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29 pages, 8947 KiB  
Article
Cultural Heritage and Lacustrine Landscape Conservation: The Case of “Procession of The Wise Men” in Cajititlán, Jalisco
by David Fabricio Alvarado-Ramírez, Pedro Lina Manjarrez, José Teodoro Silva García, Gustavo Cruz-Cárdenas and Paloma Gallegos Tejeda
Sustainability 2025, 17(13), 6047; https://doi.org/10.3390/su17136047 - 2 Jul 2025
Viewed by 492
Abstract
Although lagoons are sites of water accumulation and runoff where a variety of animal species and plant varieties inhabit, they have also been positioned as spaces where rituals and religious practices take place, from which the transmission of knowledge emanates, and social activities [...] Read more.
Although lagoons are sites of water accumulation and runoff where a variety of animal species and plant varieties inhabit, they have also been positioned as spaces where rituals and religious practices take place, from which the transmission of knowledge emanates, and social activities are strengthened. The Laguna de Cajititlán (Cajititlán Lagoon) in the town of Tlajomulco de Zúñiga, Jalisco, México is a lacustrine landscape that faces a state of fragility due to incessant processes of urbanization along with basin desiccation and wastewater pollution. However, the community of Cajititlán has managed to protect its lacustrine landscape through the rescue of the religious tradition of the Procesión Los Santos Reyes (Procession of the Wise Men). Therefore, the objective of this article is to analyze how this tradition, as cultural heritage, has influenced the conservation of the lacustrine landscape. We conclude that cultural heritage and the lacustrine landscape are bidirectionally correlated because fostering Indigenous traditions like the Procesión in Cajititlán, as a manifestation of devotion and faith, enhances identity, promotes tourism, and supports conservation practices and the sustainability of the lacustrine landscape. At the same time, conservation of the lacustrine landscape enables the preservation of cultural heritage, generating an interdependent relationship between these elements. Full article
(This article belongs to the Special Issue Cultural Heritage Conservation and Sustainable Development)
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25 pages, 9019 KiB  
Article
Petrography and Fluid Inclusions for Petroleum System Analysis of Pre-Salt Reservoirs in the Santos Basin, Eastern Brazilian Margin
by Jaques Schmidt, Elias Cembrani, Thisiane Dos Santos, Mariane Trombetta, Rafaela Lenz, Argos Schrank, Sabrina Altenhofen, Amanda Rodrigues, Luiz De Ros, Felipe Dalla Vecchia and Rosalia Barili
Geosciences 2025, 15(5), 158; https://doi.org/10.3390/geosciences15050158 - 23 Apr 2025
Viewed by 998
Abstract
The complex interaction of hydrothermal fluids and carbonate rocks is recognized to promote significant impacts on petroleum systems, reservoir porosity, and potential. The objective of this study is to investigate the fluid phases entrapped in the mineral phases of the Barra Velha Formation [...] Read more.
The complex interaction of hydrothermal fluids and carbonate rocks is recognized to promote significant impacts on petroleum systems, reservoir porosity, and potential. The objective of this study is to investigate the fluid phases entrapped in the mineral phases of the Barra Velha Formation (Santos Basin), including their petrographic paragenetic relationships, relative timing, temperatures of migration events, and maximum temperature reached by the sedimentary section. The petrographic descriptions (387), Rock-Eval pyrolysis (107), fluid inclusion petrography (14), and microthermometry (428) were performed on core and sidewall samples from two wells from one field of the Santos Basin. Hydrocarbon source intervals were primarily identified in lithologies with high argillaceous content. Chert samples still retain some organic remnants indicative of their original composition prior to extensive silicification. Redeposited intraclastic rocks exhibit the lowest organic content and oil potential. A hydrothermal petroleum system is identified by fluids consisting in gas condensate, light to heavy undersaturated oil, occasionally accompanied by aqueous fluids influenced by juvenile and evaporitic sources, and localized flash vaporization events. These hydrothermal fluids promoted silicification and dolomitization, intense brecciation, and lead to enhanced porosity in different compartments of the reservoir. The relative ordering of paleo-hydrothermal oils and the main oil migration and accumulation events has improved our understanding of the petroleum systems in the basin. This contribution is significant for future regional research on the evolution of fluid systems and their implications for carbonate reservoirs. Full article
(This article belongs to the Special Issue Petroleum Geochemistry of South Atlantic Sedimentary Basins)
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23 pages, 14258 KiB  
Article
Geochemical Variations of Kerolite, Stevensite, and Saponite from the Pre-Salt Sag Interval of the Santos Basin: An Approach Using Electron Probe Microanalysis
by Maurício Dias da Silva, Márcia Elisa Boscato Gomes, André Sampaio Mexias, Manuel Pozo, Susan Martins Drago, Everton Marques Bongiolo, Paulo Netto, Victor Soares Cardoso, Lucas Bonan Gomes and Camila Wense Ramnani
Minerals 2025, 15(3), 285; https://doi.org/10.3390/min15030285 - 11 Mar 2025
Viewed by 1020
Abstract
This study investigates the mineralogy and chemical characteristics of pre-salt clay minerals, classifies them, and defines assemblages in reactive microsites. Using Electron Probe Micro-Analysis (EPMA), the chemical formulas of Mg-rich clays were determined. Stevensite exhibited low interlayer charge and aluminum content, while kerolite [...] Read more.
