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Keywords = amorphous wires

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20 pages, 2969 KiB  
Article
A New Device for Measuring Trunk Diameter Variations Using Magnetic Amorphous Wires
by Cristian Fosalau
Sensors 2025, 25(14), 4449; https://doi.org/10.3390/s25144449 - 17 Jul 2025
Viewed by 270
Abstract
Measuring the small tree trunk variations during the day–night cycle, seasonal cycles, as well as those caused by the plant’s growth and health regime is a very important action in horticulture or forestry because by analyzing the collected data, assessments can be made [...] Read more.
Measuring the small tree trunk variations during the day–night cycle, seasonal cycles, as well as those caused by the plant’s growth and health regime is a very important action in horticulture or forestry because by analyzing the collected data, assessments can be made on the health of the trees, but also on the climatic conditions and changes in a certain region. This can be performed with devices called dendrometers. This paper presents a new type of approach to these measurement types in which the trunk volume changes are highly sensitively converted into the axial stress on sensitive elements made of magnetic materials in wire form in which the giant stress impedance effect occurs. Finally, by electronic processing of the signals provided by the sensitive elements, digital words with a decimal value proportional to the diameter variations are obtained. This paper presents the operating principle, the constructive details and the experimental results obtained by testing the device in the laboratory and in-field. The proposed dendrometer, compared to those available commercially, has the advantage of good resolution and sensitivity, good immunity to temperature variations, the possibility of transmitting the result remotely, robustness and low price. Some metrological parameters obtained from the experimental testing are the following: resolution 1.6 µm, linearity 1.4%, measurement range 0 to 5 mm, temperature coefficient 0.012%/°C. Full article
(This article belongs to the Special Issue Magnetic Field Sensing and Measurement Techniques)
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12 pages, 19666 KiB  
Article
Modulation of Giant Magnetoimpedance Effect in Co-Based Amorphous Wires by Carbon-Based Nanocoatings
by Zhen Yang, Jiabao Huang, Jingyuan Chen and Chong Lei
C 2025, 11(2), 26; https://doi.org/10.3390/c11020026 - 1 Apr 2025
Viewed by 1116
Abstract
Co-based amorphous wires (Co-AWs) are functional materials renowned for their high impedance change rate in magnetic fields and a pronounced giant magnetoimpedance (GMI) effect. In this study, magnetron sputtering (MS) and dip-coating (DC) techniques were employed to fabricate carbon-based nanocoatings aimed at modulating [...] Read more.
Co-based amorphous wires (Co-AWs) are functional materials renowned for their high impedance change rate in magnetic fields and a pronounced giant magnetoimpedance (GMI) effect. In this study, magnetron sputtering (MS) and dip-coating (DC) techniques were employed to fabricate carbon-based nanocoatings aimed at modulating the GMI properties of Co-AWs. The magnetic properties and GMI responses of the composite Co-AWs with carbon-based coatings were comparatively analyzed. The results demonstrate that both methods effectively enhanced the GMI properties of the coated Co-AWs. The DC method emerged as a rapid and efficient approach for forming the coated film, achieving a modest enhancement in GMI performance (10% enhancement). In contrast, the MS technique proved more effective in improving the GMI effect, yielding superior results. Co-AWs coated via Ms exhibited smoother surfaces and reduced coercivity. Notably, the GMI effect increased with the thickness of the sputtered carbon coatings, reaching a maximum GMI effect of 522% (a remarkable 357% enhancement) and a sensitivity of 33.8%/Oe at a coating thickness of 334 nm. The observed trend in the GMI effect with carbon layer thickness corresponded closely to variations in transverse permeability, as determined by vibrating sample magnetometry (VSM). Furthermore, the carbon coating induced changes in the initial quenching stress on the surface of the Co-AWs, leading to alterations in impedance and a significant reduction in the characteristic frequency of the Co-AWs. Our findings provide valuable insights into the modulation of GMI properties in Co-AWs, paving the way for their optimized application in advanced magnetic sensor technologies. Full article
(This article belongs to the Section Carbon Materials and Carbon Allotropes)
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10 pages, 2196 KiB  
Article
Solar Fabric Based on Amorphous Silicon Thin Film Solar Cells on Flexible Textiles
by Jonathan Plentz, Uwe Brückner, Gabriele Schmidl, Annett Gawlik, Klaus Richter and Gudrun Andrä
Energies 2025, 18(6), 1448; https://doi.org/10.3390/en18061448 - 15 Mar 2025
Viewed by 920
Abstract
Three-dimensional flexible solar fabrics based on hydrogenated amorphous silicon (a-Si:H) thin film solar cells were prepared and characterized. A glass fiber fabric with a polytetrafluoroethylene (PTFE) coating proved to be a suitable textile substrate. Interwoven metal wires enable an integrated electrical interconnection. An [...] Read more.
