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Keywords = cadmium telluride (CdTe)

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8 pages, 1541 KiB  
Proceeding Paper
Chiral Recognition of Carnitine Enantiomers Using Graphene Oxide-Modified Cadmium Telluride Quantum Dots
by Haiyan Yuan, Yu Ma, Yuhui Zhang, Jidong Yang, Zhiyuan Mei, Chengcheng Pi and Yuan Peng
Eng. Proc. 2025, 98(1), 34; https://doi.org/10.3390/engproc2025098034 - 8 Jul 2025
Viewed by 189
Abstract
Carnitine (CA) is a chiral amino acid and mostly comes from meat and dairy products. CA cannot be found in fruits, vegetables, or other plants, so vegetarians are deficient in CA. CA exists in the form of D-carnitine (D-CA) and L-carnitine (L-CA); only [...] Read more.
Carnitine (CA) is a chiral amino acid and mostly comes from meat and dairy products. CA cannot be found in fruits, vegetables, or other plants, so vegetarians are deficient in CA. CA exists in the form of D-carnitine (D-CA) and L-carnitine (L-CA); only L-carnitine has biological activity. L-CA promotes the oxidation of fatty acids and then causes the effect of weight loss. In this study, the fluorescence probe was established by using graphene oxide-modified cadmium telluride (CdTe) QDs (GO-CdTe QDs) for the chiral recognition of carnitine enantiomers. GO-CdTe QDs present fluorescence. D-CA enhances the fluorescence spectral signal of the GO-CdTe QDs system, while L-CA weakens its spectral signal. Based on this phenomenon, we determined D-carnitine and L-carnitine. Full article
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19 pages, 35077 KiB  
Article
X-Ray Emissions from Hydrogen Rydberg Matter Detected Using Timepix3 CdTe Detector
by Sindre Andre Zeiner-Gundersen and Sveinn Olafsson
Catalysts 2025, 15(6), 526; https://doi.org/10.3390/catal15060526 - 26 May 2025
Viewed by 727
Abstract
This study investigates the X-ray emissions from Hydrogen Rydberg Matter (HRM) using a state of-the-art Timepix3 detector with a Cadmium Telluride (CdTe) sensor, which offers imaging operation. The experimental setup featured an ultra-high vacuum (UHV) chamber containing potassium-doped iron oxide catalytic source, exposed [...] Read more.
This study investigates the X-ray emissions from Hydrogen Rydberg Matter (HRM) using a state of-the-art Timepix3 detector with a Cadmium Telluride (CdTe) sensor, which offers imaging operation. The experimental setup featured an ultra-high vacuum (UHV) chamber containing potassium-doped iron oxide catalytic source, exposed to hydrogen or deuterium gas flowing through the source. A 1064 nm pulsed YAG laser was used to stimulate the HRM. The Timepix detector was calibrated with Cs-137 662 keV and 21 keV source. Results show a prominent emission peak in the 25–50 keV range, with significant contributions at 406 keV identified through aluminum foil attenuation experiments. These findings advance our understanding of radiation phenomena in hydrogen-loaded systems and suggest new avenues for exploring the unique emissions from HRM, potentially impacting material science and catalysis. Full article
(This article belongs to the Special Issue Catalysis by Metals and Metal Oxides)
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50 pages, 16380 KiB  
Review
Progress in Thin-Film Photovoltaics: A Review of Key Strategies to Enhance the Efficiency of CIGS, CdTe, and CZTSSe Solar Cells
by Sivabalan Maniam Sivasankar, Carlos de Oliveira Amorim and António F. da Cunha
J. Compos. Sci. 2025, 9(3), 143; https://doi.org/10.3390/jcs9030143 - 20 Mar 2025
Cited by 3 | Viewed by 1255
Abstract
Thin-film solar cells (TFSCs) represent a promising frontier in renewable energy technologies due to their potential for cost reduction, material efficiency, and adaptability. This literature review examines the key materials and advancements that make up TFSC technologies, with a focus on Cu(In,Ga)Se2 [...] Read more.