This study investigates the mineralogy and chemical characteristics of pre-salt clay minerals, classifies them, and defines assemblages in reactive microsites. Using Electron Probe Micro-Analysis (EPMA), the chemical formulas of Mg-rich clays were determined. Stevensite exhibited low interlayer charge and aluminum content, while kerolite was characterized by a minimal charge. K/S (kerolite/stevensite) mixed layer showed intermediate compositions and charges between these endmembers. Saponite was distinguished by higher levels of Al, K, and Fe, along with a higher interlayer charge. The proposed assemblages are as follows: saponite in mudstone facies (without spherulites/shrubs), with a hybrid matrix; pure kerolite in spherulstone and shrubstone facies, marked by the absence of significant reactions and high preservation of matrix and textures; stevensite in facies with extensive matrix replacement by dolomitization/silicification; and K/S and kerolite in similar facies with intermediate matrix replacement levels and the coexistence of two intimately related clay mineral compositions. This study enables reliable differentiation of these species based on point mineral chemistry and mapping, combined with a microsite approach and conventional techniques. Additionally, it discusses the formation of pre-salt clays, influenced by significant kinetic and chemical interactions during their genesis and burial to depths of approximately 5 km. Full article
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12 pages, 2745 KiB  
Article
Single-Shot Time-Lapse Target-Oriented Velocity Inversion Using Machine Learning
by Katerine Rincon, Ramon C. F. Araújo, Moisés M. Galvão, Samuel Xavier-de-Souza, João M. de Araújo, Tiago Barros and Gilberto Corso
Appl. Sci. 2024, 14(21), 10047; https://doi.org/10.3390/app142110047 - 4 Nov 2024
Cited by 1 | Viewed by 992
Abstract
In this study, we used machine learning (ML) to estimate time-lapse velocity variations in a reservoir region using seismic data. To accomplish this task, we needed an adequate training set that could map seismic data to velocity perturbation. We generated a synthetic seismic [...] Read more.
In this study, we used machine learning (ML) to estimate time-lapse velocity variations in a reservoir region using seismic data. To accomplish this task, we needed an adequate training set that could map seismic data to velocity perturbation. We generated a synthetic seismic database by simulating reservoirs of varying velocities using a 2D velocity model typical of the Brazilian pre-salt ocean bottom node (OBN) acquisition, located in the Santos basin, Brazil. The largest velocity change in the injector well was around 3% of the empirical velocity model, which mimicked a realistic scenario. The acquisition geometry was formed by the geometry of 1 shot and 49 receivers. For each synthetic reservoir, the corresponding seismic data were obtained by estimating a one-shot forward-wave propagation using acoustic approximation. We studied the reservoir illumination to optimize the input data of the ML inversion. We split the set of synthetic reservoirs into two subsets: training (80%) and testing (20%) sets. We point out that the ML inversion was restricted to the reservoir zone, which means that it was inversion-oriented to a target. We obtained a good similarity between true and ML-inverted reservoir anomalies. The similarity diminished for a situation with non-repeatability noise. Full article
(This article belongs to the Section Earth Sciences)
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15 pages, 5798 KiB  
Article
Recognition of Artificial Gases Formed during Drill-Bit Metamorphism Using Advanced Mud Gas
by Janaina Andrade de Lima Leon, Henrique Luiz de Barros Penteado, Geoffrey S. Ellis, Alexei Milkov and João Graciano Mendonça Filho
Energies 2024, 17(17), 4383; https://doi.org/10.3390/en17174383 - 2 Sep 2024
Viewed by 1749
Abstract
Drill-bit metamorphism (DBM) is the process of thermal degradation of drilling fluid at the interface of the bit and rock due to the overheating of the bit. The heat generated by the drill when drilling into a rock formation promotes the generation of [...] Read more.
