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22 pages, 2666 KiB  
Article
Comparative Proteomic Analysis of Flammulina filiformis Reveals Substrate-Specific Enzymatic Strategies for Lignocellulose Degradation
by Weihang Li, Jiandong Han, Hongyan Xie, Yi Sun, Feng Li, Zhiyuan Gong and Yajie Zou
Horticulturae 2025, 11(8), 912; https://doi.org/10.3390/horticulturae11080912 (registering DOI) - 4 Aug 2025
Abstract
Flammulina filiformis, one of the most delicious and commercially important mushrooms, demonstrates remarkable adaptability to diverse agricultural wastes. However, it is unclear how different substrates affect the degradation of lignocellulosic biomass and the production of lignocellulolytic enzymes in F. filiformis. In [...] Read more.
Flammulina filiformis, one of the most delicious and commercially important mushrooms, demonstrates remarkable adaptability to diverse agricultural wastes. However, it is unclear how different substrates affect the degradation of lignocellulosic biomass and the production of lignocellulolytic enzymes in F. filiformis. In this study, label-free comparative proteomic analysis of F. filiformis cultivated on sugarcane bagasse, cotton seed shells, corn cobs, and glucose substrates was conducted to identify degradation mechanism across various substrates. Label-free quantitative proteomics identified 1104 proteins. Gene Ontology and Kyoto Encyclopedia of Genes and Genomes pathway analysis of protein expression differences were predominantly enriched in energy metabolism and carbohydrate metabolic pathways. Detailed characterization of carbohydrate-active enzymes among the identified proteins revealed glucanase (GH7, A0A067NSK0) as the key enzyme. F. filiformis secreted higher levels of cellulases and hemicellulases on sugarcane bagasse substrate. In the cotton seed shells substrate, multiple cellulases functioned collaboratively, while in the corn cobs substrate, glucanase predominated among the cellulases. These findings reveal the enzymatic strategies and metabolic flexibility of F. filiformis in lignocellulose utilization, providing novel insights for metabolic engineering applications in biotechnology. The study establishes a theoretical foundation for optimizing biomass conversion and developing innovative substrates using targeted enzyme systems. Full article
(This article belongs to the Special Issue Advances in Propagation and Cultivation of Mushroom)
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18 pages, 5924 KiB  
Article
Thermal Performance of Bio-Based Materials for Sustainable Building Insulation: A Numerical Study
by Labouda Ba, Abdelkrim Trabelsi, Tien Tung Ngo, Prosper Pliya, Ikram El Abbassi and Cheikh Sidi Ethmane Kane
Fibers 2025, 13(5), 52; https://doi.org/10.3390/fib13050052 - 30 Apr 2025
Viewed by 1538
Abstract
This study investigates the thermal and energy performance of various bio-based materials, including Typha Australis, straw, banana fiber, Alfa fiber, peanut shells, and VSS (a blend of wood pulp, cotton, flax, and hemp), in comparison to conventional concrete. A combined approach integrating numerical [...] Read more.
This study investigates the thermal and energy performance of various bio-based materials, including Typha Australis, straw, banana fiber, Alfa fiber, peanut shells, and VSS (a blend of wood pulp, cotton, flax, and hemp), in comparison to conventional concrete. A combined approach integrating numerical simulations and experimental analyses was employed to ensure robust and comprehensive insights. COMSOL Multiphysics was utilized for detailed thermal modeling of wall assemblies, while TRNSYS enabled dynamic simulations to evaluate the impact of these materials on overall cooling energy demand. The results demonstrate that bio-based materials offer significantly improved thermal insulation, reducing air conditioning needs by over 30% relative to concrete, with banana fiber exhibiting the highest performance. This study underscores the need for industrial-scale optimization, supportive regulatory frameworks, and real-world implementation to promote broader adoption. Despite their strong potential, challenges remain, particularly regarding cost-effectiveness, durability, and market penetration. Ultimately, this research advocates for a transition toward more sustainable and environmentally conscious construction practices, aligning with efforts to reduce CO2 emissions and enhance building energy efficiency. Full article
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13 pages, 2441 KiB  
Article
Effect of Compound Planting Mode on Nutrient Distribution in Cotton
by Lirong He, Lei Shi, Qiaoni Gao, Guobin Liu and Chutao Liang
Plants 2025, 14(7), 1051; https://doi.org/10.3390/plants14071051 - 28 Mar 2025
Viewed by 508
Abstract
Composite planting has become one of the primary agricultural practices promoted in recent years, especially in the northwest inland cotton regions of China, where various economic trees and crops are intercropped with cotton. However, research on the microclimatic differences affecting cotton growth and [...] Read more.