Thin-film solar cells (TFSCs) represent a promising frontier in renewable energy technologies due to their potential for cost reduction, material efficiency, and adaptability. This literature review examines the key materials and advancements that make up TFSC technologies, with a focus on Cu(In,Ga)Se2 (CIGS), cadmium telluride (CdTe), and Cu2ZnSnS4 (CZTS) and its sulfo-selenide counterpart Cu2ZnSn(S,Se)4 (CZTSSe). Each material’s unique properties—including tuneable bandgaps, high absorption coefficients, and low-cost scalability—make them viable candidates for a wide range of applications, from building-integrated photovoltaics (BIPV) to portable energy solutions. This review explores recent progress in the enhancement of power conversion efficiency (PCE), particularly through bandgap engineering, alkali metal doping, and interface optimization. Key innovations such as silver (Ag) alloying in CIGS, selenium (Se) alloying in CdTe, and sulfur (S) to Se ratio optimization in CZTSSe have driven PCE improvements and expanded the range of practical uses. Additionally, the adaptability of TFSCs for roll-to-roll manufacturing on flexible substrates has further cemented their role in advancing renewable energy adoption. Challenges remain, including environmental concerns, but ongoing research addresses these limitations, paving the way for TFSCs to become a crucial technology for transitioning to sustainable energy systems. Full article
(This article belongs to the Section Composites Manufacturing and Processing)
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40 pages, 1207 KiB  
Review
Recent Advances in Flexible Solar Cells; Materials, Fabrication, and Commercialization
by Maoz Maoz, Zohair Abbas, Syed Abdul Basit Shah and Vanni Lughi
Sustainability 2025, 17(5), 1820; https://doi.org/10.3390/su17051820 - 21 Feb 2025
Cited by 2 | Viewed by 5984
Abstract
Flexibility, light weight, and mechanical robustness are the key advantages of flexible photovoltaic (PV) modules, making them highly versatile for sustainable energy solutions. Unlike traditional rigid PV modules, their flexible nature makes them incredibly versatile for harnessing energy in places where doing so [...] Read more.
Flexibility, light weight, and mechanical robustness are the key advantages of flexible photovoltaic (PV) modules, making them highly versatile for sustainable energy solutions. Unlike traditional rigid PV modules, their flexible nature makes them incredibly versatile for harnessing energy in places where doing so was once impossible. They have a wide range of applications due to their flexibility and moldability, making it possible to conform these modules to surfaces like curved rooftops and other irregular structures. In this paper, we provide a comprehensive review of all the materials used in flexible PV modules with a focus on their role in sustainability. We thoroughly discuss the active-layer materials for crystalline silicon (c-Si)-based solar cells (SC) and thin-film solar cells such as cadmium telluride (CdTe), as well as copper indium gallium diselenide (CIGS), amorphous thin-film silicon (a-Si), perovskite and organic solar cells. Various properties, such as the optical, barrier, thermal, and mechanical properties of different substrate materials, are reviewed. Transport layers and conductive electrode materials are discussed with a focus on emerging trends and contributions to sustainable PV technology. Various fabrication techniques involved in making flexible PV modules, along with advantages, disadvantages, and future trends, are highlighted in the paper. The commercialization of flexible PV is also discussed, which is a crucial milestone in advancing and adapting new technologies in the PV industry with a focus on contributing toward sustainability. Full article
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11 pages, 2572 KiB  
Article
Preliminary Investigation of a Cd0.9Zn0.1Te Detector for Small-Field Dosimetry Applications Using Therapeutic MV Beams
by Sangsu Kim, Ju-Young Song, Yong-Hyub Kim, Jae-Uk Jeong, Mee Sun Yoon, Taek-Keun Nam, Sung-Ja Ahn and Shinhaeng Cho
Appl. Sci. 2025, 15(4), 1693; https://doi.org/10.3390/app15041693 - 7 Feb 2025
Viewed by 852
Abstract
Stereotactic radiosurgery (SRS) and stereotactic body radiation therapy (SBRT) require precise small-field dosimetry, verified through patient-specific quality assurance (PSQA). This study evaluated the feasibility of using a single-crystal cadmium–zinc–telluride (Cd0.9Zn0.1Te, CZT) detector for PSQA in SRS and SBRT. We [...] Read more.