Three-dimensional flexible solar fabrics based on hydrogenated amorphous silicon (a-Si:H) thin film solar cells were prepared and characterized. A glass fiber fabric with a polytetrafluoroethylene (PTFE) coating proved to be a suitable textile substrate. Interwoven metal wires enable an integrated electrical interconnection. An array of solar cells consisting of an a-Si:H layer stack with a highly p-type/intrinsic/highly n-type doping profile was deposited onto it. Silver was used as the back contact with indium tin oxide (ITO) as the front contact. The best solar cells show an efficiency of 3.9% with an open-circuit voltage of 876 mV and a short-circuit current density of 11.4 mA/cm2. The high series resistance limits the fill factor to 39%. The potential of the textile solar cells is shown by the achieved pseudo fill factor of 79% when neglecting the series resistance, resulting in a pseudo efficiency of 7.6%. With four textile solar cells connected in a series, an open-circuit voltage of about 3 V is achieved. Full article
(This article belongs to the Special Issue Recent Advances in Solar Cells and Photovoltaics)
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15 pages, 15952 KiB  
Article
Synthesis of the Titanium Oxides Using a New Microwave Discharge Method
by Marian Mogildea, George Mogildea, Sorin I. Zgura, Gabriel Chiritoi, Cristian Ionescu, Valentin Craciun, Petronela Prepelita, Natalia Mihailescu, Alexandru Paraschiv, Bogdan Stefan Vasile and Catalin Daniel Constantinescu
Int. J. Mol. Sci. 2025, 26(5), 2173; https://doi.org/10.3390/ijms26052173 - 28 Feb 2025
Viewed by 632
Abstract
This research highlights the different behaviors of titanium (Ti) wires under the action of 500 W and 800 W microwave power levels. Following the interaction between microwaves and a titanium wire placed in the node of the (TM011—transverse magnetic mode) waveguide [...] Read more.
This research highlights the different behaviors of titanium (Ti) wires under the action of 500 W and 800 W microwave power levels. Following the interaction between microwaves and a titanium wire placed in the node of the (TM011—transverse magnetic mode) waveguide in air at atmospheric pressure, plasma was generated. Using optical emission spectroscopy technique it was observed that during plasma generation at 500 W and 800 W microwaves powers, metallic ions, and gas ions were created, and the plasmas fulfilled the local thermodynamic equilibrium (LTE) conditions. The XRD analysis showed that on the surface of the Ti wire exposed to 500 W microwave power a mixture of titanium dioxide (TiO2) and titanium oxide (TiO) grew, while the Ti wire exposed to 800 W microwave power was completely vaporized and a mixture of TiO2 and TiO nanoparticles was synthesized. The SEM analysis showed that the dimensions of the titanium oxide (TiOx) nanoparticles generated by both microwave discharges ranged from 5 nm to 200 nm. The results of EDS analysis showed that the power of microwaves plays an important role in quantitative conversion from Ti wire into a TiOx mixture. The TEM analysis indicates that most of the nanoparticles are either amorphous or nanocrystalline. Using this simple and inexpensive technique one can grow a TiOx layer on the surface of titanium electrodes or can synthetize nanocrystalline TiOx particles. Full article
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13 pages, 3123 KiB  
Article
Fabrication of a Portable Magnetic Microcantilever Using Fe40Ni38Mo4B18 Amorphous Ribbon and Its Application as a Humidity Sensor by Coating with TiO2 Nanotubes
by Selçuk Atalay, Sema Erdemoglu, Hatice Çağlar Yılmaz, Emine Mete, Orhan Orcun Inan and Veli Serkan Kolat
Magnetochemistry 2024, 10(12), 98; https://doi.org/10.3390/magnetochemistry10120098 - 5 Dec 2024
Cited by 1 | Viewed by 1016 | Correction
Abstract
Microcantilevers (MCs) are highly sensitive sensors capable of detecting mass changes on the surface at the nanogram and even picogram scale. In this study, microcantilevers were fabricated for the first time using the Sodick AP250L Wire electrical discharge machining (EDM) from amorphous 2826MB [...] Read more.
