Search Results (18)

Graphite is a critical raw material due to its pivotal role in the green transition; hence, there is a renewed interest in its exploration across Europe. The Chisone and Germanasca Valleys (Piemonte, IT) were home to significant graphite exploitation until the 20th century, owing to the widespread presence of graphite ore bodies hosted in the metasedimentary succession of the Pinerolo Unit in the Dora-Maira Massif (Western Alps). This contribution presents a renewed study on the geology, mineralogy, petrography, and geochemistry of graphite ores and their host rocks, employing OM, SEM-EDS, and BSE, μRaman, and ICP-OES/MS and INAA analyses. Mineralization occurs in two metasedimentary successions: (i) the Bourcet-type succession (meta-conglomerates and meta-sandstones intercalated with meta-siltstones/metapelites) and (ii) the Pons-type succession (meta-siltstones/metapelites intercalated with minor meta-arenites). Graphite occurs as (i) high-purity, fine-grained crystals dispersed within or concentrated in layers along the regional schistosity, or (ii) low-purity, coarse-grained crystals within shear zones. Based on crystallinity, three types of graphite were distinguished: high (Type I), intermediate (Type II), and poor (Type III) crystalline graphite, likely formed under different genetic conditions. The comparison of these findings has implications for future exploration and provides new insights into the metallogeny and geological evolution of the area. Full article

During the development of the disposal concept in a crystalline massif of the Russian Federation, a question arose regarding the selection of the most suitable types of bentonite for a buffer layer. Data on the composition, structure, surface, and adsorption properties of four promising deposits have been obtained. The correlations between genesis and specific surface area (SSA) revealed in this study indicate that bentonites of volcanogenic-sedimentary origin have lower SSA in comparison with those of sedimentary and hydrothermal origin. The main contribution to the charge of the 2:1 layer is made by isomorphic substitutions in the tetrahedral sheet, which directly affects the sorption properties of bentonites. The influence of smectite structure on adsorption properties have been described. In particular, the dependencies between the layer charge and cation exchange capacity (CEC) have been analyzed. At the same time, the research indicates that, unlike the CEC, the specific surface area of a deposit is determined by its geological history. Special attention is being paid to refining methodological approaches for deriving crystal chemical formulae of smectites, which will be needed in the future for modelling changes in bentonite over a long-term perspective. Full article

Granitoids are known to crop out on ancient seashores, but the related geological evidence remains limited. The information from the Western Caucasus sheds light on the stratigraphical distribution of coarse siliciclastic beds associated with late Carboniferous granitoids of the Dakh, Rafabgo, and Sakhray crystalline massifs. For the purposes of this study, the available information was reviewed and verified against the modern stratigraphical scales. It is established that the considered coarse sisliciclastic beds occur at five stratigraphical levels of the Triassic–Jurassic succession. A rocky seashore with granitoid exposures existed for a short time around the Sakhray and probably Rufabgo massifs at the very beginning of the Triassic. The Dakh Massif possessed such a shore twice (at least), i.e., in the Norian–Rhaetian and the Early Toarcian. However, it cannot be excluded that rocky shores persisted there for >50 Ma. Generally, the Western Caucasus provides an example of granitoid exposures on Mesozoic seashores and adds knowledge of the global distribution of rocky shores in the Triassic and Jurassic periods. Full article

Since the early Paleozoic, numerous metallogenic events produced in the Sardinian massif a singular concentration of mineral deposits of various kinds. Among them, the Variscan metallogenic peak represents a late Paleozoic phase of diffuse ore formation linked to the tectonomagmatic evolution of the Variscan chain. Two main classes of ores may primarily be attributed to this peak: (1) mesothermal orogenic-type As-Au ± W ± Sb ores, only found in E Sardinia, and (2) intrusion-related Sn-W-Mo-F and base metals-bearing ores found in the whole Sardinian Batholith, but mainly occurring in central–south Sardinia. Both deposit classes formed diachronously during the Variscan post-compressional extension. The orogenic-type ores are related to regional-scale flows of mineralizing fluids, and the intrusion-related ores occur around fertile intrusions of different granite suites. Metallogenic reconstructions suggest almost entirely crustal processes of mineralization without a significant contribution from the mantle. We summarized these processes with a holistic approach and conceptualized the Sardinian Variscan Mineral System (SVMS), a crustal-scale physical system of ore mineralization in the Sardinian basement. The SVMS required suitable metal sources in the crust and diffuse crustal reworking triggered by heat that allowed (a) the redistribution of the original metal budget of the crust in magmas by partial melting and (b) the production of metal-bearing fluids by metamorphic dehydration. Heat transfer in the Sardinian Variscan crust involved shear heating in lithospheric shear zones and the role of mantle uplift as a thermal engine in an extensional tectonic setting. Lithospheric shear zones acted as effective pathways in focusing fluid flow through a large-scale plumbing system into regional-scale structural traps for ores. Pre-Variscan metal sources of metallogenic relevance may have been (1) the magmatic arc and magmatic arc-derived materials of Ordovician age, extensively documented in E Sardinia crust, and (2) an inferred Precambrian crystalline basement lying under the Phanerozoic crustal section, whose presence has been assumed from geophysical data and from petrological and geochemical characteristics of granite suites. At shallower crustal levels, important contributions of metals may have come from pre-Variscan ore sources, such as the Pb-Zn MVT Cambrian ores of SW Sardinia or the REE-bearing Upper Ordovician paleoplacers of E Sardinia. Full article