Stereotactic radiosurgery (SRS) and stereotactic body radiation therapy (SBRT) require precise small-field dosimetry, verified through patient-specific quality assurance (PSQA). This study evaluated the feasibility of using a single-crystal cadmium–zinc–telluride (Cd0.9Zn0.1Te, CZT) detector for PSQA in SRS and SBRT. We fabricated a CZT detector with Au electrodes and examined its fundamental characteristics, including dose linearity, dose rate dependence, energy dependence, angular dependence, source-to-surface distance (SSD) dependence, field size dependence, depth dependence, and reproducibility, under 6 and 10 MV LINAC beam irradiation and compared the results with those from a standard ionization chamber. The results revealed that the CZT detector demonstrated excellent linearity across 0–1000 cGy with minimal deviation in the low-dose region, negligible dose rate dependence, and minimal energy dependence, exhibiting a 2.2% drop at 15 MV relative to 6 MV. Its angular and SSD dependencies deviated slightly from the ionization chamber, consistent with the expected physical behaviors and correctable in clinical practice. The detector also revealed consistent performance over time with excellent reproducibility, and its depth dependence results were consistent with those of the ionization chamber. Thus, the CZT detector provides consistent performance in small-field measurements under varying conditions, satisfying the requirements for SRS and SBRT. Full article
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39 pages, 2858 KiB  
Review
Thin-Film Technologies for Sustainable Building-Integrated Photovoltaics
by Andrew R. Smith, Mehrdad Ghamari, Sasireka Velusamy and Senthilarasu Sundaram
Energies 2024, 17(24), 6363; https://doi.org/10.3390/en17246363 - 18 Dec 2024
Cited by 5 | Viewed by 2986
Abstract
This study investigates the incorporation of thin-film photovoltaic (TFPV) technologies in building-integrated photovoltaics (BIPV) and their contribution to sustainable architecture. The research focuses on three key TFPV materials: amorphous silicon (a-Si), cadmium telluride (CdTe), and copper indium gallium selenide (CIGS), examining their composition, [...] Read more.
This study investigates the incorporation of thin-film photovoltaic (TFPV) technologies in building-integrated photovoltaics (BIPV) and their contribution to sustainable architecture. The research focuses on three key TFPV materials: amorphous silicon (a-Si), cadmium telluride (CdTe), and copper indium gallium selenide (CIGS), examining their composition, efficiency, and BIPV applications. Recent advancements have yielded impressive results, with CdTe and CIGS achieving laboratory efficiencies of 22.10% and 23.35%, respectively. The study also explores the implementation of building energy management systems (BEMS) for optimizing energy use in BIPV-equipped buildings. Financial analysis indicates that despite 10.00–30.00% higher initial costs compared to conventional materials, BIPV systems can generate 50–150 kWh/m2 annually, with simple payback periods of 5–15 years. The research emphasizes the role of government incentives and innovative financing in promoting BIPV adoption. As BIPV technology progresses, it offers a promising solution for transforming buildings from energy consumers to producers, significantly contributing to sustainable urban development and climate change mitigation. Full article
(This article belongs to the Special Issue Energy Efficiency and Energy Performance in Buildings)
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16 pages, 2868 KiB  
Article
First Stability Characterization for a CZT Detection System in an e+e Collider Environment
by Leonardo Abbene, Francesco Artibani, Manuele Bettelli, Antonino Buttacavoli, Fabio Principato, Andrea Zappettini, Massimiliano Bazzi, Giacomo Borghi, Mario Bragadireanu, Michael Cargnelli, Marco Carminati, Alberto Clozza, Francesco Clozza, Luca De Paolis, Raffaele Del Grande, Kamil Dulski, Laura Fabbietti, Carlo Fiorini, Carlo Guaraldo, Mihail Iliescu, Masahiko Iwasaki, Aleksander Khreptak, Simone Manti, Johann Marton, Pawel Moskal, Fabrizio Napolitano, Szymon Niedźwiecki, Hiroaki Ohnishi, Kristian Piscicchia, Yuta Sada, Francesco Sgaramella, Diana Laura Sirghi, Florin Sirghi, Magdalena Skurzok, Michal Silarski, Antonio Spallone, Kairo Toho, Lorenzo Toscano, Marlene Tüchler, Oton Vasquez Doce, Johann Zmeskal, Catalina Curceanu and Alessandro Scordoadd Show full author list remove Hide full author list
Sensors 2024, 24(23), 7562; https://doi.org/10.3390/s24237562 - 27 Nov 2024
Cited by 1 | Viewed by 1030
Abstract
The SIDDHARTA-2 collaboration has developed a novel X-ray detection system based on cadmium-zinc-telluride (CZT, CdZnTe), marking the first application of this technology at the DAΦNE electron-positron collider at INFN-LNF. This work aims to demonstrate the stability of the detectors’ performance in [...] Read more.
