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Keywords = cold lateral condensation

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14 pages, 7530 KiB  
Article
Cold Consolidation of Pharmaceutical Waste Glass Powders Through Alkali Activation and Binder Jet 3D Printing
by Hamada Elsayed, Filippo Gobbin, Alberto Barci, Enrico Bernardo and Paolo Colombo
Materials 2024, 17(21), 5164; https://doi.org/10.3390/ma17215164 - 23 Oct 2024
Cited by 2 | Viewed by 1247
Abstract
The recent COVID-19 emergency has led to an impressive increase in the production of pharmaceutical vials. This has led to a parallel increase in the amounts of waste glass; manufacturers typically recover material from faulty containers by crushing, giving origin to an unrecyclable [...] Read more.
The recent COVID-19 emergency has led to an impressive increase in the production of pharmaceutical vials. This has led to a parallel increase in the amounts of waste glass; manufacturers typically recover material from faulty containers by crushing, giving origin to an unrecyclable fraction. Coarse fragments are effectively reused as feedstock for glass melting; on the contrary, fine powders (<100 microns), contaminated by metal and ceramic particles due to the same crushing operations, are landfilled. Landfilling is also suggested for pharmaceutical containers after medical use. This study aims at proposing new opportunities for the recycling of fine glass particles, according to recent findings concerning alkali activation of pharmaceutical glass, combined with novel processing, i.e., binder jetting printing. It has already been shown that pharmaceutical glass, immersed in low-molarity alkaline solution (not exceeding 2.5 M NaOH), undergoes surface dissolution and hydration; cold consolidation is later achieved, upon drying at 40–60 °C, by a condensation reaction occurring at hydrated layers of adjacent particles. Binder jetting printing does not realize a full liquid immersion of the glass powders, as the attacking solution is selectively sprayed on a powder bed. Here, we discuss the tuning of key parameters, such as the molarity of the attacking solution (from 2.5 to 10 M) and the granulometry of the waste glass, to obtain stable printed blocks. In particular, the stability depends on the formation of bridges between adjacent particles consisting of strong T-O bonds (Si-O-Si, Al-O-Si, B-O-Si), while degradation products (concentrating Na ions) remain as a secondary phase, solubilized by immersion in boiling water. Such stability is achieved by operating at 5 M NaOH. Full article
(This article belongs to the Special Issue State of the Art of Materials Science and Engineering in Italy)
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26 pages, 10630 KiB  
Article
Modelling of Cryopumps for Space Electric Propulsion Usage
by Andreas Neumann and Michaela Brchnelova
Aerospace 2024, 11(3), 177; https://doi.org/10.3390/aerospace11030177 - 23 Feb 2024
Cited by 2 | Viewed by 2230
Abstract
Electric space propulsion is a technology that is used in a continuously increasing number of spacecrafts. The qualification of these propulsion systems has to run in ground-based test facilities which requires long testing times and powerful pumping systems. In these usually large test [...] Read more.
Electric space propulsion is a technology that is used in a continuously increasing number of spacecrafts. The qualification of these propulsion systems has to run in ground-based test facilities which requires long testing times and powerful pumping systems. In these usually large test facilities, high pumping speeds are achieved with cryopumps. Cryopump operation is very expensive with respect to electrical energy and cooling water consumption. Therefore, being able to optimize pump shape, cold plate material, and pump placement in a chamber is beneficial. Pump design and tuned operating strategies can reduce costs and increase intervals between regeneration. Testing different pump configuration setups in a large facility is mostly prohibitive due to high costs and long testing times. Optimization via modelling is a better choice for design and also, later, for operation. Therefore, having a numerical model and proven guidelines at hand for optimization is very helpful. This paper describes a new model developed at DLR for the optimization of cryopump layout and operation. Model results are compared with cryopump operational and warm-up data. This validation is the basis for further optimization actions like multi-layer insulation layouts and pump cold plate upgrades, and helps in understanding and mitigating the detrimental effect of water condensates on the cryopump cold plates. Full article
(This article belongs to the Special Issue Advanced Chemical Propulsion and Electric Propulsion)
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18 pages, 2774 KiB  
Article
Assessment of the Penetration of an Endodontic Sealer into Dentinal Tubules with Three Different Compaction Techniques Using Confocal Laser Scanning Microscopy
by Ignacio Barbero-Navarro, Diego Velázquez-González, María Esther Irigoyen-Camacho, Marco Antonio Zepeda-Zepeda, Paulo Mauricio, David Ribas-Perez and Antonio Castano-Seiquer
J. Funct. Biomater. 2023, 14(11), 542; https://doi.org/10.3390/jfb14110542 - 7 Nov 2023
Cited by 3 | Viewed by 3460
Abstract
Adequate root canal sealing is essential for the success of endodontic treatment. There are numerous techniques available; identifying simple and efficient techniques is important to provide good patient care. The purpose of the study was to compare the maximum penetration depth and the [...] Read more.