Composite planting has become one of the primary agricultural practices promoted in recent years, especially in the northwest inland cotton regions of China, where various economic trees and crops are intercropped with cotton. However, research on the microclimatic differences affecting cotton growth and the nutrient allocation strategies for cotton’s key economic organs (i.e., seed, batt, and shell) in strip composite cropping systems remains limited. In this study, we examined the nutrient allocation strategies of cotton under multiple composite cropping patterns and proposed the most suitable cultivation patterns for this region in the northwest inland region of China, utilizing an allometry partitioning index and ecological stoichiometry, based on a long-term positional experiment. The results revealed that the nutrient distribution of cotton was of equal speed with the combined planting with trees, while there was an allometric distribution index of N and P between the combined planting with maize. The effect of the compound planting mode on the nutrient-use efficiency of cotton was mainly reflected in the organ differentiation stage of its reproductive growth stage. Specifically, cotton showed lower nutrient-use efficiency in reproductive organs when intercropped with low shrubs and herbaceous crops, likely due to the insufficient protective capacity of these plants for cotton. Interestingly, strip intercropping with tall trees improved cotton’s nutrient-utilization efficiency. However, it also resulted in reduced nitrogen and phosphorus content in cotton batt. Moreover, soil indicators such as available nitrogen and electrical conductivity positively influenced the nutrient uptake of cotton shells and roots, while soil phosphorus promoted the nutrient absorption of cotton seed but inhibited the nitrogen and phosphorus of cotton shell and the nitrogen of cotton batt. These findings suggest that nutrient partitioning in cotton is influenced by a variety of soil factors. According to these results, the combined planting pattern of cotton and apple trees should be considered in practice to improve cotton yield and economic benefits in the northwest inland region of China. Full article
(This article belongs to the Special Issue Effects of Conservation Tillage on Crop Cultivation and Production)
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20 pages, 6823 KiB  
Article
Biochars from Cotton Seed, Camelia Seed Shell, and Coffee Ground in Modification of Asphalt: Fundamental Properties, Rheological Performance, and Inhibition of VOC Emissions
by Xiao Zhang, Yi Zhou and Yongjie Xue
Materials 2025, 18(7), 1504; https://doi.org/10.3390/ma18071504 - 27 Mar 2025
Viewed by 439
Abstract
With the increasing requirement for asphalt modification, a new environmentally friendly asphalt modifier is needed. In this study, three varieties of biomass, cotton seed (CO), camelia seed shell (CA), and coffee ground (CG), were chosen for biochar preparation and asphalt modification to find [...] Read more.
With the increasing requirement for asphalt modification, a new environmentally friendly asphalt modifier is needed. In this study, three varieties of biomass, cotton seed (CO), camelia seed shell (CA), and coffee ground (CG), were chosen for biochar preparation and asphalt modification to find an environmentally friendly asphalt modifier. A segregation test was applied to evaluate the storage stability of the modified asphalt. A dynamic shear rheometer (DSR) temperature sweep and frequency sweep were used to characterize the high-temperature performance. The low-temperature performance was evaluated by the bending beam rheometer (BBR) test. The DSR results indicate that the rutting factor increase for modified asphalt at high temperatures is CO ≈ CG > CA, and a high temperature could reflect the biochar’s properties better in modified asphalt. Furthermore, the low-temperature deterioration is well controlled in CO and CA biochar-modified asphalt. Finally, the volatile organic compound (VOC) emission behavior was evaluated using gas chromatography–mass spectrometry (GC-MS). Full article
(This article belongs to the Special Issue Mechanical Property Research of Advanced Asphalt-Based Materials)
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11 pages, 4265 KiB  
Communication
Application of an Electrochemical Sensor Based on Nitrogen-Doped Biochar Loaded with Ruthenium Oxide for Heavy Metal Detection
by Le Li, Yonghong Zhao, Zhengjiu Wang, Jiale Tao, Manying Yang, Chen Li, Xiaoqian Zhang, Shiguo Sun and Na Zhao
Biosensors 2025, 15(3), 160; https://doi.org/10.3390/bios15030160 - 3 Mar 2025
Viewed by 896
Abstract
Cotton is a widely cultivated cash crop and represents one of the most significant raw materials for textiles on a global scale. The rapid development of the cotton industry has resulted in the production of substantial amounts of cotton husks, which are frequently [...] Read more.
