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Keywords = Subei basin

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15 pages, 5077 KB  
Article
Stability Analysis of Borehole Walls in Shale Formations of the Huazhuang Block
by Daqi Li, Shuyang Gao, Zhichuan Tang, Yayun Zhang, Huimei Wu and Wei Cheng
Processes 2025, 13(4), 1151; https://doi.org/10.3390/pr13041151 - 10 Apr 2025
Viewed by 552
Abstract
The Huazhuang block, located on the northern slope of the Gaoyou Depression in the Subei Basin of the Jiangsu Oilfield, exhibits complex stratigraphic geomechanical characteristics. During drilling, wellbore instability-related issues, such as obstruction, sticking, pump pressure buildup, bit pressure buildup, and overflow due [...] Read more.
The Huazhuang block, located on the northern slope of the Gaoyou Depression in the Subei Basin of the Jiangsu Oilfield, exhibits complex stratigraphic geomechanical characteristics. During drilling, wellbore instability-related issues, such as obstruction, sticking, pump pressure buildup, bit pressure buildup, and overflow due to abnormally high pressure, prolong the drilling cycle and significantly hinder the safe and efficient development of shale oil. In order to determine the appropriate drilling fluid density and ensure safe and efficient drilling in this block, a comprehensive wellbore profile, incorporating rock mechanical parameters, in-situ stress, and predictions of pore pressure, collapse pressure, lost circulation pressure, and fracture pressure, was established based on laboratory tests and well logging data. This study reveals the mechanisms of wellbore collapse and fluid loss in the Huazhuang block. The results indicate that the second and fourth members of the Funing Formation in the Huazhuang block have a relatively weak and unconsolidated structure with a high content of water-sensitive minerals, leading to significant hydration risks when using water-based drilling fluids. As depth increases, compressive strength, elastic modulus, and cohesion show an increasing trend, while the internal friction angle and Poisson’s ratio gradually decrease. Additionally, in-situ stress increases significantly, meeting the condition of σV > σH > σh. Above 3300 m, the equivalent density of formation pore pressure is below 1.20 g/cm3, Whereas below 3300 m, there is significant overpressure, with a maximum equivalent pore pressure density reaching 1.45 g/cm3. The deeper the formation, the narrower the safe density window, making wellbore collapse more likely. To prevent wellbore instability, both the sealing capability and density of the drilling fluid should be considered. Enhancing the sealing performance of the drilling fluid and selecting an appropriate drilling fluid density can help improve wellbore stability. The established rock mechanical parameters and four-pressure prediction profile for the Huazhuang block provide a scientific basis for optimizing wellbore structure design and selecting key engineering parameters. Full article
(This article belongs to the Section Energy Systems)
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19 pages, 15438 KB  
Article
Response of Seismic Geomorphology to Sequence Framework in Dainan Formation of the Gaoyou Sag, Eastern China
by Xiaomin Zhu, Xin Hu, Yanlei Dong, Xiaolin Wang, Yiming Xu and Qin Zhang
Appl. Sci. 2025, 15(8), 4153; https://doi.org/10.3390/app15084153 - 10 Apr 2025
Viewed by 662
Abstract
Seismic sedimentology and sequence stratigraphy, as emerging interdisciplinary fields, demonstrate unique advantages in characterizing seismic geomorphological responses of various system tracts within the stratigraphic frameworks of rift lacustrine basins. Focusing on the Paleogene Dainan Formation in the Gaoyou Sag of the Subei Basin, [...] Read more.
Seismic sedimentology and sequence stratigraphy, as emerging interdisciplinary fields, demonstrate unique advantages in characterizing seismic geomorphological responses of various system tracts within the stratigraphic frameworks of rift lacustrine basins. Focusing on the Paleogene Dainan Formation in the Gaoyou Sag of the Subei Basin, eastern China, this study integrates seismic termination patterns, sedimentary cyclicity analysis, and well-to-seismic calibration to subdivide the formation into three third-order sequences containing lowstand (LST), transgressive (TST), and highstand (HST) system tracts. The distribution of five distinct sedimentary facies exhibits pronounced sub-tectonic zonations controlled by the basin’s architecture and structural evolution, with steep slope zones dominated by nearshore subaqueous fan–fan delta complexes, gentle slopes developing normal deltaic systems, and deep-semi-deep lacustrine facies with slump turbidite fans concentrated in depositional centers. Through a novel application of 90° phase adjustment, spectral decomposition, and multi-attribute fusion techniques, the relationship between seismic amplitude attributes and lithologies are established via seismic lithology calibration. Detailed sequence evolution analyses and seismic geomorphological interpretation systematically elucidate the spatio-temporal evolution of depositional systems within different system tracts in rift lacustrine basins, providing a novel methodological framework for sequence stratigraphic analysis in continental rift settings. Full article
(This article belongs to the Section Earth Sciences)
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30 pages, 18951 KB  
Article
Identification and Sedimentary Model of Shallow-Water Deltas: A Case Study of the Funing Formation, Subei Basin, Northeast China
by Ziyi Yang, Guiyu Dong, Lianbo Zeng, Yongfeng Qiu, Chen Guo, Zhao Ma, Tianwei Wang, Xu Yang, Shuo Ran and Xing Zhao
Minerals 2025, 15(3), 207; https://doi.org/10.3390/min15030207 - 21 Feb 2025
Cited by 1 | Viewed by 657
Abstract
Shallow-water deltas are not only a hot spot for sedimentological research but also a key target for oil and gas exploration. In this paper, taking the third member (E1f3) of the Funing Formation in the Upper Jurassic as an [...] Read more.
