Search Results (8)

Membrane capacitive deionization (MCDI) is an electrochemical ion separation process that combines ion-exchange membranes (IEMs) with porous carbon electrodes to enhance desalination efficiency and address the limitations of conventional capacitive deionization (CDI). In this study, a cation-exchange membrane (CEM) embedded with a metal–organic framework (MOF) was developed to effectively separate monovalent and multivalent cations in influent solutions via MCDI. To fabricate CEMs with high monovalent ion selectivity, ZIF-8 was incorporated into sulfonated poly(2,6-dimethyl-1,4-phenylene oxide) (SPPO) at various weight ratios. The resulting membranes were systematically characterized using diverse electrochemical methods. The ZIF-8-embedded CEMs demonstrated a sieving effect based on differences in ion size and hydration energy, achieving excellent permselectivity for monovalent ions. MCDI tests using the prepared CEMs showed a Na⁺ ion removal rate exceeding 99% in Na⁺/Mg²⁺ and Na⁺/Ca²⁺ mixed feed solutions, outperforming a commercial membrane (CSE, Astom Corp., Tokyo, Japan), which achieved a removal rate of 94.1%. These findings are expected to provide valuable insights for advancing not only MCDI but also other electro-membrane processes capable of selectively separating specific ions. Full article

Polyphenol oxidase (PPO) easily causes fruits and vegetables to lose their color and nutritional value. As a non-thermal process, high-pressure processing (HPP) showed different inactivation effects on endogenous enzymes. In this work, soluble PPO (sPPO) and membrane-bound PPO (mPPO) from ‘Lijiang snow’ peaches were purified, and then the effect of high pressure on the conformation of sPPO and mPPO was investigated and compared at the molecular level. The maximum activation of sPPO and mPPO by 11.2% and 4.8% was observed after HPP at 200 MPa, while their activities both gradually decreased at 400 MPa and 600 MPa; in particular, the residual activities of sPPO and mPPO at 600 MPa for 50 min were 41.42% and 72.95%, respectively. The spectroscopic results indicated that the secondary structure of PPOs was little affected by HPP, but HPP led to obvious changes in their tertiary structure. The simulations showed that the decreasing distance between the copper ion and His residue in the copper-binding region of two PPOs at 200 MPa was favorable to catalytic activity, while the increasing distance between copper ions and His residues and the disordered movement of the loop region above 400 MPa were unfavorable. In addition, the structure of sPPO was relatively looser than that of mPPO, and high pressure showed a more significant effect on the conformation of sPPO than that of mPPO. This study clarified the effect of HPP on PPO’s structure and the relationship between its structure and activity and provided a basis for the prevention of enzymatic browning. Full article

There has been considerable interest in controlling polyphenol oxidase (PPO) activity to prevent enzymatic browning in foods. However, studies on inhibitions of different forms of PPO are very limited. Thus, this study focuses on the effects of cinnamic acid, β-cyclodextrin, L-cysteine, and ascorbic acid on soluble PPO (sPPO) and membrane-bound PPO (mPPO) in peach fruit. The activity of partially purified sPPO was 3.17 times higher than that of mPPO. However, mPPO was shown to be more stable than sPPO in the presence of inhibitors with different concentrations (i.e., 1, 3, 5 mM); activation of mPPO was found by 5 mM L-cysteine. Both sPPO and mPPO inhibitions were PPO substrate-dependent. Ascorbic acid showed the highest inhibitory effect on both sPPO and mPPO with all studied inhibitors and substrates. The inhibition of 1 mM ascorbic acid on sPPO and mPPO reached 95.42 ± 0.07% and 65.60 ± 1.16%, respectively. β-Cyclodextrin had a direct inhibitory effect only on sPPO, while the other three inhibitors had direct effects on both sPPO and mPPO. Cinnamic acid exhibited a non-competitive inhibition on sPPO and mPPO, with L-cysteine showing the same, though on sPPO. The inhibition of studied inhibitors on sPPO and mPPO is highly related to the substrate environment, type, and concentration of inhibitors. This study provides a basis for the further prevention of peach fruit browning from the perspective of different enzyme forms. Full article

Sweet potato (Ipomoea batatas L.) is a promising food and industrial crop that plays an important role in China’s agricultural poverty relief strategy. Selecting an appropriate cropping system for sweet-potato production could simultaneously achieve energy, economic, and environmental benefits. Therefore, the comprehensive assessment of diversified sweet-potato-based cropping systems (i.e., sweet potato monoculture (SP), continuous sweet potato cropping (SPSP), sweet potato–rice (SPRI), sweet potato–maize (SPMA), and sweet potato–potato (SPPO)) in South China was conducted with a field survey and life-cycle assessment. The data were collected quantitatively using a questionnaire for face-to-face interviewing of 70 farmers. The results indicated that the annual crop yield (sweet potato equivalent yield) of five cropping systems was in increasing order as SPPO > SPSP > SPMA > SPRI > SP. The SPMA system exhibited the highest net energy (499.09 GJ/ha) and energy rate (7.77). The SPSP system performed better in energy efficiency (0.90 kg/MJ), net return (140,284 CNY/ha), benefit to cost rate (3.20), and eco-efficiency (45 CNY/kg CO₂-eq). The annual greenhouse-gas (GHG) emissions of five cropping systems ranked from lowest to highest as follows: SP < SPRI < SPSP < SPMA < SPPO. With comprehensive consideration, extended rotation systems (e.g., SPMA, SPRI, and SPSP) are proposed because they could effectively reduce GHG emissions while maintaining or even increasing the system’s productivity (ensuring food safety) in South China. Full article

