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Keywords = bromatological characteristics

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16 pages, 970 KiB  
Article
Proximate Analysis, Total Phenolic Content, and Antioxidant Activity of Wild Carob Pulp from Three Mediterranean Countries
by Mohamad Ali El Chami, Guillermo Palacios-Rodríguez, José L. Ordóñez-Díaz, Raquel Rodríguez-Solana, Rafael M. Navarro-Cerrillo and José M. Moreno-Rojas
Appl. Sci. 2025, 15(3), 1340; https://doi.org/10.3390/app15031340 - 27 Jan 2025
Cited by 2 | Viewed by 1839
Abstract
(1) Background: Carob tree (Ceratonia siliqua L.) pulp is of great interest nowadays due to its nutritional benefits and diverse utilization in the food process. The nutritional and antioxidant properties of carob pulp in the Mediterranean have been assessed in several studies. [...] Read more.
(1) Background: Carob tree (Ceratonia siliqua L.) pulp is of great interest nowadays due to its nutritional benefits and diverse utilization in the food process. The nutritional and antioxidant properties of carob pulp in the Mediterranean have been assessed in several studies. Still, few studies have combined, within the same work, a comprehensive analysis of the chemical composition of carob pulp from fruits of natural populations across different countries of the Mediterranean basin, while also incorporating new research areas. (2) Methods: In the present work, we evaluated the nutritional value, total phenolic compounds, and antioxidant activity of carob pulp derived from wild populations of carob trees from three Mediterranean countries: Lebanon, Spain, and Morocco; (3) Results: All assessed bromatological characteristics, with the exception of ash and fiber content, revealed significant differences in the carob pulp from the three countries under study. High variability was observed for the total polyphenols ranging between 5.05 mg/g and 12.70 mg/g. Sucrose was the predominant sugar quantified ranging between 13.70 g/100 g and 28.10 g/100 g. The lipid content was low (0.26–0.36%). The moisture content of carob pulp ranges between 4.36% and 6.40%. Carob pulp presented a rich composition in fiber, with an average of 35.87%. The ash content was between 2.52% and 3.28%. The percentage of the protein content of the carob pulp ranged between 4.40 and 5.52, with an average carbohydrate value of 74.71%; (4) Conclusions: Spanish wild carob pulp samples offered higher carbohydrates contents and values for sucrose, fructose, and glucose, polyphenol content, and antioxidant activity, whereas Moroccan samples had higher values of carbohydrates and in concrete, the monosaccharides fructose and glucose showed higher contents in proteins and lipids. In contrast, Lebanese samples exhibit a high content of the disaccharide sucrose. These findings could be exploited in breeding programs to improve varieties that balance both the agronomical quality and nutritional values of carob pulp. Full article
(This article belongs to the Special Issue New Insights into Food Ingredients for Human Health Promotion)
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21 pages, 2062 KiB  
Article
Nutritional and Structural Components of Forage Sorghum Subjected to Nitrogen Fertilization and Molybdenum
by Glícia Rafaela Freitas da Fonsêca, Jamiles Carvalho Gonçalves de Souza Henrique, Ednaete Bezerra de Alcântara, Náthaly Vitória Santos Almeida, Alexandre Campelo de Oliveira, Maria Luana da Silva Medeiros, Arthur Lucas Júlio Silva and Evaristo Jorge Oliveira de Souza
Grasses 2025, 4(1), 1; https://doi.org/10.3390/grasses4010001 - 2 Jan 2025
Cited by 2 | Viewed by 1079
Abstract
Semi-arid regions present edaphoclimatic limitations for forage production, primarily affecting plant growth and development. Crops adapted to such conditions, like forage sorghum, and nutritional supplementation with nitrogen and molybdenum, can increase forage production. The objective of this study was to evaluate the interaction [...] Read more.
