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Keywords = clay recycling techniques

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37 pages, 3799 KiB  
Systematic Review
Improvement of Expansive Soils: A Review Focused on Applying Innovative and Sustainable Techniques in the Ecuadorian Coastal Soils
by Mariela Macías-Párraga, Francisco J. Torrijo Echarri, Olegario Alonso-Pandavenes and Julio Garzón-Roca
Appl. Sci. 2025, 15(15), 8184; https://doi.org/10.3390/app15158184 - 23 Jul 2025
Viewed by 219
Abstract
Traditional stabilization techniques, such as lime and cement, widely used for their effectiveness, albeit with economic and environmental limitations, are leading to the search for sustainable approaches that utilize agricultural and industrial waste, such as rice husk ash, bagasse, and natural fibers. These [...] Read more.
Traditional stabilization techniques, such as lime and cement, widely used for their effectiveness, albeit with economic and environmental limitations, are leading to the search for sustainable approaches that utilize agricultural and industrial waste, such as rice husk ash, bagasse, and natural fibers. These have been shown to improve key geotechnical properties, even under saturated conditions, significantly. In particular, the combination of rice husk ash and recycled ceramics has shown notable results in Ecuadorian coastal soils. The article emphasizes the importance of selecting techniques that balance effectiveness, cost, and sustainability and identifies existing limitations, such as the lack of long-term data (ten years) and predictive models adapted to the Ecuadorian climate. From a bibliographic perspective, this article analyzes the challenges posed by expansive soils in the western coastal region of Ecuador, whose high plasticity and instability to moisture negatively affect civil works such as roads and buildings. The Ecuadorian clay contained 30% kaolinite and only 1.73% CaO, limiting its chemical reactivity compared to soils such as Saudi Arabia, which contained 34.7% montmorillonite and 9.31% CaO. Natural fibers such as jute, with 85% cellulose, improved the soil’s mechanical strength, increasing the UCS by up to 130%. Rice husk ash (97.69% SiO2) and sugarcane bagasse improved the CBR by 90%, highlighting their potential as sustainable stabilizers. All of this is contextualized within Ecuador’s geoenvironmental conditions, which are influenced by climatic phenomena such as El Niño and La Niña, as well as global warming. Finally, it is proposed to promote multidisciplinary research that fosters more efficient and environmentally responsible solutions for stabilizing expansive soils. Full article
(This article belongs to the Section Civil Engineering)
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20 pages, 4701 KiB  
Article
Effect of Rubber Particle Size and Content on the Mechanical Properties of Rubber–Clay Mixtures Solidified by EICP
by Qiang Ma, Meng Li, Chen Zeng, Hang Shu, Lei Xi, Yue Tao and Xuesong Lu
Materials 2025, 18(15), 3429; https://doi.org/10.3390/ma18153429 - 22 Jul 2025
Viewed by 255
Abstract
Using the enzyme-induced carbonate precipitation (EICP) technique to solidify rubber and clay mixtures as lightweight backfill is a feasible way to reduce waste tire impacts and boost rubber recycling in geotech engineering. In this study, a comprehensive laboratory investigation, including triaxial compression, oedometer, [...] Read more.
Using the enzyme-induced carbonate precipitation (EICP) technique to solidify rubber and clay mixtures as lightweight backfill is a feasible way to reduce waste tire impacts and boost rubber recycling in geotech engineering. In this study, a comprehensive laboratory investigation, including triaxial compression, oedometer, permeability, and nuclear magnetic resonance (NMR) tests, was conducted on EICP-reinforced rubber particle solidified clay (hereafter referred to as EICP-RC solidified clay) to evaluate the effects of rubber particle content and size on the mechanical behavior of the improved soil under various solidification conditions and to elucidate the solidification mechanism. The results show that although rubber particles inhibit EICP, they significantly enhance the mechanical properties of the samples. The addition of 5% rubber particles (rubber A) increased cohesion by 11% and the internal friction angle by 18% compared to EICP-treated clay without rubber. Additionally, incorporating smaller-sized tire particles facilitated pore filling, resulting in lower compression and swelling indices and reduced permeability coefficients, making these materials suitable for use behind retaining walls and in embankment construction. Full article
(This article belongs to the Section Construction and Building Materials)
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16 pages, 2234 KiB  
Article
Comparative Life Cycle Assessment of Warehouse Construction Systems Under Distinct End-of-Life Scenarios
by Paulo Cezar Vitorio Junior, Víctor Yepes, Fabio Onetta and Moacir Kripka
Buildings 2025, 15(9), 1445; https://doi.org/10.3390/buildings15091445 - 24 Apr 2025
Cited by 1 | Viewed by 711
Abstract
There is an increasing demand to replace traditional construction techniques with more sustainable systems that can reduce environmental impacts. Emissions are typically assessed only in carbon dioxide and embodied energy terms, yet these metrics alone cannot fully capture the overall impact generated. This [...] Read more.