Shallow-water deltas are not only a hot spot for sedimentological research but also a key target for oil and gas exploration. In this paper, taking the third member (E1f3) of the Funing Formation in the Upper Jurassic as an example, based on observations made from core samples, well logging, cathode luminescence characteristics, and analytical assays, the development conditions, sedimentary characteristics, and sedimentary models of shallow-water deltas are summarized. These shallow-water deltas were deposited in conditions with the following characteristics: a gentle terrain platform, a subtropical climate with ample rainfall, an abundant source supply, strong hydrodynamic forces, shallow water bodies, and a frequently eustatic lake level. Shallow-water deltas are characterized by sediment deposition from traction currents, numerous underwater distributary channel scour structures, overlapping scouring structures, sand body distribution with planar features, underwater distributary channels as skeletal sand bodies, and undeveloped mouth bars. Based on these, it is believed that during the deposition period of E1f3, the Gaoyou Sag in the Subei Basin had favorable geological conditions for the development of shallow-water delta deposition. The shallow-water delta deposition that occurred during the sedimentary periods of the five major sand units in the Funing Formation is characterized by front subfacies, with underwater distributary channels as the framework for sand bodies, and multiple intermittent positive rhythms overlapping vertically with the Jianhu Uplift as the source of material supply. In this paper, a depositional model for shallow-water delta deposition during the E1f3 deposition period in the Gaoyou Sag is established, expanding the scope of oil reservoir exploration in the north slope region of the Gaoyou Sag and providing important geological evidence for the selection of favorable subtle zones. Full article
(This article belongs to the Special Issue Deep-Time Source-to-Sink in Continental Basins)
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29 pages, 43098 KB  
Article
Sedimentary Characteristics of Shallow Water Delta: A Case Study from the Paleogene Funing Formation in the Haian Sag of the Subei Basin, China
by Zhao Ma, Guiyu Dong, Tianwei Wang, Yongfeng Qiu, Tianzhuo Bi and Ziyi Yang
Minerals 2025, 15(1), 75; https://doi.org/10.3390/min15010075 - 14 Jan 2025
Cited by 3 | Viewed by 1251
Abstract
Haian Depression is one of the key areas for oil and gas resource replacement in Jiangsu Oilfield. Since the 13th cycle of the Five Year Plan, with the continuous improvement in the exploration level of the Taizhou Formation (K2t), the difficulty [...] Read more.