Microcantilevers (MCs) are highly sensitive sensors capable of detecting mass changes on the surface at the nanogram and even picogram scale. In this study, microcantilevers were fabricated for the first time using the Sodick AP250L Wire electrical discharge machining (EDM) from amorphous 2826MB (Fe40Ni38Mo4B18) ferromagnetic ribbons. This method is advantageous because it allows for the simultaneous production of a large number of microcantilevers, with about 100 MCs being produced in a single manufacturing process. Additionally, a straightforward and cost-effective measurement system was developed to measure the resonance frequency and frequency shift of the MC entirely through magnetic means, a technique not previously reported in the literature. To evaluate the performance of the MC, we employed it as a humidity sensor. For the TiO2-NT-coated MC, a frequency shift of approximately 202 Hz was observed when the humidity level changed from 5% to 95% relative humidity (RH). Full article
(This article belongs to the Section Applications of Magnetism and Magnetic Materials)
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12 pages, 6682 KiB  
Article
Material Removal Mechanisms of Polycrystalline Silicon Carbide Ceramic Cut by a Diamond Wire Saw
by Huyi Yang, Ming Fu, Xin Zhang, Kailin Zhu, Lei Cao and Chunfeng Hu
Materials 2024, 17(17), 4238; https://doi.org/10.3390/ma17174238 - 27 Aug 2024
Cited by 3 | Viewed by 1354
Abstract
Polycrystalline silicon carbide (SiC) is a highly valuable material with crucial applications across various industries. Despite its benefits, processing this brittle material efficiently and with high quality presents significant challenges. A thorough understanding of the mechanisms involved in processing and removing SiC is [...] Read more.
Polycrystalline silicon carbide (SiC) is a highly valuable material with crucial applications across various industries. Despite its benefits, processing this brittle material efficiently and with high quality presents significant challenges. A thorough understanding of the mechanisms involved in processing and removing SiC is essential for optimizing its production. In this study, we investigated the sawing characteristics and material removal mechanisms of polycrystalline silicon carbide (SiC) ceramic using a diamond wire saw. Experiments were conducted with high wire speeds of 30 m/s and a maximum feed rate of 2.0 mm/min. The coarseness value (Ra) increased slightly with the feed rate. Changes in the diamond wire during the grinding process and their effects on the grinding surface were analyzed using scanning electron microscopy (SEM), laser confocal microscopy, and focused ion beam (FIB)-transmission electron microscopy (TEM). The findings provide insights into the grinding mechanisms. The presence of ductile grinding zones and brittle fracture areas on the ground surface reveals that external forces induce dislocation and amorphization within the grain structure, which are key factors in material removal during grinding. Full article
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14 pages, 1327 KiB  
Article
Microfluidic Detection of SPIONs and Co-Ferrite Ferrofluid Using Amorphous Wire Magneto-Impedance Sensor
by Gabriele Barrera, Federica Celegato, Marta Vassallo, Daniele Martella, Marco Coïsson, Elena S. Olivetti, Luca Martino, Hüseyin Sözeri, Alessandra Manzin and Paola Tiberto
Sensors 2024, 24(15), 4902; https://doi.org/10.3390/s24154902 - 28 Jul 2024
Cited by 5 | Viewed by 2120
Abstract
The detection of magnetic nanoparticles in a liquid medium and the quantification of their concentration have the potential to improve the efficiency of several relevant applications in different fields, including medicine, environmental remediation, and mechanical engineering. To this end, sensors based on the [...] Read more.