Thermal waters from deep circulation systems are mixed with cold shallow system components during their ascent to drainage zones. In the current research, classic chemical geothermometers and geothermometric modeling using the GeoT app were employed to determine the temperatures of geothermal reservoirs in the Sudetic region. Moreover, models of primary deep components mixed with cold shallow circulation system components were used to determine their proportions, particularly water deposits. In the studied geothermal systems, the proportion of the cold component ranged from c. 46% to c. 75%. Classic cation thermometers (Na-K, Na-K-Ca) indicated a very wide temperature range and they proved rather unreliable. The reservoir temperatures estimated with silica thermometers ranged from 52 °C to 141 °C and they can be deemed more reliable. The temperatures obtained from modeling (54.5 ± 3–120 ± 4) were adopted as temperatures of waters pre-cooled conductively and then mixed with cold components. The temperatures of primary deep waters (74–225 °C) were adopted as geothermal system temperatures. Full article

Studies of leaching of vitrified simulated high-level radioactive waste (HLW) evidence that most of actinides or their simulators enter leaching water in a colloidal form. In this paper, we consider a mechanism of colloid-facilitated migration of radionuclides from an underground repository of HLW located at a depth of a few hundreds of meters in fractured crystalline rocks. The comparison between data of field and laboratory measurements showed that the bulk permeability of the rock massif in field tests is much greater than the permeability of rock samples in laboratory experiments due to an influence of a network of fractures in the rock massif. Our theoretical analysis presents evidence that this difference can take place even in a case when the network is not continuous, and the fractures are isolated with each other through a porous low-permeable matrix of the rock. Results of modelling revealed a possibility of mechanical retention of radionuclide-bearing colloid particles in the frame of rock during their underground migration. Full article

The present study focused on the petrography and geotechnics of aggregates of two sites around the city of Mongo for their use in construction. The study area is located in central Chad, in the Guéra province, at the eastern and north-western entrance to the city of Mongo. The area corresponds to a crystalline basement, and granitic massifs are abundant. Two deposits were studied: the Mongo massif, closest to the town of the same name, and the Oyo massif at the eastern exit of Mongo. The petrographic analysis showed that the studied materials are granites, light grey in color, composed of 30% quartz, 15% biotite, 20% feldspar, 30% plagioclase and 5% other minerals. From the geotechnical point of view, the materials of the Mongo site are more resistant to wear compared to those of Oyo which are less resistant. According to the results of micro-Deval and Los Angeles tests, the use of aggregates obtained from the Mongo site granites are usable in base courses for T1–T3 traffic admitting an axle of 8 to 10 tons and in surface dressings, contrary to those of Oyo, which are not favorable in road construction. Full article

In recent decades, constraining the timing of shear activity has been one of the main topics of research about the tectono-metamorphic evolution of orogenic belts. We present a review of a combined structural and geochronological approach to two major ductile regional shear zones, in two collisional orogens: the first one affecting the Variscan basement in northern Sardinia (Italy) and the External Crystalline Massifs of the Alps (East Variscan Shear Zone; EVSZ), and the second one deforming the medium- to high-grade rocks of the metamorphic core of the Himalaya (High Himalayan Discontinuity). High-resolution, texturally and chemically controlled monazite geochronology applied in separated shear zones of the Variscan belt allowed recognizing a similar timing of activity ranging between c. 340–330 and 300 Ma. This approach led to a better understanding of the evolution of the EVSZ, supporting a model where several branches were active according to a growth by linkage model. Following a similar approach, in situ U-Th-Pb analysis of monazite constrained the timing of top-to-the-S/SW shearing of a regional-scale High Himalayan Discontinuity in the Himalayan belt to between c. 28 Ma and 17 Ma. Earlier exhumation of the hanging wall was triggered by shear zone activity, whereas at the same time, the footwall was still experiencing burial with increasing P-T conditions. The timing of shearing of this shear zone fits with an in-sequence shearing tectonic model for the exhumation of the Himalayan mid-crust. Full article