Haian Depression is one of the key areas for oil and gas resource replacement in Jiangsu Oilfield. Since the 13th cycle of the Five Year Plan, with the continuous improvement in the exploration level of the Taizhou Formation (K2t), the difficulty of tapping potential has gradually increased. It is urgent to change our thinking and expand new exploration layers. From the perspective of oil and gas display frequency in different layers of the Haian Depression, except for K2t, the oil and gas systems with the Fusan Member (E1f3) as the main reservoir have good oil and gas display frequency, demonstrating great exploration potential. This study of sedimentary characteristics is the basis of analyzing the sedimentary environment and lithofacies paleogeographic conditions and is of great significance for determining the distribution range of subtle oil and gas reservoirs. Based on this understanding, this study was specially established to systematically analyze the logging curves of forty-three wells in the research area, combined with core observations of eighteen coring wells and the analysis of eight seismic profiles. The results show that the low slope, warm and humid climate, sufficient provenance, and frequent lake level rise and fall cycles during the deposition period of the E1f3 member of the Haian Sag provide a favorable depositional background for the development of shallow water delta in the study area. There are many gullies in the research area, mainly consisting of U-shaped gullies and W-shaped gullies. Slope breaks are mainly affected by structural factors leading to fractures, and the types are mostly fault terrbreakslope breaks. In the study area, the shallow water delta deposits during the deposition period of the four key sand groups in the Fu3 Formation are dominated by the shallow water delta front and shallow water prodelta. The shallow water delta plain subfacies are not significantly developed because of erosion. The sand bodies are mainly distributed in the Sunjiawa Subdepression, and the Fuan Subdepression in the north of the depression, and the sand bodies in the plane show the filling characteristics of the strip. Based on the above research, a sedimentary model of shallow water delta during the E1f3 section of the Haian Depression was established, providing a geological basis for the design of exploration and development plans for hidden oil and gas reservoirs in the next step. Full article
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21 pages, 6695 KB  
Article
Diabase Intrusion-Induced Changes in Shale Pore Structure in Subei Basin: Insights from Mono- and Multifractal Analysis of N2 Adsorption
by Zuxian Hua, Xiaoping Liu, Biao Sun, Tian Liu, Qidong Liu, Hongliang Duan, Shili Liu, Yue Zheng, Wendi Peng and Wenhui Xie
Fractal Fract. 2024, 8(12), 737; https://doi.org/10.3390/fractalfract8120737 - 14 Dec 2024
Viewed by 1004
Abstract
Diabase intrusion is a common geological phenomenon in lacustrine shale formations in continental basins in China, which has important effects on the physical and chemical properties of shale oil reservoirs. In this paper, we systematically analyzed the pore structure of diabase-intruded lacustrine shale [...] Read more.
Diabase intrusion is a common geological phenomenon in lacustrine shale formations in continental basins in China, which has important effects on the physical and chemical properties of shale oil reservoirs. In this paper, we systematically analyzed the pore structure of diabase-intruded lacustrine shale in the Gaoyou sag of the Subei Basin using geochemical tests, thin-section observation, argon ion polishing scanning electron microscopy (SEM), low-temperature nitrogen adsorption experiments (LTNA), and other methods combined with monofractal and multifractal theories. The results show that the intrusion metamorphic segments are a diabase zone, hornfels zone, slate zone, and normal shale zone from the intrusion center. The pores of hornfels and slate are mostly oriented and dissolution is obvious. Many microfractures and secondary minerals such as quartz and chlorite are observed. The pore volumes of diabase and hornfels are small, while those of slate and normal shale are larger. The monofractal dimensions D1 and D2 of the intrusion segment show a general trend of decreasing first and then increasing from the intrusion center to the shale zone. The multifractal parameters’ H index decreases gradually from the lower normal shale to the upper metamorphic zone hornfels, while Δα and Rd increase gradually. The total organic carbon (TOC) content of the intrusion zone has little effect on the pore structure, and the fractal characteristics fluctuate weakly, while the vitrinite reflectivity (Ro) value change has a significant impact on the monofractal characteristics of the shale pore. Pore volume also affects the pore heterogeneity; the larger the specific surface area (SSA) and total pore volume (TPV), the lower the pore heterogeneity and the higher the surface roughness and pore connectivity. The diabase intrusion caused three modification mechanisms of mechanical squeezing, the thermal effect, and chemical action on the shale surrounding rocks, resulting in different degrees of pore formation or change. The pore evolution model of the metamorphic belt with the combined action of “mechanical-thermal-chemical” is established, and the influence of diabase intrusion on the pore types and pore size distribution (PSD) of shale reservoirs is quantitatively described, providing a new perspective and method for understanding the impact of diabase intrusion on the characteristics and exploration potential of shale oil reservoirs. Full article
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23 pages, 24580 KB  
Article
Pore Structure and Heterogeneity in the Lacustrine Shale of the Second Member of the Paleogene Funing Formation, Subei Basin, China
by Zhiwei Zhu, Qiang Fu, Zongquan Hu, Hongliang Duan, Baoliang Yang, Lele Xing and Guo Chen
Minerals 2024, 14(12), 1248; https://doi.org/10.3390/min14121248 - 8 Dec 2024
Cited by 1 | Viewed by 1098
Abstract
Characterization of pore structure and heterogeneity is crucial for exploring and evaluating shale oil and gas resources. Existing methodologies exhibit various limitations, and intuitive, quantitative description techniques are lacking. To address these issues, shales from the second member of the Funing Formation (E [...] Read more.