Drill-bit metamorphism (DBM) is the process of thermal degradation of drilling fluid at the interface of the bit and rock due to the overheating of the bit. The heat generated by the drill when drilling into a rock formation promotes the generation of artificial hydrocarbon and non-hydrocarbon gas, changing the composition of the gas. The objective of this work is to recognize and evaluate artificial gases originating from DBM in wells targeting oil accumulations in pre-salt carbonates in the Santos Basin, Brazil. For the evaluation, chromatographic data from advanced mud gas equipment, drilling parameters, drill type, and lithology were used. The molar concentrations of gases and gas ratios (especially ethene/ethene+ethane and dryness) were analyzed, which identified the occurrence of DBM. DBM is most severe when wells penetrate igneous and carbonate rocks with diamond-impregnated drill bits. The rate of penetration, weight on bit, and rotation per minute were evaluated together with gas data but did not present good correlations to assist in identifying DBM. The depth intervals over which artificial gases formed during DBM are recognized should not be used to infer pay zones or predict the composition and properties of reservoir fluids because the gas composition is completely changed. Full article
(This article belongs to the Topic Advances in Oil and Gas Wellbore Integrity)
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35 pages, 10870 KiB  
Article
Geological Insights from Porosity Analysis for Sustainable Development of Santos Basin’s Presalt Carbonate Reservoir
by Richard Guillermo Vásconez Garcia, SeyedMehdi Mohammadizadeh, Michelle Chaves Kuroda Avansi, Giorgio Basilici, Leticia da Silva Bomfim, Oton Rubio Cunha, Marcus Vinícius Theodoro Soares, Áquila Ferreira Mesquita, Seyed Kourosh Mahjour and Alexandre Campane Vidal
Sustainability 2024, 16(13), 5730; https://doi.org/10.3390/su16135730 - 4 Jul 2024
Cited by 14 | Viewed by 2743
Abstract
Carbonate reservoirs, influenced by depositional and diagenetic processes and characterized by features like faults and vugs that impact storage capacity, require more than traditional Borehole Imaging logs (BHIs) for accurate porosity data. These data are essential for geological [...] Read more.
Carbonate reservoirs, influenced by depositional and diagenetic processes and characterized by features like faults and vugs that impact storage capacity, require more than traditional Borehole Imaging logs (BHIs) for accurate porosity data. These data are essential for geological assessments, production forecasting, and reservoir simulations. This work aims to address this limitation by developing methods to measure and monitor the sustainability of carbonate reservoirs and exploring the application of sustainability principles to their management. The study integrates BHIs and conventional logs from two wells to classify porosity-based facies within the Barra Velha Formation (BVF) in the Santos Basin. The methodology involves four steps: (i) analyzing conventional logs; (ii) segmenting BHI logs; (iii) integrating conventional and segmented BHI logs using Self-Organizing Maps (SOM); and (iv) interpreting the resulting classes. Matrix porosity values and non-matrix pore sizes categorize the porosity into four facies: (A to D). The results of this research indicate the following: Facies A has high non-matrix porosity with 14,560 small megapores, 5419 large megapores, and 271 gigapores (71.9%, 26.76%, and 1.34% of the 20,250 pores, respectively). Facies B shows moderate non-matrix porosity with 8,669 small megapores, 2642 large megapores, and 33 gigapores (76.42%, 23.29%, and 0.29% of the 11,344 pores, respectively) and medium matrix porosity. Facies C exhibits low non-matrix porosity with 7749 small megapores, 2132 large megapores, and 20 gigapores (78.27%, 21.53%, and 0.20% of the 9901 pores, respectively) and medium matrix porosity. Facies D has low non-matrix porosity with 9355 small megapores, 2346 large megapores, and 19 gigapores (79.82%, 20.02%, and 0.16% of the 11,720 pores, respectively) and low matrix porosity. The results of this research reveal the effectiveness of a semiautomatic methodology that combines BHI and conventional well logs to distinguish between matrix and non-matrix-related pore spaces, thus enabling a preliminary classification of reservoir facies based on porosity. This study advances our understanding of carbonate reservoir sustainability and heterogeneity, thus offering valuable insights for robust, sustainable reservoir characterization and management in the context of global environmental and geological changes. The novelty of this work lies in integrating data from two sources to classify porosity across the presalt reservoir interval, thus serving as a proxy for preliminary lithofacies identification without core data. Full article
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35 pages, 37975 KiB  
Article
Interactions between Clays and Carbonates in the Aptian Pre-Salt Reservoirs of Santos Basin, Eastern Brazilian Margin
by Argos Belmonte Silveira Schrank, Thisiane Dos Santos, Sabrina Danni Altenhofen, William Freitas, Elias Cembrani, Thiago Haubert, Felipe Dalla Vecchia, Rosalia Barili, Amanda Goulart Rodrigues, Anderson Maraschin and Luiz Fernando De Ros
Minerals 2024, 14(2), 191; https://doi.org/10.3390/min14020191 - 11 Feb 2024
Cited by 7 | Viewed by 3325
Abstract
The giant Pre-salt reservoirs represent most of the oil production in Brazil. The main Aptian sag reservoirs were deposited in a unique and highly complex hyper-alkaline lacustrine setting. These deposits are essentially constituted by fascicular and spherulitic calcite precipitated in a magnesian clay [...] Read more.
