Search Results (274)

With the advance of digital transformation, the assessment of the environmental impact of digital tools and technologies grows more relevant. Considering the inflated expectations of environmental responsibility in higher education, this study analyses how websites of Polish universities conform to sustainable web design criteria. The sustainability audit employed a methodology encompassing carbon emissions measurement, technical website analysis, and SEO evaluation. The author analysed 63 websites of public universities in Poland using seven independent audit tools, including an original AI Custom GPT agent preconfigured in the ChatGPT ecosystem. The results revealed a substantial differentiation in CO₂ emissions and website optimisation, with an average EcoImpact Score of 66.41/100. Nearly every fourth website exhibited a significant carbon footprint and excessive component sizes, which indicates poor asset optimisation and energy-intensive design techniques. The measurements exposed considerable variability in emission intensities and resource intensity among the university websites, suggesting the need for standardised digital sustainability practices. Regulations on the carbon footprint of public institutions’ websites and mobile applications could become vital strategic components for digital climate neutrality. Promoting green hosting, “Green SEO” practices, and sustainability audits could help mitigate the environmental impact of digital technologies and advance sustainable design standards for the public sector. The proposed auditing methodology can effectively support the institutional transition towards sustainable management of digital infrastructure by integrating technical, sustainability, and organisational aspects. Full article

Due to the complex mineral composition, low clay content, and strong heterogeneity of the mixed sedimentary shale in the Xinjiang Salt Lake Basin, the wettability characteristics of the reservoir and their influencing factors are not yet clear, which restricts the evaluation of oil-bearing properties and the identification of sweet spots. This paper analyzed mixed sedimentary shale samples from the Lucaogou Formation of the Jimsar Sag and the Fengcheng Formation of the Mahu Sag. Methods such as petrographic thin sections, X-ray diffraction, organic matter content analysis, and argon ion polishing scanning electron microscopy were used to examine the lithological and mineralogical characteristics, geochemical characteristics, and pore space characteristics of the mixed sedimentary shale reservoir. Alternating imbibition and nuclear magnetic resonance were employed to quantitatively characterize the wettability of the reservoir and to discuss the effects of compositional factors, lamina types, and pore structure on wettability. Research findings indicate that the total porosity, measured by the alternate imbibition method, reached 72% of the core porosity volume, confirming the effectiveness of alternate imbibition in filling open pores. The Lucaogou Formation exhibits moderate to strong oil-wet wettability, with oil-wet pores predominating and well-developed storage spaces; the Fengcheng Formation has a wide range of wettability, with a higher proportion of mixed-wet pores, strong heterogeneity, and weaker oil-wet properties compared to the Lucaogou Formation. TOC content has a two-segment relationship with wettability, where oil-wet properties increase with TOC content at low TOC levels, while at high TOC levels, the influence of minerals such as carbonates dominates; carbonate content shows an “L” type response to wettability, enhancing oil-wet properties at low levels (<20%), but reducing it due to the continuous weakening effect of minerals when excessive. Lamina types in the Fengcheng Formation significantly affect wettability differentiation, with carbonate-shale laminae dominating oil pores, siliceous laminae contributing to water pores, and carbonate–feldspathic laminae forming mixed pores; the Lucaogou Formation lacks significant laminae, and wettability is controlled by the synergistic effects of minerals, organic matter, and pore structure. Increased porosity strengthens oil-wet properties, with micropores promoting oil adsorption through their high specific surface area, while macropores dominate in terms of storage capacity. Wettability is the result of the synergistic effects of multiple factors, including TOC, minerals, lamina types, and pore structure. Based on the characteristic that oil-wet pores account for up to 74% in shale reservoirs (mixed-wet 12%, water-wet 14%), a wettability-targeted regulation strategy is implemented during actual shale development. Surfactants are used to modify oil-wet pores, while the natural state of water-wet and mixed-wet pores is maintained to avoid interference and preserve spontaneous imbibition advantages. The soaking period is thus compressed from 30 days to 3–5 days, thereby enhancing matrix displacement efficiency. Full article

