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Keywords = copper indium gallium selenide (CIGS)

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39 pages, 2858 KiB  
Review
Thin-Film Technologies for Sustainable Building-Integrated Photovoltaics
by Andrew R. Smith, Mehrdad Ghamari, Sasireka Velusamy and Senthilarasu Sundaram
Energies 2024, 17(24), 6363; https://doi.org/10.3390/en17246363 - 18 Dec 2024
Cited by 5 | Viewed by 3004
Abstract
This study investigates the incorporation of thin-film photovoltaic (TFPV) technologies in building-integrated photovoltaics (BIPV) and their contribution to sustainable architecture. The research focuses on three key TFPV materials: amorphous silicon (a-Si), cadmium telluride (CdTe), and copper indium gallium selenide (CIGS), examining their composition, [...] Read more.
This study investigates the incorporation of thin-film photovoltaic (TFPV) technologies in building-integrated photovoltaics (BIPV) and their contribution to sustainable architecture. The research focuses on three key TFPV materials: amorphous silicon (a-Si), cadmium telluride (CdTe), and copper indium gallium selenide (CIGS), examining their composition, efficiency, and BIPV applications. Recent advancements have yielded impressive results, with CdTe and CIGS achieving laboratory efficiencies of 22.10% and 23.35%, respectively. The study also explores the implementation of building energy management systems (BEMS) for optimizing energy use in BIPV-equipped buildings. Financial analysis indicates that despite 10.00–30.00% higher initial costs compared to conventional materials, BIPV systems can generate 50–150 kWh/m2 annually, with simple payback periods of 5–15 years. The research emphasizes the role of government incentives and innovative financing in promoting BIPV adoption. As BIPV technology progresses, it offers a promising solution for transforming buildings from energy consumers to producers, significantly contributing to sustainable urban development and climate change mitigation. Full article
(This article belongs to the Special Issue Energy Efficiency and Energy Performance in Buildings)
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18 pages, 1222 KiB  
Article
Computational Optimization for CdS/CIGS/GaAs Layered Solar Cell Architecture
by Satyam Bhatti, Habib Ullah Manzoor, Ahmed Zoha and Rami Ghannam
Energies 2024, 17(18), 4758; https://doi.org/10.3390/en17184758 - 23 Sep 2024
Cited by 3 | Viewed by 1826
Abstract
Multi-junction solar cells are vital in developing reliable, green, sustainable solar cells. Consequently, the computational optimization of solar cell architecture has the potential to profoundly expedite the process of discovering high-efficiency solar cells. Copper indium gallium selenide (CIGS)-based solar cells exhibit substantial performance [...] Read more.
Multi-junction solar cells are vital in developing reliable, green, sustainable solar cells. Consequently, the computational optimization of solar cell architecture has the potential to profoundly expedite the process of discovering high-efficiency solar cells. Copper indium gallium selenide (CIGS)-based solar cells exhibit substantial performance compared to those utilizing cadmium sulfide (CdS). Likewise, CIGS-based devices are more efficient according to their device performance, environmentally benign nature, and thus, reduced cost. Therefore, the paper introduces an optimization process of three-layered n-CdS/p-CIGS/p-GaAs (NPP)) solar cell architecture based on thickness and carrier charge density. An in-depth investigation of the numerical analysis for homojunction PPN-junction with the ’GaAs’ layer structure along with n-ZnO front contact was simulated using the Solar Cells Capacitance Simulator (SCAPS-1D) software. Subsequently, various computational optimization techniques for evaluating the effect of the thickness and the carrier density on the performance of the PPN layer on solar cell architecture were examined. The electronic characteristics by adding the GaAs layer on the top of the conventional (PN) junction further led to optimized values of the power conversion efficiency (PCE), open-circuit voltage (VOC), fill factor (FF), and short-circuit current density (JSC) of the solar cell. Lastly, the paper concludes by highlighting the most promising results of our study, showcasing the impact of adding the GaAs layer. Hence, using the optimized values from the analysis, thickness of 5 (μm) and carrier density of 1×1020 (1/cm) resulted in the maximum PCE, VOC, FF, and JSC of 45.7%, 1.16 V, 89.52%, and 43.88 (mA/m2), respectively, for the proposed solar cell architecture. The outcomes of the study aim to pave the path for highly efficient, optimized, and robust multi-junction solar cells. Full article