The SIDDHARTA-2 collaboration has developed a novel X-ray detection system based on cadmium-zinc-telluride (CZT, CdZnTe), marking the first application of this technology at the DAΦNE electron-positron collider at INFN-LNF. This work aims to demonstrate the stability of the detectors’ performance in terms of linearity and resolution over short and long periods, thereby establishing their suitability for precise spectroscopic measurements within a collider environment. A reference calibration spectrum is presented in association with findings from assessments of linearity and resolution stability. Additionally, this study introduces a validated model of the response function of the detector. The relative deviations from the nominal values for the source transitions, obtained by fitting the entire spectrum with a background function and the previously introduced response function, are reported. Finally, a comparison of the calibration performance with and without beams circulating in the collider’s rings is presented. These promising results pave the way for applying CZT detectors in kaonic atom studies and, more generally, in particle and nuclear physics spectroscopy. Full article
(This article belongs to the Special Issue Feature Papers in Physical Sensors 2024)
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16 pages, 8063 KiB  
Article
Thin-Film Photovoltaic Modules Characterisation Based on I-V Measurements Under Outdoor Conditions
by Slawomir Gulkowski and Ewelina Krawczak
Energies 2024, 17(23), 5853; https://doi.org/10.3390/en17235853 - 22 Nov 2024
Cited by 1 | Viewed by 951
Abstract
The characterisation of photovoltaic modules requires a specialised laboratory that guarantees precise control of irradiance and its spectrum and control of the module temperature during testing. As an alternative, characteristic parameters can be extracted from the measurements of the current-voltage characteristics (I-V [...] Read more.
The characterisation of photovoltaic modules requires a specialised laboratory that guarantees precise control of irradiance and its spectrum and control of the module temperature during testing. As an alternative, characteristic parameters can be extracted from the measurements of the current-voltage characteristics (I-V curves) carried out under outdoor conditions. This paper presents the results of the two commercial thin-film photovoltaic modules’ characterisation. The first analysed device was a cadmium telluride (CdTe) photovoltaic module fabricated on glass, while the second was the flexible copper indium gallium diselenide (CIGS) PV module. The main parameters of the PV modules were extracted based on the series of I-V curve measurements under real operating conditions in Poland with the use of the capacitor-based I-V tracer. Solar radiation together with the modules’ temperature were registered simultaneously with the I-V characterisation. Two approaches were proposed to estimate the main PV parameters at standard test conditions as output power, short circuit current or open circuit voltage. The difference in results of power for both approaches was below 1.5%. Energy, computed using the Osterwald model, was compared with the experimental measurements. The best results of absolute relative error (ARE) were found around 0.5% for both technologies. The lowest value of root mean squared error (RMSE) was 1.3% in terms of CdTe technology and 3.1% for CIGS. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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10 pages, 5611 KiB  
Article
Investigation of the Influence of Structure, Stoichiometry, and Synthesis Temperature on the Optical Properties of CdTe Nanoplatelets
by Aigerim Ospanova, Yerkebulan Koshkinbayev, Asset Kainarbay, Temirulan Alibay, Rakhima Daurenbekova, Aizhan Akhmetova, Alexander Vinokurov, Sergei Bubenov, Sergey Dorofeev and Dulat Daurenbekov
Nanomaterials 2024, 14(22), 1814; https://doi.org/10.3390/nano14221814 - 13 Nov 2024
Cited by 1 | Viewed by 1349
Abstract
Colloidal cadmium telluride (CdTe) nanoplatelets (NPLs) are promising materials for optoelectronic applications, such as photovoltaics and light-emitting diodes, due to their unique optical and electronic properties. However, controlling their growth, thickness, and stoichiometry remains challenging. This study explores the effect of synthesis temperature [...] Read more.