Cotton is a widely cultivated cash crop and represents one of the most significant raw materials for textiles on a global scale. The rapid development of the cotton industry has resulted in the production of substantial amounts of cotton husks, which are frequently underutilized or discarded. This study utilizes agricultural waste, specifically cotton shells, as a precursor for biochar, which is subsequently carbonized and nitrogen-doped with ruthenium oxide to synthesize an innovative composite material known as RuO2-NC. An electrochemical sensor was developed using this composite material to detect heavy metals, particularly lead and copper ions. The results demonstrate that the electrochemical sensor can accurately quantify concentrations of lead and copper ions across a wide linear range, exhibiting exceptional sensitivity. Furthermore, the sensor was tested on samples from Viola tianshanica Maxim (Violaceae) collected from the Xinjiang Uygur Autonomous Region (XUAR) in China, showing commendable accuracy and sensitivity. This approach promotes eco-friendly recycling of agricultural waste while offering advantages such as straightforward operation and reduced costs, thereby presenting promising prospects for practical applications. Full article
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18 pages, 10877 KiB  
Proceeding Paper
Development of an Operationally Efficient and Cost-Effective System for Removal of Dye from Wastewater Using Novel Adsorbent
by Niraj S. Topare, Sunita Raut-Jadhav and Anish Khan
Eng. Proc. 2024, 76(1), 102; https://doi.org/10.3390/engproc2024076102 - 19 Dec 2024
Viewed by 745
Abstract
An important contributor to environmental degradation is the industrial revolution, which has occurred in developed and developing nations. The present investigation aimed to tackle the escalating apprehensions regarding the discharge of various types of dyes from the paint, textile, and dyeing sectors. This [...] Read more.
An important contributor to environmental degradation is the industrial revolution, which has occurred in developed and developing nations. The present investigation aimed to tackle the escalating apprehensions regarding the discharge of various types of dyes from the paint, textile, and dyeing sectors. This research focuses on the adsorption performance of a newly developed system that uses cotton pod shell powder (CPSP) as a novel adsorbent to remove dye industry wastewater. The system has been designed, manufactured, and tested to be operationally efficient and cost-effective. The CPSP is a new adsorbent with desirable properties such as favorable functional groups and porosity, and analysis of its functional groups and porous nature was carried out using FTIR and SEM. The experimental data from the developed system showed that inlet dye concentration (50, 100, and 150 ppm), bed height (10, 20, and 30 cm), and flow rate (10, 15, and 20 mL/min) significantly affect the adsorption of dye industry wastewater by CPSP. Breakthrough curves were shown to be flow rate and bed depth dependent, according to the data. Significant experimentation was conducted on the developed system, and under optimized conditions. It was shown that the breakthrough point was affected by both bed height and flow rate. Evidence suggested that decreasing flow rate and concentration and raising bed height led to improved breakthrough and exhaustion times. At a concentration of 100 ppm and a flow rate of 15 mL/min, a bed depth of 20 cm was found to have the highest absorption capacity. Adam-Bohart, bed depth service time, and Yoon-Nelson models were utilized to examine the adsorption data. The results revealed that the developed system is effective, and the data obtained in this work can provide optimum operating conditions, suggesting its scalability to an industrial level for dye removal from wastewater by adsorption using CPSP as a novel adsorbent. Full article
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20 pages, 8623 KiB  
Article
Injection 3D Printing of Doubly Curved Ceramic Shells in Non-Synthetic Particle Suspensions
by Vesela Tabakova, Christina Klug and Thomas H. Schmitz
Materials 2024, 17(16), 3955; https://doi.org/10.3390/ma17163955 - 9 Aug 2024
Cited by 2 | Viewed by 1317
Abstract
This paper examines the application of non-synthetic particle suspensions as a support medium for the additive manufacturing of complex doubly curved ceramic shells with overhangs between 0° and 90° using clay paste. In this method, the build-up material is injected within a constant [...] Read more.