Characterization of pore structure and heterogeneity is crucial for exploring and evaluating shale oil and gas resources. Existing methodologies exhibit various limitations, and intuitive, quantitative description techniques are lacking. To address these issues, shales from the second member of the Funing Formation (E1f2) in the Subei Basin were studied in this study. A comprehensive research methodology was employed that combined petrological analysis, physical structure testing, and SEM images supplemented with multifractal analysis and partial least squares regression (PLSR) data processing to achieve nuanced qualitative and quantitative characterization of the heterogeneity in lacustrine shale pore structures. This study revealed that E1f2 shale pores predominantly consist of mesopores (2–50 nm) and macropores (>50 nm). A positive correlation was observed between the development of mesopores and calcite content, while a negative correlation exists with orthoclase content. Conversely, a positive correlation with plagioclase content was found in macropore development. The growth in total pore volume is inhibited by the total organic carbon (TOC) content. Employing multifractal methods to analyze pore morphology data extracted from scanning electron microscopy (SEM) images facilitated a quantitative characterization of the heterogeneity within the pore structures. The results showed that organic-medium mixed shale (OMMS) has the strongest heterogeneity. The weakest heterogeneity is exhibited by the organic-medium calcareous shale (OMCS). PLSR analysis indicates that the structural heterogeneity of the E1f2 shales is positively correlated with TOC content and negatively correlated with orthoclase content. Additionally, the type of pore influences the degree of heterogeneity. Increasing the total and macropore volume reduces the heterogeneity, while increasing the micropore (<2 nm) volume enhances it in the E1f2 shales. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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15 pages, 14357 KB  
Article
Paleopressure during Hydrocarbon Charging and Its Evolution in the Funing Formation of the Gaoyou Sag, Subei Basin, Eastern China
by Chunquan Li, Shiyou Qian and Yuancai Zheng
Minerals 2024, 14(8), 821; https://doi.org/10.3390/min14080821 - 14 Aug 2024
Cited by 1 | Viewed by 1385
Abstract
Abnormally high pressures are currently limited and locally developed in the Funing Formation of the Gaoyou Sag, Subei Basin, eastern China, but the paleopressure and its evolutionary history remain unclear. Based on the determination of hydrocarbon charging periods by performing systematic fluid inclusion [...] Read more.
Abnormally high pressures are currently limited and locally developed in the Funing Formation of the Gaoyou Sag, Subei Basin, eastern China, but the paleopressure and its evolutionary history remain unclear. Based on the determination of hydrocarbon charging periods by performing systematic fluid inclusion analysis on sixteen core samples from the Funing Formation, thermodynamic modeling with fluid inclusion data was adopted to reconstruct the paleopressure and redisplay its evolutionary history throughout geological time. Results showed that the Funing Formation experienced two episodes of hydrocarbon charging periods. Episode 1 occurred with the charging of lower maturity oils in the period from 52.8 Ma to 49.5 Ma, which was recorded by yellow-fluorescing oil inclusions. Episode 2 happened with the charging of higher maturity oils in the period from 47.0 Ma to 37.0 Ma, which was characterized by blue-fluorescing oil inclusions. Each episode was an abnormally high-pressured hydrocarbon charging process. The pressure coefficient of Episode 1 reached as high as 1.44, while that of Episode 2 reached as high as 1.40. The current formation pressure is the evolutionary result of paleopressure after a process of rapid increasing and decreasing and slow increasing and is not as high as what it reached during the hydrocarbon charging periods. This work is valuable for the exploration of conventional clastic oil reservoirs and unconventional shale oils in the Funing Formation. Full article
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27 pages, 33432 KB  
Article
A Multi-Faceted Approach to Determining the Provenance of the Lacustrine Rift Basin in the Initial Rifting Stage: A Case Study of the Paleocene Qintong Sag, Subei Basin, East China
by Rui Jiang, Zhen Liu, Shiqiang Xia, Maolin Zhu, Jianxin Tang, Gongyi Wu and Wei Wu
Minerals 2024, 14(4), 420; https://doi.org/10.3390/min14040420 - 18 Apr 2024
Viewed by 1643
Abstract
Research on the provenance of sedimentary systems is key to better understanding the sedimentary framework and improving exploration-associated decision-making and deployment. With regard to the provenance of sedimentary systems, there is still poor understanding in the initial rifting stage due to imbalanced and [...] Read more.