The detection of magnetic nanoparticles in a liquid medium and the quantification of their concentration have the potential to improve the efficiency of several relevant applications in different fields, including medicine, environmental remediation, and mechanical engineering. To this end, sensors based on the magneto-impedance effect have attracted much attention due to their high sensitivity to the stray magnetic field generated by magnetic nanoparticles, their simple fabrication process, and their relatively low cost. To improve the sensitivity of these sensors, a multidisciplinary approach is required to study a wide range of soft magnetic materials as sensing elements and to customize the magnetic properties of nanoparticles. The combination of magneto-impedance sensors with ad hoc microfluidic systems favors the design of integrated portable devices with high specificity towards magnetic ferrofluids, allowing the use of very small sample volumes and making measurements faster and more reliable. In this work, a magneto-impedance sensor based on an amorphous Fe73.5Nb3Cu1Si13.5B9 wire as the sensing element is integrated into a customized millifluidic chip. The sensor detects the presence of magnetic nanoparticles in the ferrofluid and distinguishes the different stray fields generated by single-domain superparamagnetic iron oxide nanoparticles or magnetically blocked Co-ferrite nanoparticles. Full article
(This article belongs to the Special Issue Challenges and Future Trends of Magnetic Sensors)
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11 pages, 6653 KiB  
Communication
Performance of Fluxgate Magnetometer with Cu-Doped CoFeSiB Amorphous Microwire Core
by Bin Wang, Weizhi Xu, Xiaoping Zheng, Sida Jiang, Zhong Yi, Peng Wang and Xiaojin Tang
Sensors 2024, 24(1), 309; https://doi.org/10.3390/s24010309 - 4 Jan 2024
Cited by 2 | Viewed by 3075
Abstract
In this study, we investigated the effects of Cu doping on the performance of CoFeSiB amorphous microwires as the core of a fluxgate magnetometer. The noise performance of fluxgate sensors primarily depends on the crystal structure of constituent materials. CoFeSiB amorphous microwires with [...] Read more.
In this study, we investigated the effects of Cu doping on the performance of CoFeSiB amorphous microwires as the core of a fluxgate magnetometer. The noise performance of fluxgate sensors primarily depends on the crystal structure of constituent materials. CoFeSiB amorphous microwires with varying Cu doping ratios were prepared using melt-extraction technology. The microstructure of microwire configurations was observed using transmission electron microscopy, and the growth of nanocrystalline was examined. Additionally, the magnetic performance of the microwire and the noise of the magnetic fluxgate sensors were tested to establish the relationship between Cu-doped CoFeSiB amorphous wires and sensor noise performance. The results indicated that Cu doping triggers a positive mixing enthalpy and the reduced difference in the atomic radius that enhances the degree of nanocrystalline formation within the system; differential scanning calorimetry analysis indicates that this is due to Cu doping reducing the glass formation capacity of the system. In addition, Cu doping affects the soft magnetic properties of amorphous microwires, with 1% low-doping samples exhibiting better soft magnetic properties. This phenomenon is likely the result of the interaction between nanocrystalline organization and magnetic domains. Furthermore, a Cu doping ratio of 1% yields the best noise performance, aligning with the trend observed in the material’s magnetic properties. Therefore, to reduce the noise of the CoFeSiB amorphous wire sensor, the primary goal should be to reduce microscopic defects in amorphous alloys and enhance soft magnetic properties. Cu doping is a superior preparation method which facilitates control over preparation conditions, ensuring the formation of stable amorphous wires with consistent performance. Full article
(This article belongs to the Special Issue Advances in Magnetic Sensors and Their Applications)
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25 pages, 15623 KiB  
Article
Thermal Evaluation of Silica-Based Insulated Magnet Wires from the Sol–Gel Process
by Giovana Pereira dos Santos Lima, Sonia Ait-Amar, Gabriel Velu, Philippe Frezel, Abdelhamid Boudiba, Soumaya Lafqir, Arnaud Nicolay, Pierre-yves Herze and Mireille Poelman
Gels 2023, 9(8), 619; https://doi.org/10.3390/gels9080619 - 31 Jul 2023
Cited by 2 | Viewed by 1786
Abstract
The conventional enameling process used in the fabrication of magnet wires requires harmful processes and products. The target of the industry in the actual context of electrification is to increase the electrical machines’ efficiency. Indeed, the electrical insulation systems (EIS) of an electrical [...] Read more.
