Search Results (48)

Non-exhaust emissions from the wear of brakes, tyres, and roads have become an increasing concern in recent years, already surpassing exhaust emissions by mass in many countries. However, there is a lack of studies in the scientific literature on test methods that include both real tyre and road materials. This is crucial for accurately replicating the tribological mechanisms and resulting emissions that occur during real-world driving. This study therefore employs a scaled experimental approach to investigate the influence of representative urban load and sliding speed conditions on tyre and road wear particle generation using commercial tyre and road materials. Friction, wear, and emissions were analysed using a pin-on-disc tribometer within a controlled environment, enabling the measurement of both airborne and non-airborne wear particles. The results demonstrate that under moderate test conditions, airborne tyre and road wear particle concentrations remained almost zero, with reasonable coefficients of friction and estimated non-airborne emission factors. However, under harsher contact conditions, the coefficients of friction, airborne tyre and road wear concentrations and estimated emission factors increased significantly, leading to excessive material detachment from both the tyre and road surface. These extreme wear conditions are not representative of real-world tyre–road interactions, emphasising the sensitivity and necessity of using more realistic test conditions in future studies. Full article

Brake wear emissions can be reduced by altering the surface of brake disks. A parametric study using a gray cast iron and a laser-cladded brake disk was performed in a pin-on-disk experiment with integrated optical pin surface characterization and particle emission measurement. Significant differences in the friction, wear and emission behavior are present. The high wear-resistance of the laser-cladded disk led to a reduction of 70% of the particle number emission relative to the gray cast iron disk, but the coefficient of friction was unstable. The surface of the pin used with the gray cast iron showed an initial large debris extension and protruding patches that were removed at high braking energies, exposing white patches and creating holes. These observations correspond to known processes from the plateau theory. The surface of the pin used with the laser-cladded disk showed a topography dominated by holes with almost no protruding patches. The braking condition did not influence the pin surface, implying that the disk and not solely the pin surface might be governing the friction process, and therefore challenging the applicability of the plateau theory to laser-cladded disks. To further study this aspect, a segmentation method was developed for the pin surface images and topographical data to extract and quantify different features on the pin, such as debris, patches, holes and the tribolayer. The correlation of the surface coverage ratios of the feature classes with the braking conditions (speed and applied pressure), the coefficient of friction and the emissions confirmed the differences between the gray cast iron and laser-cladded brake disk. Full article

In this paper, results are presented for an on-road measurement campaign for measuring the brake wear particles of disc brakes on a heavy-duty tractor trailer during the EU P012101 Pilot Project funded by the European Parliament. A novel approach was adopted using a fully open sampling system with minimal influence on air flow around the brake and brake disc temperatures. Models for brake disc heating and cooling were developed, as well as a model for the particle number emissions. It was concluded that brake wear emissions per kilometre were the highest on urban roads and the lowest on the motorway. Furthermore, when modelling heating during braking actions, the best results were seen when introducing dependencies on both the braking work and initial brake temperatures. When modelling the brake cooling, a non-linear dependence on the difference between the brake disc temperature and ambient air temperature was empirically observed. For the particle number emissions, a relationship was established between the braking work applied to the disc during the braking action and the particle number emissions of the braking action. Full article

A plasma-assisted electrochemical deposition (PAECD) technology was introduced to coat a cast iron brake disc for the possible reduction of brake wear and brake wear particle (BWP) emission. The majority of the coating consisted of alumina (Al₂O₃), determined by energy dispersive X-ray (EDX) analysis and X-ray diffraction (XRD) analysis. To validate the above strategy of the coating technology for automotive brake corners, one brake stock rotor was replaced by a PAECD-coated rotor for a vehicle road test. After the road test, weight loss of the brake components (rotors and pads) was measured, showing that the alumina coating can reduce the brake wear by more than 70%. BWPs were also collected from wheel barrels, spokes, and brake friction rings of the coated and uncoated rotors during the road test. A morphology and chemical composition analysis of the collected BWPs indicated that the coating could reduce BWP generation from the original sources and avoid a metal pick-up (MPU) issue, leading to less metallic content in BWPs. This alumina coating may provide the auto sector with a sustainable approach to overcome the brake dust emission problem, evidenced by less wear of the brake pads, minimal wear of the coated brake rotor, less MPUs, and a clean wheel rim on the coated brake corner. Full article