(This article belongs to the Special Issue Advances in High-Performance Perovskite Solar Cells)
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25 pages, 9496 KiB  
Article
Enhancing Multi-Junction Solar Cell Performance: Advanced Predictive Modeling and Cutting-Edge CIGS Integration Techniques
by Zakarya Ziani, Moustafa Yassine Mahdad, Mohammed Zakaria Bessenouci, Mohammed Chakib Sekkal and Nacera Ghellai
Energies 2024, 17(18), 4669; https://doi.org/10.3390/en17184669 - 19 Sep 2024
Cited by 3 | Viewed by 2261
Abstract
Historically, multi-junction solar cells have evolved to capture a broader spectrum of sunlight, significantly enhancing efficiency beyond conventional solar technologies. In this study, we utilized Silvaco TCAD tools to optimize a five-junction solar cell composed of AlInP, AlGaInP, AlGaInAs, GaInP, GaAs, InGaAs, and [...] Read more.
Historically, multi-junction solar cells have evolved to capture a broader spectrum of sunlight, significantly enhancing efficiency beyond conventional solar technologies. In this study, we utilized Silvaco TCAD tools to optimize a five-junction solar cell composed of AlInP, AlGaInP, AlGaInAs, GaInP, GaAs, InGaAs, and Ge, drawing on advancements documented in the literature. Our research focused on optimizing these cells through sophisticated statistical modeling and material innovation, particularly examining the relationship between layer thickness and electrical yield under one sun illumination. Employing III-V tandem solar cells, renowned for their superior efficiency in converting sunlight to electricity, we applied advanced statistical models to a reference solar cell configured with predefined layer thicknesses. Our analysis revealed significant positive correlations between layer thickness and electrical performance, with correlation coefficients (R2 values) impressively ranging from 0.86 to 0.96 across different regions. This detailed statistical insight led to an improvement in overall cell efficiency to 44.2. A key innovation in our approach was replacing the traditional germanium (Ge) substrate with Copper Indium Gallium Selenide (CIGS), known for its adjustable bandgap and superior absorption of long-wavelength photons. This strategic modification not only broadened the absorption spectrum but also elevated the overall cell efficiency to 47%. Additionally, the optimization process involved simulations using predictive profilers and Silvaco Atlas tools, which systematically assessed various configurations for their spectral absorption and current–voltage characteristics, further enhancing the cell’s performance. These findings underscore the critical role of precise material engineering and sophisticated statistical analyses in advancing solar cell technology, setting new efficiency benchmarks, and driving further developments in the field. Full article
(This article belongs to the Section D1: Advanced Energy Materials)
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10 pages, 2862 KiB  
Article
The Diagnosis of Shunt Defects in CIGS Modules Using Lock-In Thermography: An Empirical Comparative Study
by Seung Hoon Lee, Hae-Seok Lee, Donghwan Kim and Yoonmook Kang
Energies 2023, 16(21), 7226; https://doi.org/10.3390/en16217226 - 24 Oct 2023
Viewed by 1222
Abstract
Shunt defects are often detected in solar panels intended for photovoltaic applications. However, existing nondestructive detection technologies have certain inherent drawbacks depending on the application scenario. In this context, this paper reports a comprehensive empirical investigation into lock-in thermography (LIT) and its applicability [...] Read more.