Adequate root canal sealing is essential for the success of endodontic treatment. There are numerous techniques available; identifying simple and efficient techniques is important to provide good patient care. The purpose of the study was to compare the maximum penetration depth and the percentage of sealant penetration of an endodontic sealer into dentine tubules using cold lateral condensation, continuous wave, and hybrid techniques, and to contrast the effectiveness of two different tapered gutta-percha master cones (0.02 and 0.04). A sample of sixty single root teeth was used. Six experimental groups were formed from the three filling techniques and the two tapered master cones. Images were acquired using a confocal laser scanning microscope. In the apical root third, the penetration percentage was higher in the hybrid compared with the continuous wave technique. The results indicated a higher penetration depth of hybrid compared with cold lateral condensation in the middle and coronal thirds, and in the apical third, a higher penetration was identified in the hybrid group compared with the continuous wave group. No significant differences in penetration were found comparing 0.02 with 0.04 taper gutta-percha groups. The coronal cross-sections presented a higher penetration than the apical third sections. In conclusion, the hybrid technique a had higher maximum sealer penetration than the continuous wave in the apical third, and the coronal third hybrid and continuous wave had a higher penetration than cold lateral condensation. Full article
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23 pages, 29082 KiB  
Article
Analysis of the Development Mechanisms of a Polar Low over the Norwegian Sea Simulated with the Canadian Regional Climate Model
by Marta Moreno-Ibáñez, René Laprise and Philippe Gachon
Atmosphere 2023, 14(6), 998; https://doi.org/10.3390/atmos14060998 - 8 Jun 2023
Cited by 2 | Viewed by 2137
Abstract
Polar lows (PLs) are maritime mesoscale cyclones associated with severe weather. They develop during marine cold air outbreaks near coastlines and the sea ice edge. Unfortunately, our knowledge about the mechanisms leading to PL development is still incomplete. This study aims to provide [...] Read more.
Polar lows (PLs) are maritime mesoscale cyclones associated with severe weather. They develop during marine cold air outbreaks near coastlines and the sea ice edge. Unfortunately, our knowledge about the mechanisms leading to PL development is still incomplete. This study aims to provide a detailed analysis of the development mechanisms of a PL that formed over the Norwegian Sea on 25 March 2019 using the output of a simulation with the sixth version of the Canadian Regional Climate Model (CRCM6/GEM4), a convection-permitting model. First, the life cycle of the PL is described and the vertical wind shear environment is analysed. Then, the horizontal wind divergence and the baroclinic conversion term are computed, and a surface pressure tendency equation is developed. In addition, the roles of atmospheric static stability, latent heat release, and surface heat and moisture fluxes are explored. The results show that the PL developed in a forward-shear environment and that moist baroclinic instability played a major role in its genesis and intensification. Baroclinic instability was initially only present at low levels of the atmosphere, but later extended upward until it reached the mid-troposphere. Whereas the latent heat of condensation and the surface heat fluxes also contributed to the development of the PL, convective available potential energy and barotropic conversion do not seem to have played a major role in its intensification. In conclusion, this study shows that a convection-permitting model simulation is a powerful tool to study the details of the structure of PLs, as well as their development mechanisms. Full article
(This article belongs to the Section Meteorology)
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11 pages, 322 KiB  
Article
Exploring the Most Effective Apical Seal for Contemporary Bioceramic and Conventional Endodontic Sealers Using Three Obturation Techniques
by Hira Akhtar, Farah Naz, Arshad Hasan, Anum Tanwir, Danish Shahnawaz, Umair Wahid, Fariha Irfan, Muhammad Adeel Ahmed, Khalid H. Almadi, Mazen F. Alkahtany, Tariq Abduljabbar and Fahim Vohra
Medicina 2023, 59(3), 567; https://doi.org/10.3390/medicina59030567 - 14 Mar 2023
Cited by 5 | Viewed by 4388
Abstract
Background and Objective: Despite a plethora of studies conducted to date, researchers continue to investigate the best sealer and obturation technique combinations. The aim of this study is to compare the apical seal provided by two bioceramic sealers (Endoseal and Endosequence) with that [...] Read more.