The conventional enameling process used in the fabrication of magnet wires requires harmful processes and products. The target of the industry in the actual context of electrification is to increase the electrical machines’ efficiency. Indeed, the electrical insulation systems (EIS) of an electrical machine undergo various environmental constraints that can shorten their lifespans. Consequently, aspects of the insulation need to be improved, such as its thermal resistance. One of the challenges is to implement sustainable technology without losing performance. This work consists of the thermal performance evaluation of new magnet wires insulated by three types of composites of silica-based solution from the Sol–gel process and amorphous polyamide-imide (PAI). These composite coats are overcoated by an extruded thermoplastic resin with and without fillers. Different types of insulation are tested and compared to determine the better configuration. Thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR) analysis, scanning electron microscopy (SEM) analysis, curing characteristics by tangent delta curve, and thermal-aging tests at three temperatures were carried out on the different EIS systems. Dielectric measurements were made between thermal-aging cycles. Their basic mechanical, electrical, and thermal characteristics are promising: the cut-through temperature is situated above 430 °C, their breakdown voltage values are between 5 kV and 9 kV (grade 3), and a good adhesion (overcoming more than 140 turns on a peel test). The thermal-aging results have been consistent with the TGA analysis results. The thermal index following the IEC standards was estimated for the selected EIS, which would have the main basic characteristics of a magnet wire of 200 class; moreover, it would be a greener enameled wire compared to the conventional one. Full article
(This article belongs to the Special Issue Advances in Functional Gel)
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11 pages, 5331 KiB  
Article
Measurements of Stray Magnetic Fields of Fe-Rich Amorphous Microwires Using a Scanning GMI Magnetometer
by Georgy Danilov, Yury Grebenshchikov, Vladimir Odintsov, Margarita Churyukanova and Sergey Gudoshnikov
Metals 2023, 13(4), 800; https://doi.org/10.3390/met13040800 - 19 Apr 2023
Cited by 5 | Viewed by 1876
Abstract
A scanning magnetometer based on a magnetoimpedance sensor with a 1 mm spatial resolution and 10 nT sensitivity was used to study stray magnetic fields of Fe74B13Si11C2 amorphous ferromagnetic microwires. Spatial magnetic images and vertical component [...] Read more.