Semi-arid regions present edaphoclimatic limitations for forage production, primarily affecting plant growth and development. Crops adapted to such conditions, like forage sorghum, and nutritional supplementation with nitrogen and molybdenum, can increase forage production. The objective of this study was to evaluate the interaction between nitrogen and molybdenum on the bromatological and structural components of forage sorghum (SF-15) cultivated in a semi-arid environment, with the hypothesis that nitrogen fertilization combined with molybdenum would enhance nitrogen use efficiency in sorghum. The methodology involved a 5 × 2 factorial experiment in a randomized block design (RBD) with increasing doses of nitrogen (urea) (0, 50, 100, 150, 300 kg ha¹) and two doses of molybdenum (sodium molybdate): 0 and 160 g ha−1, conducted over three cultivation cycles. At the end of each cycle, morphological variables were evaluated, and yield of natural mass (YNM), yield of dry mass (YDM), crude protein production (CPP), and bromatological components were determined. Morphometric characteristics were influenced by the interaction between cycle x nitrogen doses (N) and molybdenum doses (Mo). For productive characteristics, there was an interaction between cycle and nitrogen doses, with the first regrowth cycle and the dosage of 100 kg ha−1 N showing the highest mean. Bromatological components were influenced by the N and Mo interaction. The study confirmed the synergistic effect between nitrogen and molybdenum. It is recommended to use 100 kg ha−1 nitrogen fertilization for an average production of 10 t ha−1 for SF-15 sorghum. Full article
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18 pages, 2221 KiB  
Article
Characterisation of Tenebrio molitor Reared on Substrates Supplemented with Chestnut Shell
by Irene Ferri, Matteo Dell’Anno, Mattia Spano, Benedetta Canala, Beatrice Petrali, Matilda Dametti, Stefano Magnaghi and Luciana Rossi
Insects 2024, 15(7), 512; https://doi.org/10.3390/insects15070512 - 9 Jul 2024
Cited by 7 | Viewed by 2052
Abstract
Tenebrio molitor larvae represent a sustainable protein source for food and feed. The aim of this study was to evaluate the supplementation of chestnut shell, a by-product of the agro-industrial chain, in growth substrates for T. molitor larvae rearing. Seven-week-old larvae were reared [...] Read more.
Tenebrio molitor larvae represent a sustainable protein source for food and feed. The aim of this study was to evaluate the supplementation of chestnut shell, a by-product of the agro-industrial chain, in growth substrates for T. molitor larvae rearing. Seven-week-old larvae were reared on three different growth substrates: the control group (CTRL) was fed wheat bran, treatment group one was fed wheat bran supplemented with 12.5% w/w chestnut shell (TRT1), and treatment group two was fed wheat bran supplemented with 25% w/w chestnut shell (TRT2). Larval weight, substrate consumption, and mortality were recorded weekly. After 14 days, insect meals were produced for bromatological and colorimetric analysis, and bacterial inhibition activity assay using a microdilution method. The amino acid profile of insects was determined using quantitative nuclear magnetic resonance spectroscopy. Our results showed a lower feed conversion ratio and higher larval survival rate % in TRT2 compared to CTRL (p < 0.05). Proteins and lipids of TRT2 were higher than other groups (p < 0.05). Important differences were observed in the amino acid profile of TRT1 and TRT2 compared to CTRL (p < 0.05). TRT1 and TRT2 showed higher E. coli inhibitory activity than CTRL (p < 0.05). In conclusion, chestnut shell supplementation improved the survival and functional characteristics of larvae and likely impacted the insects’ metabolism. Full article
(This article belongs to the Special Issue Insect Rearing: Reserve Forces with Commercial and Ecological Values)
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17 pages, 1085 KiB  
Article
Can Nitrogen Fertilization and Intercropping Modify the Quality and Nutrient Yield of Barley–Field Bean Forage?
by Francesco Giovanni Salvo Angeletti, Silvia Pampana, Iduna Arduini, Sergio Saia and Marco Mariotti
Agronomy 2024, 14(6), 1166; https://doi.org/10.3390/agronomy14061166 - 29 May 2024
Viewed by 1175
Abstract
Barley (Hordeum vulgare L.) and field bean (Vicia faba L. var minor) are often used for forage production in the Mediterranean environment. Their bromatological and productive characteristics are known when cultivated as sole crops, but if grown simultaneously in intercropping, [...] Read more.