Colloidal cadmium telluride (CdTe) nanoplatelets (NPLs) are promising materials for optoelectronic applications, such as photovoltaics and light-emitting diodes, due to their unique optical and electronic properties. However, controlling their growth, thickness, and stoichiometry remains challenging. This study explores the effect of synthesis temperature on the structural, optical, and stoichiometric properties of CdTe NPLs. CdTe NPLs were synthesized at temperatures of 170 °C, 180 °C, 190 °C, and 200 °C using colloidal methods. The resulting NPLs were characterized by UV–Vis absorption spectroscopy, photoluminescence (PL) spectroscopy, transmission electron microscopy (TEM), and total reflection X-ray fluorescence (TXRF) to assess their morphology, structure, and elemental composition. The results showed that the synthesis temperature significantly affected the NPL’s morphology and stoichiometry. Optimal stoichiometry was achieved at 180 °C and 190 °C, with the crystal structure transitioning from zinc blende at lower temperatures to wurtzite at higher temperatures. Optical properties, including luminescence intensity and emission peaks, also varied with temperature. The synthesis temperature is an important parameter in controlling the structural and optical properties of CdTe NPLs. The optimal conditions for obtaining NPLs with the best characteristics were identified at 190 °C, presenting important findings for further optimization of CdTe NPL synthesis for optoelectronic applications. Full article
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12 pages, 4829 KiB  
Article
Nanoscale Surface Roughness Effects on Photoluminescence and Resonant Raman Scattering of Cadmium Telluride
by Carlos Israel Medel-Ruiz, Roger Chiu, Jesús Ricardo Sevilla-Escoboza and Francisco Javier Casillas-Rodríguez
Appl. Sci. 2024, 14(17), 7680; https://doi.org/10.3390/app14177680 - 30 Aug 2024
Viewed by 1619
Abstract
Surface roughness significantly affects light reflection and absorption, which is crucial for light–matter interaction studies and material characterization. This work examines how nanoscale surface roughness affects the electronic states and vibrational properties of cadmium telluride (CdTe) single crystals, using photoluminescence (PL) and resonant [...] Read more.
Surface roughness significantly affects light reflection and absorption, which is crucial for light–matter interaction studies and material characterization. This work examines how nanoscale surface roughness affects the electronic states and vibrational properties of cadmium telluride (CdTe) single crystals, using photoluminescence (PL) and resonant Raman scattering (RRS) spectroscopies. We have evaluated the surface roughness across various sample regions as the root-mean-square (RMS) value measured by atomic force microscopy (AFM). At room temperature, increasing RMS correlated with changes in PL intensity and peak width, as well as enhanced second-order longitudinal optical (2LO) phonon mode intensity. Fitting the PL and RRS spectra with Gaussian and Lorentzian functions, respectively, allowed us to explain the relationship between surface morphology and the observed spectral changes. Our findings demonstrate that surface roughness is a critical parameter influencing the surface states and vibrational properties of CdTe, with implications for the performance of CdTe-based devices. Full article
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20 pages, 1652 KiB  
Review
Technological Advances in SPECT and SPECT/CT Imaging
by Yassine Bouchareb, Afrah AlSaadi, Jawa Zabah, Anjali Jain, Aziza Al-Jabri, Peter Phiri, Jian Qing Shi, Gayathri Delanerolle and Srinivasa Rao Sirasanagandla
Diagnostics 2024, 14(13), 1431; https://doi.org/10.3390/diagnostics14131431 - 4 Jul 2024
Cited by 15 | Viewed by 10255
Abstract
Single photon emission tomography/computed tomography (SPECT/CT) is a mature imaging technology with a dynamic role in the diagnosis and monitoring of a wide array of diseases. This paper reviews the technological advances, clinical impact, and future directions of SPECT and SPECT/CT imaging. The [...] Read more.
