and emissions and promoting sustainable urban mobility from both environmental and economic perspectives. Full article
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16 pages, 2498 KiB  
Article
Synthesis, Characteristics, and Field Applications of High-Temperature and Salt-Resistant Polymer Gel Tackifier
by Guowei Zhou, Xin Zhang, Weijun Yan and Zhengsong Qiu
Gels 2025, 11(6), 378; https://doi.org/10.3390/gels11060378 - 22 May 2025
Viewed by 401
Abstract
To address the technical challenge of high polymer gel viscosity reducers losing viscosity at elevated temperatures and difficulty in controlling fluid loss, a polymer-based nano calcium carbonate composite high-temperature tackifier named GW-VIS was prepared using acrylamide (AM), 2-acrylamido-2-methylpropanesulfonic acid (AMPS), N-vinylpyrrolidone (NVP), and [...] Read more.
To address the technical challenge of high polymer gel viscosity reducers losing viscosity at elevated temperatures and difficulty in controlling fluid loss, a polymer-based nano calcium carbonate composite high-temperature tackifier named GW-VIS was prepared using acrylamide (AM), 2-acrylamido-2-methylpropanesulfonic acid (AMPS), N-vinylpyrrolidone (NVP), and nano calcium carbonate as raw materials through water suspension polymerization. This polymer gel can absorb water well at room temperature and has a small solubility. After a long period of high-temperature treatment, most of it can dissolve in water, increasing the viscosity of the suspension. The structure of the samples was characterized by infrared spectroscopy, thermogravimetric analysis, and scanning electron microscopy, and their performance was evaluated. Rheological tests indicated that the 0.5% water suspension had a consistency coefficient (k = 761) significantly higher than the requirement for clay-free drilling fluids (k > 200). In thermal resistance experiments, the material maintained stable viscosity at 180 °C (reduction rate of 0%), and only decreased by 14.8% at 200 °C. Salt tolerance tests found that the viscosity reduction after hot rolling at 200 °C was only 17.31% when the NaCl concentration reached saturation. Field trials in three wells in the Liaohe oilfield verified that the clay-free drilling fluid supported formation operations successfully. The study shows that the polymer gel has the potential to maintain rheological stability at high temperatures by forming a network structure through polymer chain adsorption and entanglement, with a maximum temperature resistance of up to 200 °C, providing an efficient drilling fluid for deep oil and gas well development. It is feasible to select nano calcium carbonate to participate in the research of high-temperature resistant polymer materials. Meanwhile, the combined effect of monomers with large steric hindrance and inorganic materials can enhance the product’s temperature resistance and resistance to NaCl pollution. Full article
(This article belongs to the Special Issue Gels for Oil and Gas Industry Applications (3rd Edition))
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18 pages, 7391 KiB  
Article
Deep Eutectic Solvent Assisted Mechano-Enzymatic Preparation for Reprocessable Hot-Melting Starch: A Comprehensive Analysis of Molecular Structure and Thermal Properties
by Xuan Liu, Jia Man, Yanhui Li, Liming Wang, Maocheng Ji, Sixian Peng, Junru Li, Shen Wang, Fangyi Li and Chuanwei Zhang
Polymers 2025, 17(10), 1296; https://doi.org/10.3390/polym17101296 - 9 May 2025
Viewed by 589
Abstract
Unlike the hot-melting processing of thermoplastic plastics, the processing of starch-based material relies on the addition of solvents, resulting in their low productivity, hindering large-scale industrialized production. A strategy to realize the high production efficiency of starch-based material, an environmentally friendly modification process [...] Read more.
Unlike the hot-melting processing of thermoplastic plastics, the processing of starch-based material relies on the addition of solvents, resulting in their low productivity, hindering large-scale industrialized production. A strategy to realize the high production efficiency of starch-based material, an environmentally friendly modification process without waste liquid generation, was designed to prepare a hot-melting starch (HMS) that can be repeatedly hot melted. Ball milling, enzymatic digestion, and deep eutectic solvent (DES) plasticization modification were combined to prepare the HMS. Ball milling destroyed the starch’s particles and the crystallinity, exposing the hydroxyl group, which allowed amylase to achieve enzymatic hydrolysis more easily. After enzymatic hydrolysis, the molecular chains of modified starch were shortened and the entanglement of molecular chains was reduced, which promoted the slip of molecular chains. The plasticization of DES, which promoted by the broken starch particles and the destroyed crystal structure, formed stronger hydrogen bonds and facilitated hot melting. Furthermore, due to the excellent hot-melting properties, HMS can be combined with sisal fiber and polycaprolactone (PCL) under solvent-free conditions. The tensile strength of HMS/sisal fiber/PCL was increased by 109%; meanwhile, the water contact angle was stabilized at 104°, when the blending ratio of hot-melting starch was 67.5% compared with HMS. Full article
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26 pages, 20430 KiB  
Article
Influence of Partial Disentanglement of Macromolecules on the Rheological, Thermal, and Mechanical Properties of Polypropylene–Polyethylene Blends
by Justyna Krajenta, Magdalena Lipinska and Andrzej Pawlak
Molecules 2025, 30(8), 1786; https://doi.org/10.3390/molecules30081786 - 16 Apr 2025
Viewed by 648
Abstract
The properties of compatibilized blends of polyethylene (PE) and polypropylene (PP), having reduced macromolecular entanglements, were studied. The density of PP macromolecular entanglements was controlled by prior disentangling in solution. The polymer ratio in the blend was 4:1 or 1:4. An ethylene–octene copolymer [...] Read more.