Barley (Hordeum vulgare L.) and field bean (Vicia faba L. var minor) are often used for forage production in the Mediterranean environment. Their bromatological and productive characteristics are known when cultivated as sole crops, but if grown simultaneously in intercropping, the changes in their morphological and physiological characteristics could affect the quality and the nutrient yield of the resulting forages. In a two-year field research in Central Italy, we determined the bromatological traits and nutrient yields of barley and field bean, grown as sole crops or intercrops in a 1:1 additive design harvested at the heading and early dough stage with five nitrogen (N) rates (i.e., from 0 to 200 kg ha−1). Both intercropping and N fertilization increased the concentration of crude protein and fiber but decreased the general quality of the forage. However, the effects on nutrient yields were more marked; those of crude protein and total digestible nutrients increased by 46 and 29% with intercropping and by 49 and 46% with 150 kg N ha−1. Thus, we concluded that N fertilization should not exceed 50 kg ha−1 to maximize the relative feed value, while 150 kg ha−1 are suitable to boost nutrient yields. Full article
(This article belongs to the Section Innovative Cropping Systems)
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10 pages, 281 KiB  
Article
The Inclusion of Pigeon Pea Hay Improves the Quality of Giant Cactus Harvested at Different Times
by Rodrigo B. Saldanha, Gleidson G. P. de Carvalho, Carlindo S. Rodrigues, Tarcizio V. B. S. Silva, Douglas dos S. Pina, Henry D. R. Alba, Stefanie A. Santos, Manuela S. L. Tosto and Claudio de O. Romão
Agronomy 2024, 14(5), 1039; https://doi.org/10.3390/agronomy14051039 - 14 May 2024
Viewed by 1261
Abstract
The objective of this study was to evaluate the effects of giant cactus harvest time and the inclusion of pigeon pea hay in improving the ensiling process and the nutritional composition of cactus silage. In total, 40 polyvinyl chloride-PVC mini-silos (10 × 40 [...] Read more.
The objective of this study was to evaluate the effects of giant cactus harvest time and the inclusion of pigeon pea hay in improving the ensiling process and the nutritional composition of cactus silage. In total, 40 polyvinyl chloride-PVC mini-silos (10 × 40 cm) were used. Mini-silos were distributed in a 2 × 5 factorial scheme, referent to 2 harvest times (18 and 24 months) and 5 levels (0, 10%, 20%, 30%, and 40%) of pigeon pea hay inclusion in a randomized design. Effluent losses (p < 0.001) showed a negative linear effect as the inclusion of pigeon pea hay increased. Gas losses (p < 0.001), dry matter (DM) recovery (p < 0.001), and pH (p < 0.001) revealed the interactive effects between the pigeon pea hay inclusion and the harvest time. The DM content was higher in the giant cactus harvested at 24 months. The difference in nutritional composition promoted by the harvest time did not affect the silage quality. The gradual inclusion of pigeon pea hay improved the fermentative and bromatological characteristics of giant cactus silage. It is important to highlight that the inclusion of pigeon pea hay contributed to the increase in pH without affecting the necessary acidity for ideal conservation. Full article
(This article belongs to the Section Horticultural and Floricultural Crops)
24 pages, 8190 KiB  
Article
Improved Production of Marandu Palisade Grass (Brachiaria brizantha) with Mixed Gelatin Sludge Fertilization
by Eduardo André Ferreira, Joadil Gonçalves de Abreu, Wininton Mendes da Silva, Danielle Helena Müller, Dalilhia Nazaré dos Santos, Cassiano Cremon, Oscarlina Lúcia dos Santos Weber, Aaron Kinyu Hoshide, Daniel Carneiro de Abreu, Maybe Lopes Gonçalves and José Advan Pereira Pedrosa Júnior
Grasses 2024, 3(2), 45-68; https://doi.org/10.3390/grasses3020005 - 4 Apr 2024
Viewed by 2298
Abstract
Gelatin industry residues are increasingly used as fertilizer and soil conditioner. However, correct residue dosage is critical for grass development and minimizing environmental impacts. This randomized block design study determined adequate dosage of mixed gelatin sludge (MGS) for Marandu grass production in wet/dry [...] Read more.