Background and Objective: Despite a plethora of studies conducted to date, researchers continue to investigate the best sealer and obturation technique combinations. The aim of this study is to compare the apical seal provided by two bioceramic sealers (Endoseal and Endosequence) with that provided by a calcium hydroxide sealer (Sealapex), and to evaluate the effect of different obturation techniques (cold lateral condensation, continuous wave compaction and single cone) on the apical seal under a stereomicroscope. Materials and Methods: A total of 110 single-rooted mandibular premolar teeth were decoronated, cleaned and shaped using the Endosequence filing system to tip size 30/0.04 taper. Canals were irrigated with 5.25% NaOCl and 17% EDTA. The samples were randomly divided into 11 groups (9 experimental and 2 control groups) according to the designated sealer and technique. Samples were stored in an incubator for 7 days at 37 °C under 100% humidity. Samples were coated with nail varnish except for apical 2 mm and vertically placed in 0.2% rhodamine B dye solution for 48 h. Samples were split longitudinally and viewed under a stereomicroscope at 40× magnification. Results: Insignificant results were obtained between obturation techniques (p = 0.499) whereas statistically significant results were attained based on the type of endodontic sealer (p < 0.001). The overall lowest mean apical microleakage and best sealing ability was demonstrated by Sealapex (2.59 ± 1.20 mm) and amongst techniques by continuous wave compaction (3.90 ± 2.51 mm). Conclusions: Endosequence produced the best apical seal with the continuous wave compaction technique, whereas Endoseal did so with the bioceramic-coated single-cone technique. For the Sealapex sealer, the most effective apical seal was observed using cold lateral condensation. The quality and effectiveness of apical seal differed with the type of endodontic sealer and obturation technique used, and vice versa. Full article
13 pages, 5905 KiB  
Article
Experimental and Numerical Study of Thermal Performance of an Innovative Waste Heat Recovery System
by Robert Stefan Vizitiu, Andrei Burlacu, Cherifa Abid, Marina Verdes, Marius Costel Balan and Marius Branoaea
Appl. Sci. 2021, 11(23), 11542; https://doi.org/10.3390/app112311542 - 6 Dec 2021
Cited by 5 | Viewed by 2788
Abstract
One of the biggest challenges the world is facing these days is to reduce the greenhouse gases emissions in order to prevent the global warming. Since a significant quantity of CO2 emissions is the result of the energy producing process required in [...] Read more.
One of the biggest challenges the world is facing these days is to reduce the greenhouse gases emissions in order to prevent the global warming. Since a significant quantity of CO2 emissions is the result of the energy producing process required in industry or buildings, the waste heat recovery is an important aspect in the fight for preserving the planet. In this study, an innovative waste heat recovery system which can recover waste heat energy from cooling liquids used in industry or in different processes, was designed and subjected to experimental investigations. The equipment uses heat pipes to capture thermal energy from the residual fluids transiting the evaporator zone and transfer it to the cold water transiting the condenser zone. The efficiency of the heat exchanger was tested in 9 scenarios, by varying the temperature of the primary agent to 60, 65 and 70 °C and the volume flow rate of the secondary agent to 1, 2 and 3 L/min. The temperature of the secondary agent and the volume flow rate of the primary agent were kept constant at 10 °C, respectively 24 L/min. The results were later validated through numerical simulations, and confirmed that the equipment can easily recover waste thermal energy from used water with low and medium temperatures at very low costs compared to the traditional heat exchangers. The results were promising, revealing an efficiency of the equipment up to 76.7%. Full article
(This article belongs to the Special Issue Urban Sustainability and Resilience of the Built Environments)
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53 pages, 163150 KiB  
Review
What Are the Chances of Resilon to Dominate the Market Filling Materials for Endodontics?
by Joanna Dobrzańska, Lech B. Dobrzański, Leszek A. Dobrzański, Anna D. Dobrzańska-Danikiewicz and Klaudiusz Gołombek
Metals 2021, 11(11), 1744; https://doi.org/10.3390/met11111744 - 30 Oct 2021
Cited by 5 | Viewed by 6479
Abstract
This paper is a literature review with additional virtual analyses of the authors’ own experimental research results. Knowledge from various areas was synergistically combined, appropriately for concurrent engineering, presenting several possible methodological approaches used in research, optimizing the selection of engineering materials and [...] Read more.