Research on the provenance of sedimentary systems is key to better understanding the sedimentary framework and improving exploration-associated decision-making and deployment. With regard to the provenance of sedimentary systems, there is still poor understanding in the initial rifting stage due to imbalanced and insufficient exploration and a common lack of seismic data, which have seriously hindered oil exploration in the Qintong Sag, Subei Basin. This study aimed at investigating the provenance in the direction of the fault-terrace zone in the southeast part of the Qintong Sag and aimed to examine whether large-scale sedimentary systems are formed by these sediment sources. Integrated analysis of heavy minerals, sandstone petrologic maturity, drilling cutting dates, 3D seismic data, and well logs was employed to identify the provenance. This study is the first time that large-scale provenance from the direction of the fault-terrace zone has been discovered in the third member of the Paleocene Funing Formation (referred to as the third Mbr of the Funing Fm in this paper) in the Subei Basin, east China. The documentation shows that sediments from the northwest Wubao Low Uplift and the southeast Taizhou Uplift can be distinguished in the Qintong Sag, with the large-scale delta system in the central and eastern part of the Qintong Sag comprising sediments from the Taizhou Uplift, improving upon previous understanding of the sedimentary framework. The deposition formed by the Taizhou Uplift provenance system was characterized by gradual weakening of the hydrodynamic forces, a decreasing sediment supply, and shrinking of the retrogradational delta depositional systems with good reservoir qualities, which are characterized by high-quality source–reservoir–cap combinations and are likely to develop into a hydrocarbon-rich belt. The discovery of the Taizhou Uplift provenance proves that there may be major provenance and large-scale sedimentary systems from the fault-terrace zone of the rift basins in the initial rifting stage. The experience of rapid retrogradation showed that these large-scale delta systems are likely to only flourish in the initial rifting stage. This study is helpful for improving the understanding of sediment provenance and the sedimentary framework of lacustrine rift basins in the initial rifting stage. Full article
(This article belongs to the Topic Petroleum Geology and Geochemistry of Sedimentary Basins)
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20 pages, 27270 KB  
Article
Evaluation of the Potential for CO2 Storage and Saline Water Displacement in Huaiyin Sag, Subei Basin, East China
by Chenglong Zhang, Yujie Diao, Lei Fu, Xin Ma, Siyuan Wang and Ting Liu
Processes 2024, 12(3), 547; https://doi.org/10.3390/pr12030547 - 11 Mar 2024
Cited by 4 | Viewed by 1820
Abstract
CO2 geological storage combined with deep saline water recovery technology (CO2-EWR) is one of the most effective ways to reduce carbon emissions. Due to the complex structural features, it is difficult to use CO2-EWR technology in Huaiyin Sag, [...] Read more.
CO2 geological storage combined with deep saline water recovery technology (CO2-EWR) is one of the most effective ways to reduce carbon emissions. Due to the complex structural features, it is difficult to use CO2-EWR technology in Huaiyin Sag, Subei basin, East China. In this study, the multi-source information superposition evaluation technology of GIS was utilized for the selection of CO2 storage sites and water displacement potential target areas in this area, which mainly focused on the sandstone reservoirs of Cretaceous Pukou Formation. Based on the results, a three-dimensional injection–extraction model was established. Various scenarios with different production/injection well ratios (PIR) were simulated. Research has shown that the suitability of the surrounding site of Huaiyin Power Plant can be divided into two levels: relatively suitable and generally suitable; the area in the generally suitable level accounts for more than 80%. At a PIR of 1, CO2 is distributed asymmetrically, whereas at PIRs of 2 or 4, CO2 is distributed symmetrically. When the number of production wells is constant, a higher injection rate results in a faster expansion rate of the CO2 plume. This means that the time taken for the CO2 plume to reach the production wells is shorter. Reservoir pressure increases rapidly after more than 60 years of CO2 injection at lower PIR values, while at higher PIRs, reservoir pressure eventually stabilizes. Higher PIR values correspond to higher gas saturation, indicating a greater capacity for CO2 sequestration with more producing wells. When PIR = 4, the total CO2 injection increased by 55.73% compared to PIR = 1. However, the extraction of saline decreases with an increase in the number of producing wells, resulting in a decrease in replacement efficiency. This study provides a theoretical basis and technical support for the implementation of large-scale CO2-EWR engineering and technology demonstration in this region. Full article
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19 pages, 4256 KB  
Article
A Study on the Pore Structure and NMR Fractal Characteristics of Continental Shale in the Funing Formation of the Gaoyou Sag, Subei Basin
by Zipeng Wang, Yue Zhu, Zhenxue Jiang, Houjian Gong, Yu Yang, Bo Wang and Xin Wang
Appl. Sci. 2023, 13(22), 12484; https://doi.org/10.3390/app132212484 - 18 Nov 2023
Cited by 1 | Viewed by 1580
Abstract
The continental shale oil resource in China exhibits significant potential and serves as a crucial strategic alternative to the country’s conventional oil and gas reserves. The efficacy of shale oil exploration and production is heavily contingent upon the heterogeneity of the pore structure [...] Read more.