This paper examines the application of non-synthetic particle suspensions as a support medium for the additive manufacturing of complex doubly curved ceramic shells with overhangs between 0° and 90° using clay paste. In this method, the build-up material is injected within a constant volume of air-permeable particle suspension. As the used clay paste does not solidify right after injection, the suspension operates like a support medium and enables various print path strategies. Different non-synthetic suspension mixtures, including solid and flexible components such as quartz sand, refractory clay, various types of wood shavings, and cotton flocks, were evaluated for their ability to securely hold the injected material while allowing drying of the water-based clay body and its shrinkage. The balance between grain composition, added water, and the compressibility of the mixture during printing and drying played a pivotal role in the particle suspension design and assessment. Furthermore, the moisture absorption of the particle suspension and the structural integrity of the layer bond of the fired ceramics were also assessed. The examined additive manufacturing process not only enables the production of meso-scale doubly curved ceramic shells with average overhang of 56° but also introduces a new practice for designing specialized surfaces and constructions. Full article
(This article belongs to the Special Issue Additive Manufacturing of Ceramics and Composites)
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16 pages, 7330 KiB  
Article
The Highly Durable Antibacterial Gel-like Coatings for Textiles
by Seyedali Mirmohammadsadeghi, David Juhas, Mikhail Parker, Kristina Peranidze, Dwight Austin Van Horn, Aayushi Sharma, Dhruvi Patel, Tatyana A. Sysoeva, Vladislav Klepov and Vladimir Reukov
Gels 2024, 10(6), 398; https://doi.org/10.3390/gels10060398 - 13 Jun 2024
Cited by 6 | Viewed by 2860
Abstract
Hospital-acquired infections are considered a priority for public health systems since they pose a significant burden for society. High-touch surfaces of healthcare centers, including textiles, provide a suitable environment for pathogenic bacteria to grow, necessitating incorporating effective antibacterial agents into textiles. This paper [...] Read more.
Hospital-acquired infections are considered a priority for public health systems since they pose a significant burden for society. High-touch surfaces of healthcare centers, including textiles, provide a suitable environment for pathogenic bacteria to grow, necessitating incorporating effective antibacterial agents into textiles. This paper introduces a highly durable antibacterial gel-like solution, Silver Shell™ finish, which contains chitosan-bound silver chloride microparticles. The study investigates the coating’s environmental impact, health risks, and durability during repeated washing. The structure of the Silver Shell™ finish was studied using transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDX). The TEM images showed a core–shell structure, with chitosan forming a protective shell around groupings of silver microparticles. The field-emission scanning electron microscopy (FESEM) demonstrated the uniform deposition of Silver Shell™ on the surfaces of the fabrics. AATCC Test Method 100 was employed to quantitatively analyze the antibacterial properties of the fabrics coated with silver microparticles. Two types of bacteria, Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli), were used in this study. The antibacterial results showed that after 75 wash cycles, a 100% reduction for both S. aureus and E. coli in the coated samples using crosslinking agents was observed. The coated samples without a crosslinking agent exhibited 99.88% and 99.81% reductions for S. aureus and E. coli after 50 washing cycles. To compare the antibacterial properties toward non-pathogenic and pathogenic strains of the same species, MG1655 model E. coli strain (ATCC 29213) and a multidrug-resistant clinical isolate were used. The results showed the antibacterial efficiency of the Silver ShellTM solution (up to 99.99% reduction) coated on cotton fabric. AATCC-147 was performed to investigate the coated samples’ leaching properties and the crosslinking agent’s effects against S. aureus and E. coli. All coated samples demonstrated remarkable antibacterial efficacy, even after 75 wash cycles. The crosslinking agent facilitated durable attachment between the silver microparticles and cotton substrate, minimizing the release of particles from the fabrics. Color measurements were conducted to assess the color differences resulting from the coating process. The results indicated fixation values of 44%, 32%, and 28% following 25, 50, and 75 washing cycles, respectively. Full article
(This article belongs to the Special Issue Functional Gels Applied in Tissue Engineering)
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11 pages, 5270 KiB  
Article
Scalable Microwires through Thermal Drawing of Co-Extruded Liquid Metal and Thermoplastic Elastomer
by Pranjal Khakse, Falco Dangers, Rawan Elsersawy and Mohammad Abu Hasan Khondoker
Materials 2024, 17(11), 2770; https://doi.org/10.3390/ma17112770 - 6 Jun 2024
Cited by 2 | Viewed by 1634
Abstract
This article demonstrates scalable production of liquid metal (LM)-based microwires through the thermal drawing of extrudates. These extrudates were first co-extruded using a eutectic alloy of gallium and indium (EGaIn) as a core element and a thermoplastic elastomer, styrene–ethylene/butylene–styrene (SEBS), as a shell [...] Read more.