The properties of compatibilized blends of polyethylene (PE) and polypropylene (PP), having reduced macromolecular entanglements, were studied. The density of PP macromolecular entanglements was controlled by prior disentangling in solution. The polymer ratio in the blend was 4:1 or 1:4. An ethylene–octene copolymer was used as a compatibilizer. The melt blending process resulted in good dispersion of the minority component, with slightly larger inclusions when more disentangled PP was used. Rheological studies confirmed the achievement of different entanglement densities of PP macromolecules in the blends. The partial disentanglement did not affect the thermal stability of the blends. During the isothermal crystallization studies, faster growth of PP spherulites was observed in the blend with reduced entanglements, which also influenced the entire crystallization process. The recovery time of equilibrium entanglement was investigated and it turned out to be 45 min if the blend was annealed at 190 °C, which was shorter than in the analogous homopolymer. Studies of tensile properties showed that in blends with a majority share of polyethylene, the elongation at break increased with the disentanglement of the minority component, due to better bonding of the blend components and thus the reduction in microcavitation. Full article
(This article belongs to the Special Issue Macromolecular Chemistry in Europe, 2nd Edition)
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11 pages, 475 KiB  
Article
Stability of Bi-Partite Correlations in Symmetric N-Qubit States Under Deterministic Measurements
by Carlos Muñoz, Luis Roa and Andrei B. Klimov
Physics 2025, 7(2), 12; https://doi.org/10.3390/physics7020012 - 9 Apr 2025
Viewed by 583
Abstract
In this paper, we analyze the distribution of bi-partite correlations in pure symmetric N-qubit states during local deterministic measurements, which ensure the same value of the reduced purities in the outcome states. It is analytically shown that all reduced purities grow in [...] Read more.
In this paper, we analyze the distribution of bi-partite correlations in pure symmetric N-qubit states during local deterministic measurements, which ensure the same value of the reduced purities in the outcome states. It is analytically shown that all reduced purities grow in the process of deterministic measurements. This allows us to characterize the stability of bi-partite entanglement during the optimal correlation transfer under single-qubit measurements in the asymptotic limit N1. Full article
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12 pages, 1236 KiB  
Article
Protecting the Entanglement of X-Type Systems via Weak Measurement and Reversal in the Generalized Amplitude Damping Channel
by Meijiao Wang, Haojie Liu, Lianzhen Cao, Yang Yang, Xia Liu, Bing Sun and Jiaqiang Zhao
Entropy 2025, 27(4), 350; https://doi.org/10.3390/e27040350 - 27 Mar 2025
Cited by 1 | Viewed by 486
Abstract
The study of system evolution in generalized amplitude damping is of great significance in quantum information science and quantum computing. As an important quantum noise channel, the generalized amplitude damping channel can describe the general phenomenon of the energy dissipation effect in quantum [...] Read more.
The study of system evolution in generalized amplitude damping is of great significance in quantum information science and quantum computing. As an important quantum noise channel, the generalized amplitude damping channel can describe the general phenomenon of the energy dissipation effect in quantum systems at finite temperature. In this paper, we study the use of weak measurement and reversal to protect the entanglement of X-type systems in generalized amplitude damping channels, and give an experimental scheme. The results show that the closer to zero the temperature environment, the better the protection effect of weak measurement and reversal, but the lower the success rate. Therefore, when choosing an experimental environment, it is important to consider not only the temperature factor but also the probability of success. Because all quantum systems work at finite temperatures, it is hoped that the study of generalized amplitude damping channels can help design more robust quantum algorithms and protocols to improve the efficiency and stability of quantum information processing. Full article
(This article belongs to the Special Issue Quantum Entanglement—Second Edition)
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23 pages, 4612 KiB  
Article
Fuzzy C-Means and Explainable AI for Quantum Entanglement Classification and Noise Analysis
by Gabriel Marín Díaz
Mathematics 2025, 13(7), 1056; https://doi.org/10.3390/math13071056 - 24 Mar 2025
Viewed by 674
Abstract
Quantum entanglement plays a fundamental role in quantum mechanics, with applications in quantum computing. This study introduces a new approach that integrates quantum simulations, noise analysis, and fuzzy clustering to classify and evaluate the stability of quantum entangled states under noisy conditions. The [...] Read more.