The giant Pre-salt reservoirs represent most of the oil production in Brazil. The main Aptian sag reservoirs were deposited in a unique and highly complex hyper-alkaline lacustrine setting. These deposits are essentially constituted by fascicular and spherulitic calcite precipitated in a magnesian clay matrix (stevensite, kerolite, and saponite/hectorite). Although vital for understanding the origin and main reservoir quality control, the genesis and interactions of clays and carbonates are still poorly constrained. The detailed petrographic description was focused on 812 thin sections from five wells drilled in the Santos Basin Aptian Barra Velha Formation, combined with cathodoluminescence, UV epifluorescence, and X-ray diffraction analyses. The main syngenetic processes were the deposition of finely laminated peloidal and ooidal Mg-clays, the formation of fascicular calcite crusts on the sediment–water interface, and the redeposition of these materials as intraclasts. Abundant clay peloids engulfed in syngenetic shrubs indicate that calcite and clay precipitation was concomitant, though with highly variable rates. Eodiagenetic phases include matrix-replacive and -displacive spherulites and fascicular shrubs; matrix-replacive blocky calcite and dolomite; lamellar carbonates filling matrix shrinkage pores; and microcrystalline calcite, dolomite, and silica replacing the Mg-clay matrix. The preferential dolomitization and calcitization of peloidal layers were most likely due to their higher permeability and larger specific surface. Matrix-replacive saddle dolomite, macrocrystalline calcite, and dawsonite are interpreted as mesodiagenetic or hydrothermal phases after significant matrix dissolution. Unraveling the processes of the formation and alteration of the carbonates and clays and their interactions in the Pre-salt deposits is essential for constraining the depositional and diagenetic conditions in their unique environments and their diagenetic overprinting and for decreasing the exploration risks and increasing the production of those extraordinary reservoirs. Full article
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28 pages, 13868 KiB  
Article
Delimitation of Ecological Corridor Using Technological Tools
by Vinícius Duarte Nader Mardeni, Henrique Machado Dias, Alexandre Rosa dos Santos, Daniel Medina Corrêa Santos, Tais Rizzo Moreira, Rita de Cássia Freire Carvalho, Elaine Cordeiro dos Santos, Clebson Pautz and Cecilia Uliana Zandonadi
Sustainability 2023, 15(18), 13696; https://doi.org/10.3390/su151813696 - 13 Sep 2023
Cited by 3 | Viewed by 2207
Abstract
Ecological corridors are effective strategies to address the environmental consequences of forest fragmentation by connecting fragmented areas through various techniques. This study aims to propose the implementation of an ecological corridor in the Itapemirim River basin in Espírito Santo, Brazil. The specific objectives [...] Read more.