This article demonstrates scalable production of liquid metal (LM)-based microwires through the thermal drawing of extrudates. These extrudates were first co-extruded using a eutectic alloy of gallium and indium (EGaIn) as a core element and a thermoplastic elastomer, styrene–ethylene/butylene–styrene (SEBS), as a shell material. By varying the feed speed of the co-extruded materials and the drawing speed of the extrudate, it was possible to control the dimensions of the microwires, such as core diameter and shell thickness. How the extrusion temperature affects the dimensions of the microwire was also analyzed. The smallest microwire (core diameter: 52 ± 14 μm and shell thickness: 46 ± 10 μm) was produced from a drawing speed of 300.1 mm s−1 (the maximum attainable speed of the apparatus used), SEBS extrusion speed of 1.50 mm3 s−1, and LM injection rate of 5 × 105 μL s−1 at 190 °C extrusion temperature. The same extrusion condition without thermal drawing generated significantly large extrudates with a core diameter of 278 ± 26 μm and shell thickness of 430 ± 51 μm. The electrical properties of the microwires were also characterized under different degrees of stretching and wire kinking deformation which proved that these LM-based microwires change electrical resistance as they are deformed and fully self-heal once the load is removed. Finally, the sewability of these microwires was qualitatively tested by using a manual sewing machine to pattern microwires on a traditional cotton fabric. Full article
(This article belongs to the Special Issue Liquid Metals: From Fundamentals to Applications)
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14 pages, 3749 KiB  
Article
Thermo-Regulated Cotton: Enhanced Insulation through PVA Nanofiber-Coated PCM Microcapsules
by Dilara Dirlik-Uysal, David Mínguez-García, Eva Bou-Belda, Jaime Gisbert-Payá and Marilés Bonet-Aracil
Appl. Sci. 2024, 14(11), 4725; https://doi.org/10.3390/app14114725 - 30 May 2024
Cited by 3 | Viewed by 1759
Abstract
The innovative integration of phase change materials (PCMs) into textiles through microencapsulation presents a transformative approach to developing thermally regulated fabrics. This study explores the synthesis and characterization of microcapsules containing a coconut oil core and an ethylcellulose shell, and their application on [...] Read more.
The innovative integration of phase change materials (PCMs) into textiles through microencapsulation presents a transformative approach to developing thermally regulated fabrics. This study explores the synthesis and characterization of microcapsules containing a coconut oil core and an ethylcellulose shell, and their application on cotton fabrics coated with polyvinyl alcohol (PVA) nanofibers. The dual-layer system involving microcapsules and nanofibers is designed to enhance the thermal insulation properties of textiles by regulating heat through the absorption and release of thermal energy. The microencapsulation of PCMs allows for the effective incorporation of these materials into textiles without altering the fabric’s inherent properties. In this study, the coconut oil serves as the PCM, known for its suitable phase change temperature range, while ethylcellulose provides a robust shell, enhancing the microcapsules’ structural integrity. The application of a PVA nanofibers layer not only strengthens the thermal regulation properties but also protects the microcapsules from release while the fabric is manipulated, thereby prolonging the functional life of the fabric. Comprehensive testing, including scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR), confirms the successful application and durability of the microcapsules on the textiles. Thermal imaging studies demonstrate the fabric’s enhanced capability to maintain a consistent temperature, highlighting the potential of this technology in applications ranging from smart clothing to energy-efficient building materials or automotive isolation. The integration of PCMs in textiles via microencapsulation and nanofiber technology marks a significant advancement in textile engineering, offering new opportunities for the development of smart and sustainable materials. The study demonstrates the promising potential of integrating PCMs into textiles using microencapsulation and nanofiber technologies. Despite the initially modest insulation improvements, the methodology provides a robust foundation for further research and development. Full article
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32 pages, 6042 KiB  
Review
A Comprehensive Review of Nanotechnology Applications in Oil and Gas Well Drilling Operations
by Alhaitham M. Alkalbani and Girma T. Chala
Energies 2024, 17(4), 798; https://doi.org/10.3390/en17040798 - 7 Feb 2024
Cited by 28 | Viewed by 8924
Abstract
The field of nanotechnology has shown promise in addressing major problems and improving drilling effectiveness. An overview of the difficulties encountered during oil and gas well drilling operations and the demand for creative solutions opens the debate. This review explores how nanotechnology is [...] Read more.