There is an increasing demand to replace traditional construction techniques with more sustainable systems that can reduce environmental impacts. Emissions are typically assessed only in carbon dioxide and embodied energy terms, yet these metrics alone cannot fully capture the overall impact generated. This study provides a comparative Life Cycle Assessment (LCA) of three steel warehouse projects with varying cladding systems: steel walls (SW), steel-clay brick walls (SClaW), and steel-concrete block walls (SConW). Life Cycle Assessment (LCA) methodology was used to assess the environmental impact of materials used during the whole life cycle. The study used the software program SimaPro (System for Integrated Environmental Assessment of Products) version 9.6.0.1, with data extracted from the international Ecoinvent database. ReCiPe Midpoint approach were adopted to assess potential impacts. The results indicate that the SW project under end-of-life Scenario 2—waste recycling—exhibited the lowest impacts across most categories, followed by the SConW and SClaW projects. The findings emphasize the environmental benefits of utilizing steel cladding systems over brick or concrete masonry and considering recycling as the end of life of the materials. Additionally, the study provides insights into the significance of material choices in minimizing environmental impact on human health, resource availability, and ecosystems. Full article
(This article belongs to the Section Building Energy, Physics, Environment, and Systems)
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26 pages, 16070 KiB  
Article
Comparison of Field and Laboratory Tests for Soil Suitability Assessment in Raw Earth Construction
by Jacqueline Saliba, Walid Al-Shaar and Madeline Delage
Appl. Sci. 2025, 15(4), 1932; https://doi.org/10.3390/app15041932 - 13 Feb 2025
Cited by 1 | Viewed by 1532
Abstract
The demand for earth construction, primarily driven by environmental considerations, is currently growing. Earth, as a building material, has a very low carbon footprint and is easily recyclable, promoting a circular economy. It is also valued for its intrinsic qualities such as hygrothermal [...] Read more.
The demand for earth construction, primarily driven by environmental considerations, is currently growing. Earth, as a building material, has a very low carbon footprint and is easily recyclable, promoting a circular economy. It is also valued for its intrinsic qualities such as hygrothermal properties, air quality, acoustic performance, and esthetics. To meet this demand and promote earth construction, a better understanding of the local resources is essential. However, not all soils are suitable for earth construction, and their properties can significantly influence the final material performance. The assessment of soil suitability for earth construction requires both scientific rigor and practical field applicability. This study evaluates the correlation between traditional field-testing methods and standardized laboratory analyses through a comprehensive characterization of 39 soils from the Nouvelle-Aquitaine region in France. The research methodology integrated different field tests commonly used by practitioners, including sensory evaluations, plasticity tests, and cohesion assessments, with five standardized geotechnical tests covering particle size distribution, Atterberg limits, methylene blue value, organic matter content, and density measurements. The particle size distribution analysis revealed diverse soil compositions, with clay-sized particle content (<0.002 mm) ranging from 5% to 75%. Strong correlations were established between field and laboratory results, particularly between the cigar test and plasticity index (R2 = 0.8863), and between ring test scores and clay-sized particle content percentages, validating the reliability of traditional testing methods. Plasticity indices varied from 0% to 50%, indicating different soil behaviors and potential applications. These correlations demonstrate that while traditional field tests provide reliable preliminary assessment tools, laboratory testing remains essential for final material validation. The results demonstrate that while several soils are directly suitable for various earth construction techniques, other soils falling outside conventional recommendation envelopes may still be suitable for specific construction techniques when appropriately evaluated and may require modification through sieving, mixing, or stabilization. Full article
(This article belongs to the Section Civil Engineering)
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25 pages, 25475 KiB  
Article
Prediction of Strength Properties of Reinforced and Stabilized Sandy Soil as a Building Foundation Material
by Mohammad Mostafa Jafari, Mohammad Hossein Bagheripour and Ehsan Yaghoubi
Buildings 2025, 15(3), 382; https://doi.org/10.3390/buildings15030382 - 26 Jan 2025
Cited by 1 | Viewed by 1223
Abstract
Sandy soils are a type of geomaterial that may require improvements due to lack of cohesion. In this study, first, the lack of cohesion of sand was resolved using clay, and the soil was stabilized with cement and lime (4% and 3% of [...] Read more.