Ecological corridors are effective strategies to address the environmental consequences of forest fragmentation by connecting fragmented areas through various techniques. This study aims to propose the implementation of an ecological corridor in the Itapemirim River basin in Espírito Santo, Brazil. The specific objectives of this study are as follows: delimiting the Permanent Preservation Areas (APPs) in the Itapemirim River watershed and comparing land use and land cover within these areas. The MapBiomas platform and Landsat 8 satellite images were utilized to map land use and land cover, while the criteria set by Law No. 12.651 were followed to define the APP boundaries. The calculation of the landscape ecology indices and the identification of the forest fragments with the highest potential for ecological corridor implementation were conducted using the Fuzzy logic. The QGIS 3.26 application, along with the LecoS 3.0.1 plugin and Fragstats 4.2, were employed to characterize and quantify landscape ecology indices. The costs assessment and determination of the optimal route for implementing the ecological corridor were performed, considering bothdistance and physical impediments. The least cost path algorithm was utilized, taking into account land use and land cover, APP, fragment potential, slope, and subnormal clusters. Evaluating land costs and expropriation expenses required to define the ecological corridor in the study area. The identified forest fragments for inclusion in the ecological corridor were the Caparaó National Park, the Serra das Torres State Natural Monument, and other selected fragments based on the application of Fuzzy logic to landscape ecology indices. The corridor route was determined using the least cost path algorithm, considering various factors. This study revealed that the predominant land use and land cover class in the area is pasture, and a significant portion (68.58%) of the designated Permanent Preservation Areas were in conflict with legal regulations. The bare land value per hectare for pasture was the second highest among the land use and land cover categories, accounting for 64.28% of the total. The priority area analysis indicated that 31.86% of the region had high or very high importance for forest restoration, while 42.97% had low or very low priority. The findings demonstrate that the least cost path algorithm, coupled with a multi-criteria decision-making approach using the Analytic Hierarchy Process (AHP), is a valuable tool for planning and implementing ecological networks. These methods effectively consider critical factors in decision-making processes related to the optimal location of the ecological corridor. In conclusion, this study provides insights into the implementation of an ecological corridor in the Itapemirim River basin, emphasizing the importance of considering multiple factors and utilizing appropriate methodologies for effective decision-making in ecological planning. Full article
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17 pages, 11968 KiB  
Article
Source Rock Evaluation from Rock to Seismic Data: An Integrated Machine-Learning-Based Work Flow and Application in the Brazilian Presalt (Santos Basin)
by Maria Anna Abreu de Almeida dos Reis, Andrea Carvalho Damasceno, Carlos Eduardo Dias Roriz, André Leonardo Korenchendler, Atilas Meneses da Silva, Eric da Silva Praxedes and Vitor Gorni Silva
Minerals 2023, 13(9), 1179; https://doi.org/10.3390/min13091179 - 8 Sep 2023
Cited by 2 | Viewed by 2518
Abstract
The capacity to predict the occurrence and quality of source rocks in a sedimentary basin is of great economic importance in the evaluation of conventional and non-conventional petroleum resources. Direct laboratory examinations of rock samples are the most accurate way to obtain their [...] Read more.
The capacity to predict the occurrence and quality of source rocks in a sedimentary basin is of great economic importance in the evaluation of conventional and non-conventional petroleum resources. Direct laboratory examinations of rock samples are the most accurate way to obtain their geochemical properties. However, rock information is usually sparse, and source rocks are often sampled at positions that may not be representative of the average organic content and quality of oil kitchens. This work proposes a work flow supported by machine learning methods (random forest, DBSCAN, and NGBoost) to automate the source rock characterization process to maximize the use of available data, expand data information, and reduce data analysis time. From the automated quality control of the input data through the extrapolation of laboratory measurements to continuous well logs of geochemical properties, culminating in the 3D estimation of these properties, we generate volumes of total organic carbon (TOC) by applying machine learning techniques. The proposed method provides more accurate predictions, reducing uncertainties in the characterization of source rocks and assisting in exploratory decision making. This methodology was applied in the presalt source rocks from Santos Basin (Brazil) and allowed us to quantify the TOC distribution, improving the interpretation of the main source rock interval top and base based only on seismic amplitude data. The result suggests higher TOC values in the northern and western grabens of the studied area and a higher charge risk in the eastern area. Full article
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19 pages, 3829 KiB  
Article
Computational Oil-Slick Hub for Offshore Petroleum Studies
by Nelson F. F. Ebecken, Fernando Pellon de Miranda, Luiz Landau, Carlos Beisl, Patrícia M. Silva, Gerson Cunha, Maria Célia Santos Lopes, Lucas Moreira Dias and Gustavo de Araújo Carvalho
J. Mar. Sci. Eng. 2023, 11(8), 1497; https://doi.org/10.3390/jmse11081497 - 27 Jul 2023
Cited by 2 | Viewed by 1618
Abstract
The paper introduces the Oil-Slick Hub (OSH), a computational platform to facilitate the data visualization of a large database of petroleum signatures observed on the surface of the ocean with synthetic aperture radar (SAR) measurements. This Internet platform offers an information search and [...] Read more.