A scanning magnetometer based on a magnetoimpedance sensor with a 1 mm spatial resolution and 10 nT sensitivity was used to study stray magnetic fields of Fe74B13Si11C2 amorphous ferromagnetic microwires. Spatial magnetic images and vertical component profiles of stray magnetic fields of the studied microwires were obtained in a longitudinal homogeneous magnetic field of Helmholtz coils with a strength in the range of ±600 A/m. A magnetic calculation method is suggested that allows for using the measured magnetic fields to determine the magnitude and pattern of magnetization for the microwire. Characteristic values of the microwires’ average magnetization and width of closure domains for various values of bias fields were found. Full article
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9 pages, 3013 KiB  
Communication
Observation of Magnetic Domains in Amorphous Magnetic Wires with a Diameter of 10 μm Used in GSR Sensors
by Masaaki Takezawa, Yuki Harada, Yoshinobu Honkura and Shinpei Honkura
Sensors 2023, 23(7), 3506; https://doi.org/10.3390/s23073506 - 27 Mar 2023
Cited by 4 | Viewed by 2178
Abstract
The core of a Gigahertz Spin Rotation (GSR) sensor, a compact and highly sensitive magnetic sensor, is composed of Co–Fe-based amorphous magnetic wire with a diameter of 10 μm. Observations of the magnetic domain structure showed that this magnetic wire has unusual magnetic [...] Read more.
The core of a Gigahertz Spin Rotation (GSR) sensor, a compact and highly sensitive magnetic sensor, is composed of Co–Fe-based amorphous magnetic wire with a diameter of 10 μm. Observations of the magnetic domain structure showed that this magnetic wire has unusual magnetic noise characteristics. Bamboo-shaped magnetic domains a few hundred micrometers in width were observed to form inside the wire, and smaller domains a few micrometers across were observed to form inside these larger domains. The magnetic domain pattern changed abruptly when an external magnetic field was applied to the wire. Herein is shown how these changes may be a source of magnetic noise in the wire. Full article
(This article belongs to the Special Issue Recent Advances in Magnetic GSR Sensor)
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17 pages, 2171 KiB  
Article
Research on Deterioration Mechanism and High-Precision Modelling of the Core Loss for Amorphous Alloys after Wire-Cut Electric Discharge Machining
by Xinyu Yang, Shuheng Qiu, Yuheng Wang, Pengfei Zhao, Yunpeng Gao, Haifeng Wang and Chi Zhang
Materials 2023, 16(6), 2275; https://doi.org/10.3390/ma16062275 - 12 Mar 2023
Cited by 4 | Viewed by 1967
Abstract
Amorphous alloys (AAs) have the advantage of low core loss. Thus, they can be used in high-speed motor applications. However, compared with the nominal performances, the performance of the wire-cut electric discharge machine (W-EDM)-processed AA iron core changes significantly, which limits its popularization. [...] Read more.
Amorphous alloys (AAs) have the advantage of low core loss. Thus, they can be used in high-speed motor applications. However, compared with the nominal performances, the performance of the wire-cut electric discharge machine (W-EDM)-processed AA iron core changes significantly, which limits its popularization. This paper focuses on the performance degradation mechanism of the AA ribbon caused by W-EDM and establishes a modified core loss model after machining. First, a 308 × 15 mm ribbon-shaped AA sample machined by W-EDM was prepared. The characterization and analysis of the magnetic properties, phase, magnetic domain, nano-indentation, micro-morphology, and composition were carried out. In this paper, by analysing the variation in the magnetic domain distribution based on domain width and nano-mechanical properties, it is proposed that the performance degradation range of AA ribbons processed by W-EDM is within 1 mm from the edge. By comparing the microscopic morphology and chemical composition changes in the affected and the unaffected area, this paper presents a mechanism for the property deterioration of W-EDM-processed AA ribbons based on electrochemical corrosion. Finally, a modified loss model for W-EDM-processed AAs is established based on the division of the affected area. This model can significantly improve the accuracy of core loss estimation in the medium- and high-frequency bands commonly used in high-speed motors. Full article
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12 pages, 8712 KiB  
Article
A Curvature Sensor Utilizing the Matteucci Effect in Amorphous Wire
by Sahar Alimohammadi, Paul Ieuan Williams and Turgut Meydan
Sensors 2023, 23(3), 1243; https://doi.org/10.3390/s23031243 - 21 Jan 2023
Cited by 7 | Viewed by 2306
Abstract
The study of wearable sensors for human disease monitoring has developed into an important research area due to its potential for personalized health care. Various sensor types have been proposed for assessing the range of joint movement in patients with progressive diseases or [...] Read more.
