Search Results (8)

Novel polyester–polyurethane polymeric materials were formulated by combining a natural aliphatic polyester, poly(3-hydroxybutyrate) (P3HB), with a synthetic aliphatic polyurethane via melt blending. The resulting fully biodegradable compositions were functionally modified through the incorporation of urea, with the aim of enabling post-consumer utilization of the material residues as nitrogen-rich fertilizers. The fabrication process was systematically established and optimized, focusing on homogeneous blending and processability. Comprehensive mechanical characterization—including tensile strength, impact resistance, and Shore hardness—was performed. Among the tested formulations, composites containing 1 wt.% urea demonstrated superior mechanical performance and optimal processing behavior. Fourier-transform infrared (FTIR) spectroscopy was employed to investigate molecular-level interactions between polymeric phases and urea, while scanning electron microscopy (SEM) was utilized to assess the morphological characteristics of the resulting biocompositions. Comparative analyses of the physico-mechanical properties and biodegradability were conducted among the urea-modified compositions, binary P3HB–polyurethane blends, and neat P3HB. The observed improvements in mechanical integrity and functional biodegradability suggest that the developed urea-enriched compositions are promising candidates for the fabrication of eco-friendly seedling pots via injection molding technology. Full article

The application of slow-release fertilizers is essential for improving fertilizer utilization efficiency and promoting sustainable agricultural development. Unlike traditional single organic polymer-coated or inorganic-coated fertilizers, this study utilized biodegradable modified polyvinyl alcohol (PVA) as a binder and cheap, readily available phosphogypsum–bentonite as an inorganic coating material to develop a novel slow-release potassium magnesium sulfate fertilizer (SRPMSF). This study initially examined the influence of SA dosage on PVA properties. XRD, FTIR, TGA, and water resistance analyses revealed that sodium alginate exhibits good compatibility with polyvinyl alcohol, enhancing its heat and water resistance. Ultimately, PVA–SA-2 (1.2% sodium alginate) was chosen as the optimal binder for SRPMSF production. Furthermore, this study investigated the impact of bentonite on the physical and slow-release properties of the SRPMSF by varying the phosphogypsum-to-bentonite ratio. This experiment included five treatment methods: the treatments consist of SRPMSF-1 (0 g bentonite), SRPMSF-2 (phosphogypsum/bentonite ratio of 4:1), SRPMSF-3 (3:2), SRPMSF-4 (2:3), and SRPMSF-5 (1:4). A control group (PMSF) was also included. The results indicated that, as the bentonite content increased, both the particle size and compressive strength of the coated slow-release fertilizer increased, with the SRPMSF particle sizes ranging from 3.00 to 4.50 mm. The compressive strength of the SRPMSF ranged from 20.85 to 43.78 N, meeting the requirements for industrial production. The soil column leaching method was employed to assess the nutrient release rate of the fertilizers. The experimental results indicated that, compared to the PMSF, the SRPMSF effectively regulated nutrient release. Pot experiments demonstrated that the SRPMSF significantly enhanced garlic seedling growth compared to the PMSF. In conclusion, a new type of slow-release fertilizer with good slow-release performance is prepared in this paper, which can improve the utilization rate of fertilizer and reduce the economic loss and is conducive to the sustainable development of agriculture. Full article

Widespread use of plastic seedling pots has been attributed to their light weight and durable characteristics. However, these pots have limitations in facilitating efficient root establishment. Recent studies indicate that biodegradable seedling pots not only enhance seedling resilience but are also environmentally sustainable through natural decomposition. This study presents a kinematic analysis of a cabbage transplanting mechanism specifically under development for biodegradable seedling pots, focusing on position, velocity, acceleration, and power. The optimization of link combinations within the transplanting mechanism was analyzed to enhance the transplantation process, focusing on achieving precise depth and spacing for potted seedlings. A kinematic model of the mechanism was developed and simulated using commercial mechanical design and simulation software, followed by validation through performance tests. The proposed transplanter comprised a four-bar-linkage mechanism consisting of a driving link, a driven link, a connecting link, and a guide bar. Simulation trials were conducted by varying the main arm link length while keeping machine forward speed and mechanism driving speed fixed. Results indicated that the optimal mechanism parameters included a driving link of 50 mm, a connecting arm of 120 mm, a guide bar of 120 mm, and an end-effector link of 220 mm. A dibbling hopper length of 153 mm was identified as the most effective for operation. With these recommended link lengths, validated velocities of the end hopper in the ‘X’ and ‘Y’ directions were 284 mm/s and 1379 mm/s, respectively, while corresponding accelerations were measured at 1241 mm/s² and 8664 mm/s². The driving power requirement was calculated to be 17.4 W. These findings suggest that the developed mechanism provides effective planting performance, evidenced by a high degree of seedling uprightness and minimal soil disturbance. This study supports the use of biodegradable pots in mechanized transplanting as a viable alternative to conventional plastic pots, with potential benefits for both agricultural efficiency and environmental sustainability. Full article

The need for biodegradable and environmentally friendly materials is increasing due to resource shortages and rising levels of environmental pollution. Agro-food waste, which includes coffee grounds, is of great interest in the production of composite materials due to its low cost, low density, easy availability, non-abrasive nature, specific properties such as reduced wear on the machinery used, the absence of residues and toxic products, and biodegradable characteristics. The composite materials developed that include coffee grounds exhibit good characteristics. This field is evolving and requires further improvements, but, at this moment, it can be stated that coffee grounds are not just waste but can be transformed into a highly efficient material applicable in various domains. In this study, composite materials were prepared using paper pulp as a matrix, coffee grounds as a filler material, and water as a binding agent. The obtained composite materials were evaluated through thermal analysis, SEM, EDX, ATR-FTIR, and rheological behavior analysis. The composite materials created from paper pulp and coffee grounds proved to be effective for use in the production of seedling pots. The seedling pots created in this study are produced at a low cost, are environmentally friendly, exhibit thermal stability, have good stability over time, and have good resistance to deformation. Full article