Excessive friction at the wheel–rail contact can limit the lifespan of the wheels and rails. Meanwhile, insufficient friction can lead to increased braking distance, risking safety. Top-of-Rail (TOR) products are recognised for their potential to achieve intermediate friction levels at the wheel–rail contact and mitigate wear damages. However, the impact of these products on the airborne wear particles emitted from wheel–rail contact is not thoroughly evaluated. High particle concentration levels, particularly on underground train platforms, raise respiratory and cardiovascular health concerns. This research employs a pin-on-disc to study the effect of laboratory (environmentally acceptable) and commercial TOR products on friction, retentivity, wear, and airborne particle emissions at the wheel–rail interface. The results indicated that TOR products with higher retentivity offered a wider interval of desired intermediate friction levels. The TOR products significantly reduced particle emissions compared to the dry condition. TOR products can, therefore, be promising in controlling friction and mitigating wear and particle emissions at the wheel–rail interface. However, to achieve the benefits of these products, it is essential to tailor their chemical composition carefully. Full article

This study examines long-term trends in fine particulate matter (PM_2.5) composition and oxidative potential in Los Angeles based on data from the University of Southern California’s Particle Instrumentation Unit, with chemical composition retrieved from the EPA’s Air Quality System (AQS). While regulatory interventions have reduced PM_2.5 mass concentration and primary combustion-related components, our findings reveal a more complex toxicity pattern. From 2001 to 2008, the PM_2.5 oxidative potential, measured via the dithiothreitol (DTT) assay, declined from ~0.84 to ~0.16 nmol/min/m³ under stringent tailpipe controls. However, after this initial decline, PM_2.5 DTT stabilized and gradually increased from ~0.35 in 2012 to ~0.97 nmol/min/m³ by 2024, reflecting the growing influence of non-tailpipe emissions such as brake/tire wear. Metals, such as iron (Fe, ~150 ng/m³) and zinc (Zn, ~10 ng/m³), remained relatively stable as organic and elemental carbon (OC and EC) declined, resulting in non-tailpipe contributions dominating PM_2.5 toxicity. Although PM_2.5 mass concentrations were effectively reduced, the growing contribution of non-tailpipe emissions (e.g., brake/tire wear and secondary organic aerosols) underscores the limitations of mass-based standards and tailpipe-focused strategies. Our findings emphasize the need to broaden regulatory strategies, targeting emerging sources that shape PM_2.5 composition and toxicity and ensuring more improvements in public health outcomes. Full article

Extensive research about non-exhaust fine particles from tires and brakes in vehicles has been reported, focusing on the significant effects on air pollution and human harm. Significant investigations are still needed in determining the cause of influence on the environment and human health. The regulations on emissions have been discussed in earnest, starting with the introduction of brake wear particle emission standards in Euro 7. Various indoor and outdoor experiments have been conducted, such as analysis of the amount of wear on tires and brakes, and analysis of the physical and chemical properties of fine particles, and the effect of non-exhaust fine wear particles on the atmosphere and human health, as fundamental data for the introduction of emission standards and the development of low-wear tires and brakes to meet regulations. Recently, international standardized indoor experimental methods for brakes have been announced, and indoor and outdoor experimental methods for tires have been continuously studied to develop international standardized methods. In particular, tire and road wear particles, including brake wear particles, are usually mixed with each other in the non-exhaust particles from a vehicle driving on real roads, and in-depth research is being performed on their accurate classification and characteristic analysis. In this study, the characteristics of the volatile organic compounds and marker substances for tire and tire and road wear particles were analyzed. A system was installed on the vehicle to collect non-exhaust wear fine particles from the vehicle running on two different roads, urban and suburban, of the Seoul area, and the proving ground road. The specific findings are as follows: (1) From the chemical analysis of the volatile organic compounds, high n-hexane and n-dodecane were measured in the tire–road-wear particles. (2) The volatile organic compound species in the PM2.5 (aerodynamic diameter ≤ 2.5 µm) increased as the vehicle velocity increased. (3) For the PM10 (aerodynamic diameter ≤ 10 µm), high volatile organic compound species were recorded at 40 km/h of the vehicle velocity. (4) This study also revealed that higher vinylcyclohexene and dipentene were measured in the particle size below 10 μm than those in PM2.5. Full article