The continental shale oil resource in China exhibits significant potential and serves as a crucial strategic alternative to the country’s conventional oil and gas reserves. The efficacy of shale oil exploration and production is heavily contingent upon the heterogeneity of the pore structure within the reservoir. However, there remains a scarcity of research pertaining to the pore structure of continental shale and the factors that influence it. The objective of this study is to provide a quantitative characterization of the heterogeneity exhibited by the continental shale of the Funing Formation in the Gaoyou Sag. In this study, the research focus is directed toward the continental shale of the Funing Formation located in the Gaoyou Sag of the Subei Basin. This paper examines the correlation between the fractal dimension of nuclear magnetic resonance (NMR) and various factors including the total organic carbon (TOC), mineral composition, geochemical parameters, and physical properties, utilizing the principles of fractal dimension theory. The findings indicate that the primary pore types observed in the Funing Formation continental shale are inorganic matrix pores, which encompass dissolution pores, clay mineral intergranular pores, and a limited number of pyrite intergranular pores. By employing a relaxation time cutoff, the NMR fractal dimension can be categorized into two distinct dimensions: the bound-fluid-pore fractal dimension (0.5795~1.3813) and the movable-fluid-pore fractal dimension (2.9592~2.9793). The correlation between mineral composition and the fractal dimension indicates a negative relationship between the fractal dimensions of bound-fluid pores and movable-fluid pores and the content of quartz. The correlation between clay minerals and the fractal dimension indicates a significant negative relationship between the fractal dimensions of bound-fluid pores and movable-fluid pores with illite. There exists a negative correlation between the pore fractal dimension of bound fluid and the content of organic matter, whereas a positive correlation is observed between the pore fractal dimension of mobile fluid and the content of organic matter. The range of maturity of organic matter within the Funing Formation exhibits a relatively limited span, as indicated by the vitrinite reflectance (Ro) values falling between 0.8% and 0.9%. This narrow range of maturity does not exert a substantial influence on the two fractal dimensions. The NMR fractal dimension exhibits a negative correlation with permeability in relation to reservoir physical properties, while the bound-fluid-pore fractal dimension demonstrates a negative correlation with the total porosity. The findings suggest that the NMR fractal dimension can serve as a valuable indicator for evaluating the physical characteristics of reservoirs. The present study successfully examined the pore structure of continental shale through the utilization of nuclear magnetic resonance technology. This innovative technique provides a novel avenue for the assessment of continental shale reservoirs and the investigation of pore heterogeneity on a global scale. Full article
(This article belongs to the Section Energy Science and Technology)
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22 pages, 7955 KB  
Article
Paleoenvironmental Characteristics of Lacustrine Shale and Its Impact on Organic Matter Enrichment in Funing Formation of Subei Basin
by Feng Zhu, Chuxiong Li, Junying Leng, Mengyao Jia, Houjian Gong, Bo Wang, Fan Zhang, Zhenxue Jiang and Zipeng Wang
Minerals 2023, 13(11), 1439; https://doi.org/10.3390/min13111439 - 14 Nov 2023
Cited by 5 | Viewed by 1978
Abstract
Organic matter in depositional environment is the essential material for oil and gas generation. Total organic carbon (TOC) is one of the important parameters for estimating the hydrocarbon generation potential of shale oil and predicting sweet spots. The TOC of the second member [...] Read more.
Organic matter in depositional environment is the essential material for oil and gas generation. Total organic carbon (TOC) is one of the important parameters for estimating the hydrocarbon generation potential of shale oil and predicting sweet spots. The TOC of the second member of the Funing Formation (Ef2) ranges from 0.25% to 2.30%. TOC is higher in the upper shale and lower in the lower shale of the Funing Formation, showing a significant enrichment difference. However, there have been few reports on the study of the main controlling factors for the differential enrichment of organic matter in Ef2. This study aims to reconstruct the paleoenvironment of lacustrine shale in Ef2. Additionally, this study aims to clarify the influence of the paleoenvironment on the differential enrichment of organic matter in Ef2. For this purpose, systematic mineralogical and geochemical analyses were conducted on 72 samples from a representative well. The results indicate that, based on parameters such as paleoclimate (chemical index of alteration, CIA), paleosalinity (Sr/Ba), paleoredox conditions (Cu/Zn), paleoproductivity (P/Ti), water depth (Rb/K), and terrigenous clastic input (Al, Ti), the paleoenvironment during the deposition of the Ef2 shale clearly exhibited significant changes. During the early stage, the climate was hot and dry, with shallow water, weak chemical weathering, low productivity, and salinity ranging from saline to brackish. In the later stage, the climate became warm and humid, with deeper water, moderate chemical weathering, high productivity, and salinity ranging from brackish to freshwater. There are significant errors in directly using the Sr/Ba index to evaluate the paleosalinity of Ef2 shale. Carbonate minerals and calcium-rich bioclasts may increase the Sr/Ba ratio, and the corrected Sr element content is only 44.29% of the original sample. The enrichment of organic matter is clearly controlled by productivity levels and climatic conditions. The higher the paleoproductivity and the warmer and more humid the climate, the more enriched the organic matter becomes. Fundamental differences in paleoproductivity govern the enrichment of organic matter during the deposition process of the Ef2 shale. The organic matter enrichment pattern in the Ef2 shale represents a typical productivity model. Full article
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17 pages, 14542 KB  
Article
Lacustrine Shale Diagenesis—A Case Study of the Second Member of the Funing Formation in the Subei Basin
by Shuping Wang, Cunfei Ma, Xue Sun and Shili Liu
Processes 2023, 11(7), 2009; https://doi.org/10.3390/pr11072009 - 5 Jul 2023
Cited by 4 | Viewed by 1715
Abstract
Shale diagenesis differs from that of sandstone and carbonate rocks with regard to the type, evolution stage, and evolution mode. The quality of shale reservoirs is closely linked to the extent of diagenetic evolution. This study identifies the types and characteristics of shale [...] Read more.