Shunt defects are often detected in solar panels intended for photovoltaic applications. However, existing nondestructive detection technologies have certain inherent drawbacks depending on the application scenario. In this context, this paper reports a comprehensive empirical investigation into lock-in thermography (LIT) and its applicability to diagnosing shunt defects in copper indium gallium selenide (CIGS) solar modules. LIT was compared with biased thermography, and its distinctive attributes were elucidated. The comparison results demonstrate the superior capabilities of LIT at enhancing the signal-to-noise ratio, improving the visibility, resolution, and quantification of defects, and highlighting the usefulness of LIT for advanced defect analysis. We explored scenarios in which biased thermography could be appropriate despite its inherent limitations and identified conditions under which it might be preferred. The complex thermal behavior of different types of defects under various voltage conditions was analyzed, contributing to a more nuanced understanding of their behavior. Thus, integrating experimental results and theoretical understanding, we provide valuable insights and scientific guidelines for photovoltaic research. Our findings could help enhance the efficiency of defect detection in CIGS modules, highlighting the critical role of optimized thermographic techniques in developing photovoltaic technologies. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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32 pages, 1061 KiB  
Review
Overview of the Current State of Flexible Solar Panels and Photovoltaic Materials
by Rashid Dallaev, Tatiana Pisarenko, Nikola Papež and Vladimír Holcman
Materials 2023, 16(17), 5839; https://doi.org/10.3390/ma16175839 - 25 Aug 2023
Cited by 47 | Viewed by 14872
Abstract
The rapid growth and evolution of solar panel technology have been driven by continuous advancements in materials science. This review paper provides a comprehensive overview of the diverse range of materials employed in modern solar panels, elucidating their roles, properties, and contributions to [...] Read more.
The rapid growth and evolution of solar panel technology have been driven by continuous advancements in materials science. This review paper provides a comprehensive overview of the diverse range of materials employed in modern solar panels, elucidating their roles, properties, and contributions to overall performance. The discussion encompasses both traditional crystalline silicon-based panels and emerging thin-film technologies. A detailed examination of photovoltaic materials, including monocrystalline and polycrystalline silicon as well as alternative materials such as cadmium telluride (CdTe), copper indium gallium selenide (CIGS), and emerging perovskite solar cells, is presented. Furthermore, the impact of transparent conductive materials, encapsulation polymers, and antireflective coatings on solar panel efficiency and durability is explored. The review delves into the synergistic interplay between material properties, manufacturing processes, and environmental considerations. Through a comprehensive survey of materials utilized in modern solar panels, this paper provides insights into the current state of the field, highlighting avenues for future advancements and sustainable solar energy solutions. Full article
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9 pages, 2911 KiB  
Communication
Effects of Growth Temperature on the Morphological, Structural, and Electrical Properties of CIGS Thin Film for Use in Solar Cell Applications
by Hoang Lam Nguyen, Hyosang Lee, Shoyebmohamad F. Shaikh, Hassnain Abbas Khan, Mohaseen S. Tamboli, Jae Hak Jung and Nguyen Tam Nguyen Truong
Energies 2023, 16(11), 4467; https://doi.org/10.3390/en16114467 - 1 Jun 2023
Cited by 1 | Viewed by 1905
Abstract
Cu-In-Ga-Se nanoparticles (NPs) were synthesized using a colloidal route process. The effects of growth temperature (GT) on the properties of CuInGaSe2 (CIGS) thin films made from these nanoparticles were investigated using TEM, PL, XRD, and SEM techniques. The Cu-In-Ga-Se NPs were synthesized at [...] Read more.