Fruits and vegetables are crucial components of a healthy diet, which are susceptible to pests. Therefore, the application of pesticides is a basic manner of crop chemical protection. The aim of this study was a comprehensive analysis of pesticide occurrence in 1114 samples of fruits and vegetables. A unified multi-analytical protocol was used composed of primary–secondary amine/graphitized carbon black/magnesium sulfate to purify samples with diversified profile of interfering substances. Moreover, the obtained analytical data were used to evaluate the critical acute health risk in subpopulations of children and adults within European limits criteria. Out of 550 pesticides analyzed, 38 and 69 compounds were noted in 58.6% of fruits and 44.2% of vegetables, respectively. Acetamiprid (14.1% of all detections) and captan (11.3%) occurred the most frequently in fruits, while pendimethalin (10.6%) and azoxystrobin (8.6%) occurred the most frequently in vegetables. A total of 28% of vegetable and 43% of fruit samples were multiresidues with up to 13 pesticides in dill, reaching a final concentration of 0.562 mg kg⁻¹. Maximum residue level (MRL) was exceeded in 7.9% of fruits and 7.3% of vegetables, up to 7900% MRL for chlorpyrifos in dill (0.79 mg kg⁻¹). Notably, 8 out of 38 pesticides found in fruits (21%; 1.2% for carbendazim) and 24 out of 69 compounds in vegetables (35%, 7.4% for chlorpyrifos) were not approved in the EU. Concentrations of pesticides exceeding MRL were used to assess acute health risk for children and adults. Moreover, the incidence of acute health risk was proved for children consuming parsnip with linuron (156%). In other cases, it was below 100%, indicating that Polish food is safe. The work provides reliable and representative scientific data on the contamination of fruits and vegetables with pesticides. It highlights the importance of legislative changes to avoid the occurrence of not approved pesticides in the EU, increasing food and health safety. Full article

The use of geothermal energy is gaining strategic importance in the context of sustainable development and the decarbonisation of local energy systems. As a stable and low-emission renewable energy source, geothermal energy offers tangible environmental and social benefits, including improved air quality, reduced greenhouse gas emissions, and enhanced energy independence. This article presents a comprehensive overview of the social dimensions of geothermal energy deployment in Poland, with a particular focus on environmental impacts, public acceptance, and participatory governance. Based on a Polish geothermal district heating system example, the paper demonstrates that geothermal projects can significantly reduce local pollution and support low-carbon economic transitions. The study includes a comparative assessment of avoided emissions, a critical discussion of potential social barriers, and SWOT and PESTEL analyses identifying systemic enablers and constraints. The authors argue that for geothermal energy to fulfil its sustainability potential, it must be supported by inclusive planning, transparent communication, and a holistic policy framework integrating environmental, technological, and social criteria. Full article

Water pollution is a global concern, especially due to iron and manganese, which, at high concentrations, affect water quality by altering taste, odor, and color. This work explores the sustainable synthesis of hydrochar from orange peel and bagasse using hydrothermal carbonization (HTC) and a 2³ factorial design to optimize Fe²⁺ and Mn²⁺ removal for water treatment polishing. HTC was performed by varying (1) temperature (100–200 °C), (2) residence time (8–14 h), and (3) activation agent (H₃PO₄ or NaOH), with a central point at 150 °C for 11 h without activation. Characterization was performed using FTIR, TGA, SEM, nitrogen adsorption (BET) for surface area determination, elemental analysis, Brønsted acidity measurements, and zeta potential analysis. The hydrochar synthesized at 100 °C for 14 h with NaOH (HC6) showed the best Fe²⁺ and Mn²⁺ removal performance. The equilibrium time was 400 min, with pseudo-first-order kinetics best fitting the Fe²⁺ adsorption data, while pseudo-second-order kinetics provided the best fit for Mn²⁺ adsorption. The adsorption process was best described by the Freundlich and Langmuir isotherms, with maximum adsorption capacities (q_max) of 21.44 and 33.67 mg g⁻¹ for Fe²⁺ and Mn²⁺, respectively. It can be concluded that HTC-derived hydrochars offer a sustainable and efficient solution for Fe²⁺ and Mn²⁺ removal. This strategy presents a potentially valuable approach for sustainable water treatment, offering advantages for industrial application by operating at lower temperatures and eliminating the need for biomass drying, thereby reducing energy consumption and environmental impact. Full article