The field of nanotechnology has shown promise in addressing major problems and improving drilling effectiveness. An overview of the difficulties encountered during oil and gas well drilling operations and the demand for creative solutions opens the debate. This review explores how nanotechnology is transforming the oil industry and enhancing performance as a whole. The evaluation of the uses of nanotechnology for better oil recovery, real-time monitoring, innovative materials, drilling fluids, and reservoir characterization are extensively discussed in this review. The primary function of additives is to improve the fundamental characteristics of drilling fluids. The variety of fluid additives available is a reflection of the complex drilling–fluid systems that are currently being used to enable drilling in increasingly difficult subsurface conditions. Common additives used in water- and oil-based drilling fluids include lubrication, shale stability, filtration control, rheology control, viscosification, and pH regulation. Drilling fluids frequently contain filtration control additives such as starch, polyanionic cellulose (PAC), carboxymethyl cellulose (CMC), and nanoparticles (NP). Commonly used rheology-modifier additives are xanthan gum, carboxymethyl cellulose, guar gum powder, and, more recently, salt-responsive zwitterionic polymers that were used as viscosifiers to water-based drilling fluids. The three main additives that regulate pH are citric acid monohydrate, potassium hydroxide, and sodium hydroxide. Additives that stabilize shale, such as potassium and sodium salts and asphaltenes, are often used. A wide range of materials are included in the category of lubricating additives, including polymers, asphaltenes, glass beads, oils of various grades, and oil-surfactants. Various fibrous materials, including wood, cotton, fibrous minerals, shredded tires from vehicles, and paper pulp, are used as additives to control circulation. Furthermore, shredded cellophane, bits of plastic laminate, plate-like minerals like mica flakes, granulated inert materials such as nut shells, and nano-polymers are used in wellbores to reduce fluid loss. The incorporation of nanoparticles into drilling fluids has produced upgraded fluids with better features, including improved lubricity, thermal stability, and filtering capacities. These developments aid in lowering friction, enhancing wellbore stability, and enhancing drilling efficiency. This paper also emphasizes how nanotechnology has made enhanced drilling equipment and materials possible. Drilling equipment’s longevity and performance are increased by nanocomposite materials that have been reinforced with nanoparticles due to their improved mechanical strength, wear resistance, and thermal stability. Advanced reservoir characterisation tools, including nanoparticle tracers and nanoscale imaging methods, can help locate the best drilling sites and increase production effectiveness. On the other hand, nanofluids and nanoemulsions can potentially increase oil recovery because they enhance fluid mobility, lower interfacial tension, and alter rock wettability. Although nanotechnology has many advantages, there are also issues that need to be resolved. For an implementation to be effective, factors including nanoparticle stability, dispersion, and potential environmental effects must be carefully taken into account. This review highlights the need for future research to create scalable manufacturing procedures, improve nanoparticle behaviour, and determine nanomaterials’ long-term environmental effects. In conclusion, this in-depth analysis illustrates the use of nanotechnology in transforming the process of drilling oil and gas wells. Full article
(This article belongs to the Special Issue Advances in Oil and Gas Well Engineering Science and Technology)
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23 pages, 6444 KiB  
Article
Reverse Micellar Dyeing of Cotton Fabric with Reactive Dye Using Biodegradable Non-Ionic Surfactant as Nanoscale Carrier: An Optimisation Study by One-Factor-at-One-Time Approach
by Yiu Lun Alan Tang, Shixin Jin, Cheng Hao Lee, Ho Shing Law, Jiali Yu, Yanming Wang and Chi-wai Kan
Polymers 2023, 15(20), 4175; https://doi.org/10.3390/polym15204175 - 20 Oct 2023
Cited by 8 | Viewed by 2585
Abstract
This study investigates the feasibility of using biodegradable secondary alcohol ethoxylate (SAE) non-ionic surfactant as a building block for the formation of reverse micelles, functioning as reactive dye carriers for the dyeing of cotton fabric in non-aqueous octane medium. Ten dyeing parameters were [...] Read more.