Cu-In-Ga-Se nanoparticles (NPs) were synthesized using a colloidal route process. The effects of growth temperature (GT) on the properties of CuInGaSe2 (CIGS) thin films made from these nanoparticles were investigated using TEM, PL, XRD, and SEM techniques. The Cu-In-Ga-Se NPs were synthesized at growth temperatures ranging from 90 °C to 105 °C and then annealed at 550 °C for 7 min under a Se ambient. The resulting CIGS thin film, formed from Cu-In-Ga-Se NPs synthesized at a GT of 90 °C (referred to as GT90-CIGS), showed a tetragonal structure, large grain size, and high sunlight absorption. It had a band gap energy (Eg) of approximately 0.94 eV. Non-vacuum GT90-CIGS-based solar cells were investigated and fabricated using varying thicknesses of a CdS buffer layer. The maximum power conversion efficiency achieved was approximately 8.3% with an optimized device structure of Al/ITO/ZnO/CdS/CIGS/Mo. Full article
(This article belongs to the Special Issue Recent Advances in Solar Cells and Photovoltaic Systems)
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24 pages, 52009 KiB  
Review
All-Perovskite Tandem Solar Cells: From Certified 25% and Beyond
by Nour El Islam Boukortt, Claudia Triolo, Saveria Santangelo and Salvatore Patanè
Energies 2023, 16(8), 3519; https://doi.org/10.3390/en16083519 - 18 Apr 2023
Cited by 15 | Viewed by 7313
Abstract
Perovskite-based solar cells are a promising photovoltaic technology capable of offering higher conversion efficiency at low costs compared with the standard of the market. They can be produced via a thin film technology that allows for considerable environmental sustainability, thus representing an efficient, [...] Read more.
Perovskite-based solar cells are a promising photovoltaic technology capable of offering higher conversion efficiency at low costs compared with the standard of the market. They can be produced via a thin film technology that allows for considerable environmental sustainability, thus representing an efficient, sustainable, flexible, and light solution. Tandem solar cells represent the next step in the evolution of photovoltaics (PV). They promise higher power conversion efficiency (PCE) than those currently dominating the market. The tandem solar cell design overcomes the limitations of single junction solar cells by reducing the thermal losses as well as the manufacturing costs. Perovskite has been employed as a partner in different kinds of tandem solar cells, such as the Si and CIGS (copper indium gallium selenide) based cells that, in their tandem configuration with perovskite, can convert light more efficiently than standalone sub-cells. This brief review presents the main engineering and scientific challenges in the field. The state-of-the-art three main perovskite tandem technologies, namely perovskite/silicon, perovskite/CIGS, and perovskite/perovskite tandem solar cells, will be discussed, providing a side-by-side comparison of theoretical and experimental efficiencies of multijunction solar cells. Full article
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16 pages, 6006 KiB  
Article
A Platform for Outdoor Real-Time Characterization of Photovoltaic Technologies
by Sammy J. Martínez-Deusa, Carlos A. Gómez-García and Jaime Velasco-Medina
Energies 2023, 16(6), 2907; https://doi.org/10.3390/en16062907 - 22 Mar 2023
Cited by 4 | Viewed by 2396
Abstract
In recent years, thin-film and organic photovoltaic (OPV) technologies have been increasingly used as alternatives to conventional technologies due to their low weight, portability, and ease of installation. Outdoor characterization studies allow knowing the real performances of these photovoltaic (PV) technologies in different [...] Read more.
