Search Results (13)

Background/Objectives: Full-arch implant-supported prostheses have become a widely accepted solution for edentulous patients, yet long-term biological and mechanical complications remain a clinical concern. Methods: This retrospective study included 70 fully edentulous patients (362 implants) rehabilitated with either fixed or removable implant-supported prostheses. Data were collected on demographics, medical status, type and location of prostheses, implant type, abutments, method of fixation, and complications. Statistical analysis included Fisher’s exact test, the Mann–Whitney U test, and chi-squared tests, with a significance level set at p < 0.05. Results: Mechanical complications occurred in 41.4% of patients (29 out of 70), with framework fractures reported in eight cases (27.6%), ceramic chipping in six cases (20.7%), and resin discoloration in four cases (13.8%). The prostheses were fabricated using monolithic zirconia, metal–ceramic crowns, zirconia on titanium bars, and hybrid resin/PMMA on cobalt–chromium frameworks. Gingival inflammation was also noted in 41.4% of cases (n = 29), predominantly in posterior implant regions. Younger patients and those without systemic diseases showed a significantly higher incidence of mechanical complications. Conclusions: Two years post-treatment, mechanical and biological complications appear to be independent phenomena, not significantly associated with most prosthetic variables. Patient-specific factors, particularly age and general health status, may have greater predictive value than prosthetic design. Limitations of the study include its retrospective design and the lack of radiographic data to assess peri-implant bone changes. Full article

Study design: Trends in the utilization of Mandibulo-Maxillary Fixation (MMF) are shifting nowadays from tooth-borne devices over specialized screws to hybrid MMF devices. Hybrid MMF devices come in self-made Erich arch bar modifications and commercial hybrid MMF systems (CHMMFSs). Objective: We survey the available technical/clinical data. Hypothetically, the risk of tooth root damage by transalveolar screws is diminished by a targeting function of the screw holes/slots. Methods: We utilize a literature review and graphic displays to disclose parallels and dissimilarities in design and functionality with an in-depth look at the targeting properties. Results: Self-made hybrid arch bars have limitations to meet low-risk interradicular screw insertion sites. Technical/clinical information on CHMMFSs is unevenly distributed in favor of the SMARTLock System: positive outcome variables are increased speed of application/removal, the possibility to eliminate wiring and stick injuries and screw fixation with standoff of the embodiment along the attached gingiva. Inferred from the SMARTLock System, all four CHMMFs possess potential to effectively prevent tooth root injuries but are subject to their design features and targeting with the screw-receiving holes. The height profile and geometry shape of a CHMMFS may restrict three-dimensional spatial orientation and reach during placement. To bridge between interradicular spaces and tooth equators, where hooks or tie-up-cleats for intermaxillary cerclages should be ideally positioned under biomechanical aspects, can be problematic. The movability of their screw-receiving holes according to all six degrees of freedom differs. Conclusion: CHMMFSs allow simple immobilization of facial fractures involving dental occlusion. The performance in avoiding tooth root damage is a matter of design subtleties. Full article

Study design: The advent of the Matrix Wave^TM System (Depuy-Synthes)—a bone-anchored Mandibulo-Maxillary Fixation (MMF) System—merits closer consideration because of its peculiarities. Objective: This study alludes to two preliminary stages in the evolution of the Matrix Wave^TM MMF System and details its technical and functional features. Results: The Matrix Wave^TM System (MWS) is characterized by a smoothed square-shaped Titanium rod profile with a flexible undulating geometry distinct from the flat plate framework in Erich arch bars. Single MWS segments are Omega-shaped and carry a tie-up cleat for interarch linkage to the opposite jaw. The ends at the throughs of each MWS segment are equipped with threaded screw holes to receive locking screws for attachment to underlying mandibular or maxillary bone. An MWS can be partitioned into segments of various length from single Omega-shaped elements over incremental chains of interconnected units up to a horseshoe-shaped bracing of the dental arches. The sinus wave design of each segment allows for stretch, compression and torque movements. So, the entire MWS device can conform to distinctive spatial anatomic relationships. Displaced fragments can be reduced by in-situ-bending of the screw-fixated MWS/Omega segments to obtain accurate realignment of the jaw fragments for the best possible occlusion. Conclusion: The Matrix Wave^TM MMF System is an easy-to-apply modular MMF system that can be assembled according to individual demands. Its versatility allows to address most facial fracture scenarios in adults. The option of “omnidirectional” in-situ-bending provides a distinctive feature not found in alternate MMF solutions. Full article