We investigated the effect of lepidocrocite-type layered titanate, which is compounded in brake pads, to reduce brake particle emissions. The dust reduction effect of titanate was evaluated using a small-scale inertial brake material friction test dynamometer. The results suggested that brake particle emissions are related to the microphysical structure of the pad surface, such as the uniformity of the friction film and secondary plateau formation, and that friction materials containing titanate contribute significantly to reducing both particle mass (PM) and particle number (PN) emissions of brake particles in both non-asbestos organic (NAO) and low-steel (LS) pads. In particular, LS pads generally have a problem of having more brake particles than NAO pads, but this study found that brake particles can be significantly reduced by compounding titanate instead of tin sulfide. Full article

Brake wear particles, as the major component of non-exhaust particulate matter, are known to have different emissions, depending on the type of brake assembly and the specifications of the vehicle. In this study, brake wear and wear particle mass emissions were measured under realistic vehicle driving and full friction braking conditions using current commercial genuine brake assemblies. Although there were no significant differences in either PM₁₀ or PM_2.5 emissions between the different cooling air flow rates, brake wear decreased and ultrafine particle (PM_0.12) emissions increased with the increase in the cooling air flow rate. Particle mass measurements were collected on filter media, allowing chemical composition analysis to identify the source of brake wear particle mass emissions. The iron concentration in the brake wear particles indicated that the main contribution was derived from disc wear. Using a systematic approach that measured brake wear and wear particle emissions, this study was able to characterize correlations with elemental compositions in brake friction materials, adding to our understanding of the mechanical phenomena of brake wear and wear particle emissions. Full article

A current challenge in realising clean road transport is non-exhaust emissions. Important advances regarding measurement systems, including well-defined characterisation techniques, as well as regulation, will be made in the next few years. In this work, we present the detailed results of particle emission analyses, consisting of aerosol (size distribution, particle number (PN), and mass (PM)) and electron microscopy (EM) measurements, under different load conditions on a test bed for a wheel suspension and brakes. Standard tyres and brakes from serial production were tested with a high-load driving cycle, while particle measurements were conducted by gravimetric measurements and with a TSI SMPS, a TSI APS, and a GRIMM OPS. Furthermore, samples were analysed by electron microscopy. A bimodal particle size distribution (PSD) was obtained with an SMPS, with peaks at 20 $\mathrm{n}$$\mathrm{m}$ and around 400 $\mathrm{n}$$\mathrm{m}$. The results of an EM analysis of $>1400$ single particles from the electrostatic sampler match the PSD results. The EM analysis also showed ultrafine particles, mainly containing O, Fe, Si, Ba, Mg, and S, and also fractal particles with high-C fractions. Our results suggest, in agreement with the previously published literature, that particulate emissions are related to the brake disc temperature and occur in significant amounts above a threshold temperature. Full article

Brake wear particles are generated through frictional contact between the brake disc or brake drum and the brake pads. Some of these particles may be released into the atmosphere, contributing to airborne fine particulate matter (PM_2.5). In this study, an onboard system was developed and tested to measure brake wear particles emitted under real-world driving conditions. Brake wear particles were extracted from a fixed volume enclosure surrounding the pad and disc installed on the front wheel of a light-duty vehicle. Real-time data on size distribution, number concentration, PM_2.5 mass, and the contribution of semi-volatiles were obtained via a suite of instruments sub-sampling from the constant volume sampler (CVS) dilution tunnel. Repeat measurements of brake particles were obtained from a 42 min bespoke drive cycle on a chassis dynamometer, from on-road tests in an urban area, and from braking events on a test track. The results showed that particle emissions coincided with braking events, with mass emissions around 1 mg/km/brake during on-road driving. Particle number emissions of low volatility particles were between 2 and 5 × 10⁹ particles/km/brake. The highest emissions were observed under more aggressive braking. The project successfully developed a proof-of-principle measurement system for brake wear emissions from transient vehicle operation. The system shows good repeatability for stable particle metrics, such as non-volatile particle number (PN) from the solid particle counting system (SPCS), and allows for progression to a second phase of work where emissions differences between commercially available brake system components will be assessed. Full article