The paper introduces the Oil-Slick Hub (OSH), a computational platform to facilitate the data visualization of a large database of petroleum signatures observed on the surface of the ocean with synthetic aperture radar (SAR) measurements. This Internet platform offers an information search and retrieval system of a database resulting from >20 years of scientific projects that interpreted ~15 thousand offshore mineral oil “slicks”: natural oil “seeps” versus operational oil “spills”. Such a Digital Mega-Collection Database consists of satellite images and oil-slick polygons identified in the Gulf of Mexico (GMex) and the Brazilian Continental Margin (BCM). A series of attributes describing the interpreted slicks are also included, along with technical reports and scientific papers. Two experiments illustrate the use of the OSH to facilitate the selection of data subsets from the mega collection (GMex variables and BCM samples), in which artificial intelligence techniques—machine learning (ML)—classify slicks into seeps or spills. The GMex variable dataset was analyzed with simple linear discriminant analyses (LDAs), and a three-fold accuracy performance pattern was observed: (i) the least accurate subset (~65%) solely used acquisition aspects (e.g., acquisition beam mode, date, and time, satellite name, etc.); (ii) the best results (>90%) were achieved with the inclusion of location attributes (i.e., latitude, longitude, and bathymetry); and (iii) moderate performances (~70%) were reached using only morphological information (e.g., area, perimeter, perimeter to area ratio, etc.). The BCM sample dataset was analyzed with six traditional ML methods, namely naive Bayes (NB), K-nearest neighbors (KNN), decision trees (DT), random forests (RF), support vector machines (SVM), and artificial neural networks (ANN), and the most effective algorithms per sample subsets were: (i) RF (86.8%) for Campos, Santos, and Ceará Basins; (ii) NB (87.2%) for Campos with Santos Basins; (iii) SVM (86.9%) for Campos with Ceará Basins; and (iv) SVM (87.8%) for only Campos Basin. The OSH can assist in different concerns (general public, social, economic, political, ecological, and scientific) related to petroleum exploration and production activities, serving as an important aid in discovering new offshore exploratory frontiers, avoiding legal penalties on oil-seep events, supporting oceanic monitoring systems, and providing valuable information to environmental studies. Full article
(This article belongs to the Special Issue Marine Oil Spills 2023)
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18 pages, 7526 KiB  
Article
Can the Brazilian National Logistics Plan Induce Port Competitiveness by Reshaping the Port Service Areas?
by William Costa, Britaldo Soares-Filho and Rodrigo Nobrega
Sustainability 2022, 14(21), 14567; https://doi.org/10.3390/su142114567 - 5 Nov 2022
Cited by 4 | Viewed by 4979
Abstract
Brazil’s transportation infrastructure did not follow the country’s agricultural development and the macro-logistics operations still rely on trucking. Even with a lack of roads, the service areas of the ports on the Atlantic coast, particularly the port of Santos, expanded to central Brazil, [...] Read more.
Brazil’s transportation infrastructure did not follow the country’s agricultural development and the macro-logistics operations still rely on trucking. Even with a lack of roads, the service areas of the ports on the Atlantic coast, particularly the port of Santos, expanded to central Brazil, the country’s most productive agricultural area. Recently, the Federal Government released mid-term plans to build railways to reduce transportation costs until 2035. However, no simulation about port regionalization and competitiveness was performed. This research evaluated the effectiveness of the proposed transportation infrastructure regarding transportation cost and new routes that can reshape the ports’ influence areas. Our geographically explicit model used the Dinamica_EGO modeling platform and PostgreSQL, fed by official public data from transportation and agriculture authorities. Considering the hypothesis that new railways can increase port competitiveness, we computed scenarios considering the planned 2035 infrastructure and compared them to the current situation. The findings showed that the Ferrogrão railway can effectively reduce transport costs, therefore changing the spatial configuration of macro-logistics basins. In conclusion, a geospatial model can predict short-cheaper routes, port regionalization, and competitiveness regarding the geographic aspects of the supply chain. The long-distance and importance of Brazilian agriculture exportation justify and value the investigation. Full article
(This article belongs to the Collection Sustainable Maritime Policy and Management)
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14 pages, 2659 KiB  
Article
Hg Pollution Indices along the Reis Magos River Basin—Brazil: A Precursory Study
by Eldis Maria Sartori, Bruna Miurim Dalfior, Carolina Scocco Provete, Suellen Geronimo Cordeiro, Maria Tereza Weitzel Dias Carneiro, Maria de Fátima Fontes Lelis, Gilberto Fonseca Barroso and Geisamanda Pedrini Brandão
Int. J. Environ. Res. Public Health 2022, 19(19), 12626; https://doi.org/10.3390/ijerph191912626 - 3 Oct 2022
Cited by 3 | Viewed by 1855
Abstract
Mercury is a metal present in the Earth’s crust, but due to human contribution, its concentration can increase, causing environmental impacts to aquatic ecosystems, among others. The Reis Magos River Hydrographic Basin represents economic and socio-environmental importance for the state of Espírito Santo, [...] Read more.