Gelatin industry residues are increasingly used as fertilizer and soil conditioner. However, correct residue dosage is critical for grass development and minimizing environmental impacts. This randomized block design study determined adequate dosage of mixed gelatin sludge (MGS) for Marandu grass production in wet/dry seasons in Brazil. Five MGS levels (0–200% of required nitrogen) were compared to mineral fertilizer. Agronomic/productivity characteristics, bromatological composition, macro/micronutrient composition of leaves, and soil chemical attributes were evaluated. Agronomic/productivity characteristics were influenced by MGS dose in both dry/rainy seasons, except for leaf blade pseudostem ratio and percentage of leaves/pseudostem. Bromatological composition was influenced by MGS doses in dry/rainy seasons except for dry/mineral material quantities. Marandu leaf tissue chemical composition was significantly influenced by MGS dose, except for potassium, boron, and iron. Chemical composition of four soil layers between 0 and 50 cm influenced MGS dose, except for pH, organic matter, magnesium, copper, manganese, and zinc. GMS dose for Marandu production should be 200% of nitrogen requirement. MGS application increased productivity/quality of Marandu grass. Macronutrients (nitrogen, phosphorus) and micronutrients (calcium, magnesium, sulfur, copper, and zinc) increased in Marandu grass and in the soil (calcium, sulfur, and sodium). The increased sodium level was not limiting. Full article
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9 pages, 521 KiB  
Article
Sorghum Densification with Changes in Plant Spacing Arrangement: Productivity and Qualitative Characteristics of Silage Material
by Dayenne M. Herrera, Wender M. Peixoto, Joadil G. de Abreu, Rafael H. P. dos Reis, Carlos E. A. Cabral, Livia V. de Barros, Vanderley A. C. Klein and Edmilson F. dos Passos
Agronomy 2024, 14(2), 358; https://doi.org/10.3390/agronomy14020358 - 10 Feb 2024
Cited by 1 | Viewed by 1752
Abstract
The aim of this study was to evaluate the agronomic performance of sorghum grown in different combinations of row spacing and plant density, as well as possible interferences on silage quality. No other study dedicated to identifying the interference of plant spatial arrangement [...] Read more.
The aim of this study was to evaluate the agronomic performance of sorghum grown in different combinations of row spacing and plant density, as well as possible interferences on silage quality. No other study dedicated to identifying the interference of plant spatial arrangement on the cultivation of silage material has been developed in the productive context of the Amazon Biome, making it necessary to understand the behavior of the studied factors. The treatments were arranged in a split-plot scheme: the plots corresponded to three row spacings (0.45 m, 0.60 m, and 0.75 m) and subplots at four densities (105,000, 120,000, 135,000, and 150,000 plants ha−1). The agronomic and productivity characteristics of sorghum and the fermentative and bromatological characteristics of forage and silage were evaluated. The sorghum plants showed an increase in plant height and green and dry mass yield when using higher densities (p < 0.05). For the culm diameter variable, an isolated effect of the factors was observed, with reduced diameter when grown closer to inter-row spacing or using higher plant densities. No effect of the factors was found (p > 0.05) for morphological plant components. In silage, wider spacing promoted higher dry matter content. Regarding crude protein in the silage, higher percentages were obtained at closer spacing and higher plant density. The sorghum growing in dense conditions is indicated, given the positive performance in productivity and bromatological composition. Full article
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19 pages, 1801 KiB  
Article
Influence of Fermentation Time on the Chemical and Functional Composition of Different Cocoa Clones from Southern Colombia
by Paola Andrea Polanía-Hincapié, Juan Carlos Suárez, Héctor Eduardo Hernández, Vivian Yorlady Ramón-Triana, Liceth N. Cuéllar-Álvarez and Fernando Casanoves
Fermentation 2023, 9(11), 982; https://doi.org/10.3390/fermentation9110982 - 16 Nov 2023
Cited by 4 | Viewed by 2837
Abstract
Cocoa bean quality depends mainly on genetic material, edaphoclimatic factors and post-harvest processes such as fermentation. The impact of the fermentation process on the chemical and functional composition of different cocoa clones grown in southern Colombia was analyzed. A factorial design with repeated [...] Read more.
Cocoa bean quality depends mainly on genetic material, edaphoclimatic factors and post-harvest processes such as fermentation. The impact of the fermentation process on the chemical and functional composition of different cocoa clones grown in southern Colombia was analyzed. A factorial design with repeated measures over time was used to analyze the effect of clone and fermentation time on chemical characteristics (bromatology, phenolic compounds and antioxidant activity). The bromatological characteristics showed significant differences between clones and fermentation time. Clones EET-8 and CCN-51 showed higher contents of acidity (0.51%), fat (63.61%), protein (12.85%) and carbohydrates (1.63 mg g−1). Moisture, acidity and sucrose increased their values between day 4 and day 6 of fermentation (p < 0.05). Phenolic compounds and antioxidant activity had significant differences between clones, where clones CCN-51 and ICS-95 had high contents of phenols (64.56 mg g−1), flavonoids (3.30 mg g−1) and DPPH reducing capacity (325.55 µmol g−1). In this sense, we consider the FSV-41 clone as the major grain quality index based on the results of chemical composition at the bromatological level, antioxidant activity and phenolic compounds. Full article
(This article belongs to the Section Fermentation for Food and Beverages)
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18 pages, 2524 KiB  
Article
Spatial Distribution of Cocoa Quality: Relationship between Physicochemical, Functional and Sensory Attributes of Clones from Southern Colombia
by Vivian Ramón, Héctor Eduardo Hernández, Paola Polania and Juan Carlos Suárez
Agronomy 2023, 13(1), 15; https://doi.org/10.3390/agronomy13010015 - 21 Dec 2022
Cited by 8 | Viewed by 3639
Abstract
Cocoa quality is affected by genetic variability and conditions in the region of origin that impact the physicochemical, functional and sensory characteristics of the cocoa bean. For the purpose of this study, the spatial distribution was analyzed using a cocoa quality indicator that [...] Read more.