Shale diagenesis differs from that of sandstone and carbonate rocks with regard to the type, evolution stage, and evolution mode. The quality of shale reservoirs is closely linked to the extent of diagenetic evolution. This study identifies the types and characteristics of shale diagenesis using thin sections and scanning electron microscopy (SEM) observations. The stages of shale diagenesis are determined by analyzing organic matter evolution and clay mineral transformation and establishing a diagenetic evolution sequence. This paper describes the comprehensive diagenetic evolution of organic matter, clay minerals, clastic particles, and carbonate minerals to determine the diagenesis types, diagenetic sequences, and pore evolution occurring during diagenetic evolution. The results show that the diagenesis types of shale in the second member of the Funing Formation include compaction, dissolution, cementation, metasomatism, dolomitization, syneresis, and transformation of clay minerals, as well as thermal evolution of organic matter. The middle diagenetic A stage is prevalent, with some areas in the early and middle diagenetic B stages. The shale underwent a diagenetic evolution sequence, including the collapse and shrinkage of montmorillonite interlayers in the early stage; the rapid formation and transformation of illite and smectite mixed layers, massive hydrocarbon generation of organic matters, and dissolution of unstable components in the middle stage; and the occurrence of fractures filled with gypsum, quartz, ferrocalcite, or other authigenic minerals in the later stage. Dissolution pores and fractures are the dominant shale reservoirs of the second member of the Funing Formation in the Subei Basin. The results provide new insights into understanding the formation and evolution of reservoir spaces during shale diagenesis and information for the exploration and development of lacustrine shale oil and gas. Full article
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12 pages, 6851 KB  
Article
Correction of Light and Heavy Hydrocarbons and Their Application in a Shale Oil Reservoir in Gaoyou Sag, Subei Basin—A Case Study from Well SX84
by Qi Zhi, Shuangfang Lu, Pengfei Zhang, Hongsheng Huang, Junjie Wang and Zizhi Lin
Processes 2023, 11(2), 572; https://doi.org/10.3390/pr11020572 - 13 Feb 2023
Cited by 1 | Viewed by 1939
Abstract
To accurately evaluate the shale oil resources in the Funing Formation of the Gaoyou Sag, Subei Basin, light and heavy hydrocarbon correction models of S1 were developed based on the rock pyrolysis of liquefrozen, conventional, and oil-washed shales. The improved ΔlogR technique [...] Read more.
To accurately evaluate the shale oil resources in the Funing Formation of the Gaoyou Sag, Subei Basin, light and heavy hydrocarbon correction models of S1 were developed based on the rock pyrolysis of liquefrozen, conventional, and oil-washed shales. The improved ΔlogR technique was applied to establish the TOC, S1, and S2 logging evaluation methods. The results showed that the S2 values after oil washing were significantly lower than before. The difference between these two S2S2) values is the heavy hydrocarbon correction amount of S1, which is about 0.69 S2. There was almost no loss of light hydrocarbons during liquefrozen shales’ pyrolysis tests; the ratio of liquefrozen to conventional S1 values is the light hydrocarbon correction factor, which is about 1.67. The corrected S1 is about 3.2 times greater than the conventional shale-tested value. The S1 and TOC are obviously “trichotomous”; a TOC greater than 1.5% and corrected S1 larger than 4.0 mg/g corresponds to the enriched resource. The logging estimated results show that the total shale oil resources in the E1f2 of the Gaoyou Sag are about 572 million tons, of which the enriched resource is about 170 million tons. Full article
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21 pages, 6086 KB  
Article
Dissolved Organic Carbon Source Attribution in the Changjiang Outflow Region of the East China Sea
by Xiaoyu Zhang, Yong Du, Zhihua Mao, Lei Bi, Jianyu Chen, Haiyan Jin and Shuchang Ma
Sensors 2021, 21(24), 8450; https://doi.org/10.3390/s21248450 - 17 Dec 2021
Cited by 3 | Viewed by 3472
Abstract
The variable optical properties of chromophoric dissolved organic matter (CDOM) under the complicated dynamic marine environment make it difficult to establish a robust inversion algorithm for quantifying the dissolved organic carbon (DOC). To better understand the main factors affecting the relationship between the [...] Read more.