Mercury is a metal present in the Earth’s crust, but due to human contribution, its concentration can increase, causing environmental impacts to aquatic ecosystems, among others. The Reis Magos River Hydrographic Basin represents economic and socio-environmental importance for the state of Espírito Santo, Brazil. However, there are not many publications regarding the quality of water and sediments, so no data is reported concerning the total concentration of Hg. Thus, the present work aimed to evaluate the distribution of total Hg in water and sediments along this hydrographic basin. For a better inference, physicochemical parameters of the water were determined (temperature, pH, electrical conductivity, oxidation-reduction potential (ORP), turbidity, dissolved oxygen (DO), total dissolved solids (TDS), and salinity), and in the sediments, the contents of matter organic matter, pH, carbonates and granulometry. Mercury determination was performed by Thermodecomposition and Amalgamation Atomic Absorption Spectrometry (TDA AAS) with a DMA-80 spectrometer. The Hg determined in the water was lower than the limit of quantification, 0.14 µg∙L−1, which is lower than the maximum limits recommended by world reference environmental agencies. In the sediment samples, the Hg found were below 170 µg∙kg−1, values below which there is less possibility of an adverse effect on the biota. However, when the degree of anthropic contribution was evaluated using the Geoaccumulation index (IGeo), the contamination factor (CF), and the ecological risk potential index (EF), there was evidence of moderate pollution. Thus, this highlighted the need for monitoring the region since climatic variations and physical-chemical parameters influence the redistribution of Hg between the water/sediment interface. Full article
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12 pages, 3148 KiB  
Article
Preservation Factors during Cretaceous Oceanic Anoxic Events in the Espírito Santo Basin, Southeast Brazil
by Igor M. Venancio, Thiago P. Santos, Fellippe R. A. Bione, Andre L. Belem, Marcelo C. Bernardes, Rut A. Díaz, Manuel Moreira, Victor Carreira, André Spigolon, Igor V. Souza and Ana Luiza S. Albuquerque
Geosciences 2022, 12(10), 351; https://doi.org/10.3390/geosciences12100351 - 20 Sep 2022
Cited by 2 | Viewed by 2743
Abstract
The oceanic anoxic events (OAEs) are characterized by enhanced accumulation of organic matter in marine sediments. However, there is still an ongoing debate regarding the interplay between production and preservation during these events. Moreover, few studies provide quantitative estimations of primary productivity and/or [...] Read more.
The oceanic anoxic events (OAEs) are characterized by enhanced accumulation of organic matter in marine sediments. However, there is still an ongoing debate regarding the interplay between production and preservation during these events. Moreover, few studies provide quantitative estimations of primary productivity and/or the amount of carbon preserved during the OAEs. Here, we used geochemical data from multiple wells located at the Espírito Santo Basin that cover the intervals of events OAE1d and OAE2 to provide quantitative estimates of preservation factors. Our results show enhanced preservation during OAEs compared to modern conditions and a stronger preservation during OAE1d compared to OAE2 in the Espírito Santo Basin. The amount of preserved carbon could reach up to 8.6% during OAE1d, depending on the productivity of the system. In addition, we show that such improvement in preservation is linked to the bottom water with low-O2 concentrations and not due to fast burial caused by high sedimentation rates. Our findings are extremally relevant for organic carbon and source rock modelling studies since model simulations need quantitative estimations. Full article
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18 pages, 2139 KiB  
Article
Environmental Impact Assessment and Life Cycle Assessment for a Deep Water Floating Offshore Wind Turbine on the Brazilian Continental Shelf
by Laura Ferraz de Paula and Bruno Souza Carmo
Wind 2022, 2(3), 495-512; https://doi.org/10.3390/wind2030027 - 22 Jul 2022
Cited by 10 | Viewed by 5556
Abstract
Brazil is currently witnessing the dawn of its offshore wind industry, and companies, government, investors, and society must understand the risks and possible environmental impacts this technology can generate. This paper aims to partially fill this need by presenting an analysis of the [...] Read more.