Cocoa quality is affected by genetic variability and conditions in the region of origin that impact the physicochemical, functional and sensory characteristics of the cocoa bean. For the purpose of this study, the spatial distribution was analyzed using a cocoa quality indicator that related physicochemical, functional variables (phenolic and antioxidant content) and sensory attributes (organoleptic qualities and sensory notes) of cocoa samples from different cocoa clones in the municipalities of Mesetas and Vista Hermosa in the department of Meta, Colombia. In 83 sampling plots distributed in 22 farms with agroforestry cocoa arrangements, 50 pods of the main clone were selected in each plot. Subsequently, the cocoa bean samples were subjected to fermentation and drying processes using a uniform process, then each of the samples was subjected to physicochemical, functional and sensory properties. A medium quality level was found in the cocoa beans that depended on genetic variability, whose properties ranged between protein levels of 10.312%, sugars of 2.7–3.7 °Brix, and fat contents of 51.5–52.2%, with 178.4–235.2 mg GAE g−1 in total phenol content and 1208.1–3464.1 μmol AAE g−1 in antioxidant capacity. Clones TSH-565 and FEAR-5 showed respectively higher and lower grain quality. Within the sensory profile, complementary aromatic notes such as floral, fruity, nutty, malty, with high correlations between acidity and fresh fruit, astringency and cocoa, and astringency and bitterness, were found. At the clone level, ICS-95 and TSH-565 presented the best sensory attributes (floral, sweet, acidity, fresh fruit). According to the physicochemical, functional and sensory variables of the cocoa beans, it was found that only 13% of the samples presented values higher than 0.8 in the cocoa quality index, with notes of banana, melon, peach, plum, and fresh fruit related to clones such as TSH-565 and ICS-95, whose notes are considered high-quality; these cocoa plantations are located in the Palestina village in the municipality of Vistahermosa and in the Las Mercedes village in the municipality of Mesetas. Full article
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19 pages, 1533 KiB  
Article
Bioactives and Extracellular Enzymes Obtained from Fermented Macrofungi Cultivated in Cotton and Jatropha Seed Cakes
by Joice Raísa Barbosa Cunha, Daiana Wischral, Ruben Darío Romero Pelaez, Maria Aparecida de Jesus, Ceci Sales-Campos, Raquel Bombarda Campanha, Thais Demarchi Mendes, Simone Mendonça, Eustáquio Souza Dias and Félix Gonçalves de Siqueira
Microorganisms 2022, 10(8), 1670; https://doi.org/10.3390/microorganisms10081670 - 19 Aug 2022
Cited by 4 | Viewed by 2221
Abstract
This work focused on obtaining fermented oil cake (cotton or Jatropha) via macrofungi growth with potential characteristics for animal feed formulations, such as the presence of extracellular enzymes, bioactive (ergosterol and antioxidants), and detoxification of antinutritional compounds. The concentration of phorbol esters [...] Read more.