The variable optical properties of chromophoric dissolved organic matter (CDOM) under the complicated dynamic marine environment make it difficult to establish a robust inversion algorithm for quantifying the dissolved organic carbon (DOC). To better understand the main factors affecting the relationship between the DOC and the CDOM when the Changjiang diluted water (CDW) interacts with the marine currents on the wide continental shelf, we measured the DOC concentration, the absorption, and the fluorescence spectra of the CDOM along the main axis and the northern boundary of the CDW. The sources of DOC and their impacts on the relationship between the optical properties of the DOC and CDOM are discussed. We reached the following conclusions: There are strong positive correlations between the absorptive and fluorescent properties of the DOC and the CDOM as a whole. The dilution of the terrestrial DOC carried by the CDW through mixing with saline sea water is the dominant mechanism controlling the characteristics of the optical properties of the CDOM. CDOM optical properties can be adopted to establish inversion models in retrieving DOC in Changjiang River Estuary. It is concluded that the introduction of extra DOC from different sources is the main factor causing the regional optical complexity leading to the bias of DOC estimation rather than removal mechanism. As whole, the input of polluted water from Huangpujiang River with abnormally high a(355) and Fs(355) will induce the overestimation of DOC. In the main axis of CDW, the impact from autochthonous DOC input to the correlation between DOC and CDOM can be neglected in comparison with conservative dilution procedure. The relationship between the DOC and the CDOM on the northern boundary of the CDW is more complicated, which can be attributed to the continuous input of terrestrial material from the Old Huanghe Delta by the Subei Coastal Current, the input of materials from the Yellow sea by the Yellow Sea Warm Western Coastal Current, and the input of materials from the Changjiang Basin by the CDW. The results of this study suggest that long-term observations of the regional variations in the DOM inputs from multiple sources in the interior of the CDW are essential, which is conducive to assess the degree of impact to the DOC estimation through the CDOM in the East China Sea. Full article
(This article belongs to the Special Issue Sensors and Data Analysis Applied in Environmental Monitoring)
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15 pages, 4550 KB  
Article
Physicochemical Property Indexes of Sediment Lixiviums in Sea–Land Interaction Zone of Subei Basin and Their Significance to Transgression
by Qiang Shu, Shunjie Zhang and Ye Chen
J. Mar. Sci. Eng. 2021, 9(7), 719; https://doi.org/10.3390/jmse9070719 - 29 Jun 2021
Cited by 1 | Viewed by 2334
Abstract
In current studies, the physicochemical properties of water, such as total dissolved solids, salinity, and electrical conductivity, are used mainly to investigate changes in the properties of surface water and groundwater. In our experimental study, we aimed to introduce the physicochemical properties of [...] Read more.
In current studies, the physicochemical properties of water, such as total dissolved solids, salinity, and electrical conductivity, are used mainly to investigate changes in the properties of surface water and groundwater. In our experimental study, we aimed to introduce the physicochemical properties of water bodies into the field of paleoenvironmental changes. We employed the physicochemical property indexes of sediment lixiviums in two research sections of the sea–land interaction zone in the eastern margin of the Subei Basin (China). Preliminary tests determined that the optimal solvent for preparing the sediment lixiviums is ultrapure water; the use of this water can prevent errors caused by soluble solids in the solvent. Using a container with a lid to prepare the sediment lixiviums could reduce errors caused by evaporation. Furthermore, we determined the appropriate process and duration for testing the physicochemical properties of sediment lixiviums. The optimal time for testing the physicochemical properties was 120 h (mixture fully stirred daily) or 168 h (no stirring). The weight of the sediment, volume of the solvent, and test time should be consistent in the same research section. Comparing the physicochemical property indexes of sediment lixiviums with geochemical elements and diatom indicators, we found that these indexes show obvious indications of transgression, and have an obvious advantage in indicating transgression. Full article
(This article belongs to the Special Issue Climate Change and Marine Geological Dynamics)
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