In this paper, a novel process for synergistic carbon in situ capture and the utilization of blast furnace gas is proposed to produce CO via chemical looping. Through thermodynamic analysis, this process was studied in terms of the carbon fixation rate, CO yield, in situ CO₂ utilization rate, CH₄ conversion rate and energy consumption. It provides valuable insights for achieving efficient CO₂ capture and in situ conversion. FeO and CaO are used as the oxygen carrier and the carbon carrier, respectively. Under the conditions of reaction temperature of 400 °C, pressure of 1 bar and FeO/CO ratio of 1, the carbon capture rate of blast furnace gas can reach more than 99%. In the carbon release reactor, the CO yield is lower than that in the original blast furnace gas (BFG) if no reduction gas is involved. Therefore, methane is introduced as a reducing gas to increase CO yield. When the reaction temperature is increased to 1000 °C, the pressure level is reduced to 0.01 bar and the CH₄/C ratio is 1:1 (methane to carbon), the CO yield is four times that of the initial blast furnace gas. Under the optimal conditions, the energy consumption of the system is 0.2 MJ/kg, which is much lower than that of the traditional process. This paper verifies the feasibility of the new process from the perspective of thermodynamics. Full article

Since the groundbreaking work by Cleveland and McGill in 1984, studies have revealed the difficulties humans have extracting quantitative data from visualizations as simple as bar graphs. As a first step toward understanding this situation, this paper proposes a mathematical model of the interpretation effort of a bar graph using concepts drawn from eye tracking. First, three key areas of interest (AOIs) are identified, and fixations are modeled as random point clouds within the AOIs. Stochastic geometry is introduced via random triangles connecting fixations within the adjacent key visual regions. The so-called landmark methodology provides the basis for the probabilistic analysis of the constructed system. It is found that the random length of interest in a stochastic triangle has a noncentral chi distribution with a known mean. Unique to this model, in terms of previous landmark applications, is the inclusion of a correlation between fixations, which is justified by physiological studies of the eyes. This approach introduces several model parameters, such as the noncentrality parameter, variance of the fixation cloud, correlation between fixations, and a visualization scale. A detailed parametric analysis examining the dependence of the mean on these parameters is conducted. The paper ties this work to the visualization via a definition of the expected visual measurement error. An asymptotic analysis of the visual error is performed, and a simple expression is found to relate the expected visual measurement error to the key model parameters. From this expression, the influence these parameters have on a visualization’s interpretation is considered. Full article

The most important part of fruit cultivation is transplanting, which can be completed efficiently by an automatic transplanter. In this study, an automatic solanum lycopersicum transplanter was developed. It is primarily composed of the following devices: a seedling tray fixator, a mechanical transplanting arm, double horizontal driving modules, double vertical driving cylinders, a seedling separation device, double-crank five-bar planting devices, a power distribution system, and a PLC control system. An experimental test on an automatic transplanter was carried out on dry land. The experimental results showed that when the planting frequency was 80 plants/(min·row), the transplanting success rate was 93.89%, the missed planting rate was 1.58%, the replanting rate was 0.65%, the lodging rate was 1.94%, and the exposed seedling rate was 1.94%. Each device of the automatic transplanter was coordinated to complete the transplanting process. The automatic transplanter met the operation requirements, and it not only transplanted in dry land but also provided a theoretical basis for fruit cultivation in solar greenhouses in the future. Full article

Conversion of CO₂ into organic chemicals offers a promising route for advancing the circularity of carbon capture, utilisation, and storage in line with the international 2050 Net Zero agenda. The widely known commercialised chemical fixation of CO₂ into organic chemicals is the century-old Kolbe–Schmitt reaction, which carboxylates phenol (via sodium phenoxide) into salicylic acid. The carboxylation reaction is normally carried out between the gas–solid phases in a batch reactor. The mass and heat transfer limitations of such systems require rather long reaction times and a high pressure of CO₂ and are often characterised by the low formation of undesirable side products. To address these drawbacks, a novel suspension-based carboxylation method has been designed and carried out in this present study, where sodium phenoxide is dispersed in toluene to react with CO₂. Importantly, the addition of phenol played a critical role in promoting the stoichiometric conversion of phenoxide to salicylic acid. Under the optimal conditions of a phenol/phenoxide molar ratio of 2:1 in toluene, a reaction temperature of 225 °C, a CO₂ pressure of 30 bar, a reaction time of 2 h, and stirring at 1000 rpm, an impressive salicylic acid molar yield of 92.68% has been achieved. The reaction mechanism behind this has been discussed. This development provides us with the potential to achieve a carboxylation reaction of phenoxide with CO₂ more effectively in a continuous reactor. It can also facilitate the large-scale fixing of CO₂ into hydroxy aromatic carboxylic acids, which can be used as green organic chemical feedstocks for making various products, including long-lived polymeric materials. Full article