The “carbon neutral power generation” policy of the European Union requires the phasing out of fossil fuel power plants. These plants still play a crucial role in the energy mix in many countries; therefore, efforts are put forward to lower their CO₂ emissions. The available solution for an existing coal plant is the implementation of biomass co-firing, which allows it to reduce twice its carbon footprint in order to achieve the level of natural gas plants, which are preferable on the way to zero-emission power generation. However the side effect is a significant increase in the bulk fuel volumes that are acquired, handled, and finally supplied to the power plant units. A necessary extension of the complex logistic system for unloading, quality tagging, storing, and transporting biomass may increase the plant’s noise emissions beyond the allowed thresholds. For a comprehensive assessment of the concept of expanding the power plant’s biofuel supply system (BSS), a discrete simulation model was built to dimension system elements and verify the overall correctness of the proposed solutions. Then, a dedicated noise emission model was built for the purposes of mandatory environmental impact assessment procedures for the planned expansion of the BSS. The noise model showed the possibility of exceeding the permissible noise levels at night in selected locations. The new simulations of the BSS model were used to analyze various scenarios of biomass supply with regard to alternative switching off the selected branches of the whole BSS. The length of the queue of unloaded freight trains delivering an average quality biomass after a period of 2 weeks is used as a key performance parameter of the BSS. A queue shorter than 1 freight train is accepted. Assuming the rising share of RESS in the Polish energy mix, the thermal plant’s 2-week average power output shall not exceed 70% of its maximum capacity. The results of the simulations indicate that under these constraints, the biofuel supplies can be sufficient regardless of the nighttime stops, if 50% of the supplied biomass volumes are delivered by trucks. If the trucks’ share drops to 25%, the plant’s 2-week average power output is limited to 45% of its maximum power. The use of digital spatial simulation models for a complex, cyclical-continuous transport system to control its operation is an effective method of addressing environmental conflicts at the design stage of the extension of industrial installations in urbanized areas. Full article

Digital twin (DT) is a useful tool for the remote monitoring, analyzing, controlling, etc. of industrial equipment in a harsh working environment unfriendly to human workers. Although much research has been devoted to DT modeling methods, there are still limitations. For example, (1) existing DT modeling methods are usually focused on specific types of equipment rather than being generally applicable to different types of equipment and requirements. (2) Existing DT models usually emphasize working condition monitoring and have relatively limited capability for modeling the operation and maintenance mechanism of the equipment for further decision making. (3) How to integrate artificial intelligence algorithms into DT models still requires further exploration. In this regard, a systematic and general DT modeling method is proposed for the remote monitoring and intelligent maintenance of industrial equipment. The DT model contains a multi-modal digital model, a multi-layer status model, and an intelligent interaction model driven by a kind of human-readable/computer-deployable event-state knowledge graph. Using the model, the dynamic workflows, working mechanisms, working status, workpiece logistics, monitoring data, and intelligent functions, etc., during the remote monitoring and maintenance of industrial equipment can be realized. The model was verified through three different DT modeling scenarios of a robot-based carbon block polishing processing line. Full article