Ion exchange membranes (IEMs), as a part of the reverse electrodialysis (RED) system, play an important role in salinity gradient power (SGP) generation. Structure optimization of IEMs is critical to increase the power production by RED. In this work, metal organic framework (MOF)-derived nanoporous carbons (hollow zeolitic imidazolate framework (ZIF)-derived nanoporous carbons, HZCs) were incorporated in a sulfonated poly (2, 6-dimethyl-1,4-phenylene oxide) (sPPO) membrane to prepare an organic−inorganic nanocomposite cation exchange membrane (CEM). Physicochemical properties, electrochemical properties, and power generation of the synthesized nanocomposite membranes with different HZCs loading were characterized. The results show that the incorporated HZCs could tailor the microstructure of the membrane matrix, providing a superior performance of the nanocomposite membrane. With a HZCs loading of 1.0 wt.%, the nanocomposite membrane possessed the highest permselectivity of 77.61% and the lowest area resistance of 0.42 Ω·cm², along with a super gross power density of 0.45 W/m², which was 87.5% (about 1.87 times) higher than that of the blank sPPO membrane. Therefore, incorporating of an appropriate amount of HZCs in the ion-exchange membrane can improve the performance of the membrane, providing a promising method to increase the power generation of the RED system. Full article

In fuel cell applications, the proton exchange membrane (PEM) is the major component where the balance among dimensional stability, proton conductivity, and durability is a long-term trail. In this research, a series of blended SPEEK/SPPO membranes were designed by varying the amounts of sulfonated poly(ether ether ketone) (SPEEK) into sulfonated poly(phenylene) oxide (SPPO) for fuel cell application. Fourier transform infrared spectroscopy (FTIR) was used to confirm the successful synthesis of the blended membranes. Morphological features of the fabricated membranes were characterized by using scanning electron microscopy (SEM). Results showed that these membranes exhibited homogeneous structures. The fabricated blended membranes SPEEK/SPPO showed ion exchange capacity (IEC) of 1.23 to 2.0 mmol/g, water uptake (W_R) of 22.92 to 64.57% and membrane swelling (MS) of 7.53 to 25.49%. The proton conductivity of these blended membranes was measured at different temperature. The proton conductivity and chemical stability of the prepared membranes were compared with commercial membrane Nafion 117 (Sigma-Aldrich, St. Louis, Missouri, United States) under same experimental conditions. The proton conductivity of the fabricated membranes increased by enhancing the amount of SPPO into the membrane matrix. Moreover, the proton conductivity of the fabricated membranes was investigated as a function of temperature. Results demonstrated that these membranes are good for applications in proton exchange membrane fuel cell (PEMFC). Full article

Novel inorganic–organic hybrid membranes Fe@MWCNT/PPO or Fe@MWCNT-OH/SPPO (with a new type of CNTs characterized by increased iron content 5.80 wt%) were synthesized for CO₂ separation. The introduction of nanofillers into the polymer matrix has significantly improved the hybrid membrane’s gas transport (D, P, S, and α_CO2/N2), magnetic, thermal, and mechanical parameters. It was found that magnetic casting has improved the alignment and dispersion of Fe@MWCNTs. At the same time, CNTs and polymer chemical modification enhanced interphase compatibility and the membrane’s CO₂ separation efficiency. The thermo-oxidative stability and mechanical and magnetic parameters of composites were improved by increasing new CNTs loading. Cherazi’s model turned out to be suitable for describing the CO₂ transport through analyzed hybrid membranes. Full article

Unfavorable pine wilt disease expansion predictions require a rapid advance in genetic breeding against the causative agent of this disease, Bursaphelenchus xylophilus. The main strategy for breeding more resistant trees to B. xylophilus, is the use of highly virulent isolates in inoculation experiments. Different inoculation assays were conducted on Botrytis cinerea cultures, in addition to P. pinaster and P. radiata branch sections and seedlings. Seven virulent isolates of different geographic origin (The Japanese nematode isolates S10 and Ka4, the Portuguese Pt72CH and Pt72T, the Spanish SpSA1 and SpPO1, and the American USA745.) were used in the experiments. The main aim of this work is to investigate differences among the seven isolates. The experiments determined that the studied isolates are significantly different. On fungal culture, the isolate from the USA showed the highest multiplication rate. Both seedling inoculation and branch sections experiments pointed to the Portuguese isolate Pt52T and the Spanish SpPo1 as the most virulent to P. pinaster. Conversely, higher numbers of the Pt72CH isolate passed through P. pinaster branch sections. The most virulent isolate for P. radiata was the Japanese S10, though it only showed significant differences in mortality when compared to the Spanish SpSA1. These results suggest that B. xylophilus have differential host specificities. The supplementary material depicts the methodology used in the inoculation assays, as well as shows figures of the most relevant results. Full article