Today, an interdisciplinary approach to solving the problems of implantology is key to the effective use of intraosseous dental implantations. The functional properties of restoration structures for the dentition depend significantly on the mechanical stresses that occur in the structural elements and bone tissues in response to mastication loads. An orthopedic design with a bar fixation system connected to implants may be considered to restore an edentulous mandible using an overdenture. In this study, the problem of the mechanics of a complete overdenture based on a bar and four implants was formulated. A mathematical model of the interaction between the orthopedic structure and jawbone was developed, and a methodology was established for the analytical study of the stress state of the implants and adjacent bone tissue under the action of a chewing load. The novelty of the proposed model is that it operates with the minimum possible set of input data and provides adequate estimates of the most significant output parameters that are necessary for practical application. The obtained analytical results are illustrated by two examples of calculating the equivalent stresses in implants and the peri-implant tissue for real overdenture designs. To carry out the final assessment of the strength of the implants and bone, the prosthesis was loaded with mastication loads of different localization. In particular, the possibilities of loading the prosthesis in the area of the sixth and seventh teeth were investigated. Recommendations on the configuration of the distal cantilever of the overdenture and the acceptable level and distribution of the mastication load are presented. It was determined that, from a mechanical point of view, the considered orthopedic systems are capable of providing long-term success if they are used in accordance with established restrictions and recommendations. Full article

The monitoring of fracture or osteotomy healing is vital for orthopedists to help advise, if necessary, secondary treatments for improving healing outcomes and minimizing patient suffering. It has been decades since osteotomy stiffness has been identified as one main parameter to quantify and qualify the outcome of a regenerated callus. Still, radiographic imaging remains the current standard diagnostic technique of orthopedists. Hence, with recent technological advancements, engineers need to use the new branches of knowledge and improve or innovate diagnostic technologies. An electromechanical system was developed to help diagnose changes in osteotomy stiffness treated with the external fixator LRS Orthofix^®. The concept was evaluated experimentally and numerically during fracture healing simulation using two different models: a simplified model of a human tibia, consisting of a nylon bar with a diameter of 30 mm, and a synthetic tibia with the anatomical model from fourth-generation Sawbones^®. Moreover, Sawbones^® blocks with different densities simulated the mechanical characteristics of the regenerated bone in many stages of bone callus growth. The experimental measurements using the developed diagnostic were compared to the numerically simulated results. For this external fixator, it was possible to show that the displacement in osteotomy was always lower than the displacement prescribed in the elongator. Nevertheless, a relationship was established between the energy consumption by the electromechanical system used to perform callus stimulus and the degree of osteotomy consolidation. Hence, this technology may lead to methodologies of mechanical stimulation for regenerating bone, which will play a relevant role for bedridden individuals with mobility limitations. Full article

Medical titanium alloys are widely used in surgery, orthopedics, stomatology and other medical specialties because of their good biocompatibility. In traditional rigid internal fixation applications, titanium alloy strips or plates must be bent to fit the supported surface. Currently, the common practice is to bend titanium alloy bars in three degrees of freedom manually. However, it is difficult to ensure bending accuracy and achieve the best shape. In this study, we introduce a forming robot for internally fixed titanium alloy strips (FRIFTAS). The forming robot is a device that automatically reshapes the titanium strip with various specifications according to medical needs. Here, the design of mechanical and electrical systems and the development of the overall system are described to illustrate how a FRIFTAS is structured and designed. Three bending experimental tests are conducted. In the bending experiments, the robot bends an initial strip on the roll, pitch and yaw directions independently. The results show that the robot can bend a section of the alloy strip at the desired angle. Then, an overall reshaped titanium alloy strip experiment is discussed. The results show that the titanium-strip-forming robot is capable of automatically reshaping an internally fixed titanium strip. The proposed robot can perform the numerically controlled bending of the medical titanium strip according to physicians’ personalized requirements for surgery to improve the accuracy and efficiency of preoperative preparation and provide a better postoperative appearance and more effectively functioning treatment scheme for patients. Full article