This study investigates the feasibility of using biodegradable secondary alcohol ethoxylate (SAE) non-ionic surfactant as a building block for the formation of reverse micelles, functioning as reactive dye carriers for the dyeing of cotton fabric in non-aqueous octane medium. Ten dyeing parameters were optimised, by a one-factor-at-a-time approach, namely: (i) effect of colour fixation agent; (ii) surfactant-to-water mole ratio; (iii) surfactant-to-co-surfactant mole ratio; (iv) volume of soda ash; (v) volume of dye; (vi) solvent-to-cotton ratio; (vii) dyeing temperature; (viii) dyeing time; (ix) fixation time; (x) soda-ash-to-cotton ratio. The colour properties, fastness properties and physical properties of SAE-dyed samples were experimentally compared with the conventional water-dyed samples. The optimised condition was found when SAE samples were dyed as follows: (a) 1:20 surfactant-to-water ratio; (b) 1:8 surfactant-to-co-surfactant ratio; (c) 10:1 solvent ratio; (d) 40 min dyeing time; (e) 60 min fixation time; and (f) 70 °C dyeing and fixation temperature. The results showed that SAE-dyed samples have better colour strength, lower reflectance percentage and comparable levelness, fastness and physical properties than that of water-dyed samples. SEM images revealed that the dyed cotton fibres had no severe surface damage caused by an SAE-based reverse micellar dyeing system. The TEM image depicts that the reverse micelle was of nanoscale, spherical-shaped and had a core–shell structure, validating the presence of reverse micelle as a reactive dye carrier and the potential of an SAE-based reverse micellar system for dyeing of cotton fabrics. Full article
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12 pages, 2085 KiB  
Article
Development of Mosquito-Repellent Camouflage Fabric Using Eucalyptus Oil with Moringa oleifera Gum
by Faiza Anwar, Mudassar Abbas, Mumtaz Hasan Malik, Amna Aziz Cheema, Suniya Tariq, Warda Afzal and Asfandyar Khan
ChemEngineering 2023, 7(4), 64; https://doi.org/10.3390/chemengineering7040064 - 20 Jul 2023
Cited by 8 | Viewed by 4490
Abstract
Military personnel are exposed to several harsh conditions and mosquitos in mountains and wild forests. Mosquito-repellent textiles can help them to cope with such conditions. The present research work established a sustainable approach for fabricating microcapsules from Eucalyptus oil, Moringa oleifera, and [...] Read more.
Military personnel are exposed to several harsh conditions and mosquitos in mountains and wild forests. Mosquito-repellent textiles can help them to cope with such conditions. The present research work established a sustainable approach for fabricating microcapsules from Eucalyptus oil, Moringa oleifera, and Arabic gum via a complex coacervation method. Moringa oleifera and Arabic gums were utilized as the outer shell of the microcapsules, whereas the core part was made of Eucalyptus oil in different concentrations. The military camouflage-printed polyester/cotton (PC) blended fabric was coated with the as-prepared microcapsules using the pad–dry–cure technique. The surface morphology of the microcapsules was examined using an optical microscope and scanning electron microscope (SEM), and the coated fabric’s mosquito-repellent property was investigated using a specified cage test according to a standard testing protocol. The water absorbency and air permeability of the treated samples were also evaluated in order to learn about the comfort properties. The cage test results revealed that the coated fabric had a good tendency to repel the mosquitoes used in the cage test. In addition, the coated fabric showed significant durability even after several rigorous washing cycles. However, the application of microcapsules to the fabric slightly affected the water absorbency and air permeability of the fabric. This study presents a novel sustainable approach for fabricating microcapsules from the mentioned precursors and their application in the field of textiles, particularly for military purposes. Full article
(This article belongs to the Collection Green and Environmentally Sustainable Chemical Processes)
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15 pages, 3300 KiB  
Article
Effect of Low Temperature on Insecticidal Protein Contents of Cotton (Gossypium herbaceum L.) in the Boll Shell and Its Physiological Mechanism
by Zhenyu Liu, Mingyu Ji, Run He, Yuyang Dai, Yuting Liu, Nana Mou, Jianing Du, Xiang Zhang, Dehua Chen and Yuan Chen
Plants 2023, 12(9), 1767; https://doi.org/10.3390/plants12091767 - 26 Apr 2023
Cited by 4 | Viewed by 1778
Abstract
Low temperature is the main factor for global natural disasters affecting the growth and distribution of plants, and cotton may be affected by low temperature and cold damage at all growth stages. In addition, the insecticidal resistance of cultivars has been reported to [...] Read more.