In recent years, thin-film and organic photovoltaic (OPV) technologies have been increasingly used as alternatives to conventional technologies due to their low weight, portability, and ease of installation. Outdoor characterization studies allow knowing the real performances of these photovoltaic (PV) technologies in different environmental conditions. Therefore, to address the above, this article presents the hardware–software design and implementation of an integrated and scalable platform for performing the outdoor real-time characterization of modern PV/OPV technologies located at different altitudes. The platform allows knowing the outdoor performance of PV/OPV technologies in real environmental conditions by acquiring data from different monitoring stations located at different altitudes. The proposed platform allows characterizing solar panels and mini-modules and acquiring relevant information to analyze power generation capacity and efficiency. Furthermore, other devices for new PV technologies characterization can be easily added, achieving a scale-up of the platform. A preliminary study of the outdoor performance of emerging PV/OPV technologies was carried out at three different altitudes in a tropical climate region. From the results, the copper indium gallium selenide (CIGS) technology presents the best outdoor performance with an average PCE of 9.64%; the OPV technology has the best behavior at high temperatures with a voltage loss rate of 0.0206 V/°C; and the cadmium telluride (CdTe) technology is the most affected by temperature, with a voltage loss rate of 0.0803 V/°C. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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14 pages, 2968 KiB  
Article
Investigation of High-Efficiency and Stable Carbon-Perovskite/Silicon and Carbon-Perovskite/CIGS-GeTe Tandem Solar Cells
by Ahmed Saeed, Mostafa M. Salah, Abdelhalim Zekry, Mohamed Mousa, Ahmed Shaker, Mohamed Abouelatta, Fathy Z. Amer, Roaa I. Mubarak and Dalia S. Louis
Energies 2023, 16(4), 1676; https://doi.org/10.3390/en16041676 - 8 Feb 2023
Cited by 18 | Viewed by 3803
Abstract
The primary purpose of recent research on solar cells is to achieve a higher power conversion efficiency with stable characteristics. To push the developments of photovoltaic (PV) technology, tandem solar cells are being intensively researched, as they have higher power conversion efficiency (PCE) [...] Read more.
The primary purpose of recent research on solar cells is to achieve a higher power conversion efficiency with stable characteristics. To push the developments of photovoltaic (PV) technology, tandem solar cells are being intensively researched, as they have higher power conversion efficiency (PCE) than single-junction cells. Perovskite solar cells (PSCs) are recently used as a top cell of tandem solar cells thanks to their tunable energy gap, high short circuit current, and low cost of fabrication. One of the main challenges in PSCs cells is the stability issue. Carbon perovskite solar cells (CPSCs) without a hole transport material (HTM) presented a promising solution for PSCs’ stability. The two-terminal monolithic tandem solar cells demonstrate the commercial tandem cells market. Consequently, all the proposed tandem solar cells in this paper are equivalent to two-terminal monolithic tandem devices. In this work, two two-terminal tandem solar cells are proposed and investigated using the SCAPS-1D device simulator. Carbon perovskite solar cell (CPSC) without hole transport material (HTM) is used as the top cell with a new proposed gradient doping in the perovskite layer. This proposal has led to a substantial enhancement of the stability issue known to be present in carbon perovskite cells. Moreover, a higher PCE, exceeding 22%, has been attained for the proposed CPSC. Two bottom cells are examined, Si and CIGS-GeTe solar cells. The suggested CPSC/Si and CPSC/CIGS-GeTe tandem solar cells have the advantage of having just two junctions, which reduces the complexity and cost of solar cells. The performance parameters are found to be improved. In specific, the PCEs of the two proposed cells are 19.89% and 24.69%, respectively. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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14 pages, 3628 KiB  
Article
Assessment of a Therapeutic X-ray Radiation Dose Measurement System Based on a Flexible Copper Indium Gallium Selenide Solar Cell
by Dong-Seok Shin, Tae-Ho Kim, Jeong-Eun Rah, Dohyeon Kim, Hye Jeong Yang, Se Byeong Lee, Young Kyung Lim, Jonghwi Jeong, Haksoo Kim, Dongho Shin and Jaeman Son
Sensors 2022, 22(15), 5819; https://doi.org/10.3390/s22155819 - 4 Aug 2022
Cited by 3 | Viewed by 2730
Abstract
Several detectors have been developed to measure radiation doses during radiotherapy. However, most detectors are not flexible. Consequently, the airgaps between the patient surface and detector could reduce the measurement accuracy. Thus, this study proposes a dose measurement system based on a flexible [...] Read more.