We studied the chemical composition and morphostructural features of micron and submicron-sized particles of native gold in apocarbonate tremolite–diopside skarns of the Ryabinovoye deposit located on the southeastern margin of the Aldan Shield (Far East, Russia). Polished sections of lump ore samples containing native gold were analyzed by scanning electron microscopy in combination with X-ray microanalysis using different modes of visualization and X-ray diffraction methods. Gold particles, clearly visible after etching the surface of some polished sections with acids and partial or complete dissolution of some host minerals, were also examined. Native gold from the studied deposit is of high fineness (above 970‰) and contains (in wt.%) <1.59 Ag and less commonly <0.37 Cu and <0.15 Zn. Native gold is found intergrown with tremolite, diopside, and other magnesian silicates, as well as calcite, fluorite, magnetite, and sphalerite. Rare microinclusions of pyrrhotite, galena, and clinohumite are present in gold grains. It was found that native gold inherits the morphology of tremolite crystals and aggregates, which is determined by the size and shape of the voids bounded by its crystals. Gold localized in the intercrystalline spaces and in the zones of conjugation with remobilized calcite has irregular, lumpy shapes and partially or completely faceted grains with a dense structure. The nature of the localization and distribution of native gold in ores is due to the crystallization of the tremolite component of skarns. Apparently, the processes of gold accumulation are caused by the thermal activation of solid-phase differentiation of the substance of carbonate rocks, in which the processes of destruction of the original minerals and collective recrystallization play a significant role. It is likely that at some gold skarn deposits, carbonate rocks could be the source of gold. Data on the morphology and sizes of native gold segregations, as well as on the intergrown minerals, can be used to improve gold extraction technologies. A specific group of minerals intergrown with native gold in gold skarn deposits can be used as a diagnostic feature in the primary search for placer gold. The obtained results will help to better understand the formation of native gold in apocarbonate tremolite–diopside skarns. Full article

The development of the building sector to the use of renewable energy, more so in photovoltaic (PV) systems, is a great step toward enhanced environmental sustainability and improved energy efficiency. This study seeks to determine the economic, environmental, and operational effects of integrating a PV system into a Polish production plant for buildings. Case study methodology was followed with the help of actual operating histories and simulation modeling to present the estimates of carbon emission savings, cost savings, and power efficiency. Key findings illustrate that 31.8% of the business’s full-year supply of electricity is through the utilization of solar energy and that it saves as much as 10,366 kg CO₂ of emissions every year. The economic rationale of the system is provided in the form of a 3.6-year payback period against long-term savings of over EUR 128,000 in 26 years. This work also addresses the broader implications of energy storage and management systems on the basis of scalability and reproducibility of intervention at the building construction scale. This study provides evidence towards the requirement of informing decision-making by business managers and policy decisionmakers as a step towards the solution of issues of interest to the utilization of renewable energy at industrial levels towards world agenda harmonization for sustainability and business practice. Full article

Aluminium is an attractive material for proton-exchange-membrane fuel cell bipolar plates as it has a much lower density than steel and is easier to form than both steel and graphite. This work focused on the development of amorphous carbon films deposited using closed-field unbalanced magnetron sputtering (CFUBMS) in order to improve the corrosion resistance of aluminium bipolar plates and to enhance fuel cell performance and durability. Chromium and tungsten adhesion layers were used for the coatings. It was possible to achieve good electrical conductivity and high electrochemical corrosion resistance up to 70 °C on polished Aluminium alloy 6082 by tuning the deposition parameters. Coatings with a tungsten adhesion layer showed better corrosion resistance than those with a chromium adhesion layer. In situ, accelerated stress testing of single cells was performed using uncoated and coated Al6082 bipolar plates. Both coatings resulted in improved fuel cell performance compared to uncoated aluminium when used on the cathode side of the fuel cell. Full article

