Search Results (5)

This study investigates the mineralogical and physical properties of serpentinite from the Monteferrato area (Tuscany, Italy) to evaluate its potential use in Tuscany architectural restoration. The research addresses the need to identify replacement materials compatible with historic stones while preserving their original features. Representative specimens from the Bagnolo quarry were analysed through physical testing and a wide range of mineralogical and geochemical techniques, including polarised light microscopy, X-ray diffraction, electron probe micro-analysis, whole-rock chemistry, and fibre quantification. The results show a mineralogical composition dominated by serpentine-group minerals and magnetite, with physical properties generally consistent across samples. Measured capillary water absorption ranges from 3.27 to 5.27 g/m²·s^0.5, open porosity from 5.25% to 8.93%, apparent densities range from 2.49 to 2.56 g/cm³, and imbibition coefficient from 2.16% to 3.71%. Comparative analysis with serpentinite from historic sources (Figline di Prato quarry, Tuscany) and from monuments (Baptistery of San Giovanni, Florence) demonstrates close compositional and textural affinities, supporting the suitability of the rock from the studied quarry for restoration purposes in Tuscany monuments. However, chrysotile concentrations up to 14,153 mg/kg, exceeding Italian regulatory thresholds, represent a critical limitation. This not only requires the implementation of strict safety measures but also raises serious concerns regarding the practical feasibility of using this stone in conservation projects. More broadly, the presence of asbestiform minerals in serpentinites highlights a significant and often underestimated health risk associated with their extraction, processing, and use. Despite its importance, detailed fibre count data are rarely published or made publicly accessible, hindering both transparent risk assessment and informed decision-making. By integrating petrographic, mineralogical, and physical–mechanical characterisation with fibre quantification, this study not only assesses the technical suitability of Monteferrato serpentinites for restoration of Tuscan monuments but also contributes to a more responsible and evidence-based approach to their use, emphasising the urgent need for transparency and health protection in conservation practices. Full article

At the entrance of some churches in Tuscany (Italy), the reproduction of an apparently undecipherable inscription can be found. Beginning in the 18th century, this epigraphic puzzle has originated a debate on its interpretation. This study proposes a hypothesis based on the Latin alphabet used in texts contemporary to the churches where the inscription is reproduced and a possible interpretation of the message consistent with the official religious doctrine. The proposed deciphering is extended to the full text, including some signs that were previously considered geometric forms or a specific elaboration of letters not attested in other contemporary documents. Full article

Citrus trees are a very important crops that are cultivated worldwide, but not much knowledge is known about the ecophysiological responses to climatic changes in trees under natural conditions. The aim of this study was to investigate their adaptive capacity in response to seasonal phenological and environmental changes. The trial included Citrus trees (sweet orange, bitter orange, lemon, mandarin) growing under non-regular cropping conditions in a Monumental Charterhouse in Tuscany, in a subtropical Mediterranean climate with hot summer conditions. During a 1-year field trial, we determined the variations in chlorophyll fluorescence parameters and leaf biochemical traits (content of chlorophylls and carotenoids, total phenolic content (TPC), total antioxidant capacity (TAC), and total non-structural carbohydrates). In all Citrus spp., interspecific mean values of photochemical efficiency peaked during the summer, while a marked photoinhibition occurred in the winter in concomitance with higher interspecific mean values of leaf TPC, TAC, and non-structural carbohydrates. The trees showed the pivotal role played by photosynthetic acclimation as a survival strategy to tolerate abiotic stress in the climate change hotspot of Mediterranean environment. This study is included in a wider project aimed at a new valorization of Citrus trees as genetic resource and its by-products with added-value applications for innovative functional foods. Full article

Serpentinite is a low-grade metamorphic rock derived from the transformation of ultramafic rocks. Mainly because of its aesthetic characteristics it has been widely used as a building and ornamental stone. “Verde di Prato” is the most common local name used in Tuscany to refer to this type of rock, historically quarried in this area and used for many centuries in a large number of monuments of this region. In this paper, we report the results of a study carried out on the serpentinite from the pavement of the Florence baptistery, to properly characterize it from a physical point of view, describe the rock conservation state, and understand the phenomena responsible for its decay. The studied rock displays numerous forms of decay including fractures, loss of material, erosion, discolouration and efflorescence. X-ray diffractometer analyses of the efflorescence revealed the presence of numerous salts whose formation can be imputed to multiple, possibly concomitant, causes such as the high relative humidity and the variation of inside temperature, the presence of concrete and/or cementitious mortars in the subsoil, atmospheric pollution and the burial ground existing close the baptistery. Full article

We report on some recent experiences of scientific dissemination activities on geomaterials carried out by a network of scientific organizations in Tuscany (Italy). The primary message we want to disseminate is that even the most “insignificant” rock (e.g., those constituting the bar or kitchen counter-tops) stores in their interior very useful information beyond the beautiful colors and their aesthetic appearance. These rocks can tell stories of very old geological periods on how they were formed. Their structures, texture and shape, as well as their chemistry and mineralogy provide clues to the reconstruction of geological events. Moreover, the rocks used in urban architecture and monuments are an inexhaustible archive containing a lot of historical and economic information on the development of a city and its surrounding area. The role of geologists, in this context, is to provide to the public, in clear and engaging language, the tools necessary to solve the puzzle (i.e., identify the most important types of rocks and rock-forming minerals, know their physico-chemical properties, their textures and structures and discover the environments in which they formed). A specific objective of this work is to stimulate an exchange between various research organizations (universities, public research institutions, museums, associations, etc.) and the civil society. Full article