Sandy soils are a type of geomaterial that may require improvements due to lack of cohesion. In this study, first, the lack of cohesion of sand was resolved using clay, and the soil was stabilized with cement and lime (4% and 3% of the dry weight of materials, respectively) and finally reinforced with recycled tire fibers of 20 to 30 mm in length for improved strength and ductility. Next, 747 samples with different fiber contents at different curing temperatures and ages were prepared and a unconfined compressive strength (UCS) test was carried out. Next, a novel approach employing multivariate nonlinear regression techniques and obtained empirical data was applied to formulate a mathematical model for predicting the UCS and the modulus of elasticity (Es) of the reinforced and stabilized soil. This model can serve as a valuable tool for building engineers in designing building foundations. The comparison of the obtained UCS and Es results and those predicted using the proposed model showed a correlation of >95% (R2 ≥ 0.95). The fibers effectively increased the failure strain, thus resulting in the greater ductility of the samples. As an example, in 14-day samples cured at 60 °C with 0%, 0.4%, 1%, 1.7%, and 2.5% fibers, the failure strain showed an incremental trend of 1.47%, 1.87%, 2.08%, 2.20%, and 2.92%, respectively. Scanning electron microscopy (SEM) was used to study the microstructure of the samples and to explain the strength experimental outcomes. SEM images showed a desirable interaction between the fiber surfaces with the soil mass and the reduction in porosity and the occurrence of pozzolanic reactions through stabilization. The results also showed that the reinforcement effectively improved the ductility, as desired for building foundations; however, it resulted in reduced strength, although a greater strength compared to the untreated soil was achieved. Although soil stabilization has been widely studied, limited research focuses on stabilizing soil with clay, lime, cement, and recycled tire fibers. This study offers design engineers an estimation scheme of the strength properties of stabilized and reinforced foundations. Full article
(This article belongs to the Special Issue The Durability of Innovative Construction Materials and Structures)
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20 pages, 2648 KiB  
Review
Recycling Clay Waste from Excavation, Demolition, and Construction: Trends and Challenges
by Liliana Carolina Hernández García, Sergio Neves Monteiro and Henry A. Colorado Lopera
Sustainability 2024, 16(14), 6265; https://doi.org/10.3390/su16146265 - 22 Jul 2024
Cited by 6 | Viewed by 4344
Abstract
The recycling of clay waste from construction debris highly depends on the chemical and mineralogical composition of the waste. Clays and clay minerals are known to be among marginal construction waste, representing an interesting opportunity and platform to produce other low-cost and low-carbon [...] Read more.