Background/Objectives: Analyzing the carbon footprint of diets in various populations is important as it can help identify more sustainable food choices that reduce the overall impact of human activities on ongoing warming of the global climate. This pilot exploratory study analyzed the carbon footprint (measured in kg of CO₂ equivalent, eq.) using food diaries collected from Polish individuals with varying levels of animal-derived product exclusion in their diets. Methods: The study employed a food diary method, where participants from four dietary groups (vegan, vegetarian, fish-eater, and meat-eater) recorded all meals and beverages consumed over a 7-day period, including portion sizes and packaging details. These diaries were then analyzed to assess dietary adherence and calculate carbon footprints, utilizing standardized CO₂ equivalent emission data from publicly available databases. Results: The analysis revealed a decreasing trend in the carbon footprint corresponding to the degree of elimination of animal-derived products from the diet (R² = 0.96, p = 0.0217). The mean daily footprint in the vegan group was 1.38 kg CO₂ eq., which was significantly lower than in the vegetarian (2.45), fish-eater (2.72), and meat-eater groups (3.62). For each 1000 kcal, the meat-eater diet generated 39.7, 58.3, and 93.9% more CO₂ eq. than in the case of fish-eaters, vegetarians, and vegans, respectively. Over a week, a group of 10 vegans had a total carbon footprint lower than vegetarians, fish-eaters, and meat-eaters by 42.9, 52.2, and 61.8%, respectively. Hard and mozzarella cheese had the highest contribution to the carbon footprint in vegetarians, fish, and seafood in fish-eaters, and poultry, pork, and beef had the highest contribution in meat-eaters. Conclusions: Dietary carbon footprints vary considerably by dietary pattern, with lower consumption of animal-derived products associated with lower emissions. Additionally, identifying specific high-impact food items within each diet may inform strategies for reducing environmental impact across various eating patterns. Full article

An understanding of the textures (grain size, grain shape, porosity, etc.), composition (mineralogy), and distribution of constituent components of geological materials such as carbonate and siliciclastic sedimentary rocks is essential in their classification, interpretation, and significance in terms of their geomechanical strength and liquid/gas storage potential. In terms of scanning electron microscopy (SEM), this is limited to relatively flat areas of selected rough surfaces, or the analysis of polished thin sections. Here, we illustrate a new technique that can image large areas of the external surface of mini-cores (approximately 10 mm or smaller in diameter) drilled from carbonate and siliciclastic rock samples. The technique utilises a specially developed horizontal rotation stage within an SEM and allows the collection of high-resolution images that can be reconstructed into realistic surface representations of the mini-core surfaces. Elemental data (representative of mineralogy) can also be added using a combined backscattered electron and X-ray (BEX) detector. Currently, these reconstructions can be used as a useful tool for the analysis of both carbonate and siliciclastic geological materials. Further work may allow such reconstructions to aid in the improvement of resolution in micro-CT scans and the direct identification of mineral phases within such scans. Full article

Conventional rock mechanical testing approaches encounter significant limitations when applied to deeply buried fractured formations, constrained by formidable sampling difficulties, prohibitive costs, and intricate specimen preparation demands. This investigation pioneers an innovative nanoindentation-based multiscale methodology (XRD–ED–SEM integration) that revolutionizes the mechanical characterization of dolostone through drill cuttings analysis, effectively bypassing conventional coring requirements. Our integrated approach combines precision surface polishing with advanced indenter calibration protocols, enabling the continuous stiffness method to achieve unprecedented measurement accuracy in determining micromechanical properties—notably an elastic modulus of 119.47 GPa and hardness of 5.88 GPa—while simultaneously resolving complex indentation size effect mechanisms. The methodology reveals three critical advancements: remarkable 92.7% dolomite homogeneity establishes statistically significant elastic modulus–hardness correlations (R² > 0.89), while residual imprint analysis uncovers a unique brittle–plastic interaction mechanism through predominant rhomboid plasticity (84% occurrence) accompanied by microscale radial cracking (2.1–4.8 μm). Particularly noteworthy is the identification of load-dependent property variations, where surface hardening effects and defect interactions cause 28.7% parameter dispersion below 50 mN loads, progressively stabilizing to <8% variance at higher loading regimes. By developing a micro–macro bridging model that correlates nanoindentation results with triaxial test data within a 12% deviation, this work establishes a groundbreaking protocol for carbonate reservoir evaluation using minimal drill cutting material. The demonstrated methodology not only provides crucial insights for optimizing hydraulic fracture designs and wellbore stability assessments, but it also fundamentally transforms microstructural analysis paradigms in geomechanics through its successful application of nanoindentation technology to complex geological systems. Full article