Several detectors have been developed to measure radiation doses during radiotherapy. However, most detectors are not flexible. Consequently, the airgaps between the patient surface and detector could reduce the measurement accuracy. Thus, this study proposes a dose measurement system based on a flexible copper indium gallium selenide (CIGS) solar cell. Our system comprises a customized CIGS solar cell (with a size 10 × 10 cm2 and thickness 0.33 mm), voltage amplifier, data acquisition module, and laptop with in-house software. In the study, the dosimetric characteristics, such as dose linearity, dose rate independence, energy independence, and field size output, of the dose measurement system in therapeutic X-ray radiation were quantified. For dose linearity, the slope of the linear fitted curve and the R-square value were 1.00 and 0.9999, respectively. The differences in the measured signals according to changes in the dose rates and photon energies were <2% and <3%, respectively. The field size output measured using our system exhibited a substantial increase as the field size increased, contrary to that measured using the ion chamber/film. Our findings demonstrate that our system has good dosimetric characteristics as a flexible in vivo dosimeter. Furthermore, the size and shape of the solar cell can be easily customized, which is an advantage over other flexible dosimeters based on an a-Si solar cell. Full article
(This article belongs to the Special Issue Optical Fiber Sensors in Radiation Environments)
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21 pages, 4446 KiB  
Article
Performance Evaluation of 1.1 MW Grid-Connected Solar Photovoltaic Power Plant in Louisiana
by Deepak Jain Veerendra Kumar, Lelia Deville, Kenneth A. Ritter, Johnathan Richard Raush, Farzad Ferdowsi, Raju Gottumukkala and Terrence Lynn Chambers
Energies 2022, 15(9), 3420; https://doi.org/10.3390/en15093420 - 7 May 2022
Cited by 24 | Viewed by 3693
Abstract
In this work, performance analysis and comparison of three photovoltaic technologies are carried out in the Louisiana climate. During the calendar year of 2018, the University of Louisiana at Lafayette constructed and commissioned a 1.1 MW solar photovoltaic power plant for researching solar [...] Read more.
In this work, performance analysis and comparison of three photovoltaic technologies are carried out in the Louisiana climate. During the calendar year of 2018, the University of Louisiana at Lafayette constructed and commissioned a 1.1 MW solar photovoltaic power plant for researching solar power in southern Louisiana and for partial energy demand of the university. It was one of the largest solar photovoltaic power plants in Louisiana when constructed and receives an annual solar insolation of 4.88 kWh/m2/d at latitude minus five degrees (25°) tilt. The solar power plant has a total of 4142 modules and incorporates three module technologies. Preliminary performance data from the system level are presented. The evaluation of different technologies is based on final yield, performance ratio, and capacity factor for one year from September 2019 to August 2020. An economic analysis is carried out using levelized cost of energy for the three photovoltaic (PV) technologies. Finally, the results are compared with simulated results of System Advisor Model (SAM) and PVsyst. It was found that copper indium gallium selenide (CIGS) has better performance ratio of 0.79 compared with monocrystalline silicon and polycrystalline silicon, which have performance ratios of 0.77 and 0.73, respectively. The simulation results correlated with the actual performance of the plant. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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11 pages, 3970 KiB  
Article
Photoluminescence Imaging for the In-Line Quality Control of Thin-Film Solar Cells
by Johanna Zikulnig, Wolfgang Mühleisen, Pieter Jan Bolt, Marcel Simor and Martin De Biasio
Solar 2022, 2(1), 1-11; https://doi.org/10.3390/solar2010001 - 14 Jan 2022
Cited by 9 | Viewed by 5521
Abstract
Renewable energy sources such as photovoltaic (PV) technologies are considered to be key drivers towards climate neutrality. Thin-film PVs, and particularly copper indium gallium selenide (CIGS) technologies, will play a crucial role in the turnaround in energy policy due to their high efficiencies, [...] Read more.