The recycling of clay waste from construction debris highly depends on the chemical and mineralogical composition of the waste. Clays and clay minerals are known to be among marginal construction waste, representing an interesting opportunity and platform to produce other low-cost and low-carbon materials due to their possibilities for functional material design, such as adsorbents, drug delivery, catalysts and photocatalysts, and nanocomposites. The present review analyzes a wide variety of mechanisms for encapsulating organic and inorganic species between the layers of clay minerals. Through the compilation of advances in acid activation, exchange of inorganic cations, intercalation, and pillarization, new applications for clay materials are generated, paving the way to a nanometric world with functional, magnetic, adsorption, and catalytic capabilities. New trends are consolidated in the reuse of recycled clays in infrastructure projects, such as hydraulic concrete, water purification, soil fertility, pigments and paints, food packaging and storage, and ceramic appliances. It is concluded that clay waste is suitable to reuse in many industrial products and construction materials, enabling a reduction in the consumption of raw materials. Full article
(This article belongs to the Special Issue Recycling Materials for the Circular Economy—2nd Edition)
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18 pages, 5777 KiB  
Article
Improved Artificial Aggregates for Use in Green Roof Design
by Agata Stempkowska and Tomasz Gawenda
Sustainability 2024, 16(13), 5512; https://doi.org/10.3390/su16135512 - 28 Jun 2024
Cited by 5 | Viewed by 1716
Abstract
The development of surfaces in cities, as a result of progressive urbanization, not only reduces the natural retention capacity of the environment but also causes changes in the water balance. In urbanized areas, the amount and intensity of rainwater discharged to receivers increase, [...] Read more.
The development of surfaces in cities, as a result of progressive urbanization, not only reduces the natural retention capacity of the environment but also causes changes in the water balance. In urbanized areas, the amount and intensity of rainwater discharged to receivers increase, and the time of water outflow from the catchment area shortens. Low retention does not provide effective responses to the local water deficit and does not limit the effects of excess water during flood periods. Furthermore, aging drainage systems do not always have the required hydraulic efficiency in absorbing runoff after intense and heavy rainfall or snowmelt. The aim of the work was to determine the possibility of obtaining flat aggregates with a grain size of 2–16 mm from clay-silt fractions from sedimentation tanks using selected mechanical processing methods (crushing and screening in a crusher-screener system with recycling). An important issue was the examination of the physical and mechanical properties of the produced aggregates after firing, where the work required a detailed material analysis using various research techniques, such as XRD, XRF, SEM and digital microscopy. The obtained results will allow for further research on developing the concept of technology for the production of lightweight aggregates used, for example, on building roofs. Particular attention was paid to the flat shape of the aggregate, which affects a number of its properties. To obtain a flat-shaped aggregate, the authors used a patented sieving method. The obtained materials had high cavernosity of 69% on average, water absorption of 40.7% and low bulk density of 0.82 g/cm3. Full article
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17 pages, 6456 KiB  
Article
Permeable Reactive Barrier Remediation Technique Using Carbonized Food Waste in Ground Contaminated with Combined Cu and Pb
by Dong-Nam Kim, Ji-Yoon Kim, Jong-Young Lee, Jung-Geun Han and Dong-Chan Kim
Sustainability 2024, 16(11), 4794; https://doi.org/10.3390/su16114794 - 4 Jun 2024
Cited by 1 | Viewed by 1689
Abstract
In recent years, with the escalation of food waste generation, stringent legal constraints on landfill usage and incineration have necessitated the exploration of alternative disposal methods, augmenting interest in diverse recycling strategies. Notably, carbonized food waste (CFW), a byproduct of food waste carbonization, [...] Read more.
In recent years, with the escalation of food waste generation, stringent legal constraints on landfill usage and incineration have necessitated the exploration of alternative disposal methods, augmenting interest in diverse recycling strategies. Notably, carbonized food waste (CFW), a byproduct of food waste carbonization, has emerged as an efficacious adsorbent for pollutant removal. This study focuses on the application of in situ remediation techniques, specifically electrokinetic (EK) remediation combined with enhancers, to decontaminate soil afflicted with single or multiple heavy metals. The utilization of a permeable reactive barrier (PRB) infused with CFW aims to mitigate secondary environmental repercussions, including the propagation of contaminants in soil and groundwater. Experiments were conducted on clay samples contaminated with copper, lead, or a combination thereof. Observations revealed that the current density peaked during the initial 1–2 days of the experiment, experienced a resurgence post-electrode exchange, and subsequently diminished. The efficacy of metal removal was predominantly pronounced for copper, with remediation rates ranging from 85% to 92% in singly contaminated samples and 75% to 89% in dually contaminated samples after a 10-day treatment period, incorporating an electrode exchange on the eighth day. Conversely, the efficacy of lead removal was markedly lower, with rates of 0.6% to 33% in singly contaminated samples and 14% to 25% in combined contamination scenarios, suggesting the necessity for extended treatment durations. The post-experimental moisture content indicated successful enhancer injection. Additionally, pH measurements affirmed that heavy metals migrated effectively within the sample matrix, facilitated by the EK phenomenon after the electrode exchange. This study highlights the potential of CFW within PRBs for the remediation of heavy metal-contaminated soils, although the removal efficiencies between different metals is variable, emphasizing the need for tailored approaches in the treatment of lead-contaminated environments. Full article
(This article belongs to the Special Issue Toxic Effects of Heavy Metals and Microplastics in Soil)
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16 pages, 6288 KiB  
Article
Using 5TE Sensors for Monitoring Moisture Conditions in Green Parks
by Muawia Dafalla
Sensors 2024, 24(11), 3479; https://doi.org/10.3390/s24113479 - 28 May 2024
Cited by 3 | Viewed by 1202
Abstract
The ground surface and subsurface of green parks in arid and desert areas may be subjected to desiccation as a result of weather and hot temperatures. It is not wise to wait until plants are turning pale and yellow before watering is resumed. [...] Read more.