This work focused on obtaining fermented oil cake (cotton or Jatropha) via macrofungi growth with potential characteristics for animal feed formulations, such as the presence of extracellular enzymes, bioactive (ergosterol and antioxidants), and detoxification of antinutritional compounds. The concentration of phorbol esters was reduced by four macrofungi in Jatropha seed cake (JSC) to non-toxic levels. At least two macrofungi efficiently degraded free gossypol in cottonseed cake (CSC). Fermentation with Coriolopsis sp. INPA1646 and Tyromyces sp. INPA1696 resulted in increased ergosterol concentrations, antioxidant activity reduction, and high activity of laccases and proteases. Bromatological analysis indicated high crude protein concentrations, with partial solubilization by fungal proteases. Fermented products from Coriolopsis sp. and Tyromyces sp. in JSC or CSC can be considered important biological inputs for monogastric and polygastric animal feed. Full article
(This article belongs to the Special Issue Fungal Biology and Interactions)
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13 pages, 4895 KiB  
Review
Microalgae: Potential for Bioeconomy in Food Systems
by Elwi Machado Sierra, María C. Serrano, Anderson Manares, Abraham Guerra and Yani Aranguren Díaz
Appl. Sci. 2021, 11(23), 11316; https://doi.org/10.3390/app112311316 - 29 Nov 2021
Cited by 17 | Viewed by 4847
Abstract
The efficient use of natural resources is essential for the planet’s sustainability and ensuring food security. Colombia’s large availability of water resources in combination with its climatic characteristics allows for the development of many microalgae species. The use of microalgae can potentially contribute [...] Read more.
The efficient use of natural resources is essential for the planet’s sustainability and ensuring food security. Colombia’s large availability of water resources in combination with its climatic characteristics allows for the development of many microalgae species. The use of microalgae can potentially contribute to sustainable production in support of the agri-food sector. The nutritional composition (proteins, carbohydrates, fatty acids, vitamins, pigments, and antioxidants) of microalgae along with the ease of producing high biomass yields make them an excellent choice for human and animal nutrition and agriculture. Several species of microalgae have been studied seeking to develop food supplements for pigs, ruminants, poultry, fish, crustaceans, rabbits, and even bees. Important benefits to animal health, production, and improved bromatological and organoleptic characteristics of milk, meat, and eggs have been observed. Based on the functional properties of some microalgae species, foods and supplements have also been developed for human nutrition. Moreover, because microalgae contain essential nutrients, they can be utilized as biofertilizers by replacing chemical fertilizers, which are detrimental to the environment. In view of the above, the study of microalgae is a promising research area for the development of biotechnology and bioeconomy in Colombia. Full article
(This article belongs to the Topic Applied Sciences in Functional Foods)
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18 pages, 16680 KiB  
Article
Batch and Packed Bed Column Study for the Removal of Cr (VI) and Ni (II) Using Agro-Industrial Wastes
by Candelaria Tejada-Tovar, Angel Villabona-Ortíz and Rodrigo Ortega-Toro
Appl. Sci. 2021, 11(19), 9355; https://doi.org/10.3390/app11199355 - 8 Oct 2021
Cited by 9 | Viewed by 2657
Abstract
The objective of this study was to prepare bio adsorbents from agro-industrial wastes from yam starch (YSR) and plantain (PSR) production for its use in the removal of Cr (VI) and Ni (II) in aqueous solution in batch and continuous packed-bed column systems. [...] Read more.
The objective of this study was to prepare bio adsorbents from agro-industrial wastes from yam starch (YSR) and plantain (PSR) production for its use in the removal of Cr (VI) and Ni (II) in aqueous solution in batch and continuous packed-bed column systems. Bromatological analysis showed that the biomaterials are rich in cellulose, lignin, hemicellulose, and SEM micrographs that evidence a mesoporous structure characteristic of materials of lignocellulosic origin. FTIR evidenced functional groups such as hydroxyl, carbonyl, and methyl, possibly involved in the uptake of metal ions. EDS and FTIR analysis after adsorption confirmed that the retention of the metals on the surface of the adsorbent materials was successful. Cr (VI) and Ni (II) removal efficiencies above 80% were achieved using YSR and PSR in batch systems at the different conditions evaluated. The optimum conditions for removing Ni (II) on PSR were a bed height of 11.4 cm and a temperature of 33 °C, while for YSR, they were: 43 °C and 9 cm for temperature and bed height respectively. The variable with the most significant influence on the removal of Cr (VI) in a batch system on the two bio adsorbents was temperature. In contrast, the adsorbent dose and temperature are relevant factors for PSR Ni (II) removal. Therefore, the residues from the preparation of yam and plantain starch have high potential for removing heavy metals from wastewater and are presented as an alternative for their final disposal. Full article
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13 pages, 1806 KiB  
Article
Using Coffee Pulp as Bioadsorbent for the Removal of Manganese (Mn (II)) from Synthetic Wastewater
by Dora Luz Gómez Aguilar, Juan Pablo Rodríguez Miranda, Deisy Baracaldo Guzmán and Javier Andrés Esteban Muñoz
Water 2020, 12(9), 2500; https://doi.org/10.3390/w12092500 - 8 Sep 2020
Cited by 12 | Viewed by 3484
Abstract
This research focuses on the removal of contaminants from wastewaters as a matter of great interest in the field of water pollution. The first decades of the 21st century have brought numerous approaches for the development of cheaper and more effective adsorbents capable [...] Read more.