Quantum entanglement plays a fundamental role in quantum mechanics, with applications in quantum computing. This study introduces a new approach that integrates quantum simulations, noise analysis, and fuzzy clustering to classify and evaluate the stability of quantum entangled states under noisy conditions. The Fuzzy C-Means clustering model (FCM) is applied to identify different categories of quantum states based on fidelity and entropy trends, allowing for a structured assessment of the impact of noise. The presented methodology follows five key phases: a simulation of the Bell state, the introduction of the noise channel (depolarization and phase damping), noise suppression using corrective operators, clustering-based state classification, and interpretability analysis using Explainable Artificial Intelligence (XAI) techniques. The results indicate that while moderate noise levels allow for partial state recovery, strong decoherence, particularly under depolarization, remains a major challenge. Rather than relying solely on noise suppression, a classification-based strategy is proposed to identify states that retain computational feasibility despite the effects of noise. This hybrid approach combining quantum-state classification with AI-based interpretability offers a new framework for assessing the resilience of quantum systems. The results have practical implications in quantum error correction, quantum cryptography, and the optimization of quantum technologies under realistic conditions. Full article
(This article belongs to the Section E1: Mathematics and Computer Science)
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17 pages, 18798 KiB  
Article
Molecular Entanglement Facilitated Improvement of Thermal Stability of Cellulose Diacetate
by Yang Liu, Yin Hu, Jianyu Chen, Zongkai Yan, Lin Zhao, Falu Zhan, Junjie Wang and Yagang Zhang
Polymers 2025, 17(7), 835; https://doi.org/10.3390/polym17070835 - 21 Mar 2025
Viewed by 567
Abstract
As a renewable and degradable biomass material, cellulose diacetate (CDA) has significant development potential and has gained widespread interest from researchers. However, its poor thermal stability at high temperatures limits its practical use in the extrusion process and restricts its applications in other [...] Read more.
As a renewable and degradable biomass material, cellulose diacetate (CDA) has significant development potential and has gained widespread interest from researchers. However, its poor thermal stability at high temperatures limits its practical use in the extrusion process and restricts its applications in other fields, such as high-heat airflow filters, battery separators and special textile materials. To enhance the thermal stability of CDA, three heat-resistance additives, i.e., polyphenylene sulfide (PPS), polycarbonate (PC) and polyimide (PI), were introduced to synthesize PPS/CDA, PC/CDA and PI/CDA composite materials through melt extrusion. The incorporation of three heat-resistant additives increased the glass transition temperature (Tg), initial melting temperature (Tmi) and final melting temperature (Tmf) of the composites, and it reduced the heat loss at 195 °C. After conducting the isothermal thermogravimetry test for 3 h at 215 °C in an air atmosphere, the weight loss of PPS/CDA, PC/CDA and PI/CDA composites was 4.6%, 4.1% and 3.7%, respectively, which was 5.1% lower than that of pure CDA. Morphology characterization tests using a 3D digital microscope and a field emission scanning electron microscope (FESEM) revealed the compatibility order with CDA as the following: PC > PPS > PI. Additionally, Fourier transform infrared spectroscopy (FT–IR) disclosed that hydrogen bonds were formed between heat-resistant additives and CDA molecules, and the carbonyl groups in CDA showed conjugation and hyperconjugation effects with the benzene rings in the additives. Therefore, the enhanced thermal stability of CDA composites can be attributed to the molecular entanglement and crosslinking between additives and CDA molecules. Full article
(This article belongs to the Special Issue Advanced Polymer Materials: Synthesis, Structure, and Properties)
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16 pages, 3928 KiB  
Article
Combined Effect of pH and Neutralizing Solution Molarity on the Rheological Properties of Chitosan Hydrogels for Biomedical Applications
by Sofia Jansen de Medeiros Alves, Matheus Araújo Santos, João Emídio da Silva Neto, Henrique Nunes da Silva, Milena C. S. Barbosa, Marcus Vinicius Lia Fook, Rômulo Feitosa Navarro and Suédina Maria de Lima Silva
Gels 2025, 11(3), 212; https://doi.org/10.3390/gels11030212 - 18 Mar 2025
Viewed by 690
Abstract
Hydrogels are promising materials for biomedical applications due to their tunable properties. Despite significant research on optimizing the mechanical and rheological properties of chitosan hydrogels, a comprehensive analysis incorporating pH and molarity of the neutralizing solution is still lacking. This study addresses this [...] Read more.
Hydrogels are promising materials for biomedical applications due to their tunable properties. Despite significant research on optimizing the mechanical and rheological properties of chitosan hydrogels, a comprehensive analysis incorporating pH and molarity of the neutralizing solution is still lacking. This study addresses this gap by evaluating how these factors influence the rheological characteristics of chitosan hydrogels. The hydrogels were prepared using an acidic blend and were neutralized with sodium hydroxide solutions. Rheological characterization demonstrated that all samples exhibited pseudoplastic behavior, with viscosity decreasing under shear stress. Hydrogels with higher pH values exhibited lower viscosity, which is attributed to the reduced protonation and weaker electrostatic repulsion between chitosan chains. In contrast, more acidic conditions resulted in increased viscosity and greater chain entanglements. NaOH concentration impacted gel stability; lower concentrations resulted in more stable gels, whereas higher concentrations increased crosslinking but compromised integrity at elevated pH. These findings provide essential insights for optimizing chitosan hydrogels with customized properties, making them highly suitable for specific biomedical applications, such as advanced 3D-printed wound dressings. Full article
(This article belongs to the Special Issue Rheological Properties and Applications of Gel-Based Materials)
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