The ground surface and subsurface of green parks in arid and desert areas may be subjected to desiccation as a result of weather and hot temperatures. It is not wise to wait until plants are turning pale and yellow before watering is resumed. Given the scarcity of water in typical desert zones, we recommend full control of irrigation water. This study presents a method of recycling irrigation water using 5TE sensors, employing time-domain reflectometry (TDR) technology. A trial test section was constructed along the coast of the eastern province of Saudi Arabia. Water recycling involves using clay–sand liners placed below the top agricultural soils to intercept excess water and direct it towards a collection tank, and then it is pumped out to a major water supply tank. The main properties of soils and clay–sand liners normally taken into account include moisture content, density, and hydraulic conductivity. An assessment of geotechnical properties of clay–sand mixtures containing 20% clay content was conducted. The profiles of moisture and temperature changes were monitored using 5TE sensors and data loggers. The 5TE sensors provided continuous measurements at varying temperatures and watering cycles. Twenty-nine watering cycles were conducted over a six-month period. An additional section was considered with a liner consisting of the same clay but enhanced with bentonite as one-third of the clay content. The volumetric water content was found to vary from 0.150 to 0.565 following changing weather and direct watering cycles. The results indicated that the use of a TDR instrumentation is a cost-effective and time-saving technique to construct a system for saving irrigation water. Full article
(This article belongs to the Section Environmental Sensing)
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17 pages, 4481 KiB  
Article
Effects of Clay Minerals on Enzyme Activity as a Potential Biosensor of Soil Pollution in Alice Township
by Nontobeko Gloria Maphuhla and Opeoluwa Oyehan Oyedeji
Waste 2024, 2(1), 85-101; https://doi.org/10.3390/waste2010005 - 9 Feb 2024
Cited by 2 | Viewed by 1846
Abstract
Inadequate waste management and illegal trash dumping continue to be the leading causes of severe environmental pollution. Human exposure to harmful heavy metals has emerged as a serious health concern on the continent. Some people in Alice, a small town, grow their food [...] Read more.