Renewable energy sources such as photovoltaic (PV) technologies are considered to be key drivers towards climate neutrality. Thin-film PVs, and particularly copper indium gallium selenide (CIGS) technologies, will play a crucial role in the turnaround in energy policy due to their high efficiencies, high product flexibility, light weight, easy installation, lower labour-intensiveness, and lower carbon footprint when compared to silicon solar cells. Nonetheless, challenges regarding the CIGS fabrication process such as moderate reproducibility and process tolerance are still hindering a broad market penetration. Therefore, cost-efficient and easily implementable in-line process control methods are demanded that allow for identification and elimination of non-conformal cells at an early production step. As part of this work, a practical approach towards industrial in-line photoluminescence (PL) imaging as a contact-free quality inspection tool is presented. Performance parameters of 10 CIGS samples with 32 individually contacted cells each were correlated with results from PL imaging using green and red excitation light sources. The data analysis was fully automated using Python-based image processing, object detection, and non-linear regression modelling. Using the red excitation light source, the presented PL imaging and data processing approach allows for a quantitative assessment of the cell performance. Full article
(This article belongs to the Special Issue Nanotechnology in Photo-Triggered Processes)
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21 pages, 13316 KiB  
Article
Mass Transfer Study on Improved Chemistry for Electrodeposition of Copper Indium Gallium Selenide (CIGS) Compound for Photovoltaics Applications
by Mahfouz Saeed and Omar Israel González Peña
Nanomaterials 2021, 11(5), 1222; https://doi.org/10.3390/nano11051222 - 6 May 2021
Cited by 6 | Viewed by 4001
Abstract
Copper indium gallium selenium (CIGS) films are attractive for photovoltaic applications due to their high optical absorption coefficient. The generation of CIGS films by electrodeposition is particularly appealing due to the relatively low capital cost and high throughput. Numerous publications address the electrodeposition [...] Read more.
Copper indium gallium selenium (CIGS) films are attractive for photovoltaic applications due to their high optical absorption coefficient. The generation of CIGS films by electrodeposition is particularly appealing due to the relatively low capital cost and high throughput. Numerous publications address the electrodeposition of CIGS; however, very few recognize the critical significance of transport in affecting the composition and properties of the compound. This study introduces a new electrolyte composition, which is far more dilute than systems that had been previously described, which yields much improved CIGS films. The electrodeposition experiments were carried out on a rotating disk electrode, which provides quantitative control of the transport rates. Experiments with the conventional electrolyte, ten times more concentrated than the new electrolyte proposed here, yielded powdery and non-adherent deposit. By contrast, the new, low concentration electrolyte produced in the preferred potential interval of −0.64 ≤ E ≤ −0.76 V vs. NHE, a smooth and adherent uniform deposit with the desired composition across a broad range of rotation speeds. The effects of mass transport on the deposit are discussed. Sample polarization curves at different electrode rotation rates, obtained in deposition experiments from the high and the low concentration electrolytes, are critically compared. Characterization of the overall efficiency, quantum efficiency, open circuit voltage, short circuit current, dark current, band gap, and the fill factor are reported. Full article
(This article belongs to the Special Issue Advances in Nanomaterials for Photovoltaic Applications)
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26 pages, 3145 KiB  
Article
Solar Cell Technology Selection for a PV Leaf Based on Energy and Sustainability Indicators—A Case of a Multilayered Solar Photovoltaic Tree
by Nallapaneni Manoj Kumar, Shauhrat S. Chopra, Maria Malvoni, Rajvikram Madurai Elavarasan and Narottam Das
Energies 2020, 13(23), 6439; https://doi.org/10.3390/en13236439 - 5 Dec 2020
Cited by 24 | Viewed by 4531
Abstract
Harnessing energy from the sunlight using solar photovoltaic trees (SPVTs) has become popular at present as they reduce land footprint and offer numerous complimentary services that offset infrastructure. The SPVT’s complimentary services are noticeable in many ways, e.g., electric vehicle charging stations, landscaping, [...] Read more.