Low temperature is the main factor for global natural disasters affecting the growth and distribution of plants, and cotton may be affected by low temperature and cold damage at all growth stages. In addition, the insecticidal resistance of cultivars has been reported to perform poorly or unstably due to adverse environments. The present study aimed to investigate the impact of low temperature on the levels of insecticidal protein in Bacillus thuringiensis (Bt) transgenic cotton plants during the peak boll stage. To achieve this, two Bt cotton cultivars, Sikang1 (SK1) and Sikang3 (SK3), were subjected to different temperature regimes and durations. The findings of the study demonstrated that the expression of insecticidal protein in the boll shell of Bt transgenic cotton plants was significantly inhibited under low-temperature stress. Specifically, in 2020, compared to the CK (27 °C), the insecticidal protein content in the boll shell of SK3 decreased by 28.19% after a 48 h of a 16 °C temperature. These results suggest that low-temperature stress can negatively impact the expression of insecticidal protein in Bt transgenic cotton, highlighting the need for appropriate measures to minimize its adverse effects on cotton production. In addition, the threshold temperature that leads to a significant decrease in the content of insecticidal proteins symbolizes an upward trend as the duration of stress prolongs. Decreased Bt protein content at low temperatures is associated with changes in the N metabolism. The present study revealed a significant positive correlation between the levels of glutamate oxaloacetate transaminase (GOT) and glutamate pyruvate transaminase (GPT) activities, as well as in the soluble protein levels in the boll shell and the content of the Bt protein. On the other hand, a significant negative correlation was observed between the levels of free amino acids, peptidase, and protease activities, as well as of Bt protein content. These findings suggest that, in Bt cotton production, it is crucial to remain vigilant of prolonged low-temperature disasters, which last for over 12 h and drop below 17–20 °C during the peak boll stage. Such conditions may reduce insecticidal resistance, leading to substantial economic losses. Full article
(This article belongs to the Section Plant Physiology and Metabolism)
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13 pages, 5182 KiB  
Article
Electrooxidation Performance of a Cotton-Cloth-Derived, Ni-Based, Hollow Microtubular Weave Catalytic Electrode for Methanol and Urea
by Guangya Hou, Jiaxuan Wei, Qiang Chen, Jianli Zhang and Yiping Tang
Metals 2023, 13(4), 659; https://doi.org/10.3390/met13040659 - 26 Mar 2023
Cited by 3 | Viewed by 2147
Abstract
Increasing consumption produces a large amount of cotton textile waste, the conversion of which into porous metals used for energy purposes is of practical value. In this paper, a porous, Ni-based, hollow microtubular weave (Ni-HTW) is obtained from cotton weave by high-temperature carbonization [...] Read more.
Increasing consumption produces a large amount of cotton textile waste, the conversion of which into porous metals used for energy purposes is of practical value. In this paper, a porous, Ni-based, hollow microtubular weave (Ni-HTW) is obtained from cotton weave by high-temperature carbonization and hydrothermal synthesis with high-temperature reduction. The Ni-based, hollow microtubules in this weave have a diameter of 5–10 μm and a wall thickness of about 1 μm, and every 15 microtubules form a loose bundle with a diameter of 150–200 μm. For improved performance, Ni(OH)2 nanosheets are further electrodeposited on the fibers’ surface of the Ni-HTW to form a nano-Ni(OH)2/Ni-HTW composite electrode with a core–shell heterostructure where Ni is the core and Ni(OH)2 the shell. The combination of hollow microtubule weave morphology and nanosheet structure results in a large specific surface area and abundant active sites, and the composite electrode shows excellent electrocatalytic performance and long-term stability for methanol oxidation (MOR) and urea oxidation (UOR). The current densities can reach 303.1 mA/cm2 and 342.5 mA/cm2 at 0.8 V, and 92.29% (MOR) and 84.41% (UOR) of the pre-cycle current densities can be maintained after 2000 consecutive cycles. Full article
(This article belongs to the Special Issue Metallic Functional Materials)
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