Inadequate waste management and illegal trash dumping continue to be the leading causes of severe environmental pollution. Human exposure to harmful heavy metals has emerged as a serious health concern on the continent. Some people in Alice, a small town, grow their food in home gardens. They use animal manure and compost derived from soil obtained from landfills to enhance the fertility of the garden soil. Heavy metal heaps in garbage disposals are constantly present, releasing dangerous amounts of metal into the environment. The harmful effects of heavy metals on plants lead to unsanitary conditions and environmental problems. Animals and people who consume these vegetables may also be at risk for health problems. Assessing the soil’s enzyme activity can potentially lessen the negative effects of the accumulated pollutants and improve the soil’s overall health and quality. Soil enzymes are biologically active components that have a catalytic impact and are released from root exudates, crop residues, and animal remains. The activity of enzymes serves as an excellent bioindicator of soil cleanliness and quality because they are sensitive to heavy metals. X-ray diffraction (XRD) was used to quantify the mineral elements in soil using 40 kV parallel beam optics, 30 mA, and CuKα radiation. Meanwhile, the activity of the enzyme was essayed in different coupled substrates. Thirteen (13) clay minerals were found, including Talc 2M, Kaolinite 2M, and Chlorite Lawsonite Muscovite 2M1. The detected trace elements have high concentration levels that exceed the World Health Organization’s (WHO) allowed levels. The identified elements affected the enzyme activity at different levels. The Mn, Al, Si, V, Ti, and Ca negatively affect soil enzyme activity, specifically invertase (INV). However, the amount of Mg, K, Fe, and Zn showed a slightly positive effect on the same enzyme (INV). According to this view, these elements come from several sources, each with a particular impact on soil contamination and enzyme activity. High levels of heavy metals in this study may be due to improper waste disposal, limited recycling opportunities, lack of public awareness, and inadequate enforcement of waste management regulations. It is essential to employ Fourth Industrial Revolution (4IR) technologies, correct disposal techniques, suitable agricultural methods, preventive regulations, and efficient waste management to mitigate the negative effects of heavy metals on the environment. Full article
(This article belongs to the Special Issue Solid Waste Management and Environmental Protection)
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19 pages, 4618 KiB  
Article
Assessing the Effects of Refuse-Derived Fuel (RDF) Incorporation on the Extrusion and Drying Behavior of Brick Mixtures
by Ioannis Makrygiannis, Athena Tsetsekou, Orestis Papastratis and Konstantinos Karalis
Ceramics 2023, 6(4), 2367-2385; https://doi.org/10.3390/ceramics6040145 - 14 Dec 2023
Cited by 2 | Viewed by 2440
Abstract
This study explores the potential benefits of incorporating Recycled Demolition Waste (RDF) as an additive in ceramic mass for the brick industry, with a focus on applications such as thermoblocks. The research underscores the significance of sustainable waste management practices and environmental conservation [...] Read more.
This study explores the potential benefits of incorporating Recycled Demolition Waste (RDF) as an additive in ceramic mass for the brick industry, with a focus on applications such as thermoblocks. The research underscores the significance of sustainable waste management practices and environmental conservation by diverting waste from landfills. RDF, exhibiting combustion properties above 550 °C, emerges as a valuable candidate for enhancing clay-based materials, particularly in the brick production process where firing temperatures exceed 850 °C. Conducted in two phases, the research initially concentrated on RDF preparation, RDF integration with clay materials, and its influence on extrusion and drying phases. Employing innovative techniques involving brick and tile industry machinery coupled with sand incorporation yielded promising results. The grounding of RDF particles to less than 1 mm not only facilitated the mixing process but also ensured stable grinding temperatures within the hammer mill, reducing operational costs. During extrusion, challenges associated with unprocessed RDF material were addressed by utilizing ground RDF, leading to a more efficient and cost-effective process with enhanced plasticity and reduced water requirements. Practical implications for brick plant operations were identified, promoting resource and energy savings. Drying behavior analysis revealed the positive impact of RDF integration, showcasing reduced sensitivity, decreased drying linear shrinkage, and improved density properties. RDF’s role as an inert additive resulted in a 5% reduction in density, enhancing porosity and thermal insulation properties, particularly in thermoblock applications. In the brick industry, where durability, thermal performance, and cost-efficiency are paramount, this study emphasizes the potential benefits of incorporating RDF into clay-based materials. While further research is needed to address the firing procedure of RDF as a brick mass additive, the initial findings underscore the promise of this approach for sustainable and environmentally responsible brick production. This study contributes to the literature by shedding light on the advantages and challenges of integrating RDF into clay-based products, supporting sustainability and waste reduction in construction and manufacturing. The findings provide valuable insights into the performance and feasibility of these mixtures, offering crucial information for industries striving to adopt eco-conscious production methods. This article not only outlines the applied methodology and experimental setup but also presents results related to the behavior of RDF-inclusive clay block mixtures in the production environment. Anticipated to exert considerable influence on future practices and policies, this research contributes to the growing body of knowledge concerning eco-friendly and sustainable manufacturing processes. Full article
(This article belongs to the Special Issue Advances in Ceramics, 2nd Edition)
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25 pages, 2360 KiB  
Hypothesis
The Industrialisation of Sustainable Construction: A Transdisciplinary Approach to the Large-Scale Introduction of Compacted Mineral Mixtures (CMMs) into Building Construction
by Michael Max Bühler, Pia Hollenbach, Alexander Michalski, Sonja Meyer, Emanuel Birle, Rebecca Off, Christina Lang, Wolfram Schmidt, Roberto Cudmani, Oliver Fritz, Guido Baltes and Geraldine Kortmann
Sustainability 2023, 15(13), 10677; https://doi.org/10.3390/su151310677 - 6 Jul 2023
Cited by 12 | Viewed by 2653
Abstract
Increasing demand for sustainable, resilient, and low-carbon construction materials has highlighted the potential of Compacted Mineral Mixtures (CMMs), which are formulated from various soil types (sand, silt, clay) and recycled mineral waste. This paper presents a comprehensive inter- and transdisciplinary research concept that [...] Read more.