Harnessing energy from the sunlight using solar photovoltaic trees (SPVTs) has become popular at present as they reduce land footprint and offer numerous complimentary services that offset infrastructure. The SPVT’s complimentary services are noticeable in many ways, e.g., electric vehicle charging stations, landscaping, passenger shelters, onsite energy generated security poles, etc. Although the SPVT offers numerous benefits and services, its deployment is relatively slower due to the challenges it suffers. The most difficult challenges include the structure design, the photovoltaic (PV) cell technology selection for a leaf, and uncertainty in performance due to weather parameter variations. This paper aims to provide the most practical solution supported by the performance prioritization approach (PPA) framework for a typical multilayered SPVT. The proposed PPA framework considers the energy and sustainability indicators and helps in reporting the performance of a multilayered SPVT, with the aim of selecting an efficient PV leaf design. A three-layered SPVT (3-L SPVT) is simulated; moreover, the degradation-influenced lifetime energy performance and carbon dioxide (CO2) emissions were evaluated for three different PV-cell technologies, namely crystalline silicon (c-Si), copper indium gallium selenide (CIGS), and cadmium telluride (CdTe). While evaluating the performance of the 3-L SPVT, the power conversion efficiency, thermal regulation, degradation rate, and lifecycle carbon emissions were considered. The results of the 3-L SPVT were analyzed thoroughly, and it was found that in the early years, the c-Si PV leaves give better energy yields. However, when degradation and other influencing weather parameters were considered over its lifetime, the SPVT with c-Si leaves showed a lowered energy yield. Overall, the lifetime energy and CO2 emission results indicate that the CdTe PV leaf outperforms due to its lower degradation rate compared to c-Si and CIGS. On the other side, the benefits associated with CdTe cells, such as flexible and ultrathin glass structure as well as low-cost manufacturing, make them the best acceptable PV leaf for SPVT design. Through this investigation, we present the selection of suitable solar cell technology for a PV leaf. Full article
(This article belongs to the Special Issue Nano-Structured Solar Cells 2020-2022)
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13 pages, 707 KiB  
Article
Sustainable End of Life Management of Crystalline Silicon and Thin Film Solar Photovoltaic Waste: The Impact of Transportation
by Ilke Celik, Marina Lunardi, Austen Frederickson and Richard Corkish
Appl. Sci. 2020, 10(16), 5465; https://doi.org/10.3390/app10165465 - 7 Aug 2020
Cited by 24 | Viewed by 5741
Abstract
This work provides economic and environmental analyses of transportation-related impacts of different photovoltaic (PV) module technologies at their end-of-life (EoL) phase. Our results show that crystalline silicon (c-Si) modules are the most economical PV technology (United States Dollars (USD) 2.3 per 1 m [...] Read more.
This work provides economic and environmental analyses of transportation-related impacts of different photovoltaic (PV) module technologies at their end-of-life (EoL) phase. Our results show that crystalline silicon (c-Si) modules are the most economical PV technology (United States Dollars (USD) 2.3 per 1 m2 PV module (or 0.87 ¢/W) for transporting in the United States for 1000 km). Furthermore, we found that the financial costs of truck transportation for PV modules for 2000 km are only slightly more than for 1000 km. CO2-eq emissions associated with transport are a significant share of the EoL impacts, and those for copper indium gallium selenide (CIGS) PV modules are always higher than for c-Si and CdTe PV. Transportation associated CO2-eq emissions contribute 47%, 28%, and 40% of overall EoL impacts of c-Si, CdTe, and CIGS PV wastes, respectively. Overall, gasoline-fueled trucks have 65–95% more environmental impacts compared to alternative transportation options of the diesel and electric trains and ships. Finally, a hotspot analysis on the entire life cycle CO2-eq emissions of different PV technologies showed that the EoL phase-related emissions are more significant for thin-film PV modules compared to crystalline silicon PV technologies and, so, more environmentally friendly material recovery methods should be developed for thin film PV. Full article
(This article belongs to the Special Issue Advances in Future Energy Materials)
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