Fine particles from vehicles occur in a range of particulate matter (PM) sizes and influence the roadside atmosphere. The contribution of fine dust from automobiles to road pollution has reportedly been extremely high. Researchers have estimated that non-exhaust fine dust originating from brakes, tires, clutches, and road surface wear rate is increasing. Several studies have shown that brake pads account for a significant proportion of non-exhaust emissions. In this study, a friction test using vehicle brake pads was carried out with a friction tester to reveal the harmfulness of brake pad particles by the driver’s driving habits. Conditions were made considering the pressure, vehicle speed, and temperature and assuming the amount of deceleration of the vehicle. Particle collection devices were used to analyze the concentration of number and the mass distribution of particles produced in the experiment, with a range from 6 nm to 7.3 μm to gauge the toxicity of particles. The results showed that the number concentration of fine particles tended to increase linearly with changes in vehicle deceleration (braking energy) in the particle diameter region around 0.75–7.3 μm. The number concentration of fine particles tended to increase exponentially in the particle diameter region around 71–120 nm. The rapid occurrence of ultrafine particles in nanometers varied depending on the test conditions. Full article

Emissions of brake-wear particles are commonly associated with vehicular traffic. We investigated the feasibility of quantifying brake-wear particle emissions under realistic vehicle driving and braking conditions with a currently used regenerative friction brake coordination system. We used a braking system installed in commercially available plug-in hybrid electric vehicles and found that it reduced emissions by 85% for PM₁₀, 78% for PM₂.₅, and 87% for particle numbers (PNs) compared with the system installed in vehicles with internal combustion engines. Brake friction work showed a linear relationship with PM₁₀ and PM₂.₅. Nanoparticle PM emissions tended to increase slightly with regenerative braking but did not contribute significantly to the overall PM percentage. The emission events of high concentrations of nuclei-mode particles (<20 nm in diameter) in electric vehicle brake assemblies designed for regenerative braking use under high-temperature, high-load braking conditions with full-friction brakes. The nuclei-mode particles amplified the PN emissions and led to high variability. In strict regulatory certification tests where measurement reproducibility and stability are required, it is appropriate to measure PNs under brake conditions appropriate for the actual use of electric vehicles rather than under full-friction brake conditions or to remove particle measurements smaller than 20 nm. Full article

Iron (Fe), the main component of non-exhaust particulates, is known to have variable health effects that depend on the chemical species of iron. This study characterized the possible contribution of iron oxides and hydroxides to airborne brake wear particles under realistic vehicle driving and braking conditions with different brake pad friction materials. We found significant differences in wear factors and PM₁₀ and PM_2.5 emissions between non-asbestos organic (NAO) and European performance (ECE) brake pads. Iron was the dominant contributor to PM₁₀ and PM_2.5 brake wear particles for both NAO and ECE. The iron concentration ratio in the particle mass (PM) was comparable to the disc-to-pads ratio measured by wear mass. The fact that magnetite, which is of interest with respect to health effects, was less abundant in NAO than in ECE suggested that tribo-oxidations occurred in NAO. Metallic iron is generated not only from abrasive wear but also from tribo-chemical reduction with magnetite as the starting material. We found that there were differences in PM emissions between brake friction materials, and that the phase transformations of iron differed between friction materials. These differences were apparent in the distribution of iron oxides and hydroxides. Heat, tribo-oxidation, and tribo-reduction are intricately involved in these reactions. Full article

In this work, we evaluated the impact of disc rotors of gray cast iron (GCI), nitrocarburized (NC), and superhard ceramic-coated (SCC) GCI on the brake wear PM emissions of passenger vehicles using dynamometric measurements. The brake emission factor (BEF) of the SCC was greatly reduced by more than a factor of 1/5 compared with those for the GCI and NC for both low-steel and non-steel friction materials. Surface topological and microstructural analyses confirmed that more severe wear was pronounced for the NC rotor compared with the SCC, as evidenced by large concave pits in the wear tracks. Analysis of the size-classified airborne PM suggests that reduced micron-sized particles, which originated from the GCI disc, were responsible for the lower BEF due to the increased hardness of the SCC. Full article