This paper is a literature review with additional virtual analyses of the authors’ own experimental research results. Knowledge from various areas was synergistically combined, appropriately for concurrent engineering, presenting several possible methodological approaches used in research, optimizing the selection of engineering materials and the conditions of their application with particular application in endodontics. Particular attention was paid to the theoretical aspects of filling material strengths, weaknesses, opportunities, and threats SWOT analysis. Attention was paid to the original concepts of Sustainable Dentistry Development in conjunction with Dentistry 4.0, which includes endodontics as an important element. The dentists’ actions, among others, in conservative dentistry, along with endodontics, requires close cooperation with engineers and the enginering sciences. Methods of root canal preparation were described, together with selected tools, including those made of nitinol. Principles concerning the process of cleaning and shaping the pulp complex are presented. The importance of obturation methods, including the Thermo-Hydraulic-Condensation THC technique, and the selection of filling materials with the necessary sealants for the success of endodontic treatment are discussed. The experimental studies were carried out in vitro on human teeth removed for medical reasons, except for caries, for which two groups of 16 teeth were separated. After the root canal was prepared, it was filled with studs and pellets of a filling material based on polyester materials, which has gained the common trade name of resilon or, less frequently, RealSeal (SybronEndo) with an epiphany sealant. The teeth for the first group were obturated by cold lateral condensation. In the second case the obturation was performed using the Thermo-Hydraulic-Condensation technique using System B and Obtura III. The experimental leakage testing was done using a scanning electron microscope SEM and a light stereoscopic microscope LSM, as typical research tools used in materialography. The research results, in a confrontation with the data taken from the literature studies, do not indicate the domination of resilon in endodontics. Full article
(This article belongs to the Special Issue Recent Biomedical Materials)
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8 pages, 1073 KiB  
Article
Influence of Root Canal Sealers and Obturation Techniques on Vertical Root Fracture Resistance. An In Vitro Experiment
by Mazen F. Alkahtany, Khalid H. Almadi, Fahad A. Alahmad, Abdullah M. Alshehri, Abdulrahman A. AlSwayyed, Omar M. AlZahran, Ali AlHadan, Abdulaziz S. Almustafa, Fahim Vohra and Tariq Abduljabbar
Appl. Sci. 2021, 11(17), 8022; https://doi.org/10.3390/app11178022 - 30 Aug 2021
Cited by 4 | Viewed by 3967
Abstract
The aim of the present study was to determine the vertical root fracture (VRF) resistance of roots obturated with TotalFill BC Sealer and AH Plus sealer using lateral condensation and single cone techniques in comparison to untreated controls. Sixty single rooted mandibular premolars [...] Read more.
The aim of the present study was to determine the vertical root fracture (VRF) resistance of roots obturated with TotalFill BC Sealer and AH Plus sealer using lateral condensation and single cone techniques in comparison to untreated controls. Sixty single rooted mandibular premolars were sectioned and divided into six groups. Ten teeth were left untreated (positive control-Gp 1) and fifty teeth were cleaned and shaped. Ten root specimens were left unfilled (negative control-Gp 2) and the remaining roots were divided into 4 groups. Gp 3, GP and AH Plus sealer (AH Plus) using the cold lateral compaction (LC) technique; Gp 4, GP and AH Plus using the Single Cone (SC) technique; Gp 5: TotalFill GP and TotalFill BC sealer using the LC technique; Gp 6: TotalFill GP and TotalFill BC sealer with SC. VRF was performed for all specimens using a universal testing machine. Analysis of variance (ANOVA) and Tukeys post-hoc multiple comparison test was used to compare the means among tested study groups. Group 1 (positive control) displayed the highest fracture resistance (946.61 ± 166.465 N); however, the lowest fracture strength was demonstrated by the specimens in group 2 (negative control) (433.31 ± 129.350 N). Specimens treated with AH plus using different obturation techniques (group 3 and 4) showed comparable outcomes (p > 0.05). Similarly, specimens treated with TotalFill BC sealer with different obturation techniques showed statistically similar outcomes (p > 0.05). It was also observed that specimens in groups 3, 4, 5 and 6 demonstrated comparable outcomes of fracture strength (p > 0.05). The use of TotalFill-BC sealer showed similar vertical root fracture resistance as AH plus sealer in root canal treated teeth. Use of total fill-BC and AH Plus sealer in root canal treatment showed vertical root fracture resistance comparable to untreated natural teeth (positive controls). Full article