Single photon emission tomography/computed tomography (SPECT/CT) is a mature imaging technology with a dynamic role in the diagnosis and monitoring of a wide array of diseases. This paper reviews the technological advances, clinical impact, and future directions of SPECT and SPECT/CT imaging. The focus of this review is on signal amplifier devices, detector materials, camera head and collimator designs, image reconstruction techniques, and quantitative methods. Bulky photomultiplier tubes (PMTs) are being replaced by position-sensitive PMTs (PSPMTs), avalanche photodiodes (APDs), and silicon PMs to achieve higher detection efficiency and improved energy resolution and spatial resolution. Most recently, new SPECT cameras have been designed for cardiac imaging. The new design involves using specialised collimators in conjunction with conventional sodium iodide detectors (NaI(Tl)) or an L-shaped camera head, which utilises semiconductor detector materials such as CdZnTe (CZT: cadmium–zinc–telluride). The clinical benefits of the new design include shorter scanning times, improved image quality, enhanced patient comfort, reduced claustrophobic effects, and decreased overall size, particularly in specialised clinical centres. These noticeable improvements are also attributed to the implementation of resolution-recovery iterative reconstructions. Immense efforts have been made to establish SPECT and SPECT/CT imaging as quantitative tools by incorporating camera-specific modelling. Moreover, this review includes clinical examples in oncology, neurology, cardiology, musculoskeletal, and infection, demonstrating the impact of these advancements on clinical practice in radiology and molecular imaging departments. Full article
(This article belongs to the Special Issue Research Update on Nuclear Medicine)
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10 pages, 3956 KiB  
Article
Ring and Linear Structures of CdTe Clusters
by Andrii Kashuba, Ihor Semkiv, Myron Rudysh, Hryhorii Ilchuk and Pavlo Shchepanskyi
Quantum Rep. 2024, 6(3), 349-358; https://doi.org/10.3390/quantum6030022 - 30 Jun 2024
Cited by 3 | Viewed by 1602
Abstract
We report the results of an ab initio study of the linear and ring structures of cadmium telluride clusters [CdTe]n (CdnTen) n ≤ 10 within the generalized gradient approximation (GGA) and Purdue–Burke–Ernzerhof (PBE) parameterization with Hubbard corrections (GGA+ [...] Read more.
We report the results of an ab initio study of the linear and ring structures of cadmium telluride clusters [CdTe]n (CdnTen) n ≤ 10 within the generalized gradient approximation (GGA) and Purdue–Burke–Ernzerhof (PBE) parameterization with Hubbard corrections (GGA+U). We optimized the linear and ring isomers for each size to obtain the lowest-energy structures and to understand their growth behavior. The cases of n < 8 for ring-type structures and n = 6 and 9 for linear-type structures were found to be the most favorable. All observed clusters with a linear structure were found to have a small highest-occupied–lowest-unoccupied molecular orbital (HOMO–LUMO) gap. The CdTe clusters with ring structure showed larger values of the HOMO–LUMO gaps than the band gap value for the bulk crystal. Structural and electronic properties like bond length, the HOMO–LUMO gap, binding energy, and electronegativity were analyzed. Full article
(This article belongs to the Special Issue Semiconductor and Superconductor Quantum Devices)
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24 pages, 10621 KiB  
Article
Performance Analysis of Six Electro-Optical Crystals in a High-Bandwidth Traveling Wave Mach-Zehnder Light Modulator
by Abtin Ataei, Paul McManamon and Andrew Sarangan
Photonics 2024, 11(6), 498; https://doi.org/10.3390/photonics11060498 - 24 May 2024
Viewed by 1078
Abstract
In this study, a traveling wave Mach-Zehnder intensity modulator (TW-MZM) was designed and optimized for six different electro-optical (EO) crystals: lithium niobate (LNB), potassium niobate (KNB), lithium titanate (LTO), beta barium borate (BBO), cadmium telluride (CdTe), and indium phosphide (InP). The performance of [...] Read more.