The study of wearable sensors for human disease monitoring has developed into an important research area due to its potential for personalized health care. Various sensor types have been proposed for assessing the range of joint movement in patients with progressive diseases or following post-surgical treatments. Many of these methods suffer from poor accuracy, sensitivity, and linearity or are very expensive and complex to implement. To overcome some of these limitations, this paper reports on the development of a novel flexible sensor for the measurement of bending by utilizing the Matteucci effect in the amorphous wire. This paper describes a bend sensor that utilizes positive magnetostrictive amorphous wire to achieve a measurement sensitivity equal to 5.68 ± 0.02 mV/cm with a resolution of ±0.2° over a measuring range of 64 to 143°. Full article
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14 pages, 13599 KiB  
Article
The Study of the Distribution of Electrical and Magnetic Properties over the Conductor Cross-Section Using Magnetoimpedance Tomography: Modeling and Experiment
by Dmitry A. Bukreev, Michael S. Derevyanko, Alexey A. Moiseev, Andrey V. Svalov and Alexander V. Semirov
Sensors 2022, 22(23), 9512; https://doi.org/10.3390/s22239512 - 5 Dec 2022
Cited by 12 | Viewed by 1768
Abstract
A description of the method of magnetoimpedance tomography is presented. This method is based on the analysis of the frequency dependences of the impedance obtained in magnetic fields of various strengths. It allows one to determine the distribution of electrical and magnetic properties [...] Read more.
A description of the method of magnetoimpedance tomography is presented. This method is based on the analysis of the frequency dependences of the impedance obtained in magnetic fields of various strengths. It allows one to determine the distribution of electrical and magnetic properties over the cross-section of the conductor, as well as their dependence on the magnetic field. The article proposes a specific approach to the implementation of the magnetoimpedance tomography method based on computer modeling by the finite element method. The results of this method are presented for composite Cu98Be2/Fe20Co6Ni74 wires of the “highly conductive core–magnetically soft coating” type and amorphous rapidly quenched Co66Fe4Nb2.5Si12.5B15 wires. Full article
(This article belongs to the Section Sensor Materials)
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23 pages, 3391 KiB  
Article
Thermal Conductivity of Solid Triphenyl Phosphite
by Alexander Krivchikov, Ove Andersson, Oksana Korolyuk and Oleksii Kryvchikov
Molecules 2022, 27(23), 8399; https://doi.org/10.3390/molecules27238399 - 1 Dec 2022
Cited by 6 | Viewed by 1884
Abstract
The thermal conductivity, κ, of solid triphenyl phosphite was measured by using the transient hot-wire method, and its temperature and pressure dependencies were analyzed to understand heat transfer processes in the solid polymorphic phases, as well as in the glass and the [...] Read more.
The thermal conductivity, κ, of solid triphenyl phosphite was measured by using the transient hot-wire method, and its temperature and pressure dependencies were analyzed to understand heat transfer processes in the solid polymorphic phases, as well as in the glass and the exotic glacial state. Phase transformations and the structural order of the phases are discussed, and a transitional pressure–temperature diagram of triphenyl phosphite is presented. The thermal conductivity of both the crystalline and disordered states is described within the theory of two-channel heat transfer by phonons and diffusons in dielectric solids. In the glass and glacial states, the weakly temperature-dependent (glass-like) κ is described well by the term associated with heat conduction of diffusons only, and it can be represented by an Arrhenius-type function. In the crystal phases, the strongly temperature-dependent (crystal-like) κ associated with heat transfer by phonons is weakened by significant heat transfer by diffusons, and the extent of the two contributions is reflected in the temperature dependence of κ. We find that the contribution of diffusons in the crystal phases depends on pressure in the same way as that in amorphous states, thus indicating that the same mechanism is responsible for this channel of heat transfer in crystals and amorphous states. Full article
(This article belongs to the Section Physical Chemistry)
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