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15 pages, 589 KiB  
Review
Complete Obturation—Cold Lateral Condensation vs. Thermoplastic Techniques: A Systematic Review of Micro-CT Studies
by Shilpa Bhandi, Mohammed Mashyakhy, Abdulaziz S. Abumelha, Mazen F. Alkahtany, Mohamed Jamal, Hitesh Chohan, A. Thirumal Raj, Luca Testarelli, Rodolfo Reda and Shankargouda Patil
Materials 2021, 14(14), 4013; https://doi.org/10.3390/ma14144013 - 18 Jul 2021
Cited by 57 | Viewed by 9044
Abstract
To prevent re-infection and provide a hermetic seal of the root canal system, an endodontist must aim to produce a void-free obturation. This review aimed to compare the completeness of root canal obturation between the two most prevalent methods—cold lateral condensation and warm [...] Read more.
To prevent re-infection and provide a hermetic seal of the root canal system, an endodontist must aim to produce a void-free obturation. This review aimed to compare the completeness of root canal obturation between the two most prevalent methods—cold lateral condensation and warm gutta-percha techniques—using micro-CT (PROSPERO reg no. 249815). Materials and Methods: A search of Scopus, Embase, PubMed (Medline via PubMed), and Web of Science databases was done without any time restriction according to the PRISMA protocol. Articles that compared both techniques and were published in English were included. Data was extracted and the risk of bias was assessed using an adapted tool based on previous studies. Results: A total of 141 studies were identified by the search. Following the screening and selection of articles, 9 studies were included for review. Data was extracted manually and tabulated. Most studies had a moderate risk of bias. None determined operator skill in both methods before comparison. The data extracted from the included studies suggests that both techniques produce voids in the obturation. The thermoplasticized gutta-percha techniques may result in fewer voids compared to cold lateral condensation. Conclusion: Considering the limitations of the included studies, it was concluded that neither technique could completely obturate the root canal. Thermoplasticized gutta-percha techniques showed better outcomes despite a possible learning bias in favor of cold lateral condensation. Establishing operator skills before comparison may help reduce this bias. Full article
(This article belongs to the Special Issue Advances in Periodontics and Restorative Dental Materials)
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17 pages, 3275 KiB  
Article
Optimization of Cooling Utility System with Continuous Self-Learning Performance Models
by Ron-Hendrik Peesel, Florian Schlosser, Henning Meschede, Heiko Dunkelberg and Timothy G. Walmsley
Energies 2019, 12(10), 1926; https://doi.org/10.3390/en12101926 - 20 May 2019
Cited by 18 | Viewed by 3564
Abstract
Prerequisite for an efficient cooling energy system is the knowledge and optimal combination of different operating conditions of individual compression and free cooling chillers. The performance of cooling systems depends on their part-load performance and their condensing temperature, which are often not continuously [...] Read more.
Prerequisite for an efficient cooling energy system is the knowledge and optimal combination of different operating conditions of individual compression and free cooling chillers. The performance of cooling systems depends on their part-load performance and their condensing temperature, which are often not continuously measured. Recorded energy data remain unused, and manufacturers’ data differ from the real performance. For this purpose, manufacturer and real data are combined and continuously adapted to form part-load chiller models. This study applied a predictive optimization algorithm to calculate the optimal operating conditions of multiple chillers. A sprinkler tank offers the opportunity to store cold-water for later utilization. This potential is used to show the load shifting potential of the cooling system by using a variable electricity price as an input variable to the optimization. The set points from the optimization have been continuously adjusted throughout a dynamic simulation. A case study of a plastic processing company evaluates different scenarios against the status quo. Applying an optimal chiller sequencing and charging strategy of a sprinkler tank leads to electrical energy savings of up to 43%. Purchasing electricity on the EPEX SPOT market leads to additional costs savings of up to 17%. The total energy savings highly depend on the weather conditions and the prediction horizon. Full article
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