In this study, a traveling wave Mach-Zehnder intensity modulator (TW-MZM) was designed and optimized for six different electro-optical (EO) crystals: lithium niobate (LNB), potassium niobate (KNB), lithium titanate (LTO), beta barium borate (BBO), cadmium telluride (CdTe), and indium phosphide (InP). The performance of each EO crystal, including optical and radio frequency (RF) loss, applied voltage, and modulation bandwidth, was estimated and compared. The results suggest that, in theory, KNB, LTO, BBO, and CdTe have the potential to outperform LNB. However, it should be noted that the loss associated with KNB and LTO is comparable to that of LNB. The findings demonstrated that BBO and CdTe exhibit a modulation bandwidth exceeding 100 GHz and demonstrate the lowest loss among the considered crystals based on the assumed geometry. Full article
(This article belongs to the Section Optoelectronics and Optical Materials)
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20 pages, 5113 KiB  
Article
Effect of Deposition Working Power on Physical Properties of RF-Sputtered CdTe Thin Films for Photovoltaic Applications
by Ana-Maria Răduță, Ana-Maria Panaitescu, Marina Manica, Sorina Iftimie, Vlad-Andrei Antohe, Ovidiu Toma, Adrian Radu, Lucian Ion, Mirela Petruta Suchea and Ștefan Antohe
Nanomaterials 2024, 14(6), 535; https://doi.org/10.3390/nano14060535 - 18 Mar 2024
Cited by 2 | Viewed by 2151
Abstract
The main objective of this study was to determine the variation in the properties of cadmium telluride (CdTe) thin films deposited on a p-type Si substrate by the radio frequency magnetron sputtering technique at four different working powers (70 W, 80 W, 90 [...] Read more.
The main objective of this study was to determine the variation in the properties of cadmium telluride (CdTe) thin films deposited on a p-type Si substrate by the radio frequency magnetron sputtering technique at four different working powers (70 W, 80 W, 90 W, and 100 W). The substrate temperature, working pressure, and deposition time during the deposition process were kept constant at 220 °C, 0.46 Pa, and 30 min, respectively. To study the structural, morphological, and optical properties of the CdTe films grown under the mentioned experimental conditions, X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), and optical spectroscopy were used. For a better analysis of the films’ structural and optical properties, a group of films were deposited onto optical glass substrates under similar deposition conditions. The electrical characterisation of Ag/CdTe/Al “sandwich” structures was also performed using current–voltage characteristics in the dark at different temperatures. The electrical measurements allowed the identification of charge transport mechanisms through the structure. New relevant information released by the present study points towards 90 W RF power as the optimum for obtaining a high crystallinity of ~1 μm nanostructured thin films deposited onto p-Si and optical glass substrates with optical and electrical properties that are suitable for use as absorber layers. The obtained high-quality CdTe nanostructured thin films are perfectly suitable for use as absorbers in CdTe thin-film photovoltaic cells. Full article
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11 pages, 4188 KiB  
Article
Optimizing the Band Alignment of the MZO/CdSeTe/CdTe Solar Cell by Varying the Substrate Temperature of MZO Film
by Qiuchen Wu, Ruchun Li, Yufeng Zhang, Kai Huang, Heran Li and Xiangxin Liu
Energies 2024, 17(3), 592; https://doi.org/10.3390/en17030592 - 26 Jan 2024
Cited by 1 | Viewed by 1669
Abstract
Cadmium telluride (CdTe) photovoltaics is a promising and scalable technology, commanding over 90% of the thin film photovoltaics market. An appropriate window layer is crucial for high-efficiency CdTe solar cells. This study aimed to investigate a representative MgZnO (MZO) window layer and enhance [...] Read more.
Cadmium telluride (CdTe) photovoltaics is a promising and scalable technology, commanding over 90% of the thin film photovoltaics market. An appropriate window layer is crucial for high-efficiency CdTe solar cells. This study aimed to investigate a representative MgZnO (MZO) window layer and enhance device performance. We studied the properties of MZO films with different substrate temperatures and their application in CdSeTe/CdTe solar cells. Despite the high transmittance and wide band gap of MZO film, the device performance of MZO sputtered at room temperature is limited by excessive conduction band offset. Tailoring the substrate temperature for MZO sputtering helps optimize the band alignment of the MZO/CdSeTe interface, contributing to an improvement in the efficiency of CdTe solar cells. Full article
(This article belongs to the Special Issue Advances in Solar Energy Materials and Solar Energy Systems)
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