Sustainable storage and transport of hydrogen are challenges in the transition to renewable energy sources. Hydrogen embrittlement (HE), caused by atomic hydrogen absorption and diffusion into steel, influences the mechanical properties of steel pipelines and reservoirs. This work focuses on the hydrogen diffusion on X60 pipeline steel using electrochemical measurements and X-ray photoelectron spectroscopy (XPS). The hydrogen permeation tests (HPT) were performed to estimate the effective hydrogen diffusion coefficient D_eff and the subsurface hydrogen concentration C₀ in cleaned and mechanically polished X60 steel. XPS analysis confirmed the presence of a 6 nm thick film of Fe (II) oxide, Fe (III) oxide, and Fe (III) oxyhydroxide. Mechanical polishing improved oxide layer uniformity, ensuring reproducible electrochemical behavior. The effective hydrogen diffusion coefficient D_eff was determined for X60 steel using t_lag and t_b methods. It was found in the range from 2.0 (0.4) 10⁻¹⁰ m²/s to 2.9 (0.5) 10⁻¹⁰ m²/s. The subsurface hydrogen concentration, C₀, was found to be 0.7 (0.1) ppm for X60 steel. The hydrogen diffusion in X60 steel depends on its bulk properties; it is unaffected by surface preparation methods, and it is confirmed to be lower than in high-carbon and other high-strength steels. Full article

The formation and distribution of sedimentary facies of the Wufeng Formation reflect the evolution of Guangxi Movement and significantly impact shale reservoir quality in southern Sichuan Basin, China. This study characterizes the sedimentary facies and their evolution of Ordovician-Silurian transition shale based on detailed core descriptions, full-scale imaging of large slabs, and field emission scanning electron microscopy of argon-ion polished sections. There only exist fine-grained turbidite deposits, hemipelagic deposits, and shallow shoal deposits for the Wufeng shale. Fine-grained turbidite deposits consist primarily of clastic quartz and clay minerals and can be divided into nine subdivisions. Hemipelagic deposits are mainly composed of quartz, detrital carbonate, and clay minerals. Shallow shoal deposits are dominated by clay minerals, dolomite, and calcite, with carbonates primarily of autochthonous origin. The fine-grained turbidite deposits predominantly occur within the Dicellograptus complanatus and D. complexus graptolite biozones, while hemipelagic deposits are confined to the Paraorthograptus pacificus biozone, and shallow shoal deposits are restricted to the Metabolograptus extraordinarius biozone. Formation and distribution of the three sedimentary facies are closely related to the Guangxi Movement. During the strong tectonic compression stage, sufficient sediment supply and intensive volcanic eruption favored the formation of the fine-grained turbidite deposits. Along with waning tectonic activity and reduced terrestrial input, hemipelagic deposits formed and then shallow shoal deposits. Sedimentary facies exert first-order controls on shale reservoir quality, with hemipelagic deposits exhibiting optimal reservoir characteristics. Laboratory analyses reveal that hemipelagic facies possess the highest porosity (3.34–4.15%) and TOC content (2.91–4.10%) due to biogenic quartz enrichment and minimal allochthonous dilution, whereas fine-grained turbidites show degraded properties (porosity: 1.58–3.81%; TOC: 0.15–2.6%) from high-energy siliciclastic influx. Shallow shoal deposits display intermediate values (porosity: 3.92%; TOC: 3.25%), constrained by carbonate cementation. Full article