Search Results (8)

Quantitative studies of the heat transfer mechanism of permafrost subgrades and its effect on the permafrost under the subgrade are crucial for the study of permafrost subgrade disposal measures; however, few studies have been conducted in this area. In the present work, by quantitatively analyzing the permafrost subgrade heat transfer mechanism and the variations in the underlying permafrost, the preliminary parameters of the interface heat control method—such as the application period, position, and imported cold energy quantity—are determined. The cooling effects of the ideal interface heat control method for different application schemes are analyzed. Finally, by determining the optimized temporal inhomogeneous interface energy control strategy, the required inlet velocity and artificial permafrost table for a mechanical ventilation permafrost subgrade are calculated and compared. The results show that (1) the suitable cold energy application position and period are a 0.5 m interface above the subgrade bottom and the lower thaw season, respectively, and that the imported cold energy needs to vary within the subgrade service life; (2) by adopting interface heat control measures, the maximum difference between the artificial permafrost table under the subgrade and the nearby natural ground table is only 0.097 m, and the temperature of the underlying permafrost and the area of the thawing bowl are significantly reduced; and (3) the mechanical ventilation subgrade employing the cold energy importing strategy of the interface heat control parameter also achieves a protection effect for permafrost, but as the cold air inside the ventilation pipe is gradually heated, it is necessary to amplify the inlet air speed to a certain extent for a better cooling effect. Full article

The controlled source extremely low frequency (CSELF) method bears the potential for deep resource exploitation utilizing the skywave. The “Skywave” denotes the electromagnetic wave propagating through the waveguide formed by the Earth and ionosphere. It has a considerable penetration depth into the lithosphere due to its low-frequency band. Previous research on extremely low-frequency electromagnetic fields with the coupled lithosphere, atmosphere, and planar ionosphere models ignored the effect of the Earth’s curvature. Thus, we aimed to present the exact formulas for horizontal electric dipoles (HED) in a spherical “Earth-ionosphere” model. These new formulas consider the Earth’s curvature as a multilayer medium rather than a homogeneous underground. We introduce three techniques: function combination pairs, addition and subtraction terms, and Padé approximants, to handle slow convergence in numerical calculation. In the spherical waveguide, electromagnetic fields are mutually interfered with and produce oscillations, which is different from the planar model. The influence of Earth’s curvature cannot be neglected with the increase in source–receiver distance, though it is negligible within 3000 km. Furthermore, it is worth noting that apparent resistivity ρ_θφ enters the waveguide area earlier than ρ_φθ. This method can be used as Green’s function to simulate the electromagnetic field of actual antennas and 3-D models. Full article

Olivine, one of the most abundant silicates on earth, thermodynamically captures CO₂ in relevant amounts during its dissolution. Upscaling the use of this mineral as a replacement for sand or gravel may contribute to reduce concentrations of greenhouse gasses in the atmosphere. However, the reliable quantification of weathering rates and prognoses for effects of various environmental conditions on weathering are lacking. This currently inhibits the monitoring, reporting and verification of CO₂ capture and hampers the exploitation of the carbon dioxide removal economy. A mineral dissolution model was developed, and olivine weathering rates were directly coupled to particle sizes of the ground mineral. A particle size-dependent calculation approach, based on the shrinking core model, showed faster weathering rates as compared to a single-size, monodisperse approach. This provided a better underpinning of the prediction of the overall weathering and, consequently, the sequestration rate of CO₂. Weathering of olivine releases nickel, which is incorporated in the mineral. The dissolution model was coupled to advanced biotic ligand models (BLM) for nickel in order to assess potential chronic ecotoxicological risks upon release in the environment. Predicted no-effect concentrations for nickel showed that both the release of Mg and the increase of pH following olivine weathering significantly lowers nickel ecotoxicity. Full article

Nitrogen oxides and chemi-ions are atmospheric pollutants with considerable aeronomic interest. These toxicants can react with each other, producing various ionic species and highly reactive by-products that play a crucial role in aerosol clustering and mediate several important atmospheric reactions. Understanding the chemical reactivity of these pollutants can provide essential information for controlling their excess emission into the atmosphere. Computational modeling and electronic structure studies help in predicting the structure, reactivity, and thermodynamics of transient atmospheric chemical species and can guide experimental research by providing vital mechanistic insights and data. In the present study, a computational investigation into the mechanisms of the binary associative reactions between negative ions: O₂⁻ and O₃⁻ with NO, NO₂, and N₂ was conducted using the Coupled-Cluster Singles and Doubles (CCSD) theory. Five model reactions between N₂/NO_x with O_n⁻ (n = 2, 3) were considered in this work. Our calculations revealed that reactions (2) and (5) are two sequential processes involving intermediates, and all others occur in a concerted manner by direct transitions from the reactants to the products, with no isolable intermediates proceeding via single non-planar transition states. Our study revealed that the higher activation barrier required for the formation of NO₃⁻ (2) as compared to NO₂⁻ (1) could be the reason for the excess formation of NO₂⁻ ions over NO₃⁻ ions in the atmosphere. Further, all the investigated reactions except (5) are found to be feasible at room temperature. The energy required to break N-N bonds in the N₂ molecule justifies the high barrier for (5). The results obtained from the study are in close agreement with the available experimental data. Moreover, the data from the study can be utilized for the evaluation of experiments and model predictions pertaining to NOx oxidation and molecular modeling of the gas-phase chemistry of pollutants/nucleation precursors formed in the Earth’s atmosphere and aircraft engines. Full article