Increasing demand for sustainable, resilient, and low-carbon construction materials has highlighted the potential of Compacted Mineral Mixtures (CMMs), which are formulated from various soil types (sand, silt, clay) and recycled mineral waste. This paper presents a comprehensive inter- and transdisciplinary research concept that aims to industrialise and scale up the adoption of CMM-based construction materials and methods, thereby accelerating the construction industry’s systemic transition towards carbon neutrality. By drawing upon the latest advances in soil mechanics, rheology, and automation, we propose the development of a robust material properties database to inform the design and application of CMM-based materials, taking into account their complex, time-dependent behaviour. Advanced soil mechanical tests would be utilised to ensure optimal performance under various loading and ageing conditions. This research has also recognised the importance of context-specific strategies for CMM adoption. We have explored the implications and limitations of implementing the proposed framework in developing countries, particularly where resources may be constrained. We aim to shed light on socio-economic and regulatory aspects that could influence the adoption of these sustainable construction methods. The proposed concept explores how the automated production of CMM-based wall elements can become a fast, competitive, emission-free, and recyclable alternative to traditional masonry and concrete construction techniques. We advocate for the integration of open-source digital platform technologies to enhance data accessibility, processing, and knowledge acquisition; to boost confidence in CMM-based technologies; and to catalyse their widespread adoption. We believe that the transformative potential of this research necessitates a blend of basic and applied investigation using a comprehensive, holistic, and transfer-oriented methodology. Thus, this paper serves to highlight the viability and multiple benefits of CMMs in construction, emphasising their pivotal role in advancing sustainable development and resilience in the built environment. Full article
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19 pages, 4418 KiB  
Article
Management of Agricultural Water Containing Acetimidothioic Acid Pesticide through Catalytic Oxidation to Facilitate Reclaimed Water Recycling for Sustainable Food Production
by Ehssan Ahmed Hassan, Maha A. Tony, Hossam A. Nabwey and Mohamed M. Awad
Processes 2023, 11(3), 792; https://doi.org/10.3390/pr11030792 - 7 Mar 2023
Viewed by 1733
Abstract
Agro-industrial discharge contains acetimidothioic acid, which is commercially named “Lanox 90” and is a widely applied insecticide in greenhouses, and the result is wastewater loaded with this insecticide. Treating such wastewater is a must to reduce the environmental impact as well as to [...] Read more.