Nickel weathering ores are used to produce metallic nickel, stainless steels, and nickel sulfate, the main component of batteries. The global production of nickel from weathering ores is increasing and has surpassed production from sulfide magmatic deposits. The efficiency of the mining and processing of nickel ores from weathering rocks is determined by their mineralogical composition. The weathering crust profile of the Kempirsay ultramafite massif is divided into three zones—leached (kerolitized) serpentinites, nontronites, and final hydrolysis minerals (later referred to as “ochers”). The kerolitized zone consists of a mixture of Ni-bearing talc and saponites (later referred to as “kerolite”). During the geological mapping of the Donskoye, Buranovskoye, and Shelektinskoye deposits, the products of ultramafite hypergenic transformation into disintegrated and leached serpentinites, kerolites, nontronites, and ochers were selected and studied. For this purpose, 44 rock samples were studied via X-ray diffractometric and thermal analyses, supplemented with data from chemical, microscopic, and granulometric determinations. Based on the obtained numerical parameters of the crystalline structure of the weathering products, the thermochemical values were obtained. The hypergenic transformation of the initial minerals and their subsequent transformation were traced. The trace element distribution along the profile of the serpentinite weathering ores is related to the initial material composition of the ultramafites. The accumulation of nickel in industrial concentrations is associated with the nontronite–kerolite zone. X-ray diffractometric analysis can be used as a fast and reliable method for controlling the nickel content of ores and monitoring their mineralogical composition. Full article

In the present study, we unveil the real significance of mylonitic reworking of the polymetamorphic crystalline basement in the Serre Massif of Calabria (Southern Italy). We use a multidisciplinary approach to comprehend the structural, microstructural and petrologic changes that occurred along a, so far, not much considered shear zone affecting the Variscan lower crustal rocks. It was never before studied in detail, although some late Cretaceous ages were reported for these mylonites, suggesting that this shear zone is of prime importance. Our observations reveal now that the formation of the new structural fabric within the shear zone was accompanied by changes in mineral assemblages, in a dominant compressive tectonic regime. During this tectono-metamorphic event, high-P mylonitic mineral assemblages were stabilized, consisting of chloritoid, kyanite, staurolite, garnet and paragonite, whereas plagioclase became unstable. Average peak P–T conditions of 1.26–1.1 GPa and 572–626 °C were obtained using THERMOCALC software. These data question (i) that the Serre Massif represents an undisturbed continuous section of the Variscan crust, as generally suggested in the literature, and (ii) highlight the role of (eo-)Alpine high-P tectonics in the Serre Massif, recorded within mylonite zones, where the Variscan basement was completely rejuvenated. Full article

The new results have been represented of mineralogical–geochemical and geochronological studies of rocks of the Yehe-Shigna ophiolite massif located in the Tuva-Mongolian microcontinent in the northern part of the Central Asian orogenic belt (Eastern Sayan, Southern Siberia). The Yehe-Shigna ophiolite massif is part of the Belsk-Dugda ophiolite belt. The structural position, age, and geochemical characteristics of the belt indicate its formation in the setting of the back-arc basin of the Shishkhid intraoceanic island arc, developing in the period of 810–750 million years. It is assumed that together with the same-age formations of the Oka accretion wedge and the Sarkhoi active margin, it formed on the convergent margin of the Gondwana supercontinent. Its basement is represented by the Archean-Early Precambrian crystalline rocks and carbonate cover (“Gargan Glyba”). The gold-bearing Neoproterozoic deposits with dominant gold-telluride assemblages are localization in large ophiolites thrust zones along with the frame of the “Gargan Glyba”. They are allochthonous with respect to the Late Neoproterozoic-Cambrian Tuva-Mongolian island arc of the Siberian continent. A similar type of gold deposit is probably worth looking for ophiolites thrust zones in other Precambrian Gondwana-derived microcontinents. Full article