This research focuses on the removal of contaminants from wastewaters as a matter of great interest in the field of water pollution. The first decades of the 21st century have brought numerous approaches for the development of cheaper and more effective adsorbents capable of eliminating heavy metals. The study aims to examine the way coffee pulp (Castilla variety from Caldas, Colombia) was used as a bioadsorbent for the removal of Mn (II) from synthetic wastewater to fulfill goals 3 and 6 proposed in the Sustainable Development Goals stated for the 2030 Agenda, particularly in Sections 3.9 and 6.9. In order to achieve this objective, the agricultural residue was subjected to bromatological characterization, determination of the lignocellulosic composition, and identification of characteristic organic functional groups through IR spectrophotometry, using the ATR (attenuated total reflection) technique. Additionally, the optimal parameters for contaminant removal were identified, regarding the biomass quantity, the optimum pH, the stirring time, the adsorption kinetics, the zero charge potential (pHpzc), the adsorption isotherms, and the explanation of the possible adsorption mechanisms between the contaminant, the surface of the coffee pulp, and the capacity of maximum adsorption. The results show that lignocellulosic material presented a cellulose content of 29.93 ± 0.21% and a lignin content of 19.25 ± 0.16%. The optimum parameters found were as follows: Particle size of 180 µm, contact time from 90 min to 100 RPM, optimum pH of 4.0 pH units, room temperature; the kinetic model adjusted to the bioadsorption process was Ho and McKay’s pseudo-second-order, under an isotherm of the Langmuir model, for which the removal presented was 53.40%, with a maximum adsorption capacity of 8.01 mg·g−1. Finally, the novelty of the reported research consists of using coffee pulp as a bioadsorbent without chemical modification, for the removal of heavy metals, in this case Mn (II), in industrial wastewater, which would be another application of this coffee by-product. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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12 pages, 2533 KiB  
Article
Coffee Pulp: A Sustainable Alternative Removal of Cr (VI) in Wastewaters
by Dora Luz Gómez Aguilar, Juan Pablo Rodríguez Miranda, Javier Andrés Esteban Muñoz and Jhon Fredy Betancur P.
Processes 2019, 7(7), 403; https://doi.org/10.3390/pr7070403 - 1 Jul 2019
Cited by 15 | Viewed by 4324
Abstract
Currently, agricultural waste is proposed as a sustainable alternative in the removal of heavy metals present in industrial wastewater, to fulfill some of the goals proposed in the Sustainable Development Goals stated for the 2030 Agenda, in particular in Sections 3.9 and 6.9. [...] Read more.
Currently, agricultural waste is proposed as a sustainable alternative in the removal of heavy metals present in industrial wastewater, to fulfill some of the goals proposed in the Sustainable Development Goals stated for the 2030 Agenda, in particular in Sections 3.9 and 6.9. Considering this context, the coffee pulp (Castilla variety) of Caldas municipality (Colombia) was used in study for the removal of one of the most toxic chemical species of chromium: Cr (VI). Therefore, the agricultural residue was subjected to a bromatological characterization, determination of the lignocellulosic composition and elucidation of characteristic organic functional groups by IR spectrophotometry. Additionally, the optimal parameters for contaminant removal were identified, regarding particle size, biomass quantity, optimum pH, stirring time, temperature, adsorption kinetics, zero charge potential (pHpzc) and adsorption isotherms, to analyze the kinetic model that fitted the process, the explanation of the possible adsorption mechanism between the contaminant, the surface of the coffee pulp and the capacity of maximum adsorption, respectively. Finally, the innovation of the research is discussed considering two criteria: First, when a mixture was made in different proportions between two agricultural residues (coffee pulp and plantain pseudostem) to show if there was an increase in the removal of the contaminant under the same optimal conditions found experimentally; and the second criterion, the comparison of the maximum adsorption capacity, with the percentages of removal carried out by other authors using the pulp of unmodified coffee. Full article
(This article belongs to the Special Issue Wastewater Treatment Processes)
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