High-level coupled-cluster calculations in combination with two-dimensional master equation simulations were used to study the HO₂ + CH₃O₂ reaction, which plays an important role in the oxidation of methane and hydrocarbons in the Earth’s atmosphere and low-temperature combustion. The main reaction pathways taking place on the lowest-lying triplet and singlet potential energy surfaces (PES) were characterized. Interestingly, methyl hydroperoxide (CH₃OOH), the sole product, could be produced from both the triplet and singlet PESs, with a ratio of roughly 9:1. Formaldehyde is not made as a primary product, but can be formed via secondary chemistry. The formation of methyl tetraoxide (MTO) from the singlet PES is unimportant. The calculated reaction rate coefficients were found to be practically pressure-independent for p ≤ 760 Torr and can be given by $k\left(T\right)=2.75\times {10}^{-13}\times e^{+1.75 kcal mo{l}^{-1}/RT}$ (in cm³/s), an expression useful for kinetics modeling over the range T = 200–800 K. The rate constant has a slight negative Arrhenius energy dependence of about −1.75 kcal mol^–1, falling about a factor of 30 from 200 K to 800 K. Full article

Components of Earth system models (ESMs) usually use different numerical grids because of the different environments they represent. Therefore, a coupling field sent by a source model has to be regridded to be used by a target model. The regridding has to be accurate and, in some cases, conservative, in order to ensure the consistency of the coupled model. Here, we present work done to benchmark the quality of four regridding libraries currently used in ESMs, i.e., SCRIP, YAC, ESMF and XIOS. We evaluated five regridding algorithms with four different analytical functions for different combinations of six grids used in real ocean or atmosphere models. Four analytical functions were used to define the coupling fields to be regridded. This benchmark calculated some of the metrics proposed by the CANGA project, including the mean, maximum, RMS misfit, and global conservation. The results show that, besides a few very specific cases that present anomalous values, the regridding functionality in YAC, ESMF and XIOS can be considered of high quality and do not present the specific problems observed for the conservative SCRIP remapping. The evaluation of the computing performance of those libraries is not included in the current work but is planned to be performed in the coming months. This exercise shows that benchmarking can be a great opportunity to favour interactions between users and developers of regridding libraries. Full article

The ADAM (A Surface Reflectance Database for ESA’s Earth Observation Missions) product (a climatological database coupled to its companion calculation toolkit) enables users to simulate realistic hyperspectral and directional global Earth surface reflectances (i.e., top-of-canopy/bottom-of-atmosphere) over the 240–4000 nm spectral range (at 1-nm resolution) and in any illumination/observation geometry, at 0.1° × 0.1° spatial resolution for a typical year. ADAM aims to support the preparation of optical Earth observation missions as well as the design of operational processing chains for the retrieval of atmospheric parameters by characterizing the expected surface reflectance, accounting for its anisotropy. Firstly, we describe (1) the methods used in the development of the gridded monthly ADAM climatologies (over land surfaces: monthly means of normalized reflectances derived from MODIS observations in seven spectral bands for the year 2005; over oceans: monthly means over the 1999–2009 period of chlorophyll content from SeaWiFS and of wind speed from SeaWinds), and (2) the underlying modeling approaches of ADAM toolkit to simulate the spectro-directional variations of the reflectance depending on the assigned surface type. Secondly, we evaluate ADAM simulation performances over land surfaces. A comparison against POLDER multi-spectral/multi-directional measurements for year 2008 shows reliable simulation results with root mean square differences below 0.027 and R² values above 0.9 for most of the 14 land cover IGBP classes investigated, with no significant bias identified. Only for the “Snow and ice” class is the performance lower pointing to a limitation of climatological data to represent actual snow properties. An evaluation of the modeled reflectance in the specific backscatter direction against CALIPSO data reveals that ADAM tends to overestimate (underestimate) the so-called “hot-spot” by a factor of about 1.5 (1.5 to 2) for barren (vegetated) surfaces. Full article

With improved measurement and modelling technology, variability has emerged as an essential feature in non-equilibrium processes. While traditionally, mean values and variance have been heavily used, they are not appropriate in describing extreme events where a significant deviation from mean values often occurs. Furthermore, stationary Probability Density Functions (PDFs) miss crucial information about the dynamics associated with variability. It is thus critical to go beyond a traditional approach and deal with time-dependent PDFs. Here, we consider atmospheric data from the Whole Atmosphere Community Climate Model (WACCM) and calculate time-dependent PDFs and the information length from these PDFs, which is the total number of statistically different states that a system evolves through in time. Specifically, we consider the three cases of sampling data to investigate the distribution of information (information budget) along the altitude and longitude to gain a new perspective of understanding variabilities, correlation among different variables and regions. Time-dependent PDFs are shown to be non-Gaussian in general; the information length tends to increase with the altitude albeit in a complex form; this tendency is more robust for flows/shears than temperature. Much similarity among flows and shears in the information length is also found in comparison with the temperature. This means a strong correlation among flows/shears because of their coupling through gravity waves in this particular WACCM model. We also find the increase of the information length with the latitude and interesting hemispheric asymmetry for flows/shears/temperature, with the tendency of anti-correlation (correlation) between flows/shears and temperature at high (low) latitude. These results suggest the importance of high latitude/altitude in the information budget in the Earth’s atmosphere, the spatial gradient of the information length being a useful proxy for information flow. Full article