Abiotic fixation of atmospheric dinitrogen to ammonia is important in prebiotic chemistry and biological evolution in the Hadean and Archean oceans. Though it is widely accepted that nitrate (NO₃⁻) was generated in the early atmospheres, the stable pathways of ammonia production from nitrate deposited in the early oceans remain unknown. This paper reports results of the first experiments simulating high-temperature, high-pressure reactions between nitrate and komatiite to find probable chemical pathways to deliver ammonia to the vent–ocean interface of komatiite-hosted hydrothermal systems and the global ocean on geological timescales. The fluid chemistry and mineralogy of the komatiite–H₂O–NO₃⁻ system show iron-mediated production of ammonia from nitrate with yields of 10% at 250 °C and 350 °C, 500 bars. The komatiite–H₂O–NO₃^– system also generated H₂-rich and alkaline fluids, well-known prerequisites for prebiotic and primordial metabolisms, at lower temperatures than the komatiite–H₂O–CO₂ system. We estimate the ammonia flux from the komatiite-hosted systems to be 10⁵–10¹⁰ mol/y in the early oceans. If the nitrate concentration in the early oceans was greater than 10 μmol/kg, the long-term production of ammonia through thermochemical nitrate reduction for the first billion years might have allowed the subsequent development of an early biosphere in the global surface ocean. Our results imply that komatiite-hosted systems might have impacted not only H₂-based chemosynthetic ecosystems at the vent-ocean interface but also photosynthetic ecosystems on the early Earth. Full article

(1) Objective: External fixation systems are commonly used by surgeons to ensure stabilization and consolidation of bone fractures, especially in patients who are at high risk for systematic complications. Both rigid and elastic external fixations are important in the fracture healing process. This study aims to evaluate the behavior of the Orthofix Limb Reconstruction System (LRS)^® in the dynamic compression mode. (2) Methods: Experimental and numerical setups were developed using a simplified model of a human tibia which consisted of a nylon bar with a diameter of 30 mm. The bone callus was included in both setups by means of a load cell-based system, which consisted of two carbon epoxy laminated composite plates with a final stiffness of 220 N/mm. The system was evaluated experimentally and numerically, considering different numbers of pins and comparing distances between the external fixator frame and the bone, achieving a good correlation between experimental and numerical results. (3) Results: The results identified and quantified the percental load transferred to the fracture and its sensibility to the distance between the external fixator and bone. Additionally, LRS locking stiffness was evaluated which resulted from the clamp-rail clearances. The results show that the blocking effects of the free clamp movement are directly related to the fixator configuration and are responsible for changes in the amount of load that crosses the bone callus. (4) Conclusions: From the biomechanical point of view, the results suggest that the average bending span of Schanz pins and the weights of the patients should be included into clinical studies of external fixators comparisons purpose. Full article

Superbases have shown high performance as catalysts in the chemical fixation of CO₂ to epoxides. The proposed reaction mechanism typically assumes the formation of a superbase, the CO₂ adduct as the intermediate, most likely because of the well-known affinity between superbases and CO₂, i.e., superbases have actually proven quite effective for CO₂ absorption. In this latter use, concerns about the chemical stability upon successive absorption-desorption cycles also merits attention when using superbases as catalysts. In this work, ¹H NMR spectroscopy was used to get further insights about (1) whether a superbase, the CO₂ adduct, is formed as an intermediate and (2) the chemical stability of the catalyst after reaction. For this purpose, we proposed as a model system the chemical fixation of CO₂ to epichlorohydrin (EP) using a deep eutectic solvent (DES) composed of a superbase, e.g., 2,3,4,6,7,8-hexahydro-1H-pyrimido[1,2-a]pyrimidine (TBD) or 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine (DBU), as a hydrogen acceptor and an alcohol as a hydrogen bond donor, e.g., benzyl alcohol (BA), ethylene glycol (EG), and methyldiethanolamine (MDEA), as the catalyst. The resulting carbonate was obtained with yields above 90% and selectivities approaching 100% after only two hours of reaction in pseudo-mild reaction conditions, e.g., 1.2 bars and 100 °C, and after 20 h if the reaction conditions of choice were even milder, e.g., 1.2 bars and 50 °C. These results were in agreement with previous works using bifunctional catalytic systems composed of a superbase and a hydrogen bond donor (HBD) also reporting good yields and selectivities, thus confirming the suitability of our choice to perform this study. Full article