Agro-industrial discharge contains acetimidothioic acid, which is commercially named “Lanox 90” and is a widely applied insecticide in greenhouses, and the result is wastewater loaded with this insecticide. Treating such wastewater is a must to reduce the environmental impact as well as to facilitate the opportunity for water recycling. Thus, the present work introduced Montmorillonite (MMT) clay as a novel Fenton reaction source to treat wastewater loaded with Lanox 90 insecticide as a benign sustainable strategy. Scanning electron microscopy (SEM) supported with energy-dispersive X-ray spectroscopy (EDX) and Fourier-transform infrared spectroscopy (FTIR) were used to characterize the MMT sample. Response surface methodology based on Box–Behnken analysis was selected to optimize the parametric circumstances. The optimized parameters of the proposed technique were obtained at a pH of 2.6 with the addition of 0.8 and 854 mg/L of MMT and H2O2, respectively, to attain the highest predicted Lanox 90 removal rate of 97%. Analysis of variance (ANOVA) was used to examine the statistical data and displayed a significant quadratic model. Ultimately, the results reveal that the oxidation system is exothermic and has a non-spontaneous nature, and the reaction kinetics are categorized according to the second-order reaction kinetic rate. The results of the current study indicate the importance of MMT for treating wastewater. These results confirm the possibility of using oxidation technique as a suitable candidate for greenhouse effluent management to enhance the efficiency of water recycling for smart irrigation. Full article
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18 pages, 1587 KiB  
Article
Decision Support Models for Site Remediation: An Evaluation of Industry Practice in China
by Na Song, Andrew Hursthouse, Iain Mclellan and Zhenghua Wang
Sustainability 2022, 14(19), 11811; https://doi.org/10.3390/su141911811 - 20 Sep 2022
Cited by 1 | Viewed by 2174
Abstract
China is currently facing great challenges in preventing land from further contamination by industrial activity. We evaluated the current state of business activity supporting the prevention and control of soil pollution through good waste management practice to restrict further soil contamination. The study [...] Read more.
China is currently facing great challenges in preventing land from further contamination by industrial activity. We evaluated the current state of business activity supporting the prevention and control of soil pollution through good waste management practice to restrict further soil contamination. The study focused on understanding drivers to improve the development of business activity in both waste management and remediation sectors in China. The status of organizations which manage solid waste and industrial operations providing remediation, professional materials, equipment, and approaches to site management are highlighted. Using questionnaires and a limited number of follow-up interviews, we consulted with remediation practitioners (>100 respondents including construction contracting workers, consultancy, equipment suppliers, and government department employees) working across China. The results identified that the site risk assessment and the wider construction phases for site remediation are typically based on guidelines from government and/or local government. The most frequently used materials for solidification or stabilization during remediation were clay minerals. Local government funds financed most remediation activities. Waste recycling would be a path to further reduce pollution from site development and its application in remediation techniques is possible. In addition to remediation methods, a strategic framework can be employed to provide decision support when assessing sites or decision-making for remediation projects. The priorities for remediation highlight that two types of soil use (arable land and land for construction) should be prioritized for remediation. This evaluation of industry practice provides useful models for wider decision-making in site remediation. Full article
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11 pages, 1970 KiB  
Article
Adsorption of Methyl Orange on a Novel Palygorskite/UiO-66 Nanocomposite
by Ioanna A. Vasiliadou, Thaleia Ioannidou, Maria Anagnostopoulou, Antonios Polyzotou, Dimitrios Papoulis and Konstantinos C. Christoforidis
Appl. Sci. 2022, 12(15), 7468; https://doi.org/10.3390/app12157468 - 25 Jul 2022
Cited by 8 | Viewed by 2446
Abstract
Herein, a novel composite material containing UiO-66 and palygorskite (Pal) clay mineral was prepared using a facile one-pot synthesis process. The material was studied using a variety of techniques and applied as did not affect the structure of the metal-organic framework (MOF) part, [...] Read more.
Herein, a novel composite material containing UiO-66 and palygorskite (Pal) clay mineral was prepared using a facile one-pot synthesis process. The material was studied using a variety of techniques and applied as did not affect the structure of the metal-organic framework (MOF) part, but induced a small increase in specific surface area. The developed Pal/UiO-66 composite presented excellent adsorption efficiency against MO removal, as evidenced by detailed kinetic and isotherm experiments. An impressive maximum adsorption capacity at equilibrium was evidenced; 340 mg g−1 at pH = 5 and T = 25 °C. This corresponds to a 34.5 % increase compared with pure UiO-66, considering only the MOF content. Furthermore, the Pal/UiO-66 composite was proven stable and highly recyclable, losing less than 9% of the removal capacity after five consecutive cycles. The study highlights the synergistic effect of the coupling of MOF structures with low-cost and abundant clay minerals for the development of advanced absorbents. Full article
(This article belongs to the Special Issue Synthesis and Applications of Metal-Organic Frameworks (MOFs))
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