In order to improve and alleviate environmental pollution caused by the disposal of seedling pots, a rice straw fiber-based headed vegetable seedling pot material, which is suitable for mechanical transplantation and biodegradable, was studied. Used rice straw as the main raw material, a five-factor and five-level (1/2 full implementation) quadratic regression orthogonal rotation central of rotation combination test method. The experimental factors included the beating degree of rice straw fiber, quantity, the proportion of rice fiber, neutral sizing agents, and wet strength agent mass fraction. The performance evaluation index included dry and wet tensile strength, burst strength, tear strength, air permeance, and degradation period. The results showed that when the parameter combination of the beating degree of rice straw fiber was 50 ± 1°SR, the quantity was 87.5 ± 4 g/m², the proportion of fiber in rice was 70%, the neutral sizing agents mass fraction was 1 ± 0.25%, and the wet strength agent mass fraction was 1.5 ± 0.1%. The dry tensile strength was ≥ 1.8 kN·m⁻¹, the wet tensile strength was ≥ 0.7 kN·m⁻¹, the burst strength was ≥ 140 kPa, the tear strength was ≥ 350 m·N, the air permeance was ≤ 1.33 μm/Pa·s, and the degradation period was ≤ 80 d. The dry tensile strength reduction rate was 0.0274 kN/(m·d) and the wet tensile strength reduction rate was 0.0113 kN/(m·d), during the nursery period [30, 40], while the dry tensile strength was ≥ 1 kN·m⁻¹ and the wet tensile strength was ≥ 0.4 kN·m⁻¹ during the transplanting period. Full article

Mulching techniques can comprise a solution that better utilizes precipitation and irrigation water in such a manner that mitigates soil degradation and drought damage; however, there are still gaps in the literature with regard to the effect of the use of mulch materials on the development of plant–soil–microbe interactions. Waste fibers, as alternative biodegradable mulch materials, are becoming increasingly prominent. The effect of wool mulch (WM) on water use efficiency, with regard to pepper seedlings, was investigated in different soil types (sand, clay loam, peat) in a pot experiment. Two semi-field experiments were also set up to investigate the effect of WM–plant interactions on sweet pepper yields, as compared with agro textiles and straw mulches. Soil parameters (moisture, temperature, DHA, β-glucosidase enzymes, permanganate-oxidizable carbon) were measured during the growing season. The effect of WM on yield and biomass was more significant with the less frequent irrigation and the greater water-holding capacity of soils. Microbiological activity was significantly higher in the presence of plants, and because of the water retention of WM, the metabolic products of roots and the more balanced soil temperature were caused by plants. In the sandy soil, the straw mulch had a significantly better effect on microbiological parameters and yields than the agro textiles and WM. In soils with a higher water capacity, WM is a sustainable practice for improving the biological parameters and water use efficiency of soil. The effect of WM on yields cannot solely be explained by the water retention of the mulch; indeed, the development of biological activity and plant–soil–microbe interactions in the soil are also contributing factors. Full article

This study evaluates the efficacy of using textile waste blended with paper waste to form biodegradable seedling pots. A bio-composite blend of cotton (20% cotton, 40% newspaper, and 40% corrugated cardboard) and polycotton (20% polycotton, 40% newspaper, and 40% corrugated cardboard) with an optimum strength was formed into seedling pots. The appreciated seedling pots (untreated blends of cotton and polycotton) were compared with the commercial pots (cardboard seed starter pot and Jiffy pot) in terms of mechanical properties (tensile strength and compressive strength), biodegradability (soil burial test and anaerobic digestion), and seed germination. The untreated blends of cotton and polycotton pots demonstrated a comparable optimum strength, while the Jiffy pot and cardboard seed starter pot obtained the least tensile and compressive strengths, respectively. The anaerobic biodegradability assay suggests that the cotton blend pot, polycotton blend pot, and cardboard seed starter pot can degrade anaerobically because of high biogas and methane generation potential. A 100% seed germination was observed from the four seedling pots tested. Thus, the results demonstrate the efficacy of utilizing textile waste and paper waste to develop seedling pots with desirable strength and biodegradability compared to the commercial pots. Full article

This study investigates the efficacy of using discarded textile (cotton and polycotton) and paper waste (newspaper and corrugated cardboard) as substrates to form sheets with optimum tensile strength. The effect of alkali treatment (sodium hydroxide (NaOH) and sodium bicarbonate (NaHCO₃)), compressive loads (200 N and 500 N), and the use of binding agents (blackstrap molasses, sodium alginate, and cornstarch) were studied to optimize the tensile strength of homogeneous sheets. The alkali treatment using 5% NaOH for 5 h of soaking demonstrated the highest increase in tensile strength of 21% and 19% for cotton and newspaper, respectively. Increasing compressive load from 200 N to 500 N showed the highest increase in tensile strength of 37% and 42% for cotton and newspaper, respectively. Remarkably, among the binders, cornstarch at 20% concentration obtained an increase in tensile strength of 395%, 320%, 310%, and 185% for cotton, polycotton, corrugated cardboard, and newspaper sheets, respectively. The optimum results obtained from this study will be utilized to develop biodegradable seedling pots using discarded textile and paper waste. Full article