Brazil is currently witnessing the dawn of its offshore wind industry, and companies, government, investors, and society must understand the risks and possible environmental impacts this technology can generate. This paper aims to partially fill this need by presenting an analysis of the environmental impacts that would be caused by a 5 MW floating offshore wind turbine to be installed on the Brazilian continental shelf through an Environmental Impact Assessment (EIA) and a Life Cycle Assessment (LCA). We assumed that the wind turbine would supply electrical power to a floating oil and gas extraction platform, with the intention of reducing the amount of energy produced with fossil fuels in these platforms, in order to decrease the carbon footprint of this economic activity. The turbine would be mounted on a semi-submersible platform with a high mass of steel, and a battery system for energy storage. We considered two different sites for the turbine installation, Campos Basin and Santos Basin, which are the most important areas of oil and gas extraction in Brazil. The EIA examines the effects caused by the turbine in the ecosystems around it, showing that the fauna suffers from various impacts such as sedimentation, electromagnetic fields, and others, but few species are seriously affected, except for birds, which can have a risk of mortality. The LCA makes an assessment on the carbon dioxide (CO2) emissions and energy consumption for each part of the life cycle of the project, finding a total 21.61 g of CO2 emitted per kWh of energy produced by the turbine. The total energy consumed was 89,131.31 GJ, which causes an Energy Payback Ratio (EPR) of 16.28 and Energy Payback Time (EPT) of 1.23 years. Several sensitivity analyses were performed to understand the effect of the variation of several parameters related to recycling, maintenance and failures, and the capacity factor, on the values of CO2 emission and energy consumption. These analyses showed that variations in the amount of steel recycled and in the capacity factor of the system cause the most significant changes in EPR and EPT. Full article
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20 pages, 5806 KiB  
Article
Paleoenvironmental Implications of Authigenic Magnesian Clay Formation Sequences in the Barra Velha Formation (Santos Basin, Brazil)
by Paulo R. A. Netto, Manuel Pozo, Maurício Dias da Silva, Márcia Elisa Boscato Gomes, André Mexias, Camila Wense Ramnani, Yaro Parizek-Silva, Leonardo Borghi and Aristóteles de Moraes Rios-Netto
Minerals 2022, 12(2), 200; https://doi.org/10.3390/min12020200 - 4 Feb 2022
Cited by 13 | Viewed by 3124
Abstract
The characterization of Mg-clays in rock samples (well P1) from the Barra Velha Formation (Early Cretaceous) allowed the establishment of mineral assemblages on the basis of their kerolite and Mg-smectite (stevensite and saponite) content. Kerolite-rich assemblages (A and B) rarely contain saponite. Assemblage [...] Read more.
The characterization of Mg-clays in rock samples (well P1) from the Barra Velha Formation (Early Cretaceous) allowed the establishment of mineral assemblages on the basis of their kerolite and Mg-smectite (stevensite and saponite) content. Kerolite-rich assemblages (A and B) rarely contain saponite. Assemblage B is composed of kerolite-stevensite mixed layers, while assemblage A consists of more than 95% kerolite. Mg-smectite-rich assemblages (C and CB) are made up of both Mg-smectites. The predominance of stevensite in the lower interval of the stratigraphic succession suggests evaporative conditions, higher salinity and pH, which would favor its authigenesis by neoformation. In the upper portion, the occurrence of thick kerolite-rich intervals suggests regular water inputs, contributing with a decreasing in salinity and pH, favoring the neoformation of kerolite and later kerolite-stevensite mixed layering. The saponite would be the result of the transformation from Al-smectite into Mg-smectite in a Mg2+ rich medium. The results indicate that lake hydrochemical processes would have allowed the establishment of a basic depositional sequence, from base to top, as follows: (i) initial lake expansion stage marked by the occurrence of saponite, (ii) later kerolite neoformation, (iii) formation of kerolite-stevensite mixed layer with increasing salinity, and (iv) neoformation of stevensite, marking a final stage of maximum salinity (evaporation) and alkalinity of the lake. Full article
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