Radioactive (radon) groundwaters are highly valued among mineral waters for their healing effects. Between 2005 and 2015, a large exploratory event for prospecting and documenting radon water springs took place in the crystalline area of Lugicum (Bohemian Massif) under Czech–Polish cooperation. For these purposes, an exploration method was developed as a combination of GIS (ArcMap 9.1–10.2) area preparation followed by field radiohydrogeochemical mapping at a scale of 1:10,000. The gamma indication method was optimized and used for the selection of water samples. A total of 2354 water sources were examined. Radon activity concentrations were measured at 660 sources found throughout the territory. Of those, 111 sources exhibited ²²²Rn activity above 1500 Bq/L and, thus, were categorized as sources of mineral radioactive waters according to Czech legislation. The highest ²²²Rn activity was found in the Michael spring near Nové Město pod Smrkem (up to 6237 Bq/L ²²²Rn). Many discovered sources with high balneological potential are significant and, therefore, are quickly becoming popular among the public. Full article

Lądek-Zdrój is situated within the tectonic unit of the Lądek-Śnieżnik metamorphic complex. Thermal water is captured by five springs and borehole L-2. These waters are characterized by TDS content in the range of 160–230 mg/L and predominance of HCO₃⁻ (15–100% meq), SO₄²⁺ (10–36% meq), and Na⁺ (57–91% meq) ions. Increased concentrations of radon, hydrogen sulfide, and fluoride ions (7–13 mg/L) determine the medicinal properties of these waters, classified as thermal waters of Na-HCO₃-(SO₄), F⁻, H₂S, Rn type, with temperatures of 18 to 30 °C and 41 to 45 °C in springs and in the L-2 borehole, respectively. At the turn of 2018 and 2019, a new borehole LZT-1 was drilled in the area of Lądek-Zdrój. It captured thermal waters with a temperature of 37.4 °C at the outflow. The water temperature at the bottom of the heated borehole reached about 59 °C. The lithology of rocks found in the recharged areas implied that the Ca²⁺ ions present in the studied waters originated from pyroxenes, amphiboles, calcite, calcium plagioclases, and fluorite. As for Na⁺ and K⁺ ions, they originate from sodium plagioclases, microcline, and orthoclase. The probable deposit temperature of waters from this borehole was estimated with the use of chemical geothermometers, as ranging from about 87 °C to 97 °C. Full article

Geological heritage sites (geosites) are subject to conservation and exploitation for science, education, and tourism. Some geosites are big and comprise diverse phenomena. Concentration of the latter in some parts of these geosites makes them disproportionate. A typical example is the Granite Gorge in SW Russia that is of recognizable tourism importance. It stretches for ~5 km and represents a deep valley of the Belaya River and Late Paleozoic granitoids of the Dakh Crystalline Massif. However, the full spectrum of unique features is much wider. Their inventory permits the establishment of geomorphological, igneous, metamorphic, sedimentary, mineralogical, paleogeographical, tectonic, economic, engineering, and hydrological and hydrogeological types of geological heritage. Spatial distribution of these types and the relevant features indicates their significant concentration near the northern entrance to the gorge and a less important concentration near the southern entrance. This is evidence of geosite disproportion. Apparently, the latter implies the need to focus geoconservation and geotourism activities on the noted loci of concentration. However, this would ’disrupt’ the geosite integrity, and, thus, management of the Granite Gorge geosite requires attention to all its parts, including those with lower heritage value. Full article

In the Hellenides Orogen, minerals of various gem quality occur in various rock types from mainly four tectono-metamorphic units, the Rhodope, Pelagonian, and the Attico-Cycladic massifs, and the Phyllites-Quartzites unit of Crete Island. In crystalline rocks, gemstones are related to both regional metamorphic-metasomatic processes (e.g., gem corundums, Mn-andalusite, thulite/clinothulite, spessartine, titanite, jadeite), and to the formation of late alpine-type fissures, such as, for example, quartz, albite, adularia and titanite. The Tertiary (and Mesozoic) magmatic-hydrothermal environments provide gem-quality sapphire, beryl, garnet, vesuvianite, epidote, fluorite, and SiO₂ varieties. The supergene oxidation zone of the Lavrion deposit hosts gem-quality smithsonite and azurite. Coloration in the studied material is either due to various chromophore trace elements present in the crystal structure, or due to inclusions of other mineral phases. Future modern exploration methods combined with gemological investigations (such as treatment and faceting of selected stones), are necessary in order to obtain a better knowledge of the gemstone potential